CN107044345A - Avoid-dismantle ternary catalyzing unit regeneration techniques - Google Patents

Avoid-dismantle ternary catalyzing unit regeneration techniques Download PDF

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Publication number
CN107044345A
CN107044345A CN201710132195.9A CN201710132195A CN107044345A CN 107044345 A CN107044345 A CN 107044345A CN 201710132195 A CN201710132195 A CN 201710132195A CN 107044345 A CN107044345 A CN 107044345A
Authority
CN
China
Prior art keywords
catalyzing unit
ternary catalyzing
dismantle
avoid
regeneration techniques
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710132195.9A
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Chinese (zh)
Inventor
展大伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Wanluda Environmental Technology Co Ltd
Original Assignee
Jiangsu Wanluda Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Wanluda Environmental Technology Co Ltd filed Critical Jiangsu Wanluda Environmental Technology Co Ltd
Priority to CN201710132195.9A priority Critical patent/CN107044345A/en
Publication of CN107044345A publication Critical patent/CN107044345A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00Component parts, details or accessories, not otherwise provided for
    • F02B77/04Cleaning of, preventing corrosion or erosion in, or preventing unwanted deposits in, combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2260/00Exhaust treating devices having provisions not otherwise provided for
    • F01N2260/04Exhaust treating devices having provisions not otherwise provided for for regeneration or reactivation, e.g. of catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention discloses a kind of avoid-dismantle ternary catalyzing unit regeneration techniques, comprise the following steps:1st, generating apparatus and ternary catalyzing unit again are connected;2nd, carbon distribution is calcined;3rd, purge;4th, clean;5th, active liquid supplement;6th, dry;7th, activate;8th, disconnect.Avoid-dismantle ternary catalyzing unit regeneration techniques of the present invention, which compares prior art, has advantages below:Ternary catalyzing unit need not be dismantled, it is easy to operate, both ternary catalyzing unit carbon distribution can be effectively removed, the harmful elements such as Pb, Zn, Ca, Mn, Fe, Cu, Ni, P, S can be removed again, while the carried catalyst be poisoned, failed can be returned to the level dispatched from the factory close to former car.

Description

Avoid-dismantle ternary catalyzing unit regeneration techniques
Technical field:
The present invention relates to petrol engine tail gas clean-up process field, and in particular to a kind of avoid-dismantle ternary catalyzing unit regenerates skill Art.
Technical background:
At present, automobile exhaust purifier is to reduce the most effectual way of engine combustion pollutant emission.
The main composition of automobile exhaust purifier has:Metal shell, pad and carried catalyst;Wherein, carried catalyst It is the core component that processing discharges pollutants.It is in fact exactly that the transformation efficiency of carried catalyst can not expire that motor vehicle emission is not up to standard Sufficient national environmental standard, such as state four, state five.
Cause carried catalyst transformation efficiency low, or conversion capability has many reason for completely lose, wherein most normal What is seen is:1st, substantial amounts of carbon distribution covers catalyst coat;2nd, fuel oil or Pb in fuel oil additive, Zn, Ca, Mn, Fe, Cu, Catalyst poisoning caused by the elements such as Ni, P, S.
The content of the invention:
In view of the above-mentioned problems, the invention discloses a kind of avoid-dismantle ternary catalyzing unit regeneration techniques.Pass through the method for preceding lambda sensor Blue mouth, portable media reproduction equipment is connected with blast pipe, in situ to return to the carried catalyst be poisoned, failed without dismounting The level dispatched from the factory close to original car.
To reach above-mentioned purpose, technical scheme provided by the present invention is:
Avoid-dismantle ternary catalyzing unit regeneration techniques, comprises the following steps:
First, generating apparatus and ternary catalyzing unit again are connected, by the flange port of preceding lambda sensor, by portable media reproduction equipment and exhaust Pipe is connected;
2nd, carbon distribution is calcined, by the hot air duct of portable media reproduction equipment, hot blast is blown out to ternary catalyzing unit, carbon distribution is burnt Fall;
3rd, purge, turn off the heater switch of portable media reproduction equipment, while blower fan air output is adjusted into maximum, the product of residual Carbon and dust purging are clean;
4th, clean, when hot blast temperature is down to 200 DEG C, pass through the cleaning agent injection pipe jet cleaning of portable media reproduction equipment Agent;
5th, active liquid supplement, active liquid is sprayed by the renovation agent injection pipe of portable media reproduction equipment;
6th, dry, by the hot air duct of portable media reproduction equipment, blow out hot blast to ternary catalyzing unit, active liquid is dried;
7th, activate, by the hot air duct of portable media reproduction equipment, blow out hot blast to ternary catalyzing unit, active liquid is activated;
8th, disconnect, complete regeneration.
Further, the hot blast temperature in step 2 is 300 DEG C ~ 500 DEG C, and the duration is 5 ~ 20 minutes, and the specific time regards Catalyst converter aging performance is determined.
Further, in step 4, the main component of cleaning agent is hydrochloric acid, hydrogen peroxide, chelating agent.
Further, in step 5, active liquid is the renovation agent using Pt, Pd, Rh as main active component.
Further, the hot blast temperature in step 6 is 80 ~ 200 DEG C.
Further, water rate is gone to reach 100% in step 6.
Further, the hot blast temperature in step 7 can not be less than 500 DEG C.
Further, in step 7, time of the temperature more than 500 DEG C must not be less than 5 minutes.
It is an advantage of the invention that:Ternary catalyzing unit regeneration techniques of the present invention, without dismantling ternary catalyzing unit, operation It is convenient and swift, ternary catalyzing unit carbon distribution both can be effectively removed, Pb, Zn, Ca, Mn, Fe, Cu, Ni, P, S etc. can be removed again to be had Evil element, while the carried catalyst be poisoned, failed can be returned to the level dispatched from the factory close to former car.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by Skilled artisan understands that.
Comprise the following steps:
By the flange port of preceding lambda sensor, portable media reproduction equipment is connected with blast pipe, it is ensured that hot blast, cleaning agent and reparation Agent critical point is directed at ternary catalyzing unit, opens blower fan and heater switch, air quantity is adjusted between the 0.5 ~ 0.25 of maximum quantity of wind, leads to The hot air duct of portable media reproduction equipment is crossed, hot blast is blown out to ternary catalyzing unit, carbon distribution is burnt completely, notices that temperature can not Less than 300 DEG C, 500 DEG C can not be higher than, the serious ternary catalyzing unit of aging is time-consuming 20 minutes or so, after burning completely, Turn off the heater switch of portable media reproduction equipment, while blower fan air output is adjusted into maximum, carbon distribution and the dust of residual are purged Totally, when hot blast temperature is down to 200 DEG C, the cleaning agent injection pipe jet cleaner of portable media reproduction equipment, cleaning are passed through The main component of agent is hydrochloric acid and hydrogen peroxide, while also after the completion of cleaning, then passing through portable media reproduction containing chelating agents such as EDTA The renovation agent injection pipe of equipment sprays the active liquid by main active component of Pt, Pd, Rh, treats that active liquid is fully dispersed in three After on first catalyst converter, then by the hot air duct of portable media reproduction equipment, hot blast is blown out to ternary catalyzing unit, active liquid is dried Dry, drying temperature is 80 ~ 200 DEG C, while going the requirement of water rate to reach 100%, is set when being completely dried, then by portable media reproduction Standby hot air duct, blows out hot blast to ternary catalyzing unit, active liquid is activated, and hot blast temperature can not be less than 500 DEG C, and the time is not It must be less than 5 minutes.

Claims (7)

1. avoid-dismantle ternary catalyzing unit regeneration techniques, comprises the following steps:First, generating apparatus and ternary catalyzing unit again are connected, is passed through The flange port of preceding lambda sensor, portable media reproduction equipment is connected with blast pipe;2nd, carbon distribution is calcined, is set by portable media reproduction Standby hot air duct, blows out hot blast to ternary catalyzing unit, carbon distribution is burnt;3rd, purge, turn off adding for portable media reproduction equipment Thermal switch, while blower fan air output is adjusted into maximum, purges carbon distribution and the dust of residual clean;4th, clean, in hot blast temperature When being down to 200 DEG C, pass through the cleaning agent injection pipe jet cleaner of portable media reproduction equipment;5th, active liquid supplement, by just Take the active liquid of renovation agent injection pipe injection of formula generating apparatus again;6th, dry, by the hot air duct of portable media reproduction equipment, Hot blast is blown out to ternary catalyzing unit, active liquid is dried;7th, activate, by the hot air duct of portable media reproduction equipment, to ternary Catalyst converter blows out hot blast, and active liquid is activated;8th, disconnect, complete regeneration.
2. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that the hot blast in the step 2 Temperature is 300 DEG C ~ 500 DEG C, and the duration is 5 ~ 20 minutes, and the specific time determines regarding catalyst converter aging performance.
3. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that in the step 4, cleaning agent Main component be hydrochloric acid, hydrogen peroxide, chelating agent.
4. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that in the step 5, active liquid It is the renovation agent using Pt, Pd, Rh as main active component.
5. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that the hot blast in the step 6 Temperature is 80 ~ 200 DEG C.
6. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that remove water in the step 6 Rate will reach 100%.
7. avoid-dismantle ternary catalyzing unit regeneration techniques according to claim 1, it is characterised in that the hot blast in the step 7 Temperature can not be less than 500 DEG C, and the time must not be less than 5 minutes.
CN201710132195.9A 2017-03-07 2017-03-07 Avoid-dismantle ternary catalyzing unit regeneration techniques Pending CN107044345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710132195.9A CN107044345A (en) 2017-03-07 2017-03-07 Avoid-dismantle ternary catalyzing unit regeneration techniques

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710132195.9A CN107044345A (en) 2017-03-07 2017-03-07 Avoid-dismantle ternary catalyzing unit regeneration techniques

Publications (1)

Publication Number Publication Date
CN107044345A true CN107044345A (en) 2017-08-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107442133A (en) * 2017-08-18 2017-12-08 江苏万路达环保科技有限公司 Colloidal sol type ternary catalyzing unit renovation agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102619594A (en) * 2011-01-30 2012-08-01 陈温乐 Transient neutralization and purification device for black smoke and exhaust gas discharged by vehicle
US20140030159A1 (en) * 2012-07-27 2014-01-30 SerVaas Laboratories, Inc. Catalytic Converter, a Kit for Servicing a Catalytic Converter, and Methods for Servicing a Catalytic Converter
CN203710918U (en) * 2013-12-23 2014-07-16 上海斯儿特环保科技有限公司 Rapid repairing machine of automobile tail gas purifier
CN103939212A (en) * 2014-04-14 2014-07-23 吉林大学 Visual dismantling-free three-way catalyst cleaning method and device
CN105134378A (en) * 2015-06-15 2015-12-09 于宏伟 Cleaning method and device for automotive three-way catalytic converter
CN105840311A (en) * 2015-12-07 2016-08-10 江苏万路达环保科技有限公司 Repairing method for motor vehicle exhaust purifier

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102619594A (en) * 2011-01-30 2012-08-01 陈温乐 Transient neutralization and purification device for black smoke and exhaust gas discharged by vehicle
US20140030159A1 (en) * 2012-07-27 2014-01-30 SerVaas Laboratories, Inc. Catalytic Converter, a Kit for Servicing a Catalytic Converter, and Methods for Servicing a Catalytic Converter
CN203710918U (en) * 2013-12-23 2014-07-16 上海斯儿特环保科技有限公司 Rapid repairing machine of automobile tail gas purifier
CN103939212A (en) * 2014-04-14 2014-07-23 吉林大学 Visual dismantling-free three-way catalyst cleaning method and device
CN105134378A (en) * 2015-06-15 2015-12-09 于宏伟 Cleaning method and device for automotive three-way catalytic converter
CN105840311A (en) * 2015-12-07 2016-08-10 江苏万路达环保科技有限公司 Repairing method for motor vehicle exhaust purifier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107442133A (en) * 2017-08-18 2017-12-08 江苏万路达环保科技有限公司 Colloidal sol type ternary catalyzing unit renovation agent

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Application publication date: 20170815

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