CN107020382A - Complex sintered wearing plate, preparation method and Special agitating mixing device - Google Patents

Complex sintered wearing plate, preparation method and Special agitating mixing device Download PDF

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Publication number
CN107020382A
CN107020382A CN201710365434.5A CN201710365434A CN107020382A CN 107020382 A CN107020382 A CN 107020382A CN 201710365434 A CN201710365434 A CN 201710365434A CN 107020382 A CN107020382 A CN 107020382A
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China
Prior art keywords
copper powder
powder
mixing tank
graphene
substrate
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CN201710365434.5A
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CN107020382B (en
Inventor
崔明辉
郑黎明
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SHENZHEN YUANZHENG POLYMER COMPOSITE MATERIAL CO Ltd
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SHENZHEN YUANZHENG POLYMER COMPOSITE MATERIAL CO Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • B22F7/04Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers with one or more layers not made from powder, e.g. made from solid metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B01F33/402Mixers using gas or liquid agitation, e.g. with air supply tubes comprising supplementary stirring elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B01F33/406Mixers using gas or liquid agitation, e.g. with air supply tubes in receptacles with gas supply only at the bottom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/70Mixers specially adapted for working at sub- or super-atmospheric pressure, e.g. combined with de-foaming
    • B01F33/71Mixers specially adapted for working at sub- or super-atmospheric pressure, e.g. combined with de-foaming working at super-atmospheric pressure, e.g. in pressurised vessels
    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/26Mixing ingredients for casting metals

Abstract

The invention belongs to complex sintered wearing plate and preparation method technical field, a kind of complex sintered wearing plate, preparation method and Special agitating mixing device are disclosed.It is mainly characterized in that:Including substrate, the substrate side is provided with mat surface, copper powder layer is provided with the outside of the mat surface, copper powder layer lateral surface is provided with graphene copper powder mixed layer, the Graphene powder and copper powder weight ratio are 1-2:100, the Graphene powder and the granular size of copper powder are 200 --- 300 mesh, so, graphene copper powder mixed layer is combined more firm with substrate, the content of graphene is high, high lubricating effect, the product coefficient of friction such as the bearing being made is low, substantially prolongs service life, in admixed graphite alkene powder and copper powder, first mixing tank is evacuated, then gases at high pressure are blown into batch mixing pot bottom, and open rabbling mechanism, so, batch mixing is more uniform, can effectively improve Graphene powder content, improves the anti-wear performance of complex sintered wearing plate.

Description

Complex sintered wearing plate, preparation method and Special agitating mixing device
Technical field
The invention belongs to complex sintered wearing plate, process equipment and preparation method technical field, more particularly to one kind are compound Sintered wear-resistant plate, preparation method and Special agitating mixing device.
Background technology
In fields such as motor-driven bearings, in order to improve anti-wear performance, using sintered wear-resistant plate, one layer of sintering is resistance on steel plate The copper powder of mill or other powder, armor plate strength and impact resistance are stronger, and copper powder or other powder anti-wear performances are good, therefore its Combination property is greatly improved.In order to improve anti-wear performance, using adding Graphene powder in copper powder.Due to copper powder and Graphene powder Density it is different, mixed using current mixer, mix uneven when causing copper powder and Graphene powder to mix, the sintering of production Wearing plate anti-wear performance is unstable, and the bearing friction coefficient of production is different, and copper powder and Graphene powder easily come off, product matter Amount is poor, and the content of graphene is low, does not have fine lubricant effect, and coefficient of friction is high, and service life is short.
The content of the invention
The invention solves the problems that first technical problem be just to provide a kind of good anti-wear performance, copper powder and Graphene powder and do not allow The complex sintered wearing plate of easy to fall off, high lubricating effect, service life length.
To solve the above problems, the technical scheme that uses of complex sintered wearing plate of the invention for:Including substrate, in the base Plate side is provided with mat surface, and copper powder layer is provided with the outside of the mat surface, and copper powder layer lateral surface is provided with graphite Alkene copper powder mixed layer, the Graphene powder and copper powder weight ratio are 1-2:100, the granular size of the Graphene powder and copper powder For 200 --- 300 mesh.
Its additional technical feature is:
The Graphene powder and copper powder weight ratio are 1.7-1.8:100, the granular size of the Graphene powder and copper powder is 270 --- 280 mesh.
Complex sintered wearing plate provided by the present invention compared with prior art, with advantages below:First, due to including Substrate, mat surface is provided with the substrate side, and copper powder layer is provided with the outside of the mat surface, on the outside of copper powder layer Face is provided with graphene copper powder mixed layer, and the Graphene powder and copper powder weight ratio are 1-2:100, the Graphene powder and copper The granular size of powder is 200 --- 300 mesh, so, graphene copper powder mixed layer is combined with substrate more firm, and graphene contains Amount is high, high lubricating effect, and the product coefficient of friction such as bearing being made is low, substantially prolongs service life;Second, due to the stone Black alkene powder and copper powder weight ratio are 1.7-1.8:100, the granular size of the Graphene powder and copper powder is 270 --- 280 mesh, The coefficient of friction of complex sintered wearing plate provided by the present invention than existing complex sintered wearing plate coefficient of friction reduction half with On.
The invention solves the problems that second technical problem be just to provide during a kind of above-mentioned complex sintered wearing plate of production Stir mixing device.
To solve the above problems, the technical scheme that uses of stir mixing device of the present invention for:Including support body and mixing tank, The outside uniform air distribution plate connected with inflation mechanism is provided with below the mixing tank, be provided with the uniform air distribution plate into Stomata, is being provided with agitating shaft close to the mixing tank top, stirring wing is provided with the agitating shaft, the bottom Stirring wing lower surface is provided with charge door and exhaust apart from 20-30 centimetres of the batch mixing pot bottom above the mixing tank Mouthful, it is provided with discharging opening below the mixing tank.
Its additional technical feature is:
Described exhaust outlet is connected with vacuum extractor.
Stir mixing device provided by the present invention compared with prior art, with advantages below:First, due to including frame Body and mixing tank, are provided with the outside uniform air distribution plate connected with inflation mechanism, in the uniform cloth below the mixing tank Air admission hole is provided with gas plate, the mixing tank top is being provided with agitating shaft, stirring is provided with the agitating shaft Wing, the stirring wing lower surface of the bottom is set apart from 20-30 centimetres of the batch mixing pot bottom above the mixing tank Have charge door and exhaust outlet, Graphene powder and copper powder added in the mixing tank of stir mixing device, pave rear Graphene powder and Distance of the upper surface of copper powder apart from the stirring wing lower surface of bottom is more than or equal to 5 centimetres, and high pressure gas is filled with into mixing tank Body, gases at high pressure blow afloat Graphene powder and copper powder from batch mixing pot bottom, are suspended in mixing tank, are stirred while opening stirring shaft Mix, stirring wing stirs Graphene powder and copper powder, as the air pressure inside mixing tank increases, the pressure in mixing tank With when gas pressure intensity is equal in inflation mechanism, stopping supply, stop stirring after 2-3 minutes, Graphene powder and copper powder are made in gravity Fallen under, slowly open exhaust outlet, the gas in mixing tank is discharged, Graphene powder and copper powder mixing are more uniform;Improve Complex sintered wearing plate overall wear resistance energy;Second, because described exhaust outlet is connected with described vacuum extractor, in institute State in first step batch mixing step, after Graphene powder and copper powder are added in the mixing tank of stir mixing device, open and exhaust Mixing tank, is first evacuated, is then filled with gases at high pressure into mixing tank again by the vacuum extractor of mouth connection, so, takes out true After sky, the pressure reduction above Graphene powder and copper powder, it is easy to blown afloat, batch mixing is more uniform.
The invention solves the problems that the 3rd technical problem be just to provide a kind of preparation method of above-mentioned complex sintered wearing plate.
To solve the above problems, the technical scheme that uses of complex sintered wearing plate of the invention for:This method includes following step Suddenly:
The first step, batch mixing
In the mixing tank that Graphene powder and copper powder are added to stir mixing device, pave the upper surface of rear Graphene powder and copper powder away from From being more than or equal to 5 centimetres with a distance from the stirring wing lower surface of bottom, gases at high pressure are filled with into mixing tank, gases at high pressure are by stone Black alkene powder and copper powder are blown afloat from batch mixing pot bottom, are suspended in mixing tank, while opening stirring shaft stirring, stirring wing is by graphite Alkene powder and copper powder stir, as the air pressure inside mixing tank increases, gas in the pressure and inflation mechanism in mixing tank When body pressure is equal, stop supply, stop stirring after 2-3 minutes, Graphene powder and copper powder fall, slowly beaten under gravity Begun to rehearse gas port, and the gas in mixing tank is discharged;Mixed mixed powder is taken out standby from the discharging opening of mixing tank;
Second step, substrate processing
According to required dimensioned substrate, and substrate side is processed into mat surface;
3rd step, lays copper powder
Copper powder is laid above the mat surface;
4th step, makes copper powder substrate
The substrate for being covered with copper powder is placed in sintering furnace and sintered, sintering temperature is controlled in 800 DEG C -900 DEG C, sintering time control System was at 25-35 minutes, after the completion of sintering, cools 25-35 minutes, copper powder substrate is made;
5th step, mixed powder is routed on copper powder substrate and cooling is sintered
The mixed powder mixed is routed on copper powder substrate, is then placed within sintering furnace and sinters, sintering temperature control exists 800 DEG C -900 DEG C, sintering time was controlled at 25-35 minutes, after the completion of sintering, is cooled 25-35 minutes, is made complex sintered resistance to Nog plate.
Its additional technical feature is:It is mixed Graphene powder and copper powder are added into stirring in the first step batch mixing step After expecting in the mixing tank of device, the vacuum extractor connected with exhaust outlet is opened, first mixing tank is evacuated, then again to mixed Gases at high pressure are filled with batch can.
After above method batch mixing and sintering, because Graphene powder and copper powder are well mixed, contain improving Graphene powder In the case of amount, Graphene powder and copper powder also will not fall off.
Brief description of the drawings
Fig. 1 is the structural representation of complex sintered wearing plate of the invention;
Fig. 2 is the structural representation of stir mixing device.
Embodiment
With reference to the accompanying drawings and detailed description to complex sintered wearing plate of the invention, the structure of stir mixing device and Use principle and the preparation method of above-mentioned complex sintered wearing plate are described in further details.
As shown in figure 1, the structural representation of complex sintered wearing plate of the invention, complex sintered wearing plate of the invention includes base Plate 1, mat surface 2 is provided with the side of substrate 1, and copper powder layer 3 is provided with the outside of mat surface 2, is set in the lateral surface of copper powder layer 3 Graphene copper powder mixed layer 4 is equipped with, Graphene powder and copper powder weight ratio are 1-2:100, the granular size of Graphene powder and copper powder For 200 --- 300 mesh.So, graphene copper powder mixed layer 4 is combined more firm, the content height of graphene, lubrication with substrate 1 Effect is good, and the product coefficient of friction such as bearing being made is low, substantially prolongs service life.
Graphene powder and copper powder weight ratio are 1.7-1.8:100, the granular size of Graphene powder and copper powder is 270 --- 280 mesh, the coefficient of friction of complex sintered wearing plate provided by the present invention is reduced than the coefficient of friction of existing complex sintered wearing plate More than half.
As shown in Fig. 2 the structural representation of stir mixing device.Stir mixing device of the present invention includes support body 5 and batch mixing Tank 6, the outside uniform air distribution plate 8 connected with inflation mechanism 7 is provided with below mixing tank 6, is provided with uniform air distribution plate 8 Air admission hole 9, is being provided with agitating shaft 10 close to the top of mixing tank 6, be provided with stirring wing 11 on agitating shaft 10, and bottom is stirred The lower surface of wing 11 is mixed apart from 20-30 centimetres of the bottom of mixing tank 6, the top of mixing tank 6 is provided with charge door 12 and exhaust outlet 13, discharging opening 14 is provided with below mixing tank 6, Graphene powder and copper powder are added in the mixing tank 6 of stir mixing device, paving Distance of the upper surface of Graphene powder and copper powder apart from the stirring wing lower surface of bottom is more than or equal to 5 centimetres after flat, to batch mixing Gases at high pressure are filled with tank 6, Graphene powder and copper powder are blown afloat, be suspended in mixing tank 6, together by gases at high pressure from batch mixing pot bottom Shi Kaiqi stirring shafts 10 are stirred, and stirring wing 11 stirs Graphene powder and copper powder, with the air pressure inside mixing tank 6 Power increases, and the pressure in mixing tank 6 stops stirring with when gas pressure intensity is equal in inflation mechanism, stopping supply after 2-3 minutes, Graphene powder and copper powder are fallen under gravity, slowly open exhaust outlet, by mixing tank gas discharge, Graphene powder and Copper powder mixing is more uniform;Improve complex sintered wearing plate overall wear resistance energy.
Exhaust outlet 13 is connected with vacuum extractor 15, in first step batch mixing step, is added by Graphene powder and copper powder After in the mixing tank 6 of stir mixing device, the vacuum extractor 14 connected with exhaust outlet 13 is opened, is first pumped into mixing tank 6 very Sky, is then filled with gases at high pressure into mixing tank 6 again, so, after vacuumizing, the pressure reduction above Graphene powder and copper powder, It is easy to be blown afloat, batch mixing is more uniform.
The method that complex sintered wearing plate is prepared using above-mentioned stir mixing device, this method is comprised the following steps:
The first step, batch mixing
Graphene powder and copper powder are added in the mixing tank 6 of stir mixing device 5, the upper surface of rear Graphene powder and copper powder is paved Distance apart from the lower surface of stirring wing 11 of bottom is more than or equal to 5 centimetres, and gases at high pressure, high pressure gas are filled with into mixing tank 6 Body blows afloat Graphene powder and copper powder from the bottom of mixing tank 6, is suspended in mixing tank 6, stirs, stirs while opening stirring shaft 10 Mix wing 11 Graphene powder that left floating and copper powder stir, as the air pressure inside mixing tank increases, in mixing tank Pressure with when gas pressure intensity is equal in inflation mechanism, stop supply, after 2-3 minute stop stir, Graphene powder and copper powder exist Fallen under Action of Gravity Field, after Graphene powder and copper powder are all fallen, exhaust outlet 13 is slowly opened, by the gas in mixing tank 6 Discharge;Mixed mixed powder is taken out standby from the discharging opening 14 of mixing tank;
Second step, substrate processing
According to required dimensioned substrate, and substrate side is processed into mat surface;
3rd step, lays copper powder
Copper powder is laid above the mat surface;
4th step, makes copper powder substrate
The substrate for being covered with copper powder is placed in sintering furnace and sintered, sintering temperature is controlled in 800 DEG C -900 DEG C, sintering time control System was at 25-35 minutes, after the completion of sintering, cools 25-35 minutes, copper powder substrate is made;
5th step, mixed powder is routed on copper powder substrate and cooling is sintered
The mixed powder mixed is routed on copper powder substrate, is then placed within sintering furnace and sinters, sintering temperature control exists 800 DEG C -900 DEG C, sintering time was controlled at 25-35 minutes, after the completion of sintering, is cooled 25-35 minutes, is made complex sintered resistance to Nog plate.
As a further improvement on the present invention, in first step batch mixing step, stirred Graphene powder and copper powder are added After in the mixing tank 6 of mixing device, the vacuum extractor 15 connected with exhaust outlet 13 is opened, first mixing tank 6 is evacuated, so It is filled with gases at high pressure into mixing tank 6 again afterwards.
After above method batch mixing and sintering, because Graphene powder and copper powder are well mixed, contain improving Graphene powder In the case of amount, Graphene powder and copper powder also will not fall off.
Protection scope of the present invention is not limited solely to above-described embodiment, as long as structure and the present invention are complex sintered wear-resisting Plate, stir mixing device structure are same or similar, or method it is identical with the preparation method of complex sintered wearing plate of the invention or It is similar, just fall in the scope of protection of the invention.

Claims (6)

1. complex sintered wearing plate, including substrate, it is characterised in that:The substrate side is provided with mat surface, described thick Copper powder layer is provided with the outside of matte, copper powder layer lateral surface is provided with graphene copper powder mixed layer, the Graphene powder and Copper powder weight ratio is 1-2:100, the granular size of the Graphene powder and copper powder is 200-300 mesh.
2. complex sintered wearing plate according to claim 2, it is characterised in that:The Graphene powder and copper powder weight ratio are 1.7—1.8:100, the granular size of the Graphene powder and copper powder is 270-280 mesh.
3. the stir mixing device of the complex sintered wearing plate described in claim 1, including support body and mixing tank, its feature exist In:The outside uniform air distribution plate connected with inflation mechanism is provided with below the mixing tank, is set on the uniform air distribution plate Be equipped with air admission hole, the mixing tank top be provided with agitating shaft, be provided with stirring wing on the agitating shaft, it is described most The stirring wing lower surface of lower section apart from 20-30 centimetres of the batch mixing pot bottom, be provided with above the mixing tank charge door and Exhaust outlet, discharging opening is provided with below the mixing tank.
4. the stir mixing device of complex sintered wearing plate according to claim 3, it is characterised in that:Described exhaust outlet It is connected with vacuum extractor.
5. the stir mixing device described in usage right requirement 3 or 4 prepares the complex sintered wearing plate described in claim 1 or 2 Method, it is characterised in that:This method comprises the following steps:
The first step, batch mixing
In the mixing tank that Graphene powder and copper powder are added to stir mixing device, pave the upper surface of rear Graphene powder and copper powder away from From being more than or equal to 5 centimetres with a distance from the stirring wing lower surface of bottom, gases at high pressure are filled with into mixing tank, gases at high pressure are by stone Black alkene powder and copper powder are blown afloat from batch mixing pot bottom, are suspended in mixing tank, while opening stirring shaft stirring, stirring wing is by graphite Alkene powder and copper powder stir, as the air pressure inside mixing tank increases, gas in the pressure and inflation mechanism in mixing tank When body pressure is equal, stop supply, stop stirring after 2-3 minutes, Graphene powder and copper powder fall, slowly beaten under gravity Begun to rehearse gas port, and the gas in mixing tank is discharged;Mixed mixed powder is taken out standby from the discharging opening of mixing tank;
Second step, substrate processing
According to required dimensioned substrate, and substrate side is processed into mat surface;
3rd step, lays copper powder
Copper powder is laid above the mat surface;
4th step, makes copper powder substrate
The substrate for being covered with copper powder is placed in sintering furnace and sintered, sintering temperature is controlled in 800 DEG C -900 DEG C, sintering time control System was at 25-35 minutes, after the completion of sintering, cools 25-35 minutes, copper powder substrate is made;
5th step, mixed powder is routed on copper powder substrate and cooling is sintered
The mixed powder mixed is routed on copper powder substrate, is then placed within sintering furnace and sinters, sintering temperature control exists 800 DEG C -900 DEG C, sintering time was controlled at 25-35 minutes, after the completion of sintering, is cooled 25-35 minutes, is made complex sintered resistance to Nog plate.
6. the method that stir mixing device according to claim 5 prepares complex sintered wearing plate, it is characterised in that:Institute State in first step batch mixing step, after Graphene powder and copper powder are added in the mixing tank of stir mixing device, open and exhaust Mixing tank, is first evacuated, is then filled with gases at high pressure into mixing tank again by the vacuum extractor of mouth connection.
CN201710365434.5A 2017-05-22 2017-05-22 Complex sintered wearing plate, preparation method and Special agitating mixing device Active CN107020382B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108453262A (en) * 2018-03-23 2018-08-28 南通强生石墨烯科技有限公司 A kind of graphene powder metallurgy oiliness bearing and preparation method thereof
CN113061775A (en) * 2021-03-02 2021-07-02 中国科学院力学研究所 Copper-based powder metallurgy friction material, plate with same and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN105478518A (en) * 2014-09-15 2016-04-13 怀宁汉升车辆部件有限公司 Production technology of steel-copper bimetal composite material for bearing manufacture
CN205253019U (en) * 2015-12-10 2016-05-25 吉木萨尔县米克斯建材科技有限公司 High -performance polycarboxylate water reducer production facility
CN205833073U (en) * 2016-05-10 2016-12-28 宁德时代新能源科技有限公司 A kind of powder blending tank
CN106591822A (en) * 2016-11-28 2017-04-26 广东工业大学 Preparation method and application of graphene strengthened copper base composite coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105478518A (en) * 2014-09-15 2016-04-13 怀宁汉升车辆部件有限公司 Production technology of steel-copper bimetal composite material for bearing manufacture
CN205253019U (en) * 2015-12-10 2016-05-25 吉木萨尔县米克斯建材科技有限公司 High -performance polycarboxylate water reducer production facility
CN205833073U (en) * 2016-05-10 2016-12-28 宁德时代新能源科技有限公司 A kind of powder blending tank
CN106591822A (en) * 2016-11-28 2017-04-26 广东工业大学 Preparation method and application of graphene strengthened copper base composite coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108453262A (en) * 2018-03-23 2018-08-28 南通强生石墨烯科技有限公司 A kind of graphene powder metallurgy oiliness bearing and preparation method thereof
CN113061775A (en) * 2021-03-02 2021-07-02 中国科学院力学研究所 Copper-based powder metallurgy friction material, plate with same and preparation method thereof
CN113061775B (en) * 2021-03-02 2022-01-25 中国科学院力学研究所 Plate with copper-based powder metallurgy friction material and preparation method thereof

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Inventor after: Cui Minghui

Inventor after: Zheng Liming

Inventor after: Guo Tong

Inventor after: Tian Zhaoshun

Inventor after: Du Shichao

Inventor before: Cui Minghui

Inventor before: Zheng Liming

CB03 Change of inventor or designer information