CN106977099A - One kind is without zirconium spinel crystalline opaque glaze and its manufacture method - Google Patents
One kind is without zirconium spinel crystalline opaque glaze and its manufacture method Download PDFInfo
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- CN106977099A CN106977099A CN201710176121.5A CN201710176121A CN106977099A CN 106977099 A CN106977099 A CN 106977099A CN 201710176121 A CN201710176121 A CN 201710176121A CN 106977099 A CN106977099 A CN 106977099A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
- C03C2205/02—Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses one kind without zirconium spinel crystalline opaque glaze and its manufacture method.The mass percent of the component and each component without zirconium spinel crystalline opaque glaze is：Na2O：1%~5%；K2O：1%~5%；Al2O3：20%~25%；CaO：2%~6%；MgO：7%~15%；ZnO：5%~8%；B2O3：2~6%；Surplus is SiO2.Glaze layer produced by the present invention without zirconium spinel crystalline opaque glaze separates out (Mg, Zn) Al2O4Spinel crystal, crystallite dimension is 300nm ~ 1000nm, and the scattering process to visible ray is most strong, can reach the whiteness of common zirconium white frit glaze, and improve hardness, wearability and the mar-resistance of glaze.The present invention is free of zircon sand, and without any radioactive element, with low cost and milky white effect is good, and production technology and zirconium system milkiness fritted glaze are just the same, it is possible to decrease production cost.
Description
Technical field
The present invention relates to ceramic glaze field, and in particular to one kind is without zirconium spinel crystalline opaque glaze and its manufacture method.
Background technology
In order to cover the color and some defects of base substrate, the glaze decorating of ceramic product is enriched, opaque glaze is widely used
In glaze decorating.The sand that hard bottom shoestring enters（Mohs' hardness 7）Glaze can be made to produce cut.If being worn and torn through long-time, even
Mottled tire background color can be exposed, durable decorative effect is influenceed naturally.The conventional opaque glaze of current construction sanitary ceramic is aerobic
Change tin system opaque glaze, zircon system opaque glaze and titanium oxide system opaque glaze.Tin oxide system opaque glaze, opaque effect is good
But expensive, cost is high；Zircon system opaque glaze, because zirconium compounds opacifiers has opaque effect stable, is not bullied
Atmosphere influences and ZrSiO4Hardness is high（Mohs' hardness 7.5）The advantages of, it is commonly used in ceramic industry.What is mainly used at present contains
Zirconium natural material is zircon sand, and its main component is ZrSiO4(refractive index 1.94), additionally containing a small amount of rare earth element
Lead that thorium, uranium and the decay of these radioactive elements are produced etc., often carries radioactivity or toxicity, if long-term live in radiation
Property construction sanitary ceramic decoration environment in, can cause potentially hazardous to the health of people, in some instances it may even be possible to which influence is of future generation,
And its resource is more and more rare, price is jumped up in recent years；Titanium oxide is when high temperature lacks into easily with anatase from melt
Separate out, glaze is changed colour.Spinel crystallites opaque glaze, it is (Mg, Zn) Al that glaze layer, which separates out crystal,2O4Spinelle (refractive index 1.74 ~
1.86, Mohs' hardness 8), it is visible wavelength to control grain size, the scattering process of visible ray can be reached most by force, reached general
The whiteness of logical zirconium white frit glaze, improves hardness, wearability and the mar-resistance of glaze, and reduction production cost.
The content of the invention
It is an object of the invention to provide one kind without zirconium spinel crystalline opaque glaze, glaze layer separates out (Mg, Zn) Al2O4Spinelle
Crystal, crystallite dimension is 300nm ~ 1000nm, and opaque effect is good, improves hardness, wearability and the mar-resistance of glaze, reduction life
Cost is produced, the drawbacks described above for overcoming prior art to exist.
The object of the invention is achieved by the following technical programs.
One kind is made up of without zirconium spinel crystalline opaque glaze each component of following weight fraction：Na2O：1%~5%；K2O：1%~
5%；Al2O3：20%~25%；CaO：2%~6%；MgO：7%~15%；ZnO：5%~8%；B2O3：2%~6%；Surplus is SiO2。
Preferably, it is described to be made up of without zirconium spinel crystalline opaque glaze each component of following weight fraction：Na2O：
1.79%；K2O：2.68%；Al2O3：23.21%；CaO：3.57%；MgO：8.93%；ZnO：6.25%；B2O3：3.57%；SiO2：
50.00%。
A kind of above-described manufacture method without zirconium spinel crystalline opaque glaze, comprises the following steps：
（1）Potassium feldspar, albite, calcite, silica flour, talcum, boric acid, aluminum oxide and calcining zinc oxide are uniformly mixed, then
Found, then water quenching is cold, ball milling obtains frit powder；
（2）Add water ball milling into frit powder, obtains glaze slip；
（3）Glaze slip is sieved；
（4）Add water regulation glaze pulp density；
（5）Glaze spraying, burns till, and obtains no zirconium spinel crystalline opaque glaze.
It is preferred that, step（1）The raw material is uniformly after mixing, and 1480 DEG C ~ 1500 DEG C are founded 45min ~ 60min, Ran Houshui
Quenching, ball milling obtains frit powder.
It is preferred that, step（2）Needed during the ball milling plus frit powder weight 3% ~ 6% kaolin, frit powder weight
0.2% ~ 0.5% carboxymethyl cellulose and the sodium tripolyphosphate of frit powder weight 0.2% ~ 0.5%.
It is preferred that, step（3）The sieving was 200 ~ 250 mesh screens.
It is preferred that, step（3）Tailing over less than 0.15wt% during the sieving.
It is preferred that, step（4）The regulation glaze pulp density is 1.5 ~ 1.6 g/cm3。
It is preferred that, step（5）The system burnt till is 1200 DEG C ~ 1210 DEG C insulation 8min ~ 10min.
The manufacturing process flow without zirconium spinel crystalline opaque glaze is as follows：
Raw material detection → dispensing → uniform mixing → be incubated at 1480 DEG C ~ 1500 DEG C 45min ~ 60min → water quenchings it is cold → ball milling →
Sieving → enamel frit makeing slurry → glazing → burns till → finished product.
Compared with prior art, the invention has the advantages that：
The present invention without zirconium spinel crystalline opaque glaze, its hardness of glaze surface is high, wearability is good and anti-scratch, without zircon sand, no
Containing any radioactive element, with low cost and milky white effect is good, and production technology and zirconium system milkiness fritted glaze are just the same, it is possible to decrease
Production cost.
Brief description of the drawings
Fig. 1 is scanning electricity of the glaze without zirconium spinel crystalline opaque glaze after 4wt%HF solution corrosions 30s of embodiment 1
Mirror figure.
Embodiment
The specific implementation of the present invention is further described with reference to specific embodiment, but embodiments of the present invention
Not limited to this.
Embodiment 1
The present embodiment is made up of without zirconium spinel crystalline opaque glaze the component of following weight fraction：Na2O：1.79%；K2O：
2.68%；Al2O3：23.21%；CaO：3.57%；MgO：8.93%；ZnO：6.25%；B2O3：3.57%；SiO2：50.00%.
Raw materials used formula is calculated according to as above formula rate, in the present embodiment from 30.0 parts by weight potassium feldspars, 5.1
Parts by weight albite, 4.4 parts by weight calcites, 8.1 parts by weight silica flours, 24.6 parts by weight talcums, 6.0 part by weight of boric acid,
15.8 parts by weight of alumina, 6.0 parts by weight calcining zinc oxides are raw material, uniform mixing, and 60min, Ran Houshui are founded at 1480 DEG C
Quenching, ball milling obtains frit powder.By 100g frits powder, 5g kaolin, 0.3g carboxymethyl celluloses, 0.3g tripolyphosphates
Sodium, 60ml water for ball milling, cross 250 mesh mesh screens, tail over 0.1g, being added water during glazing makes glaze pulp density be adjusted to 1.55 g/cm3, glaze spraying,
1200 DEG C of insulation 10min, obtain no zirconium spinel crystalline opaque glaze.
Hardness without zirconium spinel crystalline opaque glaze obtained by the present embodiment is 8.7GPa, and L* is that 92.13, a* is -0.58, b*
For -0.10.
Scanning electron microscope (SEM) photograph of the glaze without zirconium spinel crystalline opaque glaze of the present embodiment after 4wt%HF solution corrosions 30s
As shown in figure 1, the glaze without zirconium spinel crystalline opaque glaze obtained by other embodiments is with sweeping after 4wt%HF solution corrosions 30s
Electron microscope is retouched reference can be made to Fig. 1.
Embodiment 2
The present embodiment is made up of without zirconium spinel crystalline opaque glaze the component of following weight fraction：Na2O：1%；K2O：5%；
Al2O3：20%；CaO：5%；MgO：14%；ZnO：5%；B2O3：6%；SiO2：44%.
Raw materials used formula is calculated according to as above formula rate, in the present embodiment from 38.9 parts by weight potassium feldspars, 6.1
Parts by weight calcite, 31.5 parts by weight talcums, 9.5 part by weight of boric acid, 9.5 parts by weight of alumina, 4.5 parts by weight calcining zinc oxides
For raw material, uniform mixing founds 45min, then water quenching is cold, ball milling obtains frit powder at 1480 DEG C.By 100g frits powder,
3g kaolin, 0.5g carboxymethyl celluloses, 0.5g sodium tripolyphosphates, 60ml water for ball milling, cross 250 mesh mesh screens, tail over 0.1g, apply
Being added water during glaze makes glaze pulp density be adjusted to 1.55 g/cm3, glaze spraying, 1200 DEG C be incubated 10min, obtain no zirconium spinel crystallite milkiness
Glaze.
Hardness without zirconium spinel crystalline opaque glaze obtained by the present embodiment is 8.5GPa, and L* is that 91.56, a* is -0.54, b*
For -0.12.
Embodiment 3
The present embodiment is made up of without zirconium spinel crystalline opaque glaze the component of following weight fraction：Na2O：3%；K2O：3%；
Al2O3：22.5%；CaO：4.5%；MgO：11%；ZnO：6.5%；B2O3：4%；SiO2：45.5%.
Calculate raw materials used formula according to as above formula rate, in the present embodiment from 30.0 parts by weight potassium feldspars,
15.2 parts by weight albites, 5.3 parts by weight calcites, 26.7 parts by weight talcums, 6.6 part by weight of boric acid, the oxidation of 10.1 parts by weight
Aluminium, 6.1 parts by weight calcining zinc oxides are raw material, uniform mixing, found 50min at 1490 DEG C, then water quenching is cold, ball milling is melted
Block powder.By 100g frits powder, 4g kaolin, 0.35g carboxymethyl celluloses, 0.35g sodium tripolyphosphates, 60ml water for ball milling,
250 mesh mesh screens are crossed, 0.1g is tailed over, being added water during glazing makes glaze pulp density be adjusted to 1.50 g/cm3, glaze spraying, in 1200 DEG C of insulations
10min, obtains no zirconium spinel crystalline opaque glaze.
Hardness without zirconium spinel crystalline opaque glaze obtained by the present embodiment is 8.4GPa, and L* is that 91.60, a* is -0.60, b*
For -0.13.
Embodiment 4
The present embodiment is made up of without zirconium spinel crystalline opaque glaze the component of following weight fraction：Na2O：5%；K2O：1%；
Al2O3：25%；CaO：2%；MgO：7%；ZnO：8%；B2O3：2%；SiO2：50.00%.
Raw materials used formula is calculated according to as above formula rate, in the present embodiment from 7.7 parts by weight potassium feldspars, 46.9
Parts by weight albite, 1.2 parts by weight calcites, 18.7 parts by weight talcums, 3.5 part by weight of boric acid, 14.2 parts by weight of alumina,
7.8 parts by weight calcining zinc oxides are raw material, uniform mixing, found 60min at 1480 DEG C, then water quenching is cold, ball milling obtains frit
Powder.By 100g frits powder, 6g kaolin, 0.2g carboxymethyl celluloses, 0.2g sodium tripolyphosphates, 60ml water for ball milling, mistake
250 mesh mesh screens, tail over 0.1g, and being added water during glazing makes glaze pulp density be adjusted to 1.6 g/cm3, glaze spraying, 1210 DEG C be incubated 8min, obtain
Without zirconium spinel crystalline opaque glaze.
Hardness without zirconium spinel crystalline opaque glaze obtained by the present embodiment is 8.5GPa, and L* is that 91.75, a* is -0.55, b*
For -0.10.
Obviously, the above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not pair
The restriction of embodiments of the present invention.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.There is no necessity and possibility to exhaust all the enbodiments.It is all this
Any modifications, equivalent substitutions and improvements made within the spirit and principle of invention etc., should be included in the claims in the present invention
Protection domain within.
Claims (10)
1. one kind is without zirconium spinel crystalline opaque glaze, it is characterised in that the component and each group without zirconium spinel crystalline opaque glaze
Point mass percent be：
Na2O：1%~5%；
K2O：1%~5%；
Al2O3：20%~25%；
CaO：2%~6%；
MgO：7%~15%；
ZnO：5%~8%；
B2O3：2%~6%；
Surplus is SiO2。
2. one kind as described in claim 1 is without zirconium spinel crystalline opaque glaze, it is characterised in that this is without zirconium spinel crystallite
The component of opaque glaze and the mass percent of each component are：
Na2O：1.79%；
K2O：2.68%；
Al2O3：23.21%；
CaO：3.57%；
MgO：8.93%；
ZnO：6.25%；
B2O3：3.57%；
SiO2：50.00%.
3. a kind of method without zirconium spinel crystalline opaque glaze described in manufacturing claims any one of 1-2, it is characterised in that bag
Include following steps：
（1）Potassium feldspar, albite, calcite, silica flour, talcum, boric acid, aluminum oxide and calcining zinc oxide are uniformly mixed, then
Found, then water quenching is cold, ball milling obtains frit powder；
（2）Add water ball milling into frit powder, obtains glaze slip；
（3）Glaze slip is sieved；
（4）Add water regulation glaze pulp density；
（5）Glaze spraying, burns till, and obtains no zirconium spinel crystalline opaque glaze.
4. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（1）
The temperature founded is 1480 DEG C ~ 1500 DEG C.
5. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（1）
The time founded is 45min ~ 60min.
6. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（2）
Add the kaolin of frit powder weight 3% ~ 6% during the ball milling, the carboxymethyl cellulose of frit powder weight 0.2% ~ 0.5% and molten
The sodium tripolyphosphate of block powder weight 0.2% ~ 0.5%.
7. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（3）
The sieving was 200 ~ 250 mesh mesh screens.
8. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（3）
Tailing over less than 0.15wt% during the sieving.
9. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（4）
The regulation glaze pulp density is 1.5 ~ 1.6 g/cm3。
10. a kind of manufacture method without zirconium spinel crystalline opaque glaze as claimed in claim 3, it is characterised in that step（5）
The system burnt till is 1200 DEG C ~ 1210 DEG C insulation 8min ~ 10min.
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| CN201710176121.5A CN106977099A (en) | 2017-03-23 | 2017-03-23 | One kind is without zirconium spinel crystalline opaque glaze and its manufacture method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473708A (en) * | 2017-09-22 | 2017-12-15 | 福建省德化县嘉威陶瓷有限公司 | A kind of slow heat conduction, high-strength ceramic product and its manufacturing process |
| CN109180000A (en) * | 2018-11-09 | 2019-01-11 | 广东省清远市质量计量监督检测所 | High temperature frit powdered frit material and its preparation method with wear-resisting antiskid glaze for glazed tile |
| CN109336393A (en) * | 2018-11-14 | 2019-02-15 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
| CN109354406A (en) * | 2018-11-14 | 2019-02-19 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
| CN110128016A (en) * | 2019-04-26 | 2019-08-16 | 佛山市玉矶材料科技有限公司 | A kind of no zirconium ultrawhite overglaze and preparation method thereof |
| CN112299718A (en) * | 2020-10-16 | 2021-02-02 | 蒙娜丽莎集团股份有限公司 | Magnesium aluminate spinel wear-resistant printing glaze and preparation method and application thereof |
| CN112723744A (en) * | 2021-04-06 | 2021-04-30 | 佛山市东鹏陶瓷有限公司 | Zirconium-free microcrystalline milky-white frit, zirconium-free high-white ground glaze and preparation method thereof |
| CN113788617A (en) * | 2021-09-26 | 2021-12-14 | 广东百强陶瓷有限公司 | Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof |
| CN115504670A (en) * | 2022-09-30 | 2022-12-23 | 景德镇陶瓷大学 | Preparation method of high-glossiness sweet white glaze |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473708A (en) * | 2017-09-22 | 2017-12-15 | 福建省德化县嘉威陶瓷有限公司 | A kind of slow heat conduction, high-strength ceramic product and its manufacturing process |
| CN107473708B (en) * | 2017-09-22 | 2020-05-01 | 福建省德化县嘉威陶瓷有限公司 | Slow heat conduction and high strength ceramic product and manufacturing process thereof |
| CN109180000A (en) * | 2018-11-09 | 2019-01-11 | 广东省清远市质量计量监督检测所 | High temperature frit powdered frit material and its preparation method with wear-resisting antiskid glaze for glazed tile |
| CN109336393A (en) * | 2018-11-14 | 2019-02-15 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
| CN109354406A (en) * | 2018-11-14 | 2019-02-19 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
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