CN107043564A - A kind of conducting function coating and its prepare conductive fiber method - Google Patents
A kind of conducting function coating and its prepare conductive fiber method Download PDFInfo
- Publication number
- CN107043564A CN107043564A CN201710067402.7A CN201710067402A CN107043564A CN 107043564 A CN107043564 A CN 107043564A CN 201710067402 A CN201710067402 A CN 201710067402A CN 107043564 A CN107043564 A CN 107043564A
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- CN
- China
- Prior art keywords
- conductive fiber
- coating
- fiber
- parts
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
Abstract
The invention discloses a kind of conducting function coating and its prepare conductive fiber method, coating is used as raw material material using epoxy acrylate, first class methyl acrylate, butyl acrylate, carbon black, cuprous iodide, auxiliary agent, obtain conducting function coating, general fibre is soaked in wherein afterwards, its UV-light cured step coating, obtains conductive fiber.General fibre progress surface is modified to conductive fiber by the present invention by by the way that UV photocureable coating modes are handled, being doped in by using carbon black in propenoic acid ester photocureable paint coatings.For the mode of more conventionally employed adhesive bonding, it this method solve because carbon black such as comes off at the technical problem caused by bonding strength is not enough, due to carrying out photocuring reaction directly on conductive fiber, bondability is higher, and inherit that conventional coatings method is simple to operate, direct convenience technical characterstic, it can be applied to the industrial production link of extensive conductive fiber.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of conducting function coating and its conductive fiber method is prepared.
Background technology
Conductive fiber is manufactured using the electric conductivity of carbon black, this is a kind of ancient and universal method of comparison.This method
Following three class can be divided into：1. doping method；Spinning after carbon black is mixed with fiberforming substance, carbon black in the fibre into continuous phase structure,
Assign filamentary conductive energy.This method typically uses core-sheath spinning method, neither influences the original physical property of fiber, again
Fiber is set to be provided with electric conductivity.2. coating；Coating is to coat carbon black on general fibre surface.Coating process can be using viscous
Carbon black is bonded in fiber surface by mixture, or is bonded directly by fiber surface fast softening and with carbon black.3. at fiber charing
Reason；Some fibers, such as polyacrylonitrile fibre, cellulose fibre, pitch series fiber, after charing process, the main chain master of fiber
To be carbon atom, so that fiber has conductive capability.
With regard to above method, coating often turns into the conventional of industrial conductive fiber due to simple to operate, direct convenience
Method, but the shortcoming of this method is that carbon black easily comes off, and feel is also bad, and carbon black is difficult to be uniformly distributed in fiber surface.
The content of the invention
The technical problem to be solved in the present invention is：For above-mentioned the deficiencies in the prior art, there is provided a kind of conducting function coating
And its prepare conductive fiber method.
The present invention solve its technical problem solution be：A kind of conducting function coating, it is characterised in that by below into
Divide and be formulated according to certain part by weight：
30-80 parts of epoxy acrylate
10-30 parts of first class methyl acrylate
10-15 parts of butyl acrylate
2-8 parts of carbon black
0.3-2 parts of cuprous iodide
1-3 parts of auxiliary agent.
A kind of method using coating preparation conductive fiber described above, it is characterised in that comprise the following steps：
（1）Fiber is pre-processed, the impurity such as dust are removed；
（2）Fiber is soaked in coating component described above, soak time is 1-4h；And addition light draws in component
Send out agent；
（3）By step（2）In fiber by being solidified in UV curing oven, solidification temperature be 30 DEG C -100 DEG C, solidification
Time is 1-6h；
（4）Room temperature is cooled to after solidification, is handled through pure water, after drying, final conductive fiber is obtained.
It is used as one of preferred technical scheme, it is characterised in that described light trigger is 2,4,6（Trimethylbenzoyl
Base）Diphenyl phosphine oxide.
The beneficial effects of the invention are as follows：The present invention is by the way that UV photocureable coating modes are handled, by using carbon black
It is doped in propenoic acid ester photocureable paint coatings, general fibre progress surface is modified to conductive fiber.It is more conventionally employed viscous
For the mode of mixture bonding, it this method solve because carbon black such as comes off at the technical problem caused by bonding strength is not enough, by
In carrying out photocuring reaction directly on conductive fiber, bondability is higher, and it is simple to operate, direct to inherit conventional coatings method
Convenient technical characterstic, can be applied to the industrial production link of extensive conductive fiber.
Embodiment
The technique effect of the design of the present invention, concrete structure and generation is carried out below with reference to embodiment clear, complete
Ground is described, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is the one of the present invention
Section Example, rather than whole embodiments, based on embodiments of the invention, those skilled in the art is not paying creativeness
The other embodiment obtained on the premise of work, belongs to the scope of protection of the invention.
Embodiment：A kind of conducting function coating, it is characterised in that be formulated by following component according to certain part by weight：
80 parts of epoxy acrylate；25 parts of first class methyl acrylate；12 parts of butyl acrylate；7 parts of carbon black；1.6 parts of cuprous iodide；Auxiliary agent
2 parts.
A kind of method of coating preparation conductive fiber described in use above-described embodiment, it is characterised in that comprise the following steps：
（1）Fiber is pre-processed, the impurity such as dust are removed；
（2）Fiber is soaked in the coating component described in claim 1, soak time is 3h, and added in component
Light trigger；
（3）By step（2）In fiber by being solidified in UV curing oven, solidification temperature is 70 DEG C, and hardening time is
2h；
（4）Room temperature is cooled to after solidification, is handled through pure water, after drying, final conductive fiber is obtained.
The present embodiment is doped in acrylate light by the way that UV photocureable coating modes are handled, by using carbon black and consolidated
Change in paint coatings, general fibre progress surface is modified to conductive fiber.For the mode of more conventionally employed adhesive bonding,
It this method solve because carbon black such as comes off at the technical problem caused by bonding strength is not enough, due to enterprising directly in conductive fiber
Row photocuring reaction, bondability is higher, and inherits that conventional coatings method is simple to operate, direct convenience technical characterstic, can answer
Industrial production link for extensive conductive fiber.
In addition, adding cuprous iodide composition in the present embodiment, the electrostatic interaction outside conductive fiber can be further reduced,
Improve conductive fiber conductive stability.
As one of preferred embodiment, it is characterised in that described light trigger is 2,4,6（Trimethylbenzoyl
Base）Diphenyl phosphine oxide.
The better embodiment to the present invention is illustrated above, but the invention is not limited to the implementation
Example, those skilled in the art can also make a variety of equivalent modifications or replace on the premise of without prejudice to spirit of the invention
Change, these equivalent modifications or replacement are all contained in the application claim limited range.
Claims (3)
1. a kind of conducting function coating, it is characterised in that be formulated by following component according to certain part by weight：
30-80 parts of epoxy acrylate
10-30 parts of first class methyl acrylate
10-15 parts of butyl acrylate
2-8 parts of carbon black
0.3-2 parts of cuprous iodide
1-3 parts of auxiliary agent.
2. a kind of method of coating preparation conductive fiber described in usage right requirement 1, it is characterised in that comprise the following steps：
（1）Fiber is pre-processed, the impurity such as dust are removed；
（2）Fiber is soaked in the coating component described in claim 1, soak time is 1-4h；And add in component
Enter light trigger；
（3）By step（2）In fiber by being solidified in UV curing oven, solidification temperature be 30 DEG C -100 DEG C, solidification
Time is 1-6h；
（4）Room temperature is cooled to after solidification, is handled through pure water, after drying, final conductive fiber is obtained.
3. the method according to claim 2 for preparing conductive fiber, it is characterised in that described light trigger is 2,4,6
（Trimethylbenzoyl）Diphenyl phosphine oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067402.7A CN107043564A (en) | 2017-02-07 | 2017-02-07 | A kind of conducting function coating and its prepare conductive fiber method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067402.7A CN107043564A (en) | 2017-02-07 | 2017-02-07 | A kind of conducting function coating and its prepare conductive fiber method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107043564A true CN107043564A (en) | 2017-08-15 |
Family
ID=59544031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710067402.7A Pending CN107043564A (en) | 2017-02-07 | 2017-02-07 | A kind of conducting function coating and its prepare conductive fiber method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107043564A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020015278A1 (en) * | 2018-07-16 | 2020-01-23 | 山东黄河三角洲纺织科技研究院有限公司 | Conductive far-infrared heat-generating fiber and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1749476A (en) * | 2005-10-18 | 2006-03-22 | 天津工业大学 | Method for preparing coductive fiber and its product |
| CN1836013A (en) * | 2003-08-13 | 2006-09-20 | 露温迪克有限公司 | Photocurable polymer resin composition having antistatic property for coating optical fiber |
| CN1973004A (en) * | 2004-06-10 | 2007-05-30 | 晓温-威廉姆斯公司 | Free radical curable conductive primer |
| CN1997713A (en) * | 2004-06-16 | 2007-07-11 | 汉高两合股份公司 | Radiation-curable, electrically conductive coating mixture |
| CN101949095A (en) * | 2010-09-02 | 2011-01-19 | 荣盛石化股份有限公司 | Conductive fiber preparation method and product thereof |
-
2017
- 2017-02-07 CN CN201710067402.7A patent/CN107043564A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1836013A (en) * | 2003-08-13 | 2006-09-20 | 露温迪克有限公司 | Photocurable polymer resin composition having antistatic property for coating optical fiber |
| CN1973004A (en) * | 2004-06-10 | 2007-05-30 | 晓温-威廉姆斯公司 | Free radical curable conductive primer |
| CN1997713A (en) * | 2004-06-16 | 2007-07-11 | 汉高两合股份公司 | Radiation-curable, electrically conductive coating mixture |
| CN1749476A (en) * | 2005-10-18 | 2006-03-22 | 天津工业大学 | Method for preparing coductive fiber and its product |
| CN101949095A (en) * | 2010-09-02 | 2011-01-19 | 荣盛石化股份有限公司 | Conductive fiber preparation method and product thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020015278A1 (en) * | 2018-07-16 | 2020-01-23 | 山东黄河三角洲纺织科技研究院有限公司 | Conductive far-infrared heat-generating fiber and preparation method therefor |
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Application publication date: 20170815 |