CN107083150B - A kind of UV coating for automobile interiors and its preparation method and application - Google Patents
A kind of UV coating for automobile interiors and its preparation method and application Download PDFInfo
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- CN107083150B CN107083150B CN201710320766.1A CN201710320766A CN107083150B CN 107083150 B CN107083150 B CN 107083150B CN 201710320766 A CN201710320766 A CN 201710320766A CN 107083150 B CN107083150 B CN 107083150B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of UV coating for automobile interiors and its preparation method and application, the raw material including following parts by weight: 15-20 parts of polyurethane acrylic resin；20-30 parts of epoxy resin；15-20 parts of trimethylolpropane trimethacrylate；3-5 parts of ultraviolet initiator；0.3-0.8 parts of levelling agent；10-25 parts of ethyl acetate；10-25 parts of butyl acetate.UV coating property for automobile interiors provided by the invention is excellent, and coating can be up to crosslinking be fully cured, and solvent noresidue is not after-tacked, moreover, good dispersion when spraying, levelability are moderate, thixotropy is moderate, coating uniform, without obvious tangerine peel, without pinprick bubble, free from admixture point exists.Lacquer painting levelling is plentiful, and glossiness is good.Public VW TL226 standard can be fully met.
Description
Technical field
The invention belongs to technical field of paint preparation, and in particular to a kind of UV coating for automobile interiors and preparation method thereof and
Using.
Background technique
Nowadays with the enhancing of people's environmental consciousness and the development of polymer science, it is desirable that use the cry of environmental protection coating material
Higher and higher, domestic each enterprise is to find competitive advantage all in the index for gradually tightening coating VOC content, development and application ring
Guarantor's type coating.UV paint belongs to environment-friendly type coating, has the advantages that curing rate is fast, work efficiency is high, so automobile interior decoration UV
The research and development of gloss oil series paint are to comply with market trend, and automobile interior decoration UV gloss oil series paint has in the application of automotive upholstery
Extremely wide prospect.
But automobile interior decoration is generally plastic cement system, and in existing technology, the adhesive force of UV gloss oil is insufficient, applies
Layer hardness is high, wearability, acid and alkali-resistance, salt spray resistance, fuel-proof performance are poor, therefore, how to develop has high attachment
The superior UV coating for automobile interiors of power, high rigidity, properties is technical problem now urgently to be resolved.
Summary of the invention
The present invention provides a kind of UV coating for automobile interiors and its preparation method and application, for ABS, PC, ABS+
The plastic rubber substrate of PC has good adhesive force, is formed by paint film with performances such as solvent resistant, water resistances.
Technical solution provided by the invention are as follows:
A kind of UV coating for automobile interiors, the raw material including following parts by weight:
The ultraviolet initiator is by 184 photoinitiator 2-3 parts by weight of BASF IRGACURE and BASF IRGACURE
TPO photoinitiator 1-2 parts by weight composition.Two kinds of photoinitiators share, and the ultraviolet light of ultraviolet region different-waveband can be absorbed, make
The solidification for obtaining UV coating is more thorough, to provide better surface property for paint film.
The levelling agent is by BYK-333 type levelling agent 0.2-0.5 parts by weight and BYK-371 type levelling agent 0.1-0.3 weight
Part composition.BYK-333 is organosilicon levelling agent, and BYK-371 is acrylic acid levelling agent, and the two, which is used cooperatively, can solve long shortwave
Problem makes the levelability of integral system more preferable.
The polyurethane acrylic resin is polyurethane acroleic acid oligomer；The epoxy resin is that epoxy acrylate is low
Polymers.
In above-mentioned formula, polyurethane acrylic resin is used to provide the adhesive force and surface levelability of matrix, asphalt mixtures modified by epoxy resin
Rouge provides stemness and crosslink density, and trimethylolpropane trimethacrylate is used to provide the flexility of paint film, ultraviolet light-initiated
Agent is used to cause the polymerization of monomer and polyester, and levelling agent provides the levelability of paint film, and ethyl acetate and butyl acetate are solvent, assigns
In the preferable mobility of paint and solvent release.
The invention also discloses the preparation methods of UV coating for automobile interiors, and the preparation method comprises the following steps:
(1) under the conditions of being protected from light, by 15-20 parts by weight of polyurethane acrylic resin, 20-30 parts by weight epoxy resin and
15-20 parts by weight trimethylolpropane trimethacrylate stirs 10min under the conditions of 300-700 revs/min, obtains mixture A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, is added under agitation
3-5 parts by weight ultraviolet initiator stirs 15min, obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, 0.3- is sequentially added
0.8 parts by weight levelling agent stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, ethyl acetate 10-25 parts by weight and butyl acetate 5- is added
10 parts by weight adjust viscosity to 20-30S (25 DEG C, NK-2), and the filtering of 300 mesh obtains UV coating for automobile interiors.
Further, the preparation method comprises the following steps:
(1) under the conditions of being protected from light, by 15-20 parts by weight of polyurethane acrylated oligomer, 20-30 parts by weight epoxy acrylic acid
Ester oligomer and 15-20 parts by weight trimethylolpropane trimethacrylate stir 10min under the conditions of 300-700 revs/min, obtain
To mixture A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, is added under agitation
184 ultraviolet initiator 2-3 parts by weight of IRGACURE and IRGACURE TPO ultraviolet initiator 1-2 parts by weight, stirring
15min obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling is sequentially added
Agent BYK-333 0.2-0.5 parts by weight and levelling agent BYK-371 0.1-0.3 parts by weight stir 15min；
(4) continue under 300-700 revs/min of stirring condition, ethyl acetate 10-25 parts by weight and butyl acetate 5- is added
10 parts by weight adjust viscosity to 20-30S (25 DEG C, NK-2), and the filtering of 300 mesh obtains UV coating for automobile interiors.
Above-mentioned preparation method, for the functioning efficiency for improving UV absorbers, whole preparation process need to be under the conditions of being protected from light
It carries out, causes preparation system to be cured under greenware condition to prevent it from absorbing ultraviolet light in the preparation process of coating
Crosslinking influences the quality of UV coating and the filming performance of paint film；Ultraviolet initiator must first add after butyl acetate dissolution again
Enter but in reaction system, to guarantee that it is uniformly dispersed in system.
The present invention also provides the paint film formed by UV coating for automobile interiors, paint film coating, which can reach, is fully cured friendship
Connection, solvent noresidue are not after-tacked, moreover, good dispersion when spraying, levelability is moderate, and thixotropy is moderate, and coating uniform, nothing are obvious
Tangerine peel, without pinprick bubble, free from admixture point exists.Lacquer painting levelling is plentiful, and glossiness is good.
The present invention also provides the applications of UV coating for automobile interiors, for the beautification to ABS or PC or ABS+PC substrate
And protection.
The present invention also provides the application methods of the UV coating for automobile interiors, by UV coating for automobile interiors and UV
Paint thinner is deployed by weight 10:2-3, is sprayed on prime coat, and room temperature levelling is dry after five minutes, and 80 DEG C keep the temperature 10 points
Clock, UV solidification, UV exposure energy are 600-800MJ/cm2。
The UV paint thinner includes the raw material of following parts by weight: 50 parts of ethyl acetate；50 parts of butyl acetate；It is prepared
Method are as follows: the ethyl acetate of the butyl acetate of parts by weight 50 and parts by weight 50 is mixed evenly after ten minutes.
There is good water resistance, ethyl acetate and butyl acetate using paint film prepared by the raw material and method of said ratio
With the use of ensure that the deliquescent of each raw material while improving the drying property of construction again.
Compared with prior art, UV paint disclosed by the invention is free of volatile organic compounds, and crosslinking after hardening is close
Degree is much higher than hot baking type coating, property of the coating in organic solvents various aspects such as hardness, wear-resisting, acid and alkali-resistance, salt spray resistance, resistance to gasoline
Energy index is very high, and especially its paint film is plentiful, gloss is especially prominent compares with solvent based coating, and UV paints energy phase used
When in the former 1/5 or so.It is compared with traditional heat curing coating, UV paint curing rate is fast, and high production efficiency, curing mechanism belongs to one
The chain reaction of kind free radical, crosslinking curing are completed in moment, and designed production line speed reaches as high as 100m/min, work
Part is offline to be packed, and the efficiency using UV coating is 15 times or more of traditional drying-type coating；The energy is saved, UV coating is by purple
Outer photocuring, for General Production Lines energy consumption within 50kW, energy consumption is about the 1/5 of traditional drying-type heat curing coating.
UV coating property for automobile interiors provided by the invention is excellent, and coating can be up to crosslinking be fully cured, and solvent is without residual
Stay and do not after-tack, moreover, spraying when good dispersion, levelability is moderate, and thixotropy is moderate, coating uniform, without obvious tangerine peel, without pinprick
Bubble, free from admixture point exist.Lacquer painting levelling is plentiful, and glossiness is good.
Public VW TL226 is the most stringent standard of automotive upholstery industry, present most of automotive upholstery manufacturers
Equally the performance of paint is detected using the standard of VW TL226, UV coating warp for automobile interiors provided by the invention
Multinomial performance test is crossed, the requirement of TL226 standard can be fully met.
Specific embodiment
With specific embodiment 1~5 and comparative example 1~3, the present invention is described in detail below, automobile in each embodiment
Interior trim is shown in Table 1 with the parts by weight of UV coating and raw material, each embodiment the preparation method is as follows:
(1) according to the formula of each embodiment in table 1, by polyurethane acroleic acid oligomer, epoxy acrylate oligomer and
Trimethylolpropane trimethacrylate stirs 10min under the conditions of 300-700 revs/min, obtains mixture A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, is added under agitation
184 ultraviolet initiator of IRGACURE and IRGACURE TPO ultraviolet initiator stir 15min, obtain mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling is sequentially added
Agent BYK-333 and levelling agent BYK-371 stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, ethyl acetate and butyl acetate 5-10 parts by weight are added, adjust
Thickening degree to 20-30S (25 DEG C, NK-2), the filtering of 300 mesh obtains UV coating for automobile interiors.
The whole preparation process of Examples 1 to 5 carries out under the conditions of being protected from light.
Table 1
The parts by weight of UV coating for automobile interiors and raw material are shown in Table 2 in comparative example 1~3, and the preparation method of comparative example 1 is the same as real
Example 1 is applied, only without addition epoxy acrylate oligomer；The preparation method of comparative example 2 is with embodiment 2, only wherein
It only joined a kind of ultraviolet initiator and levelling agent, but total amount be added and does not change；The same embodiment of the preparation method of comparative example 3
3, only the additional amount of part material is different.
Table 2
The UV coating that each Examples and Comparative Examples are obtained is deployed with UV lacquer diluent by weight 10:2-3, the UV
Paint thinner includes the raw material of following parts by weight: 50 parts of ethyl acetate；50 parts of butyl acetate；Preparation method are as follows: by weight
The butyl acetate of part 50 and the ethyl acetate of parts by weight 50 are mixed evenly after ten minutes；By the UV coating spray after allotment
It is applied on the prime coat of automotive upholstery after drying, room temperature levelling is dry after five minutes, and 80 DEG C keep the temperature 10 minutes, then
UV solidification is carried out, UV exposure energy is 600-800MJ/cm2, paint film coating uniform that each embodiment obtains, without obvious tangerine peel, nothing
Pinprick bubble, free from admixture point exist, and lacquer painting levelling is plentiful, and glossiness is good.
Paint film property is detected, testing result is as shown in table 3:
Table 3
It is as follows for the testing standard of UV coating for automobile interiors:
1. appearance: whether there is or not the surface blemishes such as blistering, orange peel, shrinkage cavity, ripple, prickly heat for evaluation film forming.
2. Storage period: whether evaluation paint occurs thickening within the shelf-life, layering, plays glue, changes colour, returning the abnormal feelings such as thick
Condition；
The testing standard of performance each for the above paint film is referring to public VW TL226 standard.
As can be seen that UV coating for automobile interiors disclosed by the invention can comply fully with public VW from above-mentioned table 3
TL226 standard.
The above-mentioned detailed description carried out referring to embodiment to UV coating for automobile interiors and its preparation method and application, is to say
Bright property without being restrictive, several embodiments can be enumerated according to limited range, therefore of the invention total not departing from
Change and modification under body design, should belong within protection scope of the present invention.
Claims (9)
1. a kind of UV coating for automobile interiors, which is characterized in that the raw material including following parts by weight:
The ultraviolet initiator is by 184 photoinitiator 2-3 parts by weight of BASF IRGACURE and BASF IRGACURE TPO light
Initiator 1-2 parts by weight composition.
2. UV coating for automobile interiors according to claim 1, which is characterized in that the levelling agent is by BYK-333 type stream
Flat agent 0.2-0.5 parts by weight and BYK-371 type levelling agent 0.1-0.3 parts by weight composition.
3. UV coating for automobile interiors according to claim 1, which is characterized in that the polyurethane acrylic resin is poly-
Urethane acrylated oligomer.
4. the preparation method of UV coating for automobile interiors according to claim 1, which is characterized in that the preparation method packet
Include following steps:
(1) under the conditions of being protected from light, by 15-20 parts by weight of polyurethane acrylic resin, 20-30 parts by weight epoxy acrylate oligomers
Object and 15-20 parts by weight trimethylolpropane trimethacrylate stir 10min under the conditions of 300-700 revs/min, are mixed
Expect A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, 3-5 is added under agitation
Parts by weight ultraviolet initiator stirs 15min, obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, 0.3-0.8 is sequentially added
Parts by weight levelling agent stirs 15min；
(4) continue under 300-700 revs/min of stirring condition, ethyl acetate 10-25 parts by weight and butyl acetate 5-10 weight are added
Part is measured, NK-2 viscosity is filtered to 20-30S, 300 mesh when adjusting 25 DEG C, obtains UV coating for automobile interiors.
5. the preparation method of UV coating for automobile interiors according to claim 3, which is characterized in that the preparation method packet
Include following steps:
(1) under the conditions of being protected from light, 15-20 parts by weight of polyurethane acrylated oligomer, 20-30 parts by weight epoxy acrylate is low
Polymers and 15-20 parts by weight trimethylolpropane trimethacrylate stir 10min under the conditions of 300-700 revs/min, are mixed
Close material A；
(2) butyl acetate of 10-15 parts by weight is stirred under the conditions of 300-700 revs/min, is added under agitation
184 ultraviolet initiator 2-3 parts by weight of IRGACURE and IRGACURE TPO ultraviolet initiator 1-2 parts by weight, stirring
15min obtains mixed material B；
(3) under 300-700 revs/min of stirring condition, material B is slowly added into material A, levelling agent is sequentially added
BYK-333 0.2-0.5 parts by weight and levelling agent BYK-371 0.1-0.3 parts by weight stir 15min；
(4) continue under 300-700 revs/min of stirring condition, ethyl acetate 10-25 parts by weight and butyl acetate 5-10 weight are added
Part is measured, NK-2 viscosity is filtered to 20-30S, 300 mesh when adjusting 25 DEG C, obtains UV coating for automobile interiors.
6. the paint film that UV coating for automobile interiors according to claim 1 to 3 is formed.
7. the application of UV coating for automobile interiors according to claim 1 to 3, which is characterized in that the automobile
Interior trim is with UV coating for the beautification and protection to ABS or PC or ABS+PC substrate.
8. the application method of UV coating for automobile interiors according to claim 1 to 3, which is characterized in that by vapour
In-car decorations UV coating and UV paint thinner are deployed by weight 10:2-3, are sprayed on prime coat, and room temperature levelling is 5 points dry
Zhong Hou, 80 DEG C keep the temperature 10 minutes, and UV solidification, UV exposure energy is 600-800MJ/cm2。
9. application method according to claim 8, which is characterized in that the UV paint thinner includes following parts by weight
Raw material: 50 parts of ethyl acetate；50 parts of butyl acetate；Preparation method are as follows: by the butyl acetate of parts by weight 50 and parts by weight 50
Ethyl acetate is mixed evenly after ten minutes.
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| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN108659698B (en) * | 2018-04-12 | 2020-11-10 | 广东鼎立森新材料有限公司 | Ultraviolet curing coating for automobile paint surface protective film and use method thereof |
| CN108918411A (en) * | 2018-07-27 | 2018-11-30 | 江西江铃集团新能源汽车有限公司 | A kind of paint film test method |
| CN111019092B (en) * | 2019-12-25 | 2023-04-18 | 芜湖春风新材料有限公司 | Preparation method of organic silicon modified cathode electrophoresis resin and cathode electrophoresis emulsion prepared by same |
| CN111073427B (en) * | 2019-12-31 | 2022-04-05 | 芜湖春风新材料有限公司 | Dual UV (ultraviolet) curing coating for automotive interior parts, preparation method thereof and paint film formed by dual UV curing coating |
| CN111744747B (en) * | 2020-07-06 | 2022-05-17 | 深圳市中暨复合材料有限公司 | Manufacturing method of novel high-hardness micro-ceramic metal coating plate |
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| CN105368297A (en) * | 2015-11-30 | 2016-03-02 | 江门市凌云涂料有限公司 | High-temperature resistant UV (Ultraviolet) coating material for vacuum plating, preparation method for high-temperature resistant UV coating material and application of high-temperature resistant UV coating material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368297A (en) * | 2015-11-30 | 2016-03-02 | 江门市凌云涂料有限公司 | High-temperature resistant UV (Ultraviolet) coating material for vacuum plating, preparation method for high-temperature resistant UV coating material and application of high-temperature resistant UV coating material |
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