CN106947618A - 废硫酸裂解再生装置用废硫酸喷枪清洗剂 - Google Patents
废硫酸裂解再生装置用废硫酸喷枪清洗剂 Download PDFInfo
- Publication number
- CN106947618A CN106947618A CN201710150408.0A CN201710150408A CN106947618A CN 106947618 A CN106947618 A CN 106947618A CN 201710150408 A CN201710150408 A CN 201710150408A CN 106947618 A CN106947618 A CN 106947618A
- Authority
- CN
- China
- Prior art keywords
- parts
- sulfuric acid
- added
- cleaning agent
- spray gun
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 239000007921 spray Substances 0.000 title claims abstract description 28
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 19
- 239000002699 waste material Substances 0.000 title claims abstract description 18
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004132 cross linking Methods 0.000 claims abstract description 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 10
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 9
- 235000013312 flour Nutrition 0.000 claims abstract description 9
- -1 hydroxypropyl Chemical group 0.000 claims abstract description 9
- 229920001983 poloxamer Polymers 0.000 claims abstract description 9
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims abstract description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 9
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- ITCAUAYQCALGGV-XTICBAGASA-M sodium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Na+].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O ITCAUAYQCALGGV-XTICBAGASA-M 0.000 claims abstract description 9
- 229960003511 macrogol Drugs 0.000 claims abstract description 7
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940059939 kayexalate Drugs 0.000 claims abstract description 5
- 229960000502 poloxamer Drugs 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 claims abstract description 3
- 244000275012 Sesbania cannabina Species 0.000 claims abstract 3
- 238000009413 insulation Methods 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 18
- 238000010992 reflux Methods 0.000 claims description 18
- 241000209094 Oryza Species 0.000 claims description 8
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 claims description 6
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 claims description 6
- 241001602688 Pama Species 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 230000010148 water-pollination Effects 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 11
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 7
- 241000219782 Sesbania Species 0.000 description 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 3
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 2
- AHLWZBVXSWOPPL-RGYGYFBISA-N 20-deoxy-20-oxophorbol 12-myristate 13-acetate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(C=O)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C AHLWZBVXSWOPPL-RGYGYFBISA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 229910002011 hydrophilic fumed silica Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
本发明公开了一种废硫酸裂解再生装置用废硫酸喷枪清洗剂，涉及石油化工技术领域，由如下重量份数的原料制成：亲水***联聚维酮15‑20份、聚氧化乙烯5‑10份、***型聚乙烯醇3‑6份、羟丙基二淀粉磷酸酯3‑6份、泊洛沙姆2‑4份、火山灰2‑4份、聚苯乙烯磺酸钠2‑4份、糯米粉1‑2份、聚乙二醇6000 1‑2份、田菁胶0.5‑1份、柠檬酸三丁酯0.5‑1份、松香酸钠0.5‑1份、水150‑200份。本发明所制清洗剂无毒无害，使用方便，使用该清洗剂冲洗一次后即可对喷枪进行有效清洗，其清洗率达到99％以上。
Description
技术领域：
本发明涉及石油化工技术领域，具体涉及一种废硫酸裂解再生装置用废硫酸喷枪清洗剂。
背景技术：
在石油化工生产中，经常使用高浓度的硫酸作为催化剂或进行吸收净化、洗涤等，在其过程中的水分、硫、氮化合物以及副反应物不断进入酸相，使硫酸浓度逐渐降低，最终满足不了生产工艺的要求，这是就会逐步将这些含有大量杂质的硫酸废液排出，被排出的这些废液被称为废硫酸。
废硫酸中的硫酸通过高温裂解生成二氧化硫和水，而二氧化硫再经氧化生成三氧化硫，再利用98.5％硫酸吸收生成的三氧化硫，从而实现废硫酸的裂解再生。在裂解装置中，通常采用喷枪将废硫酸喷入，以提高废硫酸的均匀受热性，从而增大二氧化硫的生成量。但由于废硫酸中含有大量杂质，经共混后形成粘度较大的混合物，这些混合物容易堵塞喷枪的内部孔道，从而降低生产效率，并且会缩短喷枪的使用寿命，因此需要对喷枪进行定期清洗。
发明内容：
本发明所要解决的技术问题在于提供一种使用方便、清洗效果好且不会产生腐蚀现象的废硫酸裂解再生装置用废硫酸喷枪清洗剂。
本发明所要解决的技术问题采用以下的技术方案来实现：
废硫酸裂解再生装置用废硫酸喷枪清洗剂，由如下重量份数的原料制成：
亲水***联聚维酮15-20份、聚氧化乙烯5-10份、***型聚乙烯醇3-6份、羟丙基二淀粉磷酸酯3-6份、泊洛沙姆2-4份、火山灰2-4份、聚苯乙烯磺酸钠2-4份、糯米粉1-2份、聚乙二醇60001-2份、田菁胶0.5-1份、柠檬酸三丁酯0.5-1份、松香酸钠0.5-1份、水150-200份。
其制备方法包括如下步骤：
(1)向水中加入聚氧化乙烯、聚乙二醇6000和田菁胶，并加热至回流状态保温混合10-15min，再加入泊洛沙姆和糯米粉，继续回流保温混合5-10min，即得物料I；
(2)向***型聚乙烯醇中加入羟丙基二淀粉磷酸酯和柠檬酸三丁酯，并加热至110-120℃保温混合10-15min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入火山灰和松香酸钠，充分混合后保温静置15-30min，即得物料II；
(3)向物料I中加入亲水***联聚维酮、聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10-15min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
所述亲水***联聚维酮由交联聚维酮经亲水改性而成，其改性方法为：将15-20份交联聚维酮加入3-5倍重量份的40-50℃水中，充分混合后静置1h，再加热至回流状态保温混合15min，然后加入1-2份阴离子聚丙烯酰胺、0.5-1份水解聚马来酸酐和0.5-1份亲水性气相二氧化硅，继续加热至回流状态保温混合10min，所得混合物转入0-5℃环境中静置3h，随后送入喷雾干燥机中，向所得颗粒中加入0.5-1份氢化蓖麻油和0.1-0.2份乳化硅油，并加热至70-80℃保温混合10min，最后经超微粉碎机制成粉末。
本发明的有益效果是：本发明所制清洗剂无毒无害，使用方便，使用该清洗剂冲洗一次后即可对喷枪进行有效清洗，其清洗率达到99％以上，再用清水对喷枪冲洗一次，即可有效除去附着在喷枪内部的清洗剂，对清洗剂的清洗率达到99.5％以上，并可将喷枪的清洗率提高到99.5％以上。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)向200份水中加入6份聚氧化乙烯、2份聚乙二醇6000和0.5份田菁胶，并加热至回流状态保温混合15min，再加入2份泊洛沙姆和1份糯米粉，继续回流保温混合5min，即得物料I；
(2)向3份***型聚乙烯醇中加入3份羟丙基二淀粉磷酸酯和0.5份柠檬酸三丁酯，并加热至110-120℃保温混合15min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入2份火山灰和0.5份松香酸钠，充分混合后保温静置15min，即得物料II；
(3)向物料I中加入20份亲水***联聚维酮、2份聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
亲水***联聚维酮的制备：将20份交联聚维酮加入5倍重量份的40-50℃水中，充分混合后静置1h，再加热至回流状态保温混合15min，然后加入1份阴离子聚丙烯酰胺、1份水解聚马来酸酐和0.5份亲水性气相二氧化硅，继续加热至回流状态保温混合10min，所得混合物转入0-5℃环境中静置3h，随后送入喷雾干燥机中，向所得颗粒中加入0.5份氢化蓖麻油和0.2份乳化硅油，并加热至70-80℃保温混合10min，最后经超微粉碎机制成粉末。
实施例2
(1)向200份水中加入8份聚氧化乙烯、1份聚乙二醇6000和0.5份田菁胶，并加热至回流状态保温混合15min，再加入3份泊洛沙姆和1份糯米粉，继续回流保温混合5min，即得物料I；
(2)向5份***型聚乙烯醇中加入3份羟丙基二淀粉磷酸酯和0.5份柠檬酸三丁酯，并加热至110-120℃保温混合10min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入2份火山灰和0.5份松香酸钠，充分混合后保温静置15min，即得物料II；
(3)向物料I中加入20份亲水***联聚维酮、2份聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
亲水***联聚维酮的制备：将20份交联聚维酮加入5倍重量份的40-50℃水中，充分混合后静置1h，再加热至回流状态保温混合15min，然后加入1份阴离子聚丙烯酰胺、0.5份水解聚马来酸酐和0.5份亲水性气相二氧化硅，继续加热至回流状态保温混合10min，所得混合物转入0-5℃环境中静置3h，随后送入喷雾干燥机中，向所得颗粒中加入0.5份氢化蓖麻油和0.2份乳化硅油，并加热至70-80℃保温混合10min，最后经超微粉碎机制成粉末。
对照例1
(1)向200份水中加入8份聚氧化乙烯、1份聚乙二醇6000和0.5份田菁胶，并加热至回流状态保温混合15min，再加入3份泊洛沙姆和1份糯米粉，继续回流保温混合5min，即得物料I；
(2)向5份***型聚乙烯醇中加入3份羟丙基二淀粉磷酸酯和0.5份柠檬酸三丁酯，并加热至110-120℃保温混合10min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入2份火山灰和0.5份松香酸钠，充分混合后保温静置15min，即得物料II；
(3)向物料I中加入20份交联聚维酮、2份聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
对照例2
(1)向200份水中加入8份聚氧化乙烯、1份聚乙二醇6000和0.5份田菁胶，并加热至回流状态保温混合15min，再加入3份泊洛沙姆和1份糯米粉，继续回流保温混合5min，即得物料I；
(2)向5份***型聚乙烯醇中加入3份羟丙基二淀粉磷酸酯和0.5份柠檬酸三丁酯，并加热至110-120℃保温混合10min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入2份火山灰和0.5份松香酸钠，充分混合后保温静置15min，即得物料II；
(3)向物料I中加入2份聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
实施例3
将等量实施例1、实施例2、对照例1和对照例2所制清洗剂用于废硫酸裂解再生装置用喷枪的污垢清洗，再用等量清水对喷枪冲洗一次，并对清洗效果进行测定，结果如表1所示。
表1所制1清洗剂的清洗效果
结果显示，使用实施例1和实施例2所制清洗剂冲洗一次后即可对喷枪进行有效清洗，其清洗率达到99％以上，再用清水对喷枪冲洗一次，即可有效除去附着在喷枪内部的清洗剂，对清洗剂的清洗率达到99.5％以上，并可将喷枪的清洗率提高到99.5％以上。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (3)
1.废硫酸裂解再生装置用废硫酸喷枪清洗剂，其特征在于，由如下重量份数的原料制成：
亲水***联聚维酮15-20份、聚氧化乙烯5-10份、***型聚乙烯醇3-6份、羟丙基二淀粉磷酸酯3-6份、泊洛沙姆2-4份、火山灰2-4份、聚苯乙烯磺酸钠2-4份、糯米粉1-2份、聚乙二醇6000 1-2份、田菁胶0.5-1份、柠檬酸三丁酯0.5-1份、松香酸钠0.5-1份、水150-200份。
2.根据权利要求1所述的废硫酸裂解再生装置用废硫酸喷枪清洗剂，其特征在于，其制备方法包括如下步骤：
(1)向水中加入聚氧化乙烯、聚乙二醇6000和田菁胶，并加热至回流状态保温混合10-15min，再加入泊洛沙姆和糯米粉，继续回流保温混合5-10min，即得物料I；
(2)向***型聚乙烯醇中加入羟丙基二淀粉磷酸酯和柠檬酸三丁酯，并加热至110-120℃保温混合10-15min，所得混合物以10-15℃/min的速度冷却降温，待温度降至50-60℃后加入火山灰和松香酸钠，充分混合后保温静置15-30min，即得物料II；
(3)向物料I中加入亲水***联聚维酮、聚苯乙烯磺酸钠和物料II，并加热至回流状态保温混合10-15min，最后将所得混合物送入球磨机中，球磨至细度小于10μm。
3.根据权利要求1或2所述的废硫酸裂解再生装置用废硫酸喷枪清洗剂，其特征在于：所述亲水***联聚维酮由交联聚维酮经亲水改性而成，其改性方法为：将15-20份交联聚维酮加入3-5倍重量份的40-50℃水中，充分混合后静置1h，再加热至回流状态保温混合15min，然后加入1-2份阴离子聚丙烯酰胺、0.5-1份水解聚马来酸酐和0.5-1份亲水性气相二氧化硅，继续加热至回流状态保温混合10min，所得混合物转入0-5℃环境中静置3h，随后送入喷雾干燥机中，向所得颗粒中加入0.5-1份氢化蓖麻油和0.1-0.2份乳化硅油，并加热至70-80℃保温混合10min，最后经超微粉碎机制成粉末。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710150408.0A CN106947618A (zh) | 2017-03-14 | 2017-03-14 | 废硫酸裂解再生装置用废硫酸喷枪清洗剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710150408.0A CN106947618A (zh) | 2017-03-14 | 2017-03-14 | 废硫酸裂解再生装置用废硫酸喷枪清洗剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106947618A true CN106947618A (zh) | 2017-07-14 |
Family
ID=59467885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710150408.0A Pending CN106947618A (zh) | 2017-03-14 | 2017-03-14 | 废硫酸裂解再生装置用废硫酸喷枪清洗剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947618A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384660A (zh) * | 2017-08-10 | 2017-11-24 | 安徽钰丰电子科技有限公司 | 一种五加皮养生啤酒的酿造工艺 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160385A (zh) * | 2013-04-03 | 2013-06-19 | 济南瑞东实业有限公司 | 一种炼油装置全清洗剂及其制备方法 |
| CN104120047A (zh) * | 2014-07-18 | 2014-10-29 | 青岛蓬勃石油技术服务有限公司 | 一种输油管道清洗剂及其制备方法 |
| CN104830556A (zh) * | 2015-05-20 | 2015-08-12 | 龚灿锋 | 化工设备表面清洗剂 |
| CN105670828A (zh) * | 2016-02-29 | 2016-06-15 | 安徽海德石油化工有限公司 | 聚醋酸乙烯-植物混合清洗剂及其制备方法 |
| CN105695161A (zh) * | 2016-03-16 | 2016-06-22 | 安徽海德石油化工有限公司 | 一种炼油厂废气吸收塔用填料清洗剂 |
| CN105754734A (zh) * | 2016-03-16 | 2016-07-13 | 安徽海德石油化工有限公司 | 一种渣油储罐清洗剂 |
-
2017
- 2017-03-14 CN CN201710150408.0A patent/CN106947618A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160385A (zh) * | 2013-04-03 | 2013-06-19 | 济南瑞东实业有限公司 | 一种炼油装置全清洗剂及其制备方法 |
| CN104120047A (zh) * | 2014-07-18 | 2014-10-29 | 青岛蓬勃石油技术服务有限公司 | 一种输油管道清洗剂及其制备方法 |
| CN104830556A (zh) * | 2015-05-20 | 2015-08-12 | 龚灿锋 | 化工设备表面清洗剂 |
| CN105670828A (zh) * | 2016-02-29 | 2016-06-15 | 安徽海德石油化工有限公司 | 聚醋酸乙烯-植物混合清洗剂及其制备方法 |
| CN105695161A (zh) * | 2016-03-16 | 2016-06-22 | 安徽海德石油化工有限公司 | 一种炼油厂废气吸收塔用填料清洗剂 |
| CN105754734A (zh) * | 2016-03-16 | 2016-07-13 | 安徽海德石油化工有限公司 | 一种渣油储罐清洗剂 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384660A (zh) * | 2017-08-10 | 2017-11-24 | 安徽钰丰电子科技有限公司 | 一种五加皮养生啤酒的酿造工艺 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109336746A (zh) | 一种甲基八溴醚的制备方法 | |
| CN106947618A (zh) | 废硫酸裂解再生装置用废硫酸喷枪清洗剂 | |
| CN102352511A (zh) | 一种铝型材表面抛光处理液的制备方法 | |
| CN105776394A (zh) | 一种煤气脱氨与剩余氨水负压蒸氨的一体化生产方法及*** | |
| CN103773151A (zh) | 一种耐高温耐酸耐碱的涂料 | |
| CN104629778B (zh) | 一种干熄炉内防焦炭堵塞装置 | |
| CN202185373U (zh) | 液硫急冷雾化喷嘴 | |
| CN108359539A (zh) | 一种新型汽车积碳清洗剂 | |
| CN107142529A (zh) | 一种羽毛球加工用羽毛洗毛工艺 | |
| CN107200309A (zh) | 硫单体淬冷聚合产物分子链封端制备不溶性硫磺的方法 | |
| CN205180328U (zh) | 一种饲料油脂添加*** | |
| CN103755393B (zh) | 三聚氰胺尾气联产硫酸钾复合肥的装置及方法 | |
| CN205199288U (zh) | 一种聚甲基三乙氧基硅烷反应尾气的吸收塔 | |
| CN104258704A (zh) | 西咪替丁和雷尼替丁生产中废气处理及甲硫醇回收工艺 | |
| CN106744707A (zh) | 一种制备不溶性硫磺工艺装置 | |
| CN106496894A (zh) | 一种低温水溶性农药包装膜及其制备方法 | |
| CN106520281A (zh) | 利用有机硅聚合物制备的建筑金属模板脱模剂用成膜助剂 | |
| CN202576446U (zh) | 一种高炉水渣蒸汽脱硫及水回收利用装置 | |
| CN107572534B (zh) | 一种制备三氯氢硅的工艺和*** | |
| CN105315896A (zh) | 车用清洁抛光液及其制备方法 | |
| CN208553645U (zh) | 硫酸铜生产过程中的废气处理装置 | |
| CN107858698A (zh) | 一种去除硫垢的清洗剂 | |
| CN110065324A (zh) | 一种芳樟醇免酒精润版液及其制备方法 | |
| CN109899136A (zh) | 车用尿素配方 | |
| CN105060314A (zh) | 处理废盐的工艺 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170714 |