CN107086307B - Lead storage battery grid - Google Patents
Lead storage battery grid Download PDFInfo
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- CN107086307B CN107086307B CN201710245767.4A CN201710245767A CN107086307B CN 107086307 B CN107086307 B CN 107086307B CN 201710245767 A CN201710245767 A CN 201710245767A CN 107086307 B CN107086307 B CN 107086307B
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- rib
- storage battery
- ribs
- lead storage
- frame rib
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/73—Grids for lead-acid accumulators, e.g. frame plates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/74—Meshes or woven material; Expanded metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
The utility model discloses a lead storage battery grid, which comprises a frame consisting of an upper frame rib, a lower frame rib and two vertical frame ribs, wherein transverse ribs and longitudinal ribs of a reticular structure are formed in the frame in a crisscross manner, and lugs arranged on the upper frame rib, the longitudinal ribs are inclined and folded towards the direction of the lugs, the extension lines of the longitudinal ribs intersect at a point, the intersection point is positioned right above the lugs, and the ratio of the spacing between the upper frame rib and the lower frame rib to the spacing between the intersection point and the lower frame rib is the golden section ratio. The longitudinal ribs of the lead storage battery grid are inclined and folded towards the direction of the lug, the extension lines of the longitudinal ribs intersect at one point, and the internal resistance is minimum; the ratio of the spacing between the upper frame rib and the lower frame rib to the spacing between the intersection point and the lower frame rib is golden section ratio, so that the depth of discharge in unit time is not easy to be too large, and the service life is effectively ensured.
Description
Technical Field
The utility model relates to the technical field of lead storage battery production, in particular to a lead storage battery grid.
Background
Lead storage batteries have been created for 150 years so far, and the application fields of the storage batteries are very wide. In recent years, electric vehicles rapidly develop in China due to better riding instead of walking performance, lower storage site requirements and excellent price advantages, and the storage battery industry is rapidly developed.
The lead-acid storage battery belongs to a reversible direct-current power supply, can convert chemical energy into electric energy, and can also convert the electric energy into chemical energy. The lead-acid storage battery mainly comprises electrolyte, a tank cover and a polar group, wherein the electrolyte of the lead-acid storage battery is sulfuric acid solution, the polar group mainly comprises a positive plate, a negative plate and a separator, and the separator mainly stores the electrolyte and serves as a gas channel for oxygen recombination to prevent active substances from falling off and prevent short circuit between the positive electrode and the negative electrode.
In the production and processing process of the storage battery, the grid is used as a carrier and a conductor of the lead plaster, the lead plaster can be used as a polar plate only after being filled on the grid and solidified and dried, the polar plate is the core of the lead-acid storage battery, and the grid is like a framework, so that the strength and the service life of the whole polar plate are directly influenced.
At present, grid ribs are generally vertically and vertically intersected, the grid current conduction path is longer, larger internal pressure drop exists, and lead plaster is easy to fall off due to uneven volume change in the use process, so that the capacity and service life are insufficient.
The Chinese patent publication No. CN201435421Y discloses an electrode grid structure of a lead-acid storage battery, which comprises a frame, wherein a convex lug is connected to the outside of the frame, transverse ribs and vertical ribs which are mutually staggered are connected in the frame, the section height of the vertical ribs is the same as that of the frame, the section height of the transverse ribs is 15-30% lower than that of the frame, and the vertical ribs are in radial layout taking the lug as the center.
The Chinese patent of the utility model with the publication number of CN201741750U discloses a grid for a lead-acid storage battery, which comprises a frame, wherein a convex lug is arranged outside the frame, criss-cross transverse ribs and vertical ribs are arranged in the frame, the transverse ribs are uniformly distributed, one ends of the vertical ribs, which are close to the lug, incline to the lug, the thickness of the vertical ribs is equal to that of the frame, supporting feet are arranged at the bottom of the frame, and the vertical ribs are radially distributed with the lug as the center.
The Chinese patent of the utility model with the authorized bulletin number of CN203406378U discloses a lead-acid storage battery grid, which consists of a tab, a frame and ribs arranged in the frame, wherein the tab is arranged at the upper end of the frame, the ribs comprise transverse ribs and vertical ribs, the transverse ribs and the vertical ribs are staggered to form a net structure, the transverse ribs are horizontally arranged in parallel, the vertical ribs are radially distributed on two sides of the middle part of the tab side along the frame, at least eight vertical ribs are provided with rib branches from a third vertical rib close to one end of the tab, the rib branches are connected with the vertical ribs through transition branches, the transition branches are arranged at the middle upper parts of the vertical ribs, and the rib branches and the vertical ribs are alternately arranged.
Disclosure of Invention
Aiming at the problems of longer current conduction path and larger internal pressure drop of the grid in the prior art, the utility model provides the lead storage battery grid, which has short current conduction path and small internal resistance.
The utility model provides a lead accumulator grid, includes the frame that comprises last frame rib, lower frame rib and two vertical frame ribs, and horizontal rib and the vertical rib of crisscross formation network structure in the frame to and set up the utmost point ear on last frame rib, vertical rib draws in to the slope of the position that utmost point ear is located, and their extension line intersects in a point, and this intersection is located the utmost point ear directly over, and the interval of upper and lower frame rib and the ratio of this intersection and the interval of lower frame rib are golden section proportion. I.e., the ratio of the spacing of the upper and lower rim ribs to the spacing of the intersection point and the lower rim rib is about 0.618. The end points of all the longitudinal ribs are straight line segments from the intersection points, the distance between the straight line segments is shortest, the resistance is proportional to the length of the ribs, the distance is shortest, and the internal resistance is smallest. If the longitudinal ribs are prolonged and finally do not intersect at one point, the current conducting paths finally become a dispersed state, the conducting paths are dispersed to lead the conducting current values to be dispersed, and the current in the dispersed state is unfavorable for the instant discharging of the storage battery. When the longitudinal ribs are prolonged and finally intersected at one point, the current value of the point is the sum of the current of the whole polar plate, so that the instant current value is increased, and the high-current discharge performance is improved. When the storage battery is discharged, the discharge performance and the service life of the storage battery are important indexes. If the depth of discharge per unit time is too large, the lifetime is reduced. And when the discharge capacity of the storage battery is 60% -65% of the whole storage battery, the storage battery is charged so as to ensure the service life.
The included angle between two adjacent longitudinal ribs is 3 degrees.
The height of the electrode lug is H, the distance between the outer edge of the electrode lug and the middle point of the upper frame rib is L, and the intersection point of the electrode lug and the upper frame rib is an elliptic focus taking 2L as a long axis and 2H as a short axis.
The width of the lug base is gradually increased. The connection effect of the lug and the upper frame rib is enhanced, and deformation and cracks are not easy to be caused by heat generated during the working of the storage battery.
The longitudinal ribs between the lower frame rib and the adjacent transverse ribs are connected end to end in a zigzag mode. The bottom of the accumulator is easy to be damaged in the process of manufacturing the polar plate and when the accumulator is vibrated, so the design is more beneficial to the effective maintenance of active substances.
The width of the longitudinal ribs gradually increases from the lower frame rib to the upper frame rib. Because the utilization rate of active substances at the upper part of the polar plate is higher, thickening of the longitudinal ribs at the upper part can reduce internal resistance, and is favorable for instant current collection.
The upper frame rib and the vertical frame rib close to the tab are thicker than the lower frame rib and the other vertical frame rib. The utilization rate of active substances of the upper frame rib and the vertical frame rib close to the tab is high, so that thickening can reduce internal resistance and is beneficial to instant current collection.
The widths of the upper frame rib and the vertical frame rib close to the tab are 3mm, and the widths of the lower frame rib and the other vertical frame rib are 2mm.
One end of each transverse rib is a tapered section with gradually changed width. One side close to the conical section is a grid casting port, and the side close to the casting port of the transverse rib is thickened to form the conical section, so that the quantity of lead flowing in per unit time in the casting process is increased, thereby being beneficial to casting and forming and being beneficial to keeping active substances in the vertical direction of the polar plate.
The longitudinal ribs of the lead storage battery grid are inclined and folded towards the direction of the lug, the extension lines of the longitudinal ribs intersect at one point, the straight line segments are arranged from the end points of all the longitudinal ribs to the intersection points, the distance between the straight line segments is shortest, the size of the resistor is in direct proportion to the length of the ribs, the distance is shortest, and the internal resistance is minimum; the ratio of the spacing between the upper frame rib and the lower frame rib to the spacing between the intersection point and the lower frame rib is golden section ratio, so that the depth of discharge in unit time is not easy to be too large, and the service life is effectively ensured.
Drawings
Fig. 1 is a schematic view of the structure of a lead storage battery grid of the present utility model.
FIG. 2 is a schematic view showing the inclination direction and extension line of longitudinal ribs
Fig. 3 is a schematic view of the tab position.
Detailed Description
Example 1
As shown in fig. 1, a lead storage battery grid comprises a frame composed of an upper frame rib 1, a lower frame rib 2 and two vertical frame ribs, transverse ribs 5 and longitudinal ribs 6 which are crisscross to form a net structure in the frame, and a tab 7 arranged on the upper frame rib 1, wherein the two vertical frame ribs are respectively a vertical frame rib 3 far away from the tab 7 and a vertical frame rib 4 close to the tab.
In order to enhance the connection effect of the tab 7 and the upper frame rib 1, deformation and cracks are not easily caused by heat generated during the working of the storage battery, and the width of the base part of the tab 7 is gradually increased. The bottom of the accumulator is easy to be damaged in the process of manufacturing the polar plate and when the accumulator is vibrated, so that the longitudinal ribs 8 between the lower frame rib 2 and the adjacent transverse ribs 5 are in a zigzag shape in order to be more beneficial to the effective retention of active substances. In order to increase the utilization rate of active substances at the upper part of the polar plate, the width of the longitudinal ribs 6 is gradually increased from the lower frame rib 2 to the upper frame rib 1, so that instant current collection is facilitated.
The utilization rate of active substances of the upper frame rib 1 and the vertical frame rib 4 close to the pole lug is high, the upper frame rib 1 and the vertical frame rib 4 close to the pole lug 7 are designed to be thicker than the lower frame rib 2 and the other vertical frame rib 3, internal resistance can be reduced by thickening, and instant current collection is facilitated. In one embodiment, the widths of the upper frame rib 1 and the vertical frame rib 4 adjacent to the tab 7 are 3mm, and the widths of the lower frame rib 2 and the other vertical frame rib 3 are 2mm.
The transverse ribs 5 have one end with a tapered section 9 of gradually changing width. The side close to the conical section 9 is a grid casting port, and the side close to the casting port of the transverse rib 5 is thickened to form the conical section 9, so that the amount of lead liquid flowing in unit time in the casting process is increased, thereby being beneficial to casting and forming and also beneficial to keeping active substances in the vertical direction of the polar plate.
As shown in fig. 2, the longitudinal ribs 6 are inclined toward the direction in which the tab 7 is located, and their extension lines intersect at a point O which is located directly above the tab 7. The angle between two adjacent longitudinal ribs 6 is 3 degrees. The end points of all the longitudinal ribs 6 to the intersection point O are straight line segments, the distance between the straight line segments is shortest, the resistance is proportional to the length of the ribs, the distance is shortest, and the internal resistance is smallest. If the longitudinal ribs 6 are not intersected at one point, the current conducting paths are dispersed, so that the conducting current values are dispersed due to the dispersion of the conducting paths, and the instant discharge of the storage battery is not facilitated by the current in the dispersed state. When the longitudinal ribs 6 are lengthened and finally intersected at a point, the current value of the point is the sum of the current of the whole polar plate, so that the instant current value is increased, and the high-current discharge performance is improved.
The spacing L1 between the upper rim rib 1 and the lower rim rib 2, the spacing L2 between the intersection point O and the lower rim rib 2, and the ratio of L1 to L2 are the golden section ratio, which is about 0.618. When the storage battery is discharged, the discharging performance and the service life of the storage battery are important indexes, if the discharging depth in unit time is too large, the service life can be shortened, and when the discharging capacity of the storage battery is 60% -65% of the whole storage battery, the storage battery is charged to ensure the service life.
As shown in fig. 3, the height of the tab 7 is H, the distance between the outer edge of the tab 7 and the midpoint of the upper rim rib 1 is L, and the intersection point of the tab 7 and the upper rim rib 1 is the focal point of an ellipse with 2L as the major axis and 2H as the minor axis. All the current of the polar plates is finally conducted through the polar lugs, and after the positive polar plates and the negative polar plates are assembled into a polar group, the two current collecting points are just positioned at the focal point of the ellipse. When the storage battery is discharged, current flows from the negative electrode to the positive electrode, and when the storage battery is charged, current flows from the positive electrode to the negative electrode. When the current collection point is positioned at the focal point of the ellipse, the electric field curve at the focal point is the most dense, and the electric field intensity is the strongest at the place where the electric field curve is dense. The electric field lines of one focus of the ellipse are totally reflected to the other focus through the ellipse surface, which means that the current generated by the anode and the cathode is 100% utilized no matter charging or discharging, so the instant current value generated by the grid designed by the ellipse focus is obviously improved.
Example 2
In the grid in the embodiment 1, the longitudinal ribs are inclined and folded towards the direction of the lug, the extension lines of the longitudinal ribs intersect at a point, the intersection point is positioned right above the lug, the ratio of the spacing between the upper frame rib and the lower frame rib to the spacing between the intersection point and the lower frame rib is the golden section ratio, and the included angle between the two adjacent longitudinal ribs is 3 degrees (D); as a comparative grid, the extensions of the longitudinal ribs intersected at a point that was 8mm (D8) upward in the vertical direction from the intersection of the grid of example 1.
After the two grids are assembled into a 6-EVF-200 storage battery, the high-current discharge conditions at different temperatures are detected, the measured data are shown in table 1, and the time of the high-current discharge is longer than that of a storage battery prepared by using the grids in example 1 in comparison group.
TABLE 1
Example 3
In the grid of the embodiment 1, the longitudinal ribs are inclined and folded towards the direction of the lug, and the extension lines of the longitudinal ribs intersect at a point, the intersection point is positioned right above the lug, and the ratio of the spacing between the upper frame rib and the lower frame rib to the spacing between the intersection point and the lower frame rib is the golden section ratio (H); as a comparative grid, the extensions of the longitudinal ribs intersected at a point that was offset by 12mm (H12) to the outside (i.e., the side of the vertical frame rib closer to the tab) and 12mm (H-12) to the inside in the horizontal direction (i.e., the lateral direction) than the corresponding intersection point of the grid in example 1, while the tab position was unchanged.
The three grids were assembled with 6-EVF-200 batteries, respectively, and then measured for life at different temperatures, and the results are shown in table 2, the life of the batteries prepared using the total grid of example 1 was relatively high.
TABLE 2
Example 4
In the grid in the embodiment 1, the height of the tab is H, the distance between the outer edge of the tab and the midpoint of the upper frame rib is L, and the intersection point of the tab and the upper frame rib is an elliptic focal point (T) taking 2L as a long axis and 2H as a short axis; for the comparative grid, the intersection point of the lug and the rib of the upper frame deviates from the elliptical focus 10mm (T10) outwards, or deviates from the elliptical focus 10mm (T-10) inwards.
The above three grids were assembled with 6-EVF-200 batteries, respectively, and then measured for instantaneous current values at different temperatures, and the results are shown in table 3, with the batteries prepared using the grids of example 1, whose instantaneous current increased.
TABLE 3 Table 3
Example 5
The grid of embodiment 1 wherein the longitudinal ribs between the lower frame ribs and their adjacent transverse ribs are Serrated (SA) end to end; in contrast, the prior art in which the transverse ribs and the longitudinal ribs are crisscrossed does not have the zigzag design (SI), and the comparison data of the reject ratio generated by the bottom in the process of manufacturing the polar plate is shown in table 4, and the result shows that the zigzag design can avoid the reject ratio of the bottom of the polar plate to a certain extent.
TABLE 4 Table 4
Claims (9)
1. The utility model provides a lead accumulator grid, includes the frame that comprises last frame rib, lower frame rib and two vertical frame ribs, and horizontal rib and the vertical rib of crisscross formation network structure in the frame to and set up the utmost point ear on last frame rib, its characterized in that, vertical rib draws in to the position slope that the utmost point ear is located, and their extension line intersects in a point, and this intersection point is located utmost point ear directly over, and the ratio of the interval of upper and lower frame rib and the interval of this intersection point and lower frame rib is golden section proportion.
2. The lead storage battery grid of claim 1 wherein the angle between adjacent longitudinal ribs is 3 degrees.
3. The lead storage battery grid according to claim 1, wherein the height of the tab is H, the distance between the outer edge of the tab and the midpoint of the upper frame rib is L, and the intersection point of the tab and the upper frame rib is the focal point of an ellipse with 2L as the major axis and 2H as the minor axis.
4. The lead storage battery grid of claim 1, wherein the tab base has a progressively increasing width.
5. The lead storage battery grid of claim 1 wherein the longitudinal ribs between the lower frame ribs and their adjacent transverse ribs are serrated end to end.
6. The lead storage battery grid of claim 1, wherein the longitudinal ribs increase in width from the lower rim ribs to the upper rim ribs.
7. The lead storage battery grid of claim 1, wherein the upper rim rib and the vertical rim rib adjacent to the tab are thicker than the lower rim rib and the other vertical rim rib.
8. The lead storage battery grid of claim 7, wherein the upper rim rib and the vertical rim rib adjacent to the tab have a width of 3mm and the lower rim rib and the other vertical rim rib have a width of 2mm.
9. The lead storage battery grid of claim 1, wherein one end of the transverse ribs is a tapered section of gradual width.
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CN201710245767.4A CN107086307B (en) | 2017-04-14 | 2017-04-14 | Lead storage battery grid |
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CN201710245767.4A CN107086307B (en) | 2017-04-14 | 2017-04-14 | Lead storage battery grid |
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CN107086307B true CN107086307B (en) | 2023-06-16 |
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Families Citing this family (2)
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JP6456537B1 (en) * | 2018-02-28 | 2019-01-23 | 古河電池株式会社 | Positive electrode grid for lead acid battery and lead acid battery |
CN112086647A (en) * | 2020-09-04 | 2020-12-15 | 广东金悦诚蓄电池有限公司 | Grid for improving utilization efficiency of lead-acid storage battery |
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KR20130064177A (en) * | 2011-12-08 | 2013-06-18 | 세방전지(주) | Grid for agm battery |
CN203225309U (en) * | 2013-04-26 | 2013-10-02 | 浙江天能动力能源有限公司 | Lead-acid storage battery grid for preventing lead plaster from falling off |
CN103560253A (en) * | 2013-10-15 | 2014-02-05 | 超威电源有限公司 | Grid with inclined rib gradient structure |
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CN105745775A (en) * | 2013-10-08 | 2016-07-06 | 江森自控汽车电池有限责任公司 | Grid arrangement for a plate-shaped battery electrode of an electrochemical accumulator, and accumulator |
CN206961945U (en) * | 2017-04-14 | 2018-02-02 | 天能电池集团有限公司 | A kind of lead accumulator grid |
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EP0589549A1 (en) * | 1992-09-21 | 1994-03-30 | Globe-Union Inc. | Lead acid batteries containing center lug plates and high performance cast-on straps |
JP2001126735A (en) * | 1999-10-26 | 2001-05-11 | Nippon Mitsubishi Oil Corp | Lead accumulator |
CN2678148Y (en) * | 2003-12-17 | 2005-02-09 | 卢建强 | Die-stamped battery grid |
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CN203225309U (en) * | 2013-04-26 | 2013-10-02 | 浙江天能动力能源有限公司 | Lead-acid storage battery grid for preventing lead plaster from falling off |
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