CN106966462A - A kind of multistage seawater desalting coupled system - Google Patents

A kind of multistage seawater desalting coupled system Download PDF

Info

Publication number
CN106966462A
CN106966462A CN201710273787.2A CN201710273787A CN106966462A CN 106966462 A CN106966462 A CN 106966462A CN 201710273787 A CN201710273787 A CN 201710273787A CN 106966462 A CN106966462 A CN 106966462A
Authority
CN
China
Prior art keywords
air
seawater
water
reverse osmosis
bittern
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710273787.2A
Other languages
Chinese (zh)
Inventor
黄斯珉
张文凯
杨敏林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan University of Technology
Original Assignee
Dongguan University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan University of Technology filed Critical Dongguan University of Technology
Priority to CN201710273787.2A priority Critical patent/CN106966462A/en
Publication of CN106966462A publication Critical patent/CN106966462A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0003Condensation of vapours; Recovering volatile solvents by condensation by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • EFIXED CONSTRUCTIONS
    • E03WATER SUPPLY; SEWERAGE
    • E03BINSTALLATIONS OR METHODS FOR OBTAINING, COLLECTING, OR DISTRIBUTING WATER
    • E03B3/00Methods or installations for obtaining or collecting drinking water or tap water
    • E03B3/28Methods or installations for obtaining or collecting drinking water or tap water from humid air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a kind of multistage seawater desalting coupled system, it includes air humidifying device, air heating apparatus and air dehumidification device;The device is a multistage humidification dehumidification and reverse osmosis seawater desalting coupling device by Driven by Solar Energy, takes full advantage of bittern out in humidifier, realizes the deep exploitation of seawater, economize on resources.Because the present apparatus is driven using solar energy, air heating uses solar thermal collector, and the electric energy that is produced in counter-infiltration to the pressurized operation of bittern using photovoltaic array drives booster pump so that the more efficient environment protecting and power-saving of the present apparatus.

Description

A kind of multistage seawater desalting coupled system
Technical field
The invention belongs to field of seawater desalination, and in particular to a kind of multistage seawater desalting coupled system.
Background technology
Freshwater resources have extremely important influence to the production and living of people, are the most important things of human survival and development One of basis is provided, but can reach that the freshwater resources of production and living conditions are very limited at present, freshwater resources both domestic and external are in short supply Situation it is increasingly serious.Contain substantial amounts of water resource in ocean, but it contains the materials such as substantial amounts of halogens, therefore can not be by people Directly utilize.Current development and utilization desalination technology, which has been increasingly becomed, solves the important of freshwater resources problem in short supply Means.
Conventional method for desalting seawater have seawater freezing process, electroosmose process, the way of distillation, hyperfiltration and ammonium carbonate from Sub- exchange process etc., by cost, limitation the problems such as technique and efficiency, current most widely used method is reverse osmosis membrane and steaming Evaporate method.Hyperfiltration make use of the pellicle with selective penetrated property to separate seawater and freshwater, apply greatly when to seawater side When the external pressure of penetration of sea water pressure, fresh water in seawater will counter-infiltration into fresh water.Compared with other technologies, counter-infiltration seawater Desalination technology has significant power saving advantages, therefore develops at present very fast, is widely used.
But the subject matter that existing Reverse-osmosis Seawater Desalination Technology faces is that equipment requirement is high, it is necessary to consume substantial amounts of High-grade energy, and the yield of fresh water is relatively low.Such as notification number is that CN106045114A Chinese invention patent applications disclose explanation Book discloses a kind of fresh water deposit station based on Reverse-osmosis Seawater Desalination Technology, there is higher fresh water yield, and a variety of fields can be achieved The application of conjunction, but there is the problem of consuming energy larger, higher to equipment requirement etc., it is necessary to progress, which is improved, could reduce energy consumption. If notification number is that CN105923708A Chinese invention patent application prospectus discloses a kind of self-supporting power supply formula counter-infiltration sea Water desalination apparatus, can utilize wind energy, solar energy and waterpower equal energy source, but fresh water yield is relatively low.
The content of the invention
For deficiencies of the prior art, the present invention provides a kind of deep exploitation and green energy conservation ring to seawater The multistage seawater desalting coupled system of guarantor.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of multistage seawater desalting coupled system, including air humidifying device, air heating apparatus and air dehumidification device:
Described air heating apparatus includes being used for the air-introduced machine of the outer air of intake system and the sun for heating air Energy heat collector, the air outlet of described air-introduced machine passes through the air inlet of the heating breather pipe inside air inlet pipe and solar thermal collector Connection, is heated for air outside the system to suction, to form hot-air;The gas outlet of the heating breather pipe and described sky Gas humidification device is connected.
Described air humidifying device includes spray column, and the gas outlet of the heating breather pipe passes through pipeline and the spray column Bottom connection, to introduce hot-air;Top in spray column is provided with some spray heads, for sprayed sea water so that sea Water and the air of heated breather pipe input carry out mass-and heat-transfer, and form the residual seawater and aqueous sky for completing mass-and heat-transfer Gas;Residual seawater discharge pipe is communicated with the bottom of spray column, for residual seawater to be discharged;On the side wall of the spray column Spray column exhaust outlet is provided with, for discharging air contained water.
Described air dehumidification device is dividing wall type heat exchanger, and the import of the tube side of the dividing wall type heat exchanger enters for seawater Mouthful, the air contained water in shell side is condensed for being introduced into seawater, and form condensation fresh water and condensation air;The dividing wall type heat exchanger The outlet of tube side connected by pipeline with described spray head, to provide seawater to spray head;The dividing wall type heat exchanger The import of shell side connected by pipeline with described spray column exhaust outlet, for introducing air contained water;The dividing wall type heat exchanger The water out of shell side be opened in the bottom of dividing wall type heat exchanger and connected with fresh-water pool, for discharging condensation fresh water;The partition The condensation air outlet slit of the shell side of formula heat exchanger is opened in the bottom of dividing wall type heat exchanger, for discharging condensation air.
Further, described condensation air outlet slit is connected by air circulating umbilical with the air outlet of the air-introduced machine, is used to Amount of the air circulation using air outside the system to reduce air-introduced machine introducing will be condensed, to save the energy.
Further, in addition to reverse osmosis seawater desalination system, the reverse osmosis seawater desalination system includes reverse osmosis unit, should Reverse osmosis unit includes a booster pump and a reverse osmosis membrane assembly;The water inlet of booster pump is discharged with described residual seawater Pipe is connected, for introducing residual seawater;The water inlet end of reverse osmosis membrane assembly is connected with the delivery port of booster pump;Reverse osmosis membrane group The fresh water outlet end of part is connected with described with fresh-water pool, to reclaim fresh water;The bittern water side of reverse osmosis membrane assembly and bittern Delivery pipe is connected.
Further, described reverse osmosis seawater desalination system includes N grades of reverse osmosis units, wherein, N is >=2 natural number; Every grade of reverse osmosis unit includes a booster pump and a reverse osmosis membrane assembly;The water inlet of first order booster pump is remained with described Remaining seawater discharge pipe connection, for introducing residual seawater;The water inlet end of reverse osmosis membrane assemblies at different levels with booster pump at the same level Delivery port is connected;The fresh water outlet end of reverse osmosis membrane assemblies at different levels is connected with described with fresh-water pool, to reclaim fresh water;It is at different levels anti- The bittern water side of permeable membrane element is connected with the water inlet of the booster pump of next stage reverse osmosis unit;By that analogy;N grades anti- The bittern water side of permeable membrane element is connected with bittern delivery pipe.
Further, described fresh-water pool is connected with the water inlet end of reverse osmosis membrane assemblies at different levels by regulation pipe, for adjusting Water inlet end salinity simultaneously improves water quality;Regulation pump and regulating valve are provided with described regulation pipe.
Further, the water side of bittern delivery pipe is also communicated with solar evaporation pond, to reclaim bittern and improve its salinity; Also include the crystallizing pond connected with solar evaporation pond, to reclaim salt;The crystallizing pond set discharge gate, to discharge finished product salt and Mother liquor.
Further, screen pack is provided with described spray column exhaust outlet, for intercepting drop discharge.
Further, described N=3.
Further, described solar thermal collector is solar thermal collector generating set, and its generating set draws with described Blower fan and booster pump at different levels connection, to realize the confession of electric energy.
Further, the tube side of described dividing wall type heat exchanger is coiled pipe.
Air is heated present invention uses solar thermal collector, the booster pump in counter-infiltration is by photovoltaic array The electricity of generation is driven, and seawater desalination system is made up of multi-stage reverse osmosis membrane module, realize the deep exploitation of seawater, fresh water is simultaneously Produced by air setting and reverse osmosis seawater desalting, so as to substantially increase fresh water yield, bittern is formed through pervaporation and crystallization Salt and mother liquor, realize the deep exploitation to seawater, meet the demand of fresh water and salt, and more energy-saving and environment friendly.
Compared with prior art, the present invention has the advantages that:
1st, desalination rate is high.It is of the invention compared with existing sea water desalinating unit, the heating of seawater by being tapped into solar energy OK, and using solar energy as drive energy, coupled, taken full advantage of in humidifier with reverse osmosis seawater desalting by humidification, dehumidification Fresh water out, to seawater with having carried out depth, multipath desalination, desalination rate is high.
2nd, solar energy utilization ratio is high.Because the present invention is driven using solar energy, air heating uses solar energy heating Device, is also the waste heat that make use of the sun indirectly to the heating of seawater, the pressurized operation of bittern has then been used too in counter-infiltration It is positive can the photovoltaic array electric energy that produces drive booster pump.
3rd, environmental protection.Because the present invention can realize power self-support, high-quality electric energy, efficient green ring are supplied without using outer Protect energy-conservation.
4th, resource recovery is high.The present invention can simultaneously output electric energy, fresh water and salt, fully using beach seawater and Solar energy resources, meets the direction of development of modern industry, beneficial to being widely applied and use.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
In accompanying drawing:1 --- seawater inlet;3 --- air dehumidification device;4 --- air circulating umbilical;5 --- air-introduced machine; 6 --- solar thermal collector;8 --- spray column;9 --- screen pack;10 --- booster pump;11 --- pressure-regulating valve; 12 --- reverse osmosis membrane assembly;13 --- regulation pump;15 --- solar evaporation pond;16 --- crystallizing pond;17 --- discharge gate; 18 --- fresh-water pool.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
A kind of multistage seawater desalting coupled system, including air humidifying device, air heating apparatus and air dehumidification device 3:
Described air heating apparatus includes being used for the air-introduced machine 5 of the outer air of intake system and the sun for heating air Can heat collector 6, the air outlet of described air-introduced machine 5 entered by air inlet pipe and the heating breather pipe inside solar thermal collector 6 Gas port is connected, and is heated for air outside the system to suction, to form hot-air;It is described heating breather pipe gas outlet with it is described Air humidifying device connection.Heated using solar energy, the substantial amounts of energy can be saved, be conducive to the protection of environment, also Be conducive to walking in the mass-and heat-transfer effect with seawater and extract more moisture.
Described air humidifying device includes spray column 8, and the gas outlet of the heating breather pipe passes through pipeline and the spray The bottom connection of tower 8, to introduce hot-air;Top in spray column 8 is provided with some spray heads, for sprayed sea water with The air for inputting seawater and heated breather pipe carries out mass-and heat-transfer, and forms the residual seawater for completing mass-and heat-transfer and aqueous Air;Residual seawater discharge pipe is communicated with the bottom of spray column 8, for residual seawater to be discharged;In the side of the spray column 8 Spray column exhaust outlet is provided with wall, for discharging air contained water.
Described air dehumidification device 3 is dividing wall type heat exchanger, and the import of the tube side of the dividing wall type heat exchanger is seawater Entrance 1, the air contained water in shell side is condensed for being introduced into seawater, and form condensation fresh water and condensation air;The dividing wall type is changed The outlet of the tube side of hot device is connected by pipeline with described spray head, to provide seawater to spray head;The dividing wall type is changed The import of the shell side of hot device is connected by pipeline with the described exhaust outlet of spray column 8, for introducing air contained water;The dividing wall type is changed The water out of the shell side of hot device is opened in the bottom of dividing wall type heat exchanger and connected with fresh-water pool 18, for discharging condensation fresh water; The condensation air outlet slit of the shell side of the dividing wall type heat exchanger is opened in the bottom of dividing wall type heat exchanger, for discharging condensation air.Institute It is a kind of non-direct contact type heat exchanger to state dividing wall type condenser, there is two runners of air and seawater, described air flow channel (shell Journey) in flowing be hot and humid air, and then flowed in seawater runner (tube side) is seawater, the flowing side of two kinds of fluids To on the contrary, and the completion heat transfer during flowing --- seawater is given air contained water to cool and condensed, and air contained water gives seawater to carry out Preheating, the utilization rate of the energy can be so improved to greatest extent.
Heated by solar thermal collector 6 to air outside the system introduced, it is empty with the heat for being allowed to be converted into dry, high temperature Gas, when hot-air enters spray column 8, heat sky water bottom-up motion, and the seawater generation mass-and heat-transfer gone out from top spray, Formed outside air contained water and residual seawater containing a large amount of vapor, residual seawater and arranged.Air contained water then enters wall-type heat exchange Device is condensed, and condensed water is fresh water, can be recycled.This uses seawater, that is, reached cold during one in tube side Solidifying effect, can utilize the heat in air contained water to be heated for seawater again, then the seawater heated importing spray column 8 is carried out Spray, this not only contributes to improve the mass-and heat-transfer efficiency in spray column 8, also drastically increases the utilization rate of the energy.
In addition, the effect in order to further improve the heat transfer of the inner transmission matter of spray column 8, structured packing, tower can be set wherein Plate or film contact filler.
As optimization, described condensation air outlet slit is connected by air circulating umbilical 4 with the air outlet of the air-introduced machine 5, Air circulation will be condensed using the amount of air outside the system that air-introduced machine 5 is introduced is reduced, to save the energy.Condense in air Also contain higher moisture content, and after condensation, temperature is relatively low, pressure is higher, by it be recycled to the air outlet of air-introduced machine 5 with it is new The extraneous air of introducing is mixed with two big advantages:One is available with the higher advantage of its pressure, promotes mixing air to spray Tower 8 flows, and reduces the amount of the extraneous air of introducing, reduces the load of air-introduced machine 5, reduces power consumption;Two be can make it is cold The moisture of solidifying air is again introduced into spray column 8 and recycled, and can improve fresh water yield.
A part of fresh water of extraction process is only capable of by spray column 8, remaining fresh water is still present in surplus in the form of solvent In remaining seawater, it is therefore necessary to carry out further desalt processing to it, to obtain more fresh water.Therefore, the present invention is also wrapped Reverse osmosis seawater desalination system is included, the reverse osmosis seawater desalination system includes reverse osmosis unit, the reverse osmosis unit includes one Booster pump 10 and a reverse osmosis membrane assembly 12;The water inlet of booster pump 10 is connected with described residual seawater discharge pipe, is used for Introduce residual seawater;Delivery port of the water inlet end of reverse osmosis membrane assembly 12 with booster pump 10 is connected;Reverse osmosis membrane assembly 12 Fresh water outlet end is connected with described with fresh-water pool 18, to reclaim fresh water;The bittern water side of reverse osmosis membrane assembly 12 and bittern Delivery pipe is connected.Seawater pressurizes through booster pump 10, passes through reverse osmosis membrane assembly 12, is arrived the hydraulic pressure in seawater using osmotic pressure Among fresh water stream, so as to realize the desalination of seawater.On pipeline between booster pump 10 and reverse osmosis membrane assembly 12, it can also set Pressure-regulating valve 11 is equipped with, more accurately to adjust pressure.
As optimization, in order to improve the effect of desalinization, described reverse osmosis seawater desalination system can include N grades instead Permeability apparatus (N is >=2 natural number):Every grade of reverse osmosis unit includes a booster pump 10 and a reverse osmosis membrane assembly 12; The water inlet of first order booster pump 10 is connected with described residual seawater discharge pipe, for introducing residual seawater;Counter-infiltrations at different levels Delivery port of the water inlet end of membrane module 12 with booster pump 10 at the same level is connected;The fresh water outlet end of reverse osmosis membrane assemblies 12 at different levels Connected with described with fresh-water pool 18, to reclaim fresh water;The bittern water side of reverse osmosis membrane assemblies 12 at different levels and next stage reverse osmosis The water inlet connection of the booster pump 10 of saturating device;By that analogy;Arranged with bittern the bittern water side of N grades of reverse osmosis membrane assemblies 12 Put pipe connection.Seawater pressurizes through booster pump 10, passes through reverse osmosis membrane assembly 12, using osmotic pressure by the hydraulic pressure in seawater to light Among current, so as to realize the one-level desalination of seawater, seawater passes through second level reverse osmosis unit afterwards, carries out identical behaviour Make, by that analogy, so as to realize that multi-stage reverse osmosis is operated, reach the purpose of desalinization.In booster pumps 10 at different levels and counter-infiltration On pipeline between membrane module 12, pressure-regulating valve 11 is also provided with, more accurately to adjust pressure.
As further optimization, the water inlet end of described fresh-water pool 18 and reverse osmosis membrane assemblies 12 at different levels is connected by regulation pipe It is logical, for adjusting water inlet end salinity and improving water quality;Regulation pump 13 and regulating valve are provided with described regulation pipe.Pass through Regulation regulation pump 13 and regulating valve, can control the fresh water amount into reverse osmosis seawater desalination system.Why this design is had, There are two reasons:One is also to remain certain salt solution in the fresh water reclaimed by condensation, is carried out at least one times Counter-infiltration can improve the purity of fresh water;Two be that can adjust the salinity of the reduction water inlet degree of reverse osmosis membrane assembly 12, anti-to extend The service life of permeable membrane element 12.
As further optimization, the water side of bittern delivery pipe is also communicated with solar evaporation pond 15, to reclaim bittern simultaneously Improve its salinity;Also include the crystallizing pond 16 connected with solar evaporation pond 15, to reclaim salt;The crystallizing pond 16 sets discharge gate 17, to discharge finished product salt and mother liquor.The waste liquid after desalination --- contain substantial amounts of salt in bittern, can recycle, Bittern is through pervaporation and crystallization, and forming salt and mother liquor realize the deep exploitation to seawater, meet the demand of salt, more green energy conservation Environmental protection.
As optimization, screen pack 9 is provided with described spray column exhaust outlet, for intercepting drop discharge.
It is used as further optimization, described N=3.Air humidifying device, air heating apparatus and the air dehumidification of the present invention The desalinization rate of device 3 is 30% or so, but can reduce the use of high-grade electric energy, and seawater is desalinated in advance, adopted It is 40% left per the desalinization efficiency of one-level reverse osmosis membrane assembly 12 with the further deep exploitation of three-level reverse osmosis membrane assembly 12 The right side, if using three-level counter-infiltration, can by seawater, always desalination rate brings up to 95% or so, realize the deep exploitation to seawater.
As further optimization, solar thermal collector 6 is in addition to heating air, and also substantial amounts of waste heat is therefore, described Solar thermal collector 6 can contemplate using more ripe solar thermal collector generating set (such as photovoltaic array), Its generating set is connected with described air-introduced machine 5 and booster pump at different levels 10, to realize the confession of electric energy, and high-grade is not used directly Electric energy so as to farthest utilize the energy, when electricity is had a surplus, outer can also supply.
As further optimization, the tube side of described dividing wall type heat exchanger is coiled pipe.The seawater runner can be so set to be Spirally coiled structure, it is surrounded by the air flow channel of shell side, is conducive to improving the efficiency of heat exchange.
Compared with existing sea water desalinating unit, the heating to seawater is carried out by solar thermal collector 6, using solar energy as drive Energy source, is pressurizeed using booster pump 10 to seawater, is run through multi-stage reverse osmosis membrane module 12, real using reverse osmosis Existing desalinization.The device is a multistage humidification dehumidification and reverse osmosis seawater desalting coupling device by Driven by Solar Energy, is filled Divide the bittern that make use of and come out in humidifier, realize the deep exploitation of bittern.Because the present apparatus is driven using solar energy, Air heating uses solar thermal collector 6, and the electricity that photovoltaic array is produced is used to the pressurized operation of bittern in counter-infiltration Booster pump 10 can be driven so that the present apparatus more efficient environment protecting and power-saving.
The above embodiment of the present invention is only example to illustrate the invention, and is not the implementation to the present invention The restriction of mode.For those of ordinary skill in the field, other can also be made not on the basis of the above description With the change and variation of form.Here all embodiments can not be exhaustive.It is every to belong to technical scheme Row of the obvious changes or variations amplified out still in protection scope of the present invention.

Claims (10)

1. a kind of multistage seawater desalting coupled system, it is characterised in that including air humidifying device, air heating apparatus and air Dehumidifying device;
Described air heating apparatus includes being used for the air-introduced machine of the outer air of intake system and the solar energy collection for heating air Hot device, the air outlet of described air-introduced machine is connected by the air inlet of the heating breather pipe inside air inlet pipe and solar thermal collector It is logical, heated for air outside the system to suction, to form hot-air;The gas outlet of the heating breather pipe and described air Humidification device is connected;
Described air humidifying device includes spray column, and the gas outlet of the heating breather pipe passes through under pipeline and the spray column Portion is connected, to introduce hot-air;Top in spray column is provided with some spray heads, for sprayed sea water so that seawater and The air of heated breather pipe input carries out mass-and heat-transfer, and forms the residual seawater and air contained water for completing mass-and heat-transfer; The bottom of spray column is communicated with residual seawater discharge pipe, for residual seawater to be discharged;It is provided with the side wall of the spray column Spray column exhaust outlet, for discharging air contained water;
Described air dehumidification device is dividing wall type heat exchanger, and the import of the tube side of the dividing wall type heat exchanger is seawater inlet, The air contained water in shell side is condensed for being introduced into seawater, and forms condensation fresh water and condensation air;The dividing wall type heat exchanger The outlet of tube side is connected by pipeline with described spray head, to provide seawater to spray head;The dividing wall type heat exchanger The import of shell side is connected by pipeline with described spray column exhaust outlet, for introducing air contained water;The dividing wall type heat exchanger The water out of shell side is opened in the bottom of dividing wall type heat exchanger and connected with fresh-water pool, for discharging condensation fresh water;The dividing wall type The condensation air outlet slit of the shell side of heat exchanger is opened in the bottom of dividing wall type heat exchanger, for discharging condensation air.
2. multistage seawater desalting coupled system according to claim 1, it is characterised in that described condensation air outlet slit leads to The air outlet that air circulating umbilical is crossed with the air-introduced machine is connected, to will condense air circulation utilize reduce air-introduced machine introduce The amount of the outer air of system, to save the energy.
3. multistage seawater desalting coupled system according to claim 1, it is characterised in that also including reverse osmosis seawater desalting System, the reverse osmosis seawater desalination system includes reverse osmosis unit, and the reverse osmosis unit includes a booster pump and a reverse osmosis Permeable membrane component;The water inlet of booster pump is connected with described residual seawater discharge pipe, for introducing residual seawater;Reverse osmosis membrane group The water inlet end of part is connected with the delivery port of booster pump;The fresh water outlet end of reverse osmosis membrane assembly connects with described with fresh-water pool It is logical, to reclaim fresh water;The bittern water side of reverse osmosis membrane assembly is connected with bittern delivery pipe.
4. multistage seawater desalting coupled system according to claim 1, it is characterised in that described reverse osmosis seawater desalting System includes N grades of reverse osmosis units, wherein, N is >=2 natural number;
Every grade of reverse osmosis unit includes a booster pump and a reverse osmosis membrane assembly;The water inlet of first order booster pump with it is described Residual seawater discharge pipe connection, for introducing residual seawater;Supercharging of the water inlet end of reverse osmosis membrane assemblies at different levels with peer The delivery port connection of pump;The fresh water outlet end of reverse osmosis membrane assemblies at different levels is connected with described with fresh-water pool, to reclaim fresh water;Respectively The bittern water side of level reverse osmosis membrane assembly is connected with the water inlet of the booster pump of next stage reverse osmosis unit;By that analogy;
The bittern water side of N grades of reverse osmosis membrane assemblies is connected with bittern delivery pipe.
5. multistage seawater desalting coupled system according to claim 4, it is characterised in that described fresh-water pool with it is at different levels anti- The water inlet end of permeable membrane element is connected by regulation pipe, for adjusting water inlet end salinity and improving water quality;Described regulation Regulation pump and regulating valve are provided with pipe.
6. multistage seawater desalting coupled system according to claim 4, it is characterised in that the water side of bittern delivery pipe is also Solar evaporation pond is communicated with, to reclaim bittern and improve its salinity;Also include the crystallizing pond connected with solar evaporation pond, with Reclaim salt;The crystallizing pond sets discharge gate, to discharge finished product salt and mother liquor.
7. multistage seawater desalting coupled system according to claim 1, it is characterised in that on described spray column exhaust outlet Screen pack is provided with, for intercepting drop discharge.
8. according to the multistage seawater desalting coupled system described in claim 4, it is characterised in that described N=3.
9. according to the multistage seawater desalting coupled system described in claim 4, it is characterised in that described solar thermal collector is too Positive energy heat collector generating set, its generating set is connected with described air-introduced machine and booster pump at different levels, to realize the confession of electric energy.
10. multistage seawater desalting coupled system according to claim 1, it is characterised in that described dividing wall type heat exchanger Tube side be coiled pipe.
CN201710273787.2A 2017-04-25 2017-04-25 A kind of multistage seawater desalting coupled system Pending CN106966462A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710273787.2A CN106966462A (en) 2017-04-25 2017-04-25 A kind of multistage seawater desalting coupled system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710273787.2A CN106966462A (en) 2017-04-25 2017-04-25 A kind of multistage seawater desalting coupled system

Publications (1)

Publication Number Publication Date
CN106966462A true CN106966462A (en) 2017-07-21

Family

ID=59334015

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710273787.2A Pending CN106966462A (en) 2017-04-25 2017-04-25 A kind of multistage seawater desalting coupled system

Country Status (1)

Country Link
CN (1) CN106966462A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108203198A (en) * 2018-01-17 2018-06-26 上海交通大学 A kind of PV/T drives hotting mask combination seawater desalination system
CN108439512A (en) * 2018-05-17 2018-08-24 北京今大禹环境技术股份有限公司 A kind of thermal drivers high organic wastewater Zero-discharge treating process with high salt
CN112484174A (en) * 2020-11-23 2021-03-12 自然资源部天津海水淡化与综合利用研究所 Humidification and dehumidification seawater desalination and air conditioning all-in-one machine based on vapor compression heat pump technology

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201634462U (en) * 2009-09-15 2010-11-17 江苏大学 Seawater desalting device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201634462U (en) * 2009-09-15 2010-11-17 江苏大学 Seawater desalting device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
冯旭东: "《给水排水设计手册 第4册——工业给水处理 第二版》", 30 April 2002, 中国建筑工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108203198A (en) * 2018-01-17 2018-06-26 上海交通大学 A kind of PV/T drives hotting mask combination seawater desalination system
CN108203198B (en) * 2018-01-17 2021-03-09 上海交通大学 PV/T driving hot film combined seawater desalination system
CN108439512A (en) * 2018-05-17 2018-08-24 北京今大禹环境技术股份有限公司 A kind of thermal drivers high organic wastewater Zero-discharge treating process with high salt
CN108439512B (en) * 2018-05-17 2020-07-03 北京今大禹环境技术股份有限公司 Thermal-drive high-salinity high-organic-matter wastewater zero-discharge treatment process
CN112484174A (en) * 2020-11-23 2021-03-12 自然资源部天津海水淡化与综合利用研究所 Humidification and dehumidification seawater desalination and air conditioning all-in-one machine based on vapor compression heat pump technology

Similar Documents

Publication Publication Date Title
CN103265089B (en) High temperature high efficiency multi-effect seawater distillation desalination apparatus and method
CN105417606A (en) Multi-effect distillation and multi-stage flash evaporation solar sea water desalination method
CN101723476B (en) Seawater desalination device employing solar energy and vapor compressing distillation
CN104211130A (en) Low-temperature evaporation, concentration and crystallization system and method using waste heat
CN108793299A (en) A kind of small-sized solar energy sea water desalination apparatus and method
CN103058438B (en) Hot film coupling seawater desalination system
CN103112985A (en) Multi-stage flash distillation seawater desalination system of low-temperature multi-effect steamer vapor compression distillation
CN204051448U (en) High-efficient flat-plate distillation device
CN107434327A (en) The hotting mask coupling seawater desalination system of Water Sproading more than a kind of waste heat overbottom pressure
CN106966462A (en) A kind of multistage seawater desalting coupled system
CN104190260A (en) Decompression combination airgap membrane distillation method and device thereof
CN105084445A (en) Efficient membrane distillation method and device
CN104803532A (en) Seawater desalting device adopting membrane type humidification and dehumidification and seawater desalting method
CN109647208A (en) A kind of energy conservation film distilling seawater desalination system
CN201834781U (en) Single-stage vacuum distillation seawater desalination device
CN103663589B (en) Seawater desalinization method and seawater desalinization device
CN102679468B (en) Regeneration system of dehumidifying solution for moist air
CN103359800B (en) Stirling heat pump seawater desalination device
CN201660457U (en) Novel multiple-effect distilled sea water desalination device
CN101792190B (en) Novel solar seawater desalination system
CN203781962U (en) Household solar-powered seawater desalination system
CN108128831A (en) Solar heat pump desalination plant
CN102583608B (en) Ejection type solar seawater desalination device
CN205061622U (en) Efficient membrane distillation plant
CN105236504B (en) Single vacuum chamber hypergravity normal-temp multi-stage flash evaporation seawater desalting system

Legal Events

Date Code Title Description
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170721