CN107033780A - The easy polishing inner wall coating of high rigidity for kitchen use and preparation method - Google Patents
The easy polishing inner wall coating of high rigidity for kitchen use and preparation method Download PDFInfo
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- CN107033780A CN107033780A CN201710289757.0A CN201710289757A CN107033780A CN 107033780 A CN107033780 A CN 107033780A CN 201710289757 A CN201710289757 A CN 201710289757A CN 107033780 A CN107033780 A CN 107033780A
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- agent
- water
- silane
- high rigidity
- wall coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses the easy polishing inner wall coating of high rigidity for kitchen use and preparation method, by weight percentage, comprising:Water 14~24%, wetting dispersing agent 0.4~0.6%, cellulose 0.2~0.25%, defoamer 0.1~0.2%, antifreezing agent 0.8~1.2%, scratching resistant 0.3~0.6%, titanium dioxide 0~10%, calcite in powder 20~30%, pH adjusting agent 0.1~0.2%, silane silicone emulsion 40~50%, coalescents 2~2.5%, mould inhibitor 0.5~1%, bactericide 0.1~0.3%, water-repelling agent 0.2~0.4%, anti-graffiti dose 0.2~0.3%.The reactivity and permeability of silane, can be combined, molecular volume is minimum by the emulsion of the present invention with the mobility and water droplet effect of siloxanes, and being coated in after substrate surface can depth infiltration base material.Can be with base material and itself reacting, so as to realize durability.It after solidification, it is allowed to which vapor penetrates into, but can prevent from that base material may be penetrated into containing the chlorion after dissolving or sour aqueous water.It also occur that polycondensation reaction, constitutes Si O Si polymer, the alkyl towards outer side surface can be effectively hydrophobic between silane, the protection for being directed to impaired freeze thawing, infiltration, permeability and mould can be provided.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to the easy polishing inner wall coating of high rigidity for kitchen use and preparation method.
Background technology
Coating for kitchen use due to kitchen it is dark, moist, be also easy to produce the particularity such as greasy dirt, the requirement to coating is very high.
It should meet moistureproof, mould proof, the requirement of greasy dirt easy-clear is met again.When kitchen is fitted up, a part of user selects common interior wall
Coating decorates kitchen.Some user can select ceramic tile or wallpaper, because kitchen is also easy to produce greasy dirt and condensed on wall,
And the greasy dirt on ceramic tile and wallpaper is easier to remove.
This existing product for resulting on the market has the following disadvantages:
From common interior wall coating:Because common interior wall coating moistureproof and mildewproof effect is general, and scrub performance is general, only
Suitable for parlor, bedroom etc. to the less demanding region of coating;
Paste ceramic tile:Kitchen place is in the back of building, it is impossible to avoid the generation of moist bacterium of easily mildewing, a period of time
Ceramic tile or wallpaper easily come off from wall top layer in the presence of moisture afterwards;And the time-consuming feed consumption of construction, it is costly, and used when pasting
Substantial amounts of adhesive, toxicity is big;Come off or often maintenance is needed after damaging or is changed;
Some kitchen special coating scrub resistances do not reach actual use demand, and dry linting or paint can be produced after being cleaned with wet cloth
Film is damaged, bacterium of easily mildewing.
The content of the invention
Weak point present in regarding to the issue above, the present invention provides the easy polishing inner wall coating of high rigidity for kitchen use and system
Preparation Method.
To achieve the above object, the present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage
Meter, the coating includes following components:
Water 14~24%, wetting dispersing agent 0.4~0.6%, cellulose 0.2~0.25%, defoamer 0.1~0.2% is prevented
Freeze agent 0.8~1.2%, scratching resistant 0.3~0.6%, titanium dioxide 0~10%, calcite in powder 20~30%, pH adjusting agent 0.1
~0.2%, silane-siloxanes emulsion 40~50%, coalescents 2~2.5%, mould inhibitor 0.5~1%, bactericide 0.1~
0.3%, water-repelling agent 0.2~0.4%, anti-graffiti dose 0.2~0.3%.
The present invention also provides a kind of preparation method of the easy polishing inner wall coating of high rigidity for kitchen use, including:
Step 1, according to raw material proportioning, first add water in container, wetting and dispersing added under 300r/min rotating speed
Agent;Cellulose is slowly added to, 2min is stirred;Defoamer, antifreezing agent are added, is 500r/min by adjustment of rotational speed, stirs 5min;Plus
Enter scratching resistant, titanium dioxide, calcite in powder, be 1500r/min by adjustment of rotational speed, add pH adjusting agent, stir 30min;
Step 2, according to raw material proportioning, be slowly added under 800r/min rotating speeds silane-siloxanes emulsion, coalescents,
Mould inhibitor, bactericide, water-repelling agent and anti-graffiti dose, are prepared into the easy polishing inner wall coating of high rigidity for kitchen use.
Compared with prior art, beneficial effects of the present invention are:
The present invention selects silane-siloxanes emulsion, can by the mobility of the reactivity of silane and permeability and siloxanes and
Water droplet effect is combined, and molecular volume is minimum, and being coated in after substrate surface can depth infiltration base material.It can be with base material and itself hair
Raw reaction, so as to realize durability.After solidification, it is allowed to vapor penetrate into, but can prevent may containing dissolving after chlorion or
The aqueous water of acid penetrates into base material.It also occur that polycondensation reaction, constitutes Si-O-Si polymer, towards the alkane of outer side surface between silane
Base can be effectively hydrophobic, can provide the protection for being directed to impaired freeze thawing, infiltration, permeability and mould.
The present invention selects scratching resistant, significantly improves the durability of the hardness, wearability and coating of paint film, improves paint film
Adhesive force, greatly improves anti-stain characteristic, chemical resistance, scrub resistance and the water resistance of paint film.
The present invention is used cooperatively from water-repelling agent, anti-graffiti dose, reduces surface tension so that film coated surface hydrophobicity increases
By force, " lotus leaf effect " is produced, the globule can not be soaked, and prevent moisture from penetrating into, strengthens the stain resistance of paint film, and surface and oil contaminant is easily clear
Wash.
The present invention is not required construction method and personnel, can both be sprayed, and can be brushed again or roller coat, form of construction work is more
Sample, suitable small area and private finishing, are not required to prepare the construction tools such as air pump, tracheae, spray gun special.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the one of the present invention
Section Example, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not doing
The every other embodiment obtained on the premise of going out creative work, belongs to the scope of protection of the invention.
The present invention is described in further detail below:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 14~24%, wetting dispersing agent 0.4~0.6%, cellulose 0.2~0.25%, defoamer 0.1~0.2% is prevented
Freeze agent 0.8~1.2%, scratching resistant 0.3~0.6%, titanium dioxide 0~10%, calcite in powder 20~30%, pH adjusting agent 0.1
~0.2%, silane-siloxanes emulsion 40~50%, coalescents 2~2.5%, mould inhibitor 0.5~1%, bactericide 0.1~
0.3%, water-repelling agent 0.2~0.4%, anti-graffiti dose 0.2~0.3%.
Silane emulsion preparation method:Solvent and emulsifying agent are added, catalyst and thickener are added after dissolving, is added after emulsification
Emulsion acrylic resin, carry out high speed emulsification, adjustment system pH be 7-9, at a high speed emulsify after add stabilizer and sterilization and, after
Continuous emulsification, that is, complete.
Polysiloxanes uses emulsion polymerization:By the silicon monomers such as octamethylcy-clotetrasiloxane, water, emulsifying agent, catalyst etc.
Raw material, is emulsified and polymerization one with hydroxy-end capped aqueous emulsion of dimethyl polysiloxane fluid prepared by certain condition polymerize, in this method
Step is completed.
Silane-siloxanes emulsion is the mixed liquor of silane emulsion and silicone emulsion.
Wherein:
The wetting dispersing agent of the present invention is the Emulsogen LCN 070 of Clariant.
The cellulose of the present invention is Akzo Nobel Bermocoll E 451FQ.
The defoamer of the present invention is Cognis Foamaster DS, froth breaking persistent.
The antifreezing agent of the present invention is propane diols.
The scratching resistant of the present invention is the VK-S01W nano silicon water slurrys of Hangzhou Wanjing New Material Co., Ltd..
The titanium dioxide of the present invention is the R996 of the imperial boa in Sichuan.
The calcite in powder of the present invention is the CC-700 of Guangfu Building Materials (Jiaoling) Fine Chemicals Industry Co., Ltd..
The pH adjusting agent of the present invention is AMP-95.
The emulsion of the present invention is DOW CORNING IE6683 silane-siloxanes emulsions.
The coalescents of the present invention are Yi Shiman alcohol ester-12.
The mould inhibitor of the present invention is Lamberti Carbosan 802, and long-acting mould-proof algae preventive effect is amenable to high humidity ring
Border, wet rubbing and water drench.
The bactericide of the present invention is the BIT 10F of Clariant.
The water-repelling agent of the present invention is Tego Phobe 1500N, paint film is reached good lotus leaf effect, is improved hydrophobic
Property.
Anti-graffiti dose of the present invention is BYK-SILCLEAN 3720, and the easy-clear of greasy dirt can be dramatically increased after addition.
The present invention also provides a kind of preparation method of the easy polishing inner wall coating of high rigidity for kitchen use, including:
Step 1, according to raw material proportioning, first add water in container, wetting and dispersing added under 300r/min rotating speed
Agent;Cellulose is slowly added to, 2min is stirred;Defoamer, antifreezing agent are added, is 500r/min by adjustment of rotational speed, stirs 5min;Plus
Enter scratching resistant, titanium dioxide, calcite in powder, be 1500r/min by adjustment of rotational speed, add pH adjusting agent, stir 30min;
Step 2, according to raw material proportioning, be slowly added under 800r/min rotating speeds silane-siloxanes emulsion, coalescents,
Mould inhibitor, bactericide, water-repelling agent and anti-graffiti dose, are prepared into the easy polishing inner wall coating of high rigidity for kitchen use.
Embodiment 1:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 14.5%, wetting dispersing agent 0.4%, cellulose 0.2%, defoamer 0.1%, antifreezing agent 0.8%, scratching resistant
0.3%, titanium dioxide 0%, calcite in powder 30%, pH adjusting agent 0.1%, silane-siloxanes emulsion 50%, coalescents 2.5%,
Mould inhibitor 0.5%, bactericide 0.1%, water-repelling agent 0.2%, anti-graffiti dose 0.3%.
Embodiment 2:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 18.72%, wetting dispersing agent 0.5%, cellulose 0.23%, defoamer 0.15%, antifreezing agent 1%, scratch resistance
Agent 0.45%, titanium dioxide 5%, calcite in powder 25%, pH adjusting agent 0.15%, silane-siloxanes emulsion 45%, coalescents
2.3%, mould inhibitor 0.75%, bactericide 0.2%, water-repelling agent 0.3%, anti-graffiti dose 0.25%.
Embodiment 3:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 23.05%, wetting dispersing agent 0.6%, cellulose 0.25%, defoamer 0.2%, antifreezing agent 1.2%, scratch resistance
Agent 0.6%, titanium dioxide 10%, calcite in powder 20%, pH adjusting agent 0.2%, silane-siloxanes emulsion 40%, coalescents
2%, mould inhibitor 1%, bactericide 0.3%, water-repelling agent 0.4%, anti-graffiti dose 0.2%.
Embodiment 4:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 14%, wetting dispersing agent 0.4%, cellulose 0.2%, defoamer 0.1%, antifreezing agent 0.8%, scratching resistant
0.3%, titanium dioxide 0.5%, calcite in powder 30%, pH adjusting agent 0.1%, silane-siloxanes emulsion 50%, coalescents
2.5%, mould inhibitor 0.5%, bactericide 0.1%, water-repelling agent 0.2%, anti-graffiti dose 0.3%.
Embodiment 5:
The present invention provides a kind of easy polishing inner wall coating of high rigidity for kitchen use, by weight percentage, the coating include with
Lower component:
Water 24%, wetting dispersing agent 0.6%, cellulose 0.25%, defoamer 0.2%, antifreezing agent 1.2%, scratching resistant
0.6%, titanium dioxide 9.05%, calcite in powder 20%, pH adjusting agent 0.2%, silane-siloxanes emulsion 40%, coalescents
2%, mould inhibitor 1%, bactericide 0.3%, water-repelling agent 0.4%, anti-graffiti dose 0.2%.
In above-described embodiment 1-5, silane-siloxanes emulsion is the mixed liquor of silane emulsion and silicone emulsion.Wherein, silicon
Alkane emulsion preparation method:Solvent and emulsifying agent are added, catalyst and thickener are added after dissolving, acrylic resin is added after emulsification
Emulsion, carry out high speed emulsification, adjustment system pH be 7-9, at a high speed emulsify after add stabilizer and sterilization and, continue emulsify, i.e.,
Complete.Polysiloxanes uses emulsion polymerization:By originals such as the silicon monomers such as octamethylcy-clotetrasiloxane, water, emulsifying agent, catalyst
Material, with hydroxy-end capped aqueous emulsion of dimethyl polysiloxane fluid prepared by certain condition polymerize, emulsification and polymerisation step in this method
Complete.
The performance of interior wall coating prepared by above-described embodiment 1-5 is as shown in table 1:
Table 1
The present invention selects silane-siloxanes emulsion, can by the mobility of the reactivity of silane and permeability and siloxanes and
Water droplet effect is combined, and molecular volume is minimum, and being coated in after substrate surface can depth infiltration base material.It can be with base material and itself hair
Raw reaction, so as to realize durability.After solidification, it is allowed to vapor penetrate into, but can prevent may containing dissolving after chlorion or
The aqueous water of acid penetrates into base material.It also occur that polycondensation reaction, constitutes Si-O-Si polymer, towards the alkane of outer side surface between silane
Base can be effectively hydrophobic, can provide the protection for being directed to impaired freeze thawing, infiltration, permeability and mould.
The present invention selects scratching resistant, significantly improves the durability of the hardness, wearability and coating of paint film, improves paint film
Adhesive force, greatly improves anti-stain characteristic, chemical resistance, scrub resistance and the water resistance of paint film.
The present invention is used cooperatively from water-repelling agent, anti-graffiti dose, reduces surface tension so that film coated surface hydrophobicity increases
By force, " lotus leaf effect " is produced, the globule can not be soaked, and prevent moisture from penetrating into, strengthens the stain resistance of paint film, and surface and oil contaminant is easily clear
Wash.
The present invention is not required construction method and personnel, can both be sprayed, and can be brushed again or roller coat, form of construction work is more
Sample, suitable small area and private finishing, are not required to prepare the construction tools such as air pump, tracheae, spray gun special.
The preferred embodiments of the present invention are these are only, are not intended to limit the invention, for those skilled in the art
For member, the present invention can have various modifications and variations.Any modification within the spirit and principles of the invention, being made,
Equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (2)
1. a kind of easy polishing inner wall coating of high rigidity for kitchen use, it is characterised in that by weight percentage, the coating is comprising following
Component:
Water 14~24%, wetting dispersing agent 0.4~0.6%, cellulose 0.2~0.25%, defoamer 0.1~0.2%, antifreezing agent
0.8~1.2%, scratching resistant 0.3~0.6%, titanium dioxide 0~10%, calcite in powder 20~30%, pH adjusting agent 0.1~
0.2%, silane-siloxanes emulsion 40~50%, coalescents 2~2.5%, mould inhibitor 0.5~1%, bactericide 0.1~
0.3%, water-repelling agent 0.2~0.4%, anti-graffiti dose 0.2~0.3%.
2. a kind of preparation method of the easy polishing inner wall coating of high rigidity for kitchen use as claimed in claim 1, it is characterised in that bag
Include:
Step 1, according to raw material proportioning, first add water in container, wetting dispersing agent added under 300r/min rotating speed;It is slow
It is slow to add cellulose, stir 2min;Defoamer, antifreezing agent are added, is 500r/min by adjustment of rotational speed, stirs 5min;Add anti-
Agent, titanium dioxide, calcite in powder are scratched, is 1500r/min by adjustment of rotational speed, adds pH adjusting agent, stir 30min;
Step 2, according to raw material proportioning, silane-siloxanes emulsion is slowly added under 800r/min rotating speeds, coalescents, mould proof
Agent, bactericide, water-repelling agent and anti-graffiti dose, are prepared into the easy polishing inner wall coating of high rigidity for kitchen use.
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Cited By (2)
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CN108329829A (en) * | 2017-10-31 | 2018-07-27 | 河北晨阳工贸集团有限公司 | Interior wall coating and its preparation method and application |
CN109652007A (en) * | 2018-12-06 | 2019-04-19 | 成都硅宝科技股份有限公司 | Impervious oily bi-component silicone sealant of one kind and preparation method thereof |
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CN103725141A (en) * | 2013-12-17 | 2014-04-16 | 江苏苏博特新材料股份有限公司 | Water-based emulsion for protecting external wall of building and preparation method for water-based emulsion |
CN105670497A (en) * | 2014-11-21 | 2016-06-15 | 沈阳顺风新城建筑材料有限公司 | Exterior wall alkali resistant seal primer |
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CN103725141A (en) * | 2013-12-17 | 2014-04-16 | 江苏苏博特新材料股份有限公司 | Water-based emulsion for protecting external wall of building and preparation method for water-based emulsion |
CN105670497A (en) * | 2014-11-21 | 2016-06-15 | 沈阳顺风新城建筑材料有限公司 | Exterior wall alkali resistant seal primer |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108329829A (en) * | 2017-10-31 | 2018-07-27 | 河北晨阳工贸集团有限公司 | Interior wall coating and its preparation method and application |
CN109652007A (en) * | 2018-12-06 | 2019-04-19 | 成都硅宝科技股份有限公司 | Impervious oily bi-component silicone sealant of one kind and preparation method thereof |
CN109652007B (en) * | 2018-12-06 | 2021-05-18 | 成都硅宝科技股份有限公司 | Oil-seepage-resistant bi-component silicone sealant and preparation method thereof |
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