CN106978535B - A kind of blow-in method with waste heat boiler fuming furnace - Google Patents

A kind of blow-in method with waste heat boiler fuming furnace Download PDF

Info

Publication number
CN106978535B
CN106978535B CN201710164749.3A CN201710164749A CN106978535B CN 106978535 B CN106978535 B CN 106978535B CN 201710164749 A CN201710164749 A CN 201710164749A CN 106978535 B CN106978535 B CN 106978535B
Authority
CN
China
Prior art keywords
fuming furnace
furnace
waste heat
heat boiler
fuming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710164749.3A
Other languages
Chinese (zh)
Other versions
CN106978535A (en
Inventor
贾著红
吴红林
马雁鸿
蒋荣生
俞兵
王勇
马绍斌
刘俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Chihong Zinc and Germanium Co Ltd
Original Assignee
Yunnan Chihong Zinc and Germanium Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yunnan Chihong Zinc and Germanium Co Ltd filed Critical Yunnan Chihong Zinc and Germanium Co Ltd
Priority to CN201710164749.3A priority Critical patent/CN106978535B/en
Publication of CN106978535A publication Critical patent/CN106978535A/en
Application granted granted Critical
Publication of CN106978535B publication Critical patent/CN106978535B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/16Dry methods smelting of sulfides or formation of mattes with volatilisation or condensation of the metal being produced
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/02Obtaining lead by dry processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/02Obtaining lead by dry processes
    • C22B13/025Recovery from waste materials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/04Obtaining zinc by distilling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/30Obtaining zinc or zinc oxide from metallic residues or scraps
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001Dry processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of blow-in method with waste heat boiler fuming furnace, the method is heated by high pressure steam heating fuming furnace waste heat boiler water, then with fine coal, is finally directly added into hot slag, is realized the safe blow-on with waste heat boiler fuming furnace.The blow-in method of the present invention is easy safely, effectively realizes the safe blow-on with waste heat boiler fuming furnace, while realizes the safe operation with waste heat boiler;The present invention adds in fuming furnace waste heat boiler drum using external high pressure steam pipe, and than being heated using firewood, coke, the time is short, and low energy consumption, while can ensure fuming furnace waste heat boiler safe operation.

Description

A kind of blow-in method with waste heat boiler fuming furnace
Technical field
The invention belongs to metallurgical technology fields, and in particular to a kind of blow-in method with waste heat boiler fuming furnace.
Background technology
Material containing zincs, the follow-up pyrogenic processing methods such as lead zinc mineral intergrowth, zinc wet method slag mainly have kiln process and fuming furnace Method.It is handled using kiln process, there is a problems such as ability is relatively low, and energy consumption is higher, and environmental pollution is larger, waste heat recovery is difficult.Mesh It is preceding that mainstream technology is increasingly becoming using fuming oven process volatilization lead zinc alloying technology.In recent years, fuming furnace lead, copper, tin, nickel and The field of metallurgy such as steel are reached its maturity.The method that side-blown converter all cold charge makes molten bath, has had been reported that.Band waste heat boiler fuming The blow-in method of stove is not reported.General fuming furnace blow-on, enters fuming furnace by reduction furnace or electric furnace hot slag, then, opens Dynamic feeder is to coal, igniting, with regard to that can complete fuming furnace blow-on.
Fuming furnace in processing lead zinc mineral intergrowth, the material containing zincs such as zinc wet method slag, in order to effectively recycle the valuable metals such as zinc and Recovery waste heat, general fuming furnace are all had a surplus heat boiler recovery waste heat.Fuming furnace tradition heating mode is to utilize reduction furnace or electric furnace Hot slag(t≥1100℃)It is directly added by hot feed mouth in fuming furnace, it is first a small amount of to add when tertiary air orifice has red slightly Enter fine coal igniting, fire box temperature can be raised to 1150 DEG C or so, such temperature gradient waste heat in 10~20 minutes from room temperature Boiler can not be born, and Wen Sheng is no more than 40 DEG C per hour for waste heat boiler stove water, for fuming furnace safe operation, so must examine Consider other heating modes.
The content of the invention
It is an object of the invention to provide a kind of blow-in methods with waste heat boiler fuming furnace
The object of the present invention is achieved like this, comprises the following steps:
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, and fuming furnace waste heat boiler drum is made to keep ordinary water level, that is, water level is kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 10~40 DEG C/h, heat up 3~14h, and stove coolant-temperature gage is protected It holds at 130~160 DEG C, pressure rises to 0.27~0.62MPa, opens stop valve aperture 3~5%, and heating coil is carried out to steam pipe;
3)5~20t of material containing zinc paving furnace bottoms are added in from fuming furnace cold burden mouth;
4)1~5t of firewood is put into fuming furnace, igniting makes fuming furnace in-furnace temperature be raised to 160~190 DEG C, waste heat pot Stove drum boosts to 0.62~1.25MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler 0.62~1.25MPa of drum pressure, opens fuming furnace heat Material mouth adds in hot slag to fuming furnace, is directly added by hot material mouth in fuming furnace, after 5~10min, when tertiary air orifice is pico- When having red, fine coal igniting is added in, point catches fire after 10~20min, and fuming furnace furnace temperature is raised to 1000~1200 DEG C, thus completes Fuming furnace blow-on, then can carry out the normal fuming furnace operation of next round.
Compared with prior art, beneficial effects of the present invention are:
1st, blow-in method of the invention is easy safely, effectively realizes the safe blow-on with waste heat boiler fuming furnace, while real The safe operation with waste heat boiler is showed.
2nd, the present invention adds in fuming furnace waste heat boiler drum using external high pressure steam pipe, than being heated using firewood, coke, Time is short, and low energy consumption, while can ensure fuming furnace waste heat boiler safe operation.
Description of the drawings
Fig. 1 is present invention process flow chart.
Specific embodiment
With reference to embodiment and attached drawing, the present invention is further illustrated, but the present invention is not subject in any way Limitation, based on present invention teach that any conversion or replacement made, all belong to the scope of protection of the present invention.
Blow-in method of the present invention with waste heat boiler fuming furnace, comprises the following steps:
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 10~40 DEG C/h, heat up 3~14h, and stove coolant-temperature gage is protected It holds at 130~160 DEG C, pressure rises to 0.27~0.62MPa, opens stop valve aperture 3~5%, and heating coil is carried out to steam pipe;
3)5~20t of material containing zinc paving furnace bottoms are added in from fuming furnace cold burden mouth;
4)1~5t of firewood is put into fuming furnace, igniting makes fuming furnace in-furnace temperature be raised to 160~190 DEG C, waste heat pot Stove drum boosts to 0.62~1.25MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler 0.62~1.25MPa of drum pressure, opens fuming furnace heat Material mouth adds in hot slag to fuming furnace, is directly added by hot material mouth in fuming furnace, after 5~10min, when tertiary air orifice is pico- When having red, fine coal igniting is added in, point catches fire after 10~20min, and fuming furnace furnace temperature is raised to 1000~1200 DEG C, thus completes Fuming furnace blow-on, then can carry out the normal fuming furnace operation of next round.
Step(3)Described in material containing zinc be lead zinc mineral intergrowth and/or zinc wet method slag.
The ingredient of the lead zinc mineral intergrowth is Pb:2~5%, Zn:11~25%, S:0.3~1%, SiO2:10~13%, CaO:10~14%.
The ingredient of the zinc wet method slag is Pb:4~8%, Zn:14~22%, S:4~8%, SiO2:3~6%, CaO:1~ 2%。
Step(4)Described in igniting to use cotton yarn and diesel ignition.
Step(5)Described in hot slag be reduction furnace hot slag and/or electric furnace hot slag.
Step(5)Described in hot slag ingredient be Pb:2~4%, Zn:8~12%, S:0.2~1.2%, SiO2:20~ 24%、CaO:10~14%.
Embodiment 1
First, external high pressure steam pipe is accessed in fuming furnace waste heat boiler drum, starts fuming furnace forced circulation pump, risen Warm process should be noted that boiler drum water level changes, and adjust level control valve, and fuming furnace waste heat boiler drum is made to keep ordinary water level.
Then, external high pressure steam pipe heating steam pipe is opened, is heated up by 10 DEG C/h, heat up 11h, and stove coolant-temperature gage is maintained at 140 DEG C, pressure rises to 0.36MPa, opens stop valve aperture 3%, and heating coil is carried out to steam pipe.
Lead zinc mineral intergrowth is added in from fuming furnace cold burden mouth(Ingredient Pb:2%、Zn: 25%、S:0.3%、SiO2:10%、CaO: 10%), zinc wet method slag(Ingredient Pb:4%, Zn:16%、S:8%、SiO2:3%、CaO:1%)Wait material containing zincs 5t paving furnace bottoms.To fuming Input firewood 2t, with cotton yarn and diesel ignition, makes fuming furnace in-furnace temperature be raised to 160 DEG C, waste heat boiler drum boosts in stove 0.62MPa.Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 0.62MPa, opens fuming furnace hot material mouth, to Fuming furnace adds in reduction furnace hot slag(Ingredient Pb:2%, Zn:8%、S:0.2%、SiO2:24%、CaO:14%), it is straight by hot material mouth It connects and adds in fuming furnace, after 10min, when tertiary air orifice has red slightly, add in fine coal igniting, point catches fire after 20min, fuming Stove furnace temperature is raised to 1000 DEG C, and this completes fuming furnace blow-ons, then carry out the normal fuming furnace operation of next round.
Embodiment 2
First, external high pressure steam pipe is accessed in fuming furnace waste heat boiler drum, starts fuming furnace forced circulation pump, risen Warm process should be noted that boiler drum water level changes, and adjust level control valve, and fuming furnace waste heat boiler drum is made to keep ordinary water level.
Then, external high pressure steam pipe heating steam pipe is opened, is heated up by 20 DEG C/h, heat up 6h, and stove coolant-temperature gage is maintained at 150 DEG C, pressure rises to 0.48MPa, opens stop valve aperture 4%, and heating coil is carried out to steam pipe.
Lead zinc mineral intergrowth is added in from fuming furnace cold burden mouth(Ingredient Pb:3%、Zn:18%、S:0.7%、SiO2:12%、CaO: 12%), zinc wet method slag(Ingredient Pb:6%, Zn:20%、S:6%、SiO2:5%、CaO:1.5%)Wait material containing zincs 15t paving furnace bottoms.To cigarette Change input firewood 3t in stove, with cotton yarn and diesel ignition, fuming furnace in-furnace temperature is made to be raised to 175 DEG C, the boosting of waste heat boiler drum To 0.89MPa.Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 0.89MPa, opens fuming furnace hot material mouth, Electric furnace hot slag is added in fuming furnace(Ingredient Pb:3%, Zn:10%、S:0.6%、SiO2:22%、CaO:12%), it is straight by hot material mouth It connects and adds in fuming furnace, after 8min, when tertiary air orifice has red slightly, add in fine coal igniting, point catches fire after 15min, fuming Stove furnace temperature is raised to 1100 DEG C, and this completes fuming furnace blow-ons, then carry out the normal fuming furnace operation of next round.
Embodiment 3
First, external high pressure steam pipe is accessed in fuming furnace waste heat boiler drum, starts fuming furnace forced circulation pump, risen Warm process should be noted that boiler drum water level changes, and adjust level control valve, and fuming furnace waste heat boiler drum is made to keep ordinary water level.
Then, external high pressure steam pipe heating steam pipe is opened, is heated up by 30 DEG C/h, heat up 4.5h, and stove coolant-temperature gage is kept At 160 DEG C, pressure rises to 0.62MPa, opens stop valve aperture 5%, and heating coil is carried out to steam pipe.
Lead zinc mineral intergrowth is added in from fuming furnace cold burden mouth(Ingredient Pb:5%、Zn:11%、S:1%、SiO2:13%、CaO:14%)、 Zinc wet method slag(Ingredient Pb:8%, Zn:22%、S:4%、SiO2: 8%、CaO:2%)Wait material containing zincs 20t paving furnace bottoms.Into fuming furnace Firewood 5t is put into, with cotton yarn and diesel ignition, fuming furnace in-furnace temperature is made to be raised to 190 DEG C, waste heat boiler drum boosts to 1.25MPa.Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 1.25MPa, opens fuming furnace hot material mouth, to Fuming furnace adds in electric furnace hot slag(Ingredient Pb:4%, Zn:12%、S:1.2%、SiO2:20%、CaO:10%), it is direct by hot material mouth It adds in fuming furnace, after 5min, when tertiary air orifice has red slightly, adds in fine coal igniting, point catches fire after 20min, fuming furnace Furnace temperature is raised to 1200 DEG C, and this completes fuming furnace blow-ons, then carry out the normal fuming furnace operation of next round.
Embodiment 4
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 10 DEG C/h, heat up 3h, and stove coolant-temperature gage is maintained at 130 DEG C, pressure rises to 0.27MPa, opens stop valve aperture 3%, and heating coil is carried out to steam pipe;
3)Material containing zinc 5t paving furnace bottoms are added in from fuming furnace cold burden mouth;The material containing zinc is lead zinc mineral intergrowth;It is described Lead zinc mineral intergrowth ingredient include Pb:2%、Zn:11%、S:0.3%、SiO2:10%、CaO:10%;
4)Firewood 1t is put into fuming furnace, igniting makes fuming furnace in-furnace temperature be raised to 160 DEG C, waste heat boiler drum liter It is depressed into 0.62MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 0.62MPa, opens fuming furnace hot material mouth, To fuming furnace add in hot slag, the hot slag be reduction furnace hot slag, ingredient Pb:2%, Zn:8%、S:0.2%、SiO2: 20%、CaO:10%;It is directly added by hot material mouth in fuming furnace, after 5min, when tertiary air orifice has red slightly, adds in fine coal Igniting, point catch fire after 10min, and fuming furnace furnace temperature is raised to 1000 DEG C, and this completes fuming furnace blow-ons, then can carry out down The normal fuming furnace operation of one wheel.
Embodiment 5
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 20 DEG C/h, heat up 5h, and stove coolant-temperature gage is maintained at 140 DEG C, pressure rises to 0.30MPa, opens stop valve aperture 3.5%, and heating coil is carried out to steam pipe;
3)Material containing zinc 10t paving furnace bottoms are added in from fuming furnace cold burden mouth;The material containing zinc is lead zinc mineral intergrowth;It is described Lead zinc mineral intergrowth ingredient be Pb:5%、Zn: 25%、S:1%、SiO2:13%、CaO:14%;
4)Firewood 2t is put into fuming furnace, igniting using cotton yarn and diesel ignition, is raised to fuming furnace in-furnace temperature 170 DEG C, waste heat boiler drum boosts to 0.80MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 0.80MPa, opens fuming furnace hot material mouth, To fuming furnace add in hot slag, the hot slag be electric furnace hot slag, ingredient Pb:4%, Zn:12%、S:1.2%、SiO2: 24%、CaO:14%;It is directly added by hot material mouth in fuming furnace, after 6min, when tertiary air orifice has red slightly, adds in fine coal Igniting, point catch fire after 12min, and fuming furnace furnace temperature is raised to 1080 DEG C, and this completes fuming furnace blow-ons, then can carry out down The normal fuming furnace operation of one wheel.
Embodiment 6
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 30 DEG C/h, heat up 7h, and stove coolant-temperature gage is maintained at 150 DEG C, pressure rises to 0.50MPa, opens stop valve aperture 4%, and heating coil is carried out to steam pipe;
3)Material containing zinc 15t paving furnace bottoms are added in from fuming furnace cold burden mouth;The material containing zinc is zinc wet method slag;Described The ingredient of zinc wet method slag is Pb:4%, Zn:14%、S:4%、SiO2:3%、CaO:1%;
4)Firewood 3t is put into fuming furnace, using cotton yarn and diesel ignition, fuming furnace in-furnace temperature is made to be raised to 180 DEG C, Waste heat boiler drum boosts to 1.00MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 1.00MPa, opens fuming furnace hot material mouth, To fuming furnace add in hot slag, the hot slag be reduction furnace hot slag and electric furnace hot slag, ingredient Pb:3%, Zn:10%、 S:0.6%、SiO2:22%、CaO:12%;Be directly added by hot material mouth in fuming furnace, after 7min, when tertiary air orifice have slightly it is red During color, fine coal igniting is added in, point catches fire after 14min, and fuming furnace furnace temperature is raised to 1120 DEG C, this completes fuming furnace blow-on, Then the normal fuming furnace operation of next round can be carried out.
Embodiment 7
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 40 DEG C/h, heat up 14h, and stove coolant-temperature gage is maintained at 160 DEG C, pressure rises to 0.62MPa, opens stop valve aperture 5%, and heating coil is carried out to steam pipe;
3)Material containing zinc 20t paving furnace bottoms are added in from fuming furnace cold burden mouth;The material containing zinc is zinc wet method slag;Described The ingredient of zinc wet method slag is Pb:8%, Zn: 22%、S:8%、SiO2:6%、CaO:2%;
4)Firewood 5t is put into fuming furnace, using cotton yarn and diesel ignition, fuming furnace in-furnace temperature is made to be raised to 190 DEG C, Waste heat boiler drum boosts to 1.25MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 1.25MPa, opens fuming furnace hot material mouth, To fuming furnace add in hot slag, the hot slag be reduction furnace hot slag and electric furnace hot slag, ingredient Pb:4%, Zn: 12%、S:1.2%、SiO2:24%、CaO:14%;It is directly added by hot material mouth in fuming furnace, after 10min, when tertiary air orifice is pico- When having red, fine coal igniting is added in, point catches fire after 20min, and fuming furnace furnace temperature is raised to 1200 DEG C, and this completes fuming furnaces to open Then stove can carry out the normal fuming furnace operation of next round.
Embodiment 8
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, Heating adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 35 DEG C/h, heat up 12h, and stove coolant-temperature gage is maintained at 155 DEG C, pressure rises to 0.56MPa, opens stop valve aperture 4.5%, and heating coil is carried out to steam pipe;
3)Material containing zinc 18t paving furnace bottoms are added in from fuming furnace cold burden mouth;The material containing zinc is lead zinc mineral intergrowth and zinc Wet method slag;The ingredient of the lead zinc mineral intergrowth is Pb:3%、Zn:15%、S:0.7%、SiO2:11%、CaO:13%;The zinc The ingredient of wet method slag is Pb:7%, Zn:19%、S:7%、SiO2:5%、CaO:1.8%;
4)Firewood 4.5t is put into fuming furnace, using cotton yarn and diesel ignition, fuming furnace in-furnace temperature is made to be raised to 185 DEG C, waste heat boiler drum boosts to 1.11MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler drum pressure 1.11MPa, opens fuming furnace hot material mouth, To fuming furnace add in hot slag, the hot slag be reduction furnace hot slag and electric furnace hot slag, ingredient Pb:3.5%, Zn: 11%、S:1.1%、SiO2:23%、CaO:13%;It is directly added by hot material mouth in fuming furnace, after 9min, when tertiary air orifice is pico- When having red, fine coal igniting is added in, point catches fire after 18min, and fuming furnace furnace temperature is raised to 1180 DEG C, and this completes fuming furnaces to open Then stove can carry out the normal fuming furnace operation of next round.

Claims (7)

1. a kind of blow-in method with waste heat boiler fuming furnace, it is characterised in that the blow-in method comprises the following steps:
1)External high pressure steam pipe is accessed in fuming furnace waste heat boiler drum first, starts fuming furnace forced circulation pump, is risen Temperature adjusts level control valve, makes fuming furnace waste heat boiler drum that water level be kept to be more than 60%;
2)External high pressure steam pipe heating steam pipe is opened, is heated up by 10~40 DEG C/h, heat up 3~14h, and stove coolant-temperature gage is maintained at 130~160 DEG C, pressure rises to 0.27~0.62MPa, opens stop valve aperture 3~5%, and heating coil is carried out to steam pipe;
3)5~20t of material containing zinc paving furnace bottoms are added in from fuming furnace cold burden mouth;
4)1~5t of firewood is put into fuming furnace, igniting makes fuming furnace in-furnace temperature be raised to 160~190 DEG C, waste heat boiler pot Cylinder boosts to 0.62~1.25MPa;
5)Heating steam pipe is closed, keeps fuming furnace waste heat boiler 0.62~1.25MPa of drum pressure, opens fuming furnace hot material Mouthful, hot slag is added in fuming furnace, is directly added by hot material mouth in fuming furnace, after 5~10min, when tertiary air orifice has slightly When red, fine coal igniting is added in, point catches fire after 10~20min, and fuming furnace furnace temperature is raised to 1000~1200 DEG C, this completes Then fuming furnace blow-on can carry out the normal fuming furnace operation of next round.
2. the blow-in method according to claim 1 with waste heat boiler fuming furnace, it is characterised in that step(3)Described in Material containing zinc is lead zinc mineral intergrowth and/or zinc wet method slag.
3. the blow-in method according to claim 2 with waste heat boiler fuming furnace, it is characterised in that the lead zinc symbiosis The ingredient of ore deposit is Pb:2~5%, Zn:11~25%, S:0.3~1%, SiO2:10~13%, CaO:10~14%.
4. the blow-in method according to claim 2 with waste heat boiler fuming furnace, it is characterised in that the zinc wet method slag Ingredient be Pb:4~8%, Zn:14~22%, S:4~8%, SiO2:3~6%, CaO:1~2%.
5. the blow-in method according to claim 1 with waste heat boiler fuming furnace, it is characterised in that step(4)Described in It lights a fire as using cotton yarn and diesel ignition.
6. the blow-in method according to claim 1 with waste heat boiler fuming furnace, it is characterised in that step(5)Described in Hot slag is reduction furnace hot slag and/or electric furnace hot slag.
7. the blow-in method according to claim 1 with waste heat boiler fuming furnace, it is characterised in that step(5)Described in The ingredient of hot slag is Pb:2~4%, Zn:8~12%, S:0.2~1.2%, SiO2:20~24%, CaO:10~14%.
CN201710164749.3A 2017-03-20 2017-03-20 A kind of blow-in method with waste heat boiler fuming furnace Active CN106978535B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710164749.3A CN106978535B (en) 2017-03-20 2017-03-20 A kind of blow-in method with waste heat boiler fuming furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710164749.3A CN106978535B (en) 2017-03-20 2017-03-20 A kind of blow-in method with waste heat boiler fuming furnace

Publications (2)

Publication Number Publication Date
CN106978535A CN106978535A (en) 2017-07-25
CN106978535B true CN106978535B (en) 2018-05-18

Family

ID=59338878

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710164749.3A Active CN106978535B (en) 2017-03-20 2017-03-20 A kind of blow-in method with waste heat boiler fuming furnace

Country Status (1)

Country Link
CN (1) CN106978535B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108330294A (en) * 2018-03-20 2018-07-27 云南驰宏锌锗股份有限公司 A kind of four connect the method for stove processing smelting charge of lead and zinc

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1540006A (en) * 2003-10-24 2004-10-27 广西堂汉锌铟有限公司 Technique for integrated treatment for fuming of dregs of lead/stibium blast furnace
CN101144121A (en) * 2007-09-26 2008-03-19 广西铜业有限公司 Solid blowing in method for fused bath smelting
CN102634653A (en) * 2012-05-22 2012-08-15 云南驰宏锌锗股份有限公司 Side-blowing material-smelting production method
WO2015016086A1 (en) * 2013-07-30 2015-02-05 国立大学法人東北大学 Method for recovering zinc from electric-furnace steelmaking dust and device for recovering zinc from electric-furnace steelmaking dust

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1540006A (en) * 2003-10-24 2004-10-27 广西堂汉锌铟有限公司 Technique for integrated treatment for fuming of dregs of lead/stibium blast furnace
CN101144121A (en) * 2007-09-26 2008-03-19 广西铜业有限公司 Solid blowing in method for fused bath smelting
CN102634653A (en) * 2012-05-22 2012-08-15 云南驰宏锌锗股份有限公司 Side-blowing material-smelting production method
WO2015016086A1 (en) * 2013-07-30 2015-02-05 国立大学法人東北大学 Method for recovering zinc from electric-furnace steelmaking dust and device for recovering zinc from electric-furnace steelmaking dust

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
周良均.烟化炉直接处理高硅锡渣的工业实践.《有色冶炼》.1992,(第2期),第24、30-35页. *
雷德军 等.曲靖烟化炉新工艺处理锌湿法渣生产实践.《云南冶金》.2009,第38卷第56-62页. *

Also Published As

Publication number Publication date
CN106978535A (en) 2017-07-25

Similar Documents

Publication Publication Date Title
CN105865193B (en) A kind of electric arc furnaces sealed feeding device and flue gas temperature control method
CN108624740A (en) A kind of steelmaking equipment and smelting process with steel scrap steel-making
CN102745651A (en) Energy-saving and environmental-friendly method for heating fluidized bed furnace
CN104073649A (en) Iron-containing zinc powder recycling process
CN106431024A (en) Method for preparing titanium carbide slag
CN103307889B (en) Gradient utilization method for waste heat of cupola furnace
CN106978535B (en) A kind of blow-in method with waste heat boiler fuming furnace
CN102225749B (en) Start-up method of fluidized bed roaster
CN204752780U (en) Melting reduction iron -smelting device
CN205933969U (en) Low carbon ferromanganese's production system
CN207655905U (en) A kind of online apparatus for baking of hot-metal bottle
CN107022680B (en) A kind of all cold charge blow-in method with waste heat boiler fuming furnace
CN116240380A (en) Method for forming full-cold-charge open furnace molten pool of oxygen-enriched pulverized coal side-blown melting furnace
CN107367168A (en) A kind of gas-fired heater and its method for heating titanium and titanium alloy ingot casting
CN202792954U (en) Energy-saving and environment-friendly high temperature fluidized bed roasting oven
CN103950973A (en) Low-temperature fluidizing chlorination method and low-temperature fluidizing chlorination furnace
CN204490904U (en) Blast furnace banking structure
CN204281779U (en) Steel scrap steelmaking equipment
CN206682949U (en) Heat storage and flame stabilization device
CN106517317A (en) Lead tetraoxide oxidation technology
CN105886688A (en) Iron and steel making with hydrogen
CN203464707U (en) Safety strengthened metallurgical furnace
CN104745799B (en) A kind of method of control rotary kiln redox condition
CN206089763U (en) Liquid lead's device is added to bottom blowing stove
CN109631569A (en) A kind of environmentally friendly smelting rotary kiln handling the cadmium of lead containing zinc-iron dangerous waste material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant