CN106957551A - A kind of oil colour of quick-drying freedom from cracking and preparation method thereof - Google Patents
A kind of oil colour of quick-drying freedom from cracking and preparation method thereof Download PDFInfo
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- CN106957551A CN106957551A CN201710330401.7A CN201710330401A CN106957551A CN 106957551 A CN106957551 A CN 106957551A CN 201710330401 A CN201710330401 A CN 201710330401A CN 106957551 A CN106957551 A CN 106957551A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention provides a kind of oil colour of quick-drying freedom from cracking and preparation method thereof, and the oil colour is made up of the raw material of following parts by weight：20 30 parts of acrylic emulsion, 10 15 parts of ester-polyurethane resin emulsion, 5 10 parts of tertiary ethylene carbonate, 15 20 parts of zeolite powder, 10 15 parts of pigment toner, 36 parts of dipropylene glycol n-butyl ether, 36 parts of butyl acetate, 0.5 1 parts of polyethylene glycol methacrylic acid copolymer body, 0.2 1 parts of beeswax, 0.2 1 parts of drier, 0.2 1 parts of Sodium Benzoate, 10 20 parts of distilled water.Each formula collective effect, effectively improves the air-dried speed of oil colour in the present invention, while the color and luster of pigment, hardness, stability can also be improved, drawing efficiency is improved, with good application value.
Description
Technical field
The present invention relates to oil colour technical field, and in particular to a kind of oil colour of quick-drying freedom from cracking and its preparation side
Method.
Background technology
Oil colour is a kind of special drawing pigment of oil painting, is refueled by pigment powder and glue agitation grinding is formed.For oil painting
For, some thickness are applied can not solidify simultaneously in the table of part, it is necessary to be carried out by longer period of time after general oil painting is completed
In dry, what is had needs several months ability, and the picture top layer time easily chaps too long.In the process, due to the electrostatic on picture
Effect, it will usually adsorb some trifle in the worlds or tiny hair, and storage is infiltrated by the oiliness surface permanent of picture, this is in larger journey
The quality of oil painting is have impact on degree.And in recent years, with the development of drawing industry, requirement of the people to painting pigment is also more next
It is higher, higher requirement is proposed to antistatic property, resistance to ag(e)ing, adhesive force, crack resistance, glossiness.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of oil colour of quick-drying freedom from cracking and preparation method thereof.
To realize object above, the present invention is achieved by the following technical programs：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：It is 20-30 parts of acrylic emulsion, poly-
10-15 parts of urethane resin emulsion, 5-10 parts of tertiary ethylene carbonate, 15-20 parts of zeolite powder, 10-15 parts of pigment toner, DPG
3-6 parts of n-butyl ether, 3-6 parts of butyl acetate, 0.5-1 parts of polyethylene glycol methacrylic acid copolymer body, 0.2-1 parts of beeswax, urge
Dry 0.2-1 parts of agent, 0.2-1 parts of Sodium Benzoate, 10-20 parts of distilled water.
Preferably, it is made up of the raw material of following parts by weight：25 parts of acrylic emulsion, 12 parts of ester-polyurethane resin emulsion, tertiary carbon
8 parts of vinyl acetate, 18 parts of zeolite powder, 12 parts of pigment toner, 4 parts of dipropylene glycol n-butyl ether, 5 parts of butyl acetate, polyethylene second two
0.6 part of alcohol methacrylic acid copolymer body, 0.4 part of beeswax, 0.5 part of drier, 0.4 part of Sodium Benzoate, 15 parts of distilled water.
Preferably, the drier is selected from cobalt borate.
Preferably, the particle diameter of the zeolite powder is 600-800 mesh.
The preparation method of the oil colour of quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under agitation, polyaminoester emulsion is added in acrylic emulsion, 10-20min is stirred, obtains base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, drier, are added in grinder and grind
3-5 times, slurry is obtained, sealed storage is produced.
Preferably, the step 1) in stir speed (S.S.) be 300-400rpm.
Beneficial effect of the present invention：Zeolite powder rough surface in the present invention, and with loose structure, so as to improve in oil painting
The mixing uniformity of each composition, is conducive to improving the rate of drying of oil painting paintings pigment inside, and zeolite powder does not produce electrostatic and showed
As；Tertiary ethylene carbonate assigns pigment excellent anti-oxidant, UV resistance, and excellent cracking resistance, and oil painting paintings are done
Dry rear surface is not easily cracked；Ester-polyurethane resin emulsion can improve the glossiness, pliability and hardness of pigment；Polyethylene glycol
Methacrylic acid copolymer body can effectively prevent that paintings surface generation Electrostatic Absorption ash is miscellaneous, each formula collective effect in the present invention,
The air-dried speed of oil colour is effectively improved, while the color and luster of pigment, hardness, stability can also be improved, drawing efficiency is improved,
With good application value.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：22 parts of acrylic emulsion, polyurethane
12 parts of resin emulsion, 6 parts of tertiary ethylene carbonate, 16 parts of zeolite powder, 12 parts of pigment toner, 4 parts of dipropylene glycol n-butyl ether, acetic acid fourth
3 parts of ester, 0.6 part of polyethylene glycol methacrylic acid copolymer body, 0.3 part of beeswax, 0.3 part of drier, 0.3 part of Sodium Benzoate,
15 parts of distilled water.
The preparation method of the oil colour of quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under agitation, polyaminoester emulsion is added in acrylic emulsion, 15min is stirred, obtains base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, drier, are added in grinder and grind
4 times, slurry is obtained, sealed storage is produced.
Embodiment 2：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：25 parts of acrylic emulsion, polyurethane
12 parts of resin emulsion, 8 parts of tertiary ethylene carbonate, 18 parts of zeolite powder (700 mesh), 12 parts of pigment toner, dipropylene glycol n-butyl ether 4
Part, 5 parts of butyl acetate, 0.6 part of polyethylene glycol methacrylic acid copolymer body, 0.4 part of beeswax, 0.5 part of cobalt borate, benzoic acid
0.4 part of sodium, 15 parts of distilled water.
The preparation method of the oil colour of quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under rotating speed 350rpm stirring condition, polyaminoester emulsion is added in acrylic emulsion, 15min is stirred,
Obtain base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, cobalt borate, are added in grinder and grind
4 times, slurry is obtained, sealed storage is produced.
Embodiment 3：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：30 parts of acrylic emulsion, polyurethane
15 parts of resin emulsion, 8 parts of tertiary ethylene carbonate, 20 parts of zeolite powder (800 mesh), 13 parts of pigment toner, dipropylene glycol n-butyl ether 5
Part, 5 parts of butyl acetate, 0.8 part of polyethylene glycol methacrylic acid copolymer body, 0.5 part of beeswax, 0.6 part of cobalt borate, benzoic acid
0.6 part of sodium, 18 parts of distilled water.
The preparation method of the oil colour of quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under rotating speed 300rpm stirring condition, polyaminoester emulsion is added in acrylic emulsion, 20min is stirred,
Obtain base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, cobalt borate, are added in grinder and grind
3 times, slurry is obtained, sealed storage is produced.
Embodiment 4：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：20 parts of acrylic emulsion, polyurethane
15 parts of resin emulsion, 5 parts of tertiary ethylene carbonate, 20 parts of zeolite powder (800 mesh), 10 parts of pigment toner, dipropylene glycol n-butyl ether 6
Part, 3 parts of butyl acetate, 1 part of polyethylene glycol methacrylic acid copolymer body, 0.2 part of beeswax, 1 part of cobalt borate, Sodium Benzoate
0.2 part, 20 parts of distilled water.
The preparation method of the oil colour of quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under rotating speed 400rpm stirring condition, polyaminoester emulsion is added in acrylic emulsion, 10min is stirred,
Obtain base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, cobalt borate, are added in grinder and grind
3 times, slurry is obtained, sealed storage is produced.
Embodiment 5：
A kind of oil colour of quick-drying freedom from cracking, is made up of the raw material of following parts by weight：30 parts of acrylic emulsion, polyurethane
10 parts of resin emulsion, 10 parts of tertiary ethylene carbonate, 15 parts of zeolite powder (600 mesh), 15 parts of pigment toner, dipropylene glycol n-butyl ether 3
Part, 6 parts of butyl acetate, 0.5 part of polyethylene glycol methacrylic acid copolymer body, 1 part of beeswax, 0.2 part of cobalt borate, Sodium Benzoate
1 part, 10 parts of distilled water.
The preparation method of the oil colour of excellent quick-drying freedom from cracking, it is characterised in that step is as follows：
1) under rotating speed 300rpm stirring condition, polyaminoester emulsion is added in acrylic emulsion, 20min is stirred,
Obtain base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner,
Obtain pigment moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and tertiary ethylene carbonate, dipropyl two are added thereto
Alcohol n-butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, cobalt borate, are added in grinder and grind
5 times, slurry is obtained, sealed storage is produced.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those
Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a kind of oil colour of quick-drying freedom from cracking, it is characterised in that be made up of the raw material of following parts by weight：Acrylic emulsion
20-30 parts, 10-15 parts of ester-polyurethane resin emulsion, 5-10 parts of tertiary ethylene carbonate, 15-20 parts of zeolite powder, pigment toner 10-15
Part, 3-6 parts of dipropylene glycol n-butyl ether, 3-6 parts of butyl acetate, 0.5-1 parts of polyethylene glycol methacrylic acid copolymer body, beeswax
0.2-1 parts, 0.2-1 parts of drier, 0.2-1 parts of Sodium Benzoate, 10-20 parts of distilled water.
2. the oil colour of quick-drying freedom from cracking as claimed in claim 1, it is characterised in that by the raw material group of following parts by weight
Into：25 parts of acrylic emulsion, 12 parts of ester-polyurethane resin emulsion, 8 parts of tertiary ethylene carbonate, 18 parts of zeolite powder, 12 parts of pigment toner,
4 parts of dipropylene glycol n-butyl ether, 5 parts of butyl acetate, 0.6 part of polyethylene glycol methacrylic acid copolymer body, 0.4 part of beeswax, urge
Dry 0.5 part of agent, 0.4 part of Sodium Benzoate, 15 parts of distilled water.
3. the oil colour of quick-drying freedom from cracking as claimed in claim 2, it is characterised in that the drier is selected from cobalt borate.
4. the oil colour of quick-drying freedom from cracking as claimed in claim 2, it is characterised in that the particle diameter of the zeolite powder is 600-
800 mesh.
5. the preparation method of the oil colour of the quick-drying freedom from cracking as described in claim 1-4 is any, it is characterised in that step is such as
Under：
1) under agitation, polyaminoester emulsion is added in acrylic emulsion, 10-20min is stirred, obtains base material；
2) Sodium Benzoate is dissolved in distilled water, in the homogeneous mixture for adding it to zeolite powder and pigment toner, obtains face
Expect moist wood；
3) by step 1) base material and step 2) pigment moist wood is well mixed, and is adding tertiary ethylene carbonate, DPG just thereto
Butyl ether, butyl acetate, polyethylene glycol methacrylic acid copolymer body, beeswax, drier, are added in grinder and grind 3-5
It is secondary, slurry is obtained, sealed storage is produced.
6. the preparation method of the oil colour of quick-drying freedom from cracking as claimed in claim 5, it is characterised in that the step 1) in
Stir speed (S.S.) is 300-400rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710330401.7A CN106957551A (en) | 2017-05-11 | 2017-05-11 | A kind of oil colour of quick-drying freedom from cracking and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710330401.7A CN106957551A (en) | 2017-05-11 | 2017-05-11 | A kind of oil colour of quick-drying freedom from cracking and preparation method thereof |
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| CN106957551A true CN106957551A (en) | 2017-07-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710330401.7A Pending CN106957551A (en) | 2017-05-11 | 2017-05-11 | A kind of oil colour of quick-drying freedom from cracking and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107828265A (en) * | 2017-12-21 | 2018-03-23 | 温州维特利颜料科技有限公司 | A kind of art oil paint and preparation method thereof |
| CN109796860A (en) * | 2019-02-28 | 2019-05-24 | 烟台南山学院 | A kind of drawing aqueous polyurethane art painting and preparation method thereof |
| CN110903687A (en) * | 2019-12-13 | 2020-03-24 | 珠海闲云艺术有限公司 | Water-based oil painting pigment and preparation method thereof |
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| CN104151903A (en) * | 2014-08-21 | 2014-11-19 | 宁波高新区康大美术新材料有限公司 | Graphene-containing high-luster propylene pigment and preparation method thereof |
| CN104449002A (en) * | 2014-12-18 | 2015-03-25 | 李泳博 | Oil paint with prevention function |
| CN104497673A (en) * | 2014-12-23 | 2015-04-08 | 宁波高新区康大美术新材料有限公司 | Paint pigment containing graphene and preparation method of paint pigment |
| WO2015125816A1 (en) * | 2014-02-19 | 2015-08-27 | 東亞合成株式会社 | Water-based paint composition and coating process using same, and coating film and product obtained using coating process |
| CN105419435A (en) * | 2015-12-24 | 2016-03-23 | 青岛大方智慧网络科技有限公司 | Oil paint pigment |
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2017
- 2017-05-11 CN CN201710330401.7A patent/CN106957551A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015125816A1 (en) * | 2014-02-19 | 2015-08-27 | 東亞合成株式会社 | Water-based paint composition and coating process using same, and coating film and product obtained using coating process |
| CN104151903A (en) * | 2014-08-21 | 2014-11-19 | 宁波高新区康大美术新材料有限公司 | Graphene-containing high-luster propylene pigment and preparation method thereof |
| CN104449002A (en) * | 2014-12-18 | 2015-03-25 | 李泳博 | Oil paint with prevention function |
| CN104497673A (en) * | 2014-12-23 | 2015-04-08 | 宁波高新区康大美术新材料有限公司 | Paint pigment containing graphene and preparation method of paint pigment |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107828265A (en) * | 2017-12-21 | 2018-03-23 | 温州维特利颜料科技有限公司 | A kind of art oil paint and preparation method thereof |
| CN109796860A (en) * | 2019-02-28 | 2019-05-24 | 烟台南山学院 | A kind of drawing aqueous polyurethane art painting and preparation method thereof |
| CN110903687A (en) * | 2019-12-13 | 2020-03-24 | 珠海闲云艺术有限公司 | Water-based oil painting pigment and preparation method thereof |
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Application publication date: 20170718 |
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