CN107029761A - A kind of preparation method of support type silver phosphate photocatalyst - Google Patents
A kind of preparation method of support type silver phosphate photocatalyst Download PDFInfo
- Publication number
- CN107029761A CN107029761A CN201710201051.4A CN201710201051A CN107029761A CN 107029761 A CN107029761 A CN 107029761A CN 201710201051 A CN201710201051 A CN 201710201051A CN 107029761 A CN107029761 A CN 107029761A
- Authority
- CN
- China
- Prior art keywords
- silver
- phosphoric acid
- zinc
- brush
- sediment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 title abstract description 13
- 239000011941 photocatalyst Substances 0.000 title description 12
- 229940019931 silver phosphate Drugs 0.000 title description 11
- 229910000161 silver phosphate Inorganic materials 0.000 title description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 24
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000084 colloidal system Substances 0.000 claims abstract description 15
- NDYNABNWLRVCDO-UHFFFAOYSA-N phosphoric acid silver Chemical compound [Ag].P(O)(O)(O)=O NDYNABNWLRVCDO-UHFFFAOYSA-N 0.000 claims abstract description 15
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 229910000397 disodium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims abstract description 6
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000005083 Zinc sulfide Substances 0.000 claims abstract 7
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000013049 sediment Substances 0.000 claims abstract 6
- 150000001875 compounds Chemical class 0.000 claims abstract 4
- 238000010438 heat treatment Methods 0.000 claims abstract 4
- 239000011259 mixed solution Substances 0.000 claims abstract 4
- 239000000843 powder Substances 0.000 claims abstract 4
- 238000005406 washing Methods 0.000 claims abstract 4
- 239000000243 solution Substances 0.000 claims abstract 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract 2
- 239000008367 deionised water Substances 0.000 claims abstract 2
- 229910021641 deionized water Inorganic materials 0.000 claims abstract 2
- 238000001556 precipitation Methods 0.000 claims abstract 2
- 238000000926 separation method Methods 0.000 claims abstract 2
- 239000006228 supernatant Substances 0.000 claims abstract 2
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims abstract 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims abstract 2
- 235000009529 zinc sulphate Nutrition 0.000 claims abstract 2
- 239000011686 zinc sulphate Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- XRRQZKOZJFDXON-UHFFFAOYSA-N nitric acid;silver Chemical compound [Ag].O[N+]([O-])=O XRRQZKOZJFDXON-UHFFFAOYSA-N 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000003643 water by type Substances 0.000 claims 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 claims 1
- 235000013904 zinc acetate Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 14
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000004246 zinc acetate Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- 239000011248 coating agent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 14
- 239000011521 glass Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- GQSZSSZBQBNNQF-UHFFFAOYSA-N ethanol;styrene Chemical compound CCO.C=CC1=CC=CC=C1 GQSZSSZBQBNNQF-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000004042 decolorization Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- YYYARFHFWYKNLF-UHFFFAOYSA-N 4-[(2,4-dimethylphenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=C12 YYYARFHFWYKNLF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 229940043267 rhodamine b Drugs 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- -1 Disodium hydrogen Chemical class 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
-
- B01J35/39—
-
- B01J35/59—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The present invention discloses a kind of preparation method of the silver-colored photochemical catalyst of zinc sulphide compound phosphoric acid.In turn include the following steps：Zinc acetate and thioacetamide and cetyl trimethylammonium bromide are added in deionized water, stirring is to being completely dissolved, obtain mixed solution, mixed solution is transferred to water heating kettle and is placed in 105~140 DEG C of heated at constant temperature in baking oven, question response takes out water heating kettle after terminating, and naturally cools to and supernatant is discarded after room temperature, collects sediment, washing, freeze-day with constant temperature, obtain zinc sulfide powder；Silver nitrate solution and disodium phosphate soln are mixed, yellow green colloid substance is formed, phosphoric acid silver colloid is generated；Obtained zinc sulphate powder is added in phosphoric acid silver colloid, stirring, precipitation separation, washing, drying produce a kind of silver-colored photochemical catalyst of zinc sulphide compound phosphoric acid.Silver orthophosphate is effectively distributed without assembling, and in the smaller particle of vulcanization zinc surface formation, improve catalytic activity.It can make zinc sulphide that there is visible light catalytic effect.
Description
Technical field
The present invention relates to a kind of preparation method for being used to handle the support type silver phosphate photocatalyst of organic wastewater, belong to and urge
Change field of material preparation.
Background technology
In the industrial wastewaters such as sanitary sewage, food processing and papermaking, contain carbohydrate, protein, grease, wooden
The organic substances such as element.These materials, can be by the biological chemistry action of microorganism to suspend or dissolved state is present in sewage
And decompose.Need to consume oxygen in its decomposable process, thus be referred to as oxygen consumption pollutant.This pollutant can cause molten in water
Solve oxygen to reduce, the growth of influence fish and other aquatiles.After oxygen in water exhausts, organic matter carries out anaerobic digestion, production
The bad smells such as raw hydrogen sulfide, ammonia and mercaptan, make water quality deterioration.
With the development of production, the murder by poisoning organic pollution produced in industrial and agricultural production seriously threatens environment and people
The health of class, seeks a kind of new and effective environmental improvement technology and has great importance.Photocatalysis technology is because of its energy-conservation, height
Effect, contaminant degradation are thorough, non-secondary pollution advantage, turn into a kind of emerging environmental improvement with important application prospect at present
Technology.In recent years, the development of new and effective visible-light photocatalyst turns into an important research content in photocatalysis technology.
In June, 2010, material research institution researcher has found that silver orthophosphate has the effect of photochemical catalyst, and photooxidation effect is
It is more than the decades of times for being currently known various photochemical catalysts.Because its unique Surface Physical Chemistry property and efficient visible ray light are urged
Change one of performance, focus as research.
But nanoparticles are easily reunited, surface area is greatly reduced after reunion, decreased effectiveness.Need to use appropriate carrier
Or change catalyst macrostructure to obtain preferable catalytic effect.
The content of the invention
The purpose of the present invention be for overcome in the prior art particulate matter be easy to reunion and cause effect difference etc. not enough there is provided one kind
The preparation method of support type silver phosphate photocatalyst.
The technical solution adopted by the present invention is in turn include the following steps：
1) in 10~30cm2It is molten that clean Quartz glass surfaces dip in the styrene ethanol that concentration is 2~6mol/L with brush
Liquid brush places 10~12h, then one layer of brush in atmosphere in quartz glass both side surface after drying naturally, then after drying naturally
Place 10~12h in atmosphere, then one layer of brush, 4~5 layers of brush altogether per side obtain a layers of polymer in quartz glass both side surface
Styrene；
2) quartz glass is placed in Muffle furnace, under nitrogen protection, is progressively warming up to 400~550 DEG C, and keep being somebody's turn to do
1~2h of temperature, is made the quartz glass of carbon-coating covering；
3) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid is weighed
Disodium hydrogen, is configured to 20mmol/L disodium phosphate soln；
4) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, continued
3~4h is stirred, disodium hydrogen phosphate and nitric acid silver reaction in whipping process generate phosphoric acid silver colloid；
5) phosphoric acid silver colloid brush is dipped with brush in both side surface of the quartz glass covered with carbon-coating, after drying naturally again
One layer of brush, then one layer of brush again after drying naturally, 4~5 layers of brush altogether per side, thin layer phosphorus is obtained on quartz glass carbon-coating surface
Sour Argent grain, is made support type silver phosphate photocatalyst.
The beneficial effects of the invention are as follows：
After Quartz glass surfaces obtain polystyrene film by the method for rendering, high temperature cabonization, acquisition carbon-coating, and
Accelerate electron transmission using colloidal property formation catalyst film, obtain preferable degradation effect in carbon-coating surface.
Embodiment
3 embodiments of the present invention are provided further below：
Embodiment 1
In 30cm2Clean Quartz glass surfaces dip in styrene ethanol solution brush that concentration is 6mol/L with brush in quartz
Glass both side surface, places 12h, then one layer of brush in atmosphere after drying naturally, then places in atmosphere after drying naturally
12h, then one layer of brush, per side 5 layers of brush altogether, the styrene of a layers of polymer is obtained in quartz glass both side surface；By the quartzy glass
Glass is placed in Muffle furnace, under nitrogen protection, is progressively warming up to 550 DEG C, and keeps temperature 2h, and the quartz of carbon-coating covering is made
Glass；24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates is weighed, is configured to
20mmol/L disodium phosphate soln；Both the above solution is mixed under 400 revs/min of rotating speed, yellowish green coloring agent is formed
Shape material, persistently stirs 4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；Dipped in brush
Phosphoric acid silver colloid brush is taken in both side surface of the quartz glass covered with carbon-coating, one layer of the brush, then dry naturally again after drying naturally
One layer of brush again afterwards, 5 layers of brush altogether per side, obtains thin layer phosphoric acid Argent grain on quartz glass carbon-coating surface, support type is made
Silver phosphate photocatalyst.
Obtained support type silver phosphate photocatalyst is used to handle waste water containing acid scarlet：By obtained support type phosphoric acid
Silver-colored photochemical catalyst is placed in the waste water containing acid scarlet that pending 50mL concentration is 20mg/L, and light is penetrated in phosphoric acid silver surface,
Under the irradiation of 300W Metal halogen lamps, 40min is reacted, percent of decolourization is 97.9%.
Embodiment 2
In 10cm2Clean Quartz glass surfaces dip in styrene ethanol solution brush that concentration is 2mol/L with brush in quartz
Glass both side surface, places 10h, then one layer of brush in atmosphere after drying naturally, then places in atmosphere after drying naturally
10h, then one layer of brush, per side 4 layers of brush altogether, the styrene of a layers of polymer is obtained in quartz glass both side surface；By the quartzy glass
Glass is placed in Muffle furnace, under nitrogen protection, is progressively warming up to 400 DEG C, and keeps temperature 1h, and the quartz of carbon-coating covering is made
Glass；20mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6mmol disodium hydrogen phosphates is weighed, is configured to
20mmol/L disodium phosphate soln；Both the above solution is mixed under 350 revs/min of rotating speed, yellowish green coloring agent is formed
Shape material, persistently stirs 3h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；Dipped in brush
Phosphoric acid silver colloid brush is taken in both side surface of the quartz glass covered with carbon-coating, one layer of the brush, then dry naturally again after drying naturally
One layer of brush again afterwards, 4 layers of brush altogether per side, obtains thin layer phosphoric acid Argent grain on quartz glass carbon-coating surface, support type is made
Silver phosphate photocatalyst.
Obtained support type silver phosphate photocatalyst is used to handle wastewater containing methylene blue：By obtained support type phosphoric acid
Silver-colored photochemical catalyst is placed in the wastewater containing methylene blue that pending 50mL concentration is 20mg/L, light irradiation in phosphoric acid silver surface,
Under the irradiation of 300W Metal halogen lamps, 40min is reacted, percent of decolourization is 96.5%.
Embodiment 3
In 20cm2Clean Quartz glass surfaces dip in styrene ethanol solution brush that concentration is 4mol/L with brush in quartz
Glass both side surface, places 12h, then one layer of brush in atmosphere after drying naturally, then places in atmosphere after drying naturally
12h, then one layer of brush, per side 5 layers of brush altogether, the styrene of a layers of polymer is obtained in quartz glass both side surface；By the quartzy glass
Glass is placed in Muffle furnace, under nitrogen protection, is progressively warming up to 550 DEG C, and keeps temperature 2h, and the quartz of carbon-coating covering is made
Glass；24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates is weighed, is configured to
20mmol/L disodium phosphate soln；Both the above solution is mixed under 350 revs/min of rotating speed, yellowish green coloring agent is formed
Shape material, persistently stirs 4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；Dipped in brush
Phosphoric acid silver colloid brush is taken in both side surface of the quartz glass covered with carbon-coating, one layer of the brush, then dry naturally again after drying naturally
One layer of brush again afterwards, 4 layers of brush altogether per side, obtains thin layer phosphoric acid Argent grain on quartz glass carbon-coating surface, support type is made
Silver phosphate photocatalyst.
Obtained support type silver phosphate photocatalyst is used to handle and contains rhodamine B：By obtained support type phosphoric acid
Silver-colored photochemical catalyst is placed in pending 50mL concentration containing in rhodamine B for 20mg/L, light irradiation in phosphoric acid silver surface,
Under the irradiation of 300W Metal halogen lamps, 40min is reacted, percent of decolourization is 96.5%.
Claims (1)
1. the preparation method of the silver-colored photochemical catalyst of a kind of zinc sulphide compound phosphoric acid, it is characterized in that in turn including the following steps：
1) 1~5g zinc acetates and 3~20g thioacetamides and 0.5~1.2g cetyl trimethylammonium bromides are added to 40~
In 80mL deionized waters, stir to being completely dissolved, obtain mixed solution, mixed solution is transferred into water heating kettle is placed in baking oven
105~140 DEG C of 24~36h of heated at constant temperature, question response takes out water heating kettle after terminating, naturally cools to and supernatant is discarded after room temperature,
Collect sediment；
2) above-mentioned sediment is washed each 3~4 times with deionized water and absolute ethyl alcohol respectively, by the sediment after washing 50~
Freeze-day with constant temperature at 70 DEG C, obtains zinc sulfide powder；
3) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid hydrogen two is weighed
Sodium, is configured to 20mmol/L disodium phosphate soln；
4) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, lasting stirring
3~4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process generate phosphoric acid silver colloid；
5) obtained zinc sulphate powder is added in phosphoric acid silver colloid, stirs 3~4h, precipitation separation is washed with deionized
Sediment 4~5 times, will be dried at 105 DEG C of sediment after washing, produce a kind of silver-colored photochemical catalyst of zinc sulphide compound phosphoric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201051.4A CN107029761A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of support type silver phosphate photocatalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201051.4A CN107029761A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of support type silver phosphate photocatalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107029761A true CN107029761A (en) | 2017-08-11 |
Family
ID=59533473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710201051.4A Pending CN107029761A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of support type silver phosphate photocatalyst |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107029761A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115475635A (en) * | 2022-10-12 | 2022-12-16 | 华东师范大学 | Photocatalytic device with silver phosphate loaded in transparent medium tube and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103506142A (en) * | 2013-10-08 | 2014-01-15 | 江苏大学 | Molybdenum disulfide/silver phosphate composite visible light photocatalytic material and preparation method thereof |
| CN103623803A (en) * | 2012-08-30 | 2014-03-12 | 上海纳晶科技有限公司 | Visible light photocatalyst and preparation method therefor |
| CN104324740A (en) * | 2014-10-11 | 2015-02-04 | 武汉理工大学 | Flower-shaped MoS2 loaded Ag3PO4 nanosphere composite visible light catalyst and preparation method thereof |
| CN104437548A (en) * | 2013-09-12 | 2015-03-25 | 华东师范大学 | Visible light photocatalytic film and preparation method thereof and lighting lamp with visible light photocatalytic film |
| CN105170165A (en) * | 2015-09-07 | 2015-12-23 | 武汉理工大学 | Flake Ag2S-loaded Ag3PO4 nano-sphere composite visible light catalyst and preparation method thereof |
-
2017
- 2017-03-30 CN CN201710201051.4A patent/CN107029761A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103623803A (en) * | 2012-08-30 | 2014-03-12 | 上海纳晶科技有限公司 | Visible light photocatalyst and preparation method therefor |
| CN104437548A (en) * | 2013-09-12 | 2015-03-25 | 华东师范大学 | Visible light photocatalytic film and preparation method thereof and lighting lamp with visible light photocatalytic film |
| CN103506142A (en) * | 2013-10-08 | 2014-01-15 | 江苏大学 | Molybdenum disulfide/silver phosphate composite visible light photocatalytic material and preparation method thereof |
| CN104324740A (en) * | 2014-10-11 | 2015-02-04 | 武汉理工大学 | Flower-shaped MoS2 loaded Ag3PO4 nanosphere composite visible light catalyst and preparation method thereof |
| CN105170165A (en) * | 2015-09-07 | 2015-12-23 | 武汉理工大学 | Flake Ag2S-loaded Ag3PO4 nano-sphere composite visible light catalyst and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115475635A (en) * | 2022-10-12 | 2022-12-16 | 华东师范大学 | Photocatalytic device with silver phosphate loaded in transparent medium tube and preparation method |
| CN115475635B (en) * | 2022-10-12 | 2023-06-23 | 华东师范大学 | Photocatalytic device for loading silver phosphate in transparent medium tube and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103623849B (en) | A kind of Graphene/BiOCl xbr 1-xmicro-nano composite photo-catalyst and preparation method thereof | |
| CN102764650B (en) | Modified titanium dioxide/ bamboo charcoal composite material and preparation method thereof | |
| CN109847786A (en) | A kind of preparation method and application of Z-type photochemical catalyst MgAlLDH/CN-H | |
| CN105080526B (en) | A kind of titanium dioxide-diatom ooze composite process of indoor formaldehyde degradation by photocatalytic oxidation process prepared by biological template | |
| CN112108150A (en) | Based on magnetic Fe3O4Modified corncob biomass carbon dot composite Bi2WO6Preparation method and application of photocatalyst | |
| CN109226240B (en) | Catalytic type contaminated soil remediation device | |
| CN103230802A (en) | Preparation method of composite photocatalyst with visible light response and arsenic removing method | |
| CN106824227A (en) | A kind of In2S3/Zn2GeO4The preparation method and application of composite visible light catalyst | |
| CN103272647B (en) | A kind of preparation method for dye decolored cellulose base ZnO-CdS composite photo-catalyst | |
| CN109675547A (en) | A kind of preparation method and applications of hollow cube type zinc stannate photochemical catalyst | |
| CN102553649B (en) | 17beta-estradiol molecular imprinted silver-doped TiO2 nanotube and preparation method thereof | |
| CN107486200A (en) | A kind of preparation method of the compound wolframic acid Mn catalyst of carbon | |
| CN106925253A (en) | A kind of preparation method of nanoscale ozone oxidation catalyst and application | |
| CN107029761A (en) | A kind of preparation method of support type silver phosphate photocatalyst | |
| CN103721713A (en) | Three-phase composite visible-light-driven photocatalyst capable of efficiently degrading dyes | |
| CN107008464B (en) | A kind of visible light-responded NaYF4:La,Ce@TiO2The preparation method and application of composite material | |
| CN106944066A (en) | A kind of preparation method of hud typed nickel oxide/nickel photochemical catalyst | |
| CN103506104A (en) | Carbon-doped TiO2 visible light-responding catalytic film on glass carrier and preparation method thereof | |
| CN102698786A (en) | Method for preparing titanium dioxide photocatalyst carried by nitric-acid-modified coal ash serving as carrier | |
| CN103787413B (en) | Hexagon hollow tubulose Bi 2o (OH) 2sO 4the preparation method of photochemical catalyst and application | |
| CN103127943B (en) | Preparation method of FeS2/S composite material, and application of FeS2/S composite material | |
| CN110152687A (en) | A method of composite photo-catalyst is prepared using Natural pyrite | |
| CN105129903A (en) | Titanium dioxide sieve for photocatalytic treatment of phenol-containing wastewater | |
| CN109663590A (en) | It is a kind of using egg shell as catalysis material of reactor and the preparation method and application thereof | |
| CN109095546A (en) | A kind of method of photocatalysis treatment of waste water collaboration hydrogen making |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170811 |