CN107012015A - A kind of fruits and vegetables detergent and preparation method thereof - Google Patents
A kind of fruits and vegetables detergent and preparation method thereof Download PDFInfo
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- CN107012015A CN107012015A CN201710416785.4A CN201710416785A CN107012015A CN 107012015 A CN107012015 A CN 107012015A CN 201710416785 A CN201710416785 A CN 201710416785A CN 107012015 A CN107012015 A CN 107012015A
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of fruits and vegetables detergent and preparation method thereof.The fruits and vegetables detergent, includes the raw material of following parts by weight:25 35 parts of starch, 6 10 parts of soyasaponin, 15 parts of Fatty acid methyl ester sodium sulfonate, 15 parts of APES, 3 10 parts of sodium gluconate, 13 parts of polyethylene glycol, 15 parts of hydroxyethyl cellulose, 0.5 2 parts of disodium ethylene diamine tetraacetate, 0.2 0.8 parts of preservative, 25 40 parts of ethanol, 0.6 1.8 parts of essential oil, 40 60 parts of water.The detergent of the present invention can carry out cleaning to the surface of fruits and vegetables and deep layer, and activity is higher, and residue is few, and environmental protection, toxic side effect is small.
Description
Technical field
The present invention relates to detergent applications, and in particular to a kind of fruits and vegetables detergent and preparation method thereof.
Background technology
The main component of detergent is surfactant, and surfactant is to contain hydrophilic group and lipophilic group in molecular structure
Two-part organic compound.Can ion be usually decomposed into according to surfactant in aqueous, be classified as again from
Two major classes of subtype surfactant and nonionic surface active agent.Ionic surfactant can be divided into cationic surface again
Three kinds of activating agent, anion surfactant and zwitterionic surfactant.
The patent of invention of application number 201410703449.4 discloses a kind of detergent, including all-transparent thickening powder, nanometer
Except emulsifier, foaming agent, wire drawing powder, preservative and essence, it has abundant foam, and foam stability is very good, resistance to hard
Water.Above-mentioned detergent has used the nanometer of costliness to remove emulsifier, although cleaning performance is very good, but cost is but very high, warp
When the bad area of Ji condition needs to use detergent, it is easy for the problem of purchasing power is not enough occur.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of fruits and vegetables detergent and its preparation side
Method, the detergent can carry out cleaning to the surface of fruits and vegetables and deep layer, and activity is higher, and residue is few, environmental protection, toxic side effect
It is small.
The present invention solves technical problem and adopted the following technical scheme that:
The invention provides a kind of fruits and vegetables detergent, include the raw material of following parts by weight:25-35 parts of starch, soyasaponin 6-10
Part, 1-5 parts of Fatty acid methyl ester sodium sulfonate, 1-5 parts of APES, 3-10 parts of sodium gluconate, polyethylene glycol 1-3
Part, 1-5 parts of hydroxyethyl cellulose, 0.5-2 parts of disodium ethylene diamine tetraacetate, 0.2-0.8 parts of preservative, 25-40 parts of ethanol, essential oil
0.6-1.8 parts, 40-60 parts of water.
Preferably, the detergent includes the raw material of following parts by weight:28 parts of starch, 6 parts of soyasaponin, Fatty acid methyl ester
3 parts of sodium sulfonate, 4 parts of APES, 6 parts of sodium gluconate, 1 part of polyethylene glycol, 2 parts of hydroxyethyl cellulose, second two
1.3 parts of amine tetraacethyl disodium, 0.5 part of preservative, 37 parts of ethanol, 0.9 part of essential oil, 50 parts of water.
Preferably, the detergent includes the raw material of following parts by weight:32 parts of starch, 8 parts of soyasaponin, Fatty acid methyl ester
2 parts of sodium sulfonate, 2 parts of APES, 5 parts of sodium gluconate, 3 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, second two
0.9 part of amine tetraacethyl disodium, 0.3 part of preservative, 28 parts of ethanol, 1.6 parts of essential oil, 55 parts of water.
Preferably, the starch is one or more in farina, water caltrop starch, Rhizoma Nelumbinis starch, cornstarch
Combination.
Preferably, the preservative is selected from Kathon CG or KF88.
Preferably, the essential oil is lemon or Lavender.
The preparation method of above-mentioned fruits and vegetables detergent, comprises the following steps:
(1)Starch, sodium gluconate are dissolved in the water according to parts by weight, stirring obtains mixture a in 20-30 minutes;
(2)According to parts by weight by soyasaponin, Fatty acid methyl ester sodium sulfonate, APES, hydroxyethyl cellulose, second
Alcohol is mixed, and is stirred, and after 30-40 DEG C is reacted 10-20 minutes, obtains reactant b;
(3)Mixture a, reactant b are mixed, polyethylene glycol, disodium ethylene diamine tetraacetate, essential oil, preservative, 40-50 is added
DEG C stirring 20-30 minutes, the fruits and vegetables detergent is obtained after standing.
Preferably, the step(3)The time of standing is 1-2 hours.
Compared with prior art, the present invention has following beneficial effect:
(1)The detergent of the present invention is mixed using the chelating agent, dispersant, thickener of a variety of natural extract component and organic compound
Close, cleaning can be carried out to the surface of fruits and vegetables and deep layer, activity is higher, and fragrant odour, residue is few, environmental protection, poison is secondary to be made
With small.
(2)In the detergent ingredients of the present invention, starch forms colloid in water, and colloid is powered, can adsorb miscellaneous in water
Matter;Soyasaponins has foaminess and emulsibility, is widely used as the additive of food;Fatty acid methyl ester sodium sulfonate safety non-toxic,
Resistance to hard water is strong, and fully biodegradable is the surfactant of real environmental protection;APES is a kind of
Property stabilization, acid and alkali-resistance, lower-cost nonionic surfactant;Sodium gluconate has excellent corrosion-mitigation scale-inhibition effect,
Acid-base balance is adjusted, the toxicity of detergent is reduced;Polyethylene glycol has good lubricity, dispersiveness, antistatic behaviour, bonding
Property, and having good intermiscibility with many organic matter components so that the impurity dirt on fruits and vegetables is more easily washed away with water;Hydroxyl second
Base cellulose have thickening, suspend, bonding, emulsification, it is scattered, keep the performance such as moisture and colloid, further increase detergent
Viscosity;Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination) and KF88 can effectively suppress and go out except mushroom and various microorganisms, and antiseptic effect is notable,
Bacterium, mould, the growth of saccharomycete can be completely inhibited under 150ppm concentration.To sum up, after the compounding of Multiple components so that the washing
Agent function admirable, environmental protection.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1.
A kind of fruits and vegetables detergent, includes the raw material of following parts by weight:
28 parts of farina;
6 parts of soyasaponin;
3 parts of Fatty acid methyl ester sodium sulfonate;
4 parts of APES;
6 parts of sodium gluconate;
1 part of polyethylene glycol;
2 parts of hydroxyethyl cellulose;
1.3 parts of disodium ethylene diamine tetraacetate;
0.5 part of Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination);
37 parts of ethanol;
0.9 part of lemon;
50 parts of water.
The preparation method of above-mentioned fruits and vegetables detergent, comprises the following steps:
(1)Starch, sodium gluconate are dissolved in the water according to parts by weight, stirring obtains mixture a in 20-30 minutes;
(2)According to parts by weight by soyasaponin, Fatty acid methyl ester sodium sulfonate, APES, hydroxyethyl cellulose, second
Alcohol is mixed, and is stirred, and after 30-40 DEG C is reacted 10-20 minutes, obtains reactant b;
(3)Mixture a, reactant b are mixed, polyethylene glycol, disodium ethylene diamine tetraacetate, essential oil, preservative, 40-50 is added
DEG C stirring 20-30 minute, standing 1-2 hours after obtain the fruits and vegetables detergent.
Embodiment 2.
A kind of fruits and vegetables detergent, includes the raw material of following parts by weight:
32 parts of Rhizoma Nelumbinis starch;
8 parts of soyasaponin;
2 parts of Fatty acid methyl ester sodium sulfonate;
2 parts of APES;
5 parts of sodium gluconate;
3 parts of polyethylene glycol;
3 parts of hydroxyethyl cellulose;
0.9 part of disodium ethylene diamine tetraacetate;
0.3 part of preservative KF88;
28 parts of ethanol;
1.6 parts of Lavender;
55 parts of water.
Preparation method be the same as Example 1.
Embodiment 3.
A kind of fruits and vegetables detergent, includes the raw material of following parts by weight:
26 parts of cornstarch;
8 parts of soyasaponin;
1 part of Fatty acid methyl ester sodium sulfonate;
2 parts of APES;
3 parts of sodium gluconate;
2 parts of polyethylene glycol;
3 parts of hydroxyethyl cellulose;
1.8 parts of disodium ethylene diamine tetraacetate;
0.6 part of Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination);
28 parts of ethanol;
1.3 parts of lemon;
48 parts of water.
Preparation method be the same as Example 1.
Embodiment 4.
A kind of fruits and vegetables detergent, includes the raw material of following parts by weight:
32 parts of farina;
8 parts of soyasaponin;
2 parts of Fatty acid methyl ester sodium sulfonate;
2 parts of APES;
8 parts of sodium gluconate;
2 parts of polyethylene glycol;
3 parts of hydroxyethyl cellulose;
1.5 parts of disodium ethylene diamine tetraacetate;
0.8 part of preservative KF88;
36 parts of ethanol;
1.3 parts of lemon;
55 parts of water.
Preparation method be the same as Example 1.
Embodiment 5.
A kind of fruits and vegetables detergent, includes the raw material of following parts by weight:
34 parts of water caltrop starch;
10 parts of soyasaponin;
3 parts of Fatty acid methyl ester sodium sulfonate;
4 parts of APES;
6 parts of sodium gluconate;
1 part of polyethylene glycol;
2 parts of hydroxyethyl cellulose;
1.3 parts of disodium ethylene diamine tetraacetate;
0.5 part of Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination);
37 parts of ethanol;
0.9 part of Lavender;
50 parts of water.
Preparation method be the same as Example 1.
The detergent of the present invention is using a variety of natural extract component and chelating agent, dispersant, the thickener of organic compound
Mixing, can carry out cleaning, activity is higher, and fragrant odour, residue is few, environmental protection, and poison is secondary to the surface of fruits and vegetables and deep layer
Effect is small.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of fruits and vegetables detergent, it is characterised in that include the raw material of following parts by weight:25-35 parts of starch, soyasaponin 6-10
Part, 1-5 parts of Fatty acid methyl ester sodium sulfonate, 1-5 parts of APES, 3-10 parts of sodium gluconate, polyethylene glycol 1-3
Part, 1-5 parts of hydroxyethyl cellulose, 0.5-2 parts of disodium ethylene diamine tetraacetate, 0.2-0.8 parts of preservative, 25-40 parts of ethanol, essential oil
0.6-1.8 parts, 40-60 parts of water.
2. fruits and vegetables detergent according to claim 1, it is characterised in that the detergent includes the original of following parts by weight
Material:28 parts of starch, 6 parts of soyasaponin, 3 parts of Fatty acid methyl ester sodium sulfonate, 4 parts of APES, sodium gluconate 6
Part, 1 part of polyethylene glycol, 2 parts of hydroxyethyl cellulose, 1.3 parts of disodium ethylene diamine tetraacetate, 0.5 part of preservative, 37 parts of ethanol, essence
Oily 0.9 part, 50 parts of water.
3. fruits and vegetables detergent according to claim 1, it is characterised in that the detergent includes the original of following parts by weight
Material:32 parts of starch, 8 parts of soyasaponin, 2 parts of Fatty acid methyl ester sodium sulfonate, 2 parts of APES, sodium gluconate 5
Part, 3 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 0.9 part of disodium ethylene diamine tetraacetate, 0.3 part of preservative, 28 parts of ethanol, essence
Oily 1.6 parts, 55 parts of water.
4. fruits and vegetables detergent according to claim 1, it is characterised in that the starch be farina, water caltrop starch,
One or more combinations in Rhizoma Nelumbinis starch, cornstarch.
5. fruits and vegetables detergent according to claim 1, it is characterised in that the preservative is selected from Kathon CG or KF88.
6. fruits and vegetables detergent according to claim 1, it is characterised in that the essential oil is lemon or lavender essence
Oil.
7. the preparation method of a kind of fruits and vegetables detergent according to claim 1-6 any one, it is characterised in that including such as
Lower step:
(1)Starch, sodium gluconate are dissolved in the water according to parts by weight, stirring obtains mixture a in 20-30 minutes;
(2)According to parts by weight by soyasaponin, Fatty acid methyl ester sodium sulfonate, APES, hydroxyethyl cellulose, second
Alcohol is mixed, and is stirred, and after 30-40 DEG C is reacted 10-20 minutes, obtains reactant b;
(3)Mixture a, reactant b are mixed, polyethylene glycol, disodium ethylene diamine tetraacetate, essential oil, preservative, 40-50 is added
DEG C stirring 20-30 minutes, the fruits and vegetables detergent is obtained after standing.
8. the preparation method of fruits and vegetables detergent according to claim 7, it is characterised in that the step(3)Standing when
Between be 1-2 hours.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710416785.4A CN107012015A (en) | 2017-06-06 | 2017-06-06 | A kind of fruits and vegetables detergent and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710416785.4A CN107012015A (en) | 2017-06-06 | 2017-06-06 | A kind of fruits and vegetables detergent and preparation method thereof |
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CN107012015A true CN107012015A (en) | 2017-08-04 |
Family
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CN201710416785.4A Withdrawn CN107012015A (en) | 2017-06-06 | 2017-06-06 | A kind of fruits and vegetables detergent and preparation method thereof |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1059931A (en) * | 1991-09-21 | 1992-04-01 | 广州白云科技开发中心 | Vegetables, fruit cleaning agent of remanent pesticide |
CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
CN102453639A (en) * | 2010-10-19 | 2012-05-16 | 南通玺路贸易有限公司 | Natural fruit detergent |
CN102492571A (en) * | 2011-11-28 | 2012-06-13 | 广州立白企业集团有限公司 | Detergent composition containing amino acid component for washing fruits, vegetables and dishes |
CN104130878A (en) * | 2014-07-04 | 2014-11-05 | 广州立白企业集团有限公司 | Fruit and vegetable cleaning agent with fruit-wax-removing effect, and preparation method thereof |
CN104611159A (en) * | 2014-12-31 | 2015-05-13 | 鲁东大学 | Cleaning agent for cleaning fruits and vegetables |
-
2017
- 2017-06-06 CN CN201710416785.4A patent/CN107012015A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1059931A (en) * | 1991-09-21 | 1992-04-01 | 广州白云科技开发中心 | Vegetables, fruit cleaning agent of remanent pesticide |
CN102453639A (en) * | 2010-10-19 | 2012-05-16 | 南通玺路贸易有限公司 | Natural fruit detergent |
CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
CN102492571A (en) * | 2011-11-28 | 2012-06-13 | 广州立白企业集团有限公司 | Detergent composition containing amino acid component for washing fruits, vegetables and dishes |
CN104130878A (en) * | 2014-07-04 | 2014-11-05 | 广州立白企业集团有限公司 | Fruit and vegetable cleaning agent with fruit-wax-removing effect, and preparation method thereof |
CN104611159A (en) * | 2014-12-31 | 2015-05-13 | 鲁东大学 | Cleaning agent for cleaning fruits and vegetables |
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Application publication date: 20170804 |