CN106946328A - A kind of organic environmental-protection water quality cleansing agent and preparation method thereof - Google Patents
A kind of organic environmental-protection water quality cleansing agent and preparation method thereof Download PDFInfo
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- CN106946328A CN106946328A CN201710175775.6A CN201710175775A CN106946328A CN 106946328 A CN106946328 A CN 106946328A CN 201710175775 A CN201710175775 A CN 201710175775A CN 106946328 A CN106946328 A CN 106946328A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The present invention relates to a kind of organic environmental-protection water quality cleansing agent, be made up of natural clinoptilolite, rock-forming mineral, clay mineral, volcanic ash and such as muscovite mineral and the mixing of green tea natural plants concentrate, with being flocculated to water pollutant, precipitate, on float and maximum improve the effect of water transparency.The contaminant collecting on floating can be discharged into simultaneously outside water body, effectively prevention, improvement Water Eutrophication.Carry out sowing operation on the surface water such as reservoir, sanitary sewage, drainage ditch and natural lake, the water quality by blue, red algae and various contaminants can be improved.
Description
Technical field
The present invention relates to environmental technology field, and in particular to purification of water quality or water treatment agent field, more particularly to one kind have
Machine environmental protection water quality cleansing agent and preparation method thereof.
Background technology
Reservoir, sanitary sewage, drainage ditch and the pollution in natural lake, come from it is various a little or non-point pollution source inflow
And water temperature rise etc. eutrophication cause the accumulation of blue-green algae and the red algae of fresh water to occur, while also have flood and architectural engineering etc. occur
Caused by pollutant flow into possibility.Such water pollution of type, the solution at initial stage has had various sewage disposals
Facility, water treatment agent can be sowed to the water system polluted.Reservoir, municipal sewage, drainage ditch and the turbidity in natural lake are not only
Cause the decline of water quality, and the landscape on influence periphery, equally also can be into while also destroy the habitat of aquatic animals and plants
The major reason broken out for blue-green algae, red algae.It is noted that it is from point or non-point pollution source to cause the eutrophic root of water quality
Excessive organic matter, nutrient salts are flowed into, existing sewage disposal device, which plays, can suppress what Fresh Watcr Blue Algae, red algae occurred
Role, can also solve organic matter, the pollution of chemotrophy salt of various high concentrations, but can only be limited in specific pollution sources
Capacity in processing sewage, can't resolve the problem of general river and lake water quality pollutes with same method.Using other solution party
During formula, such as when with lime is sowed to solve, but lime has stronger alkalescence, therefore aquatic animals and plants habitat is destroyed
Seriously.Generally it will become blue in the color of the organic planktonic organism increase of the slower irrigation canals and ditches in the river lake polluted or flow velocity, water
Referred to as blue algae bloom, water dissolves oxygen is greatly decreased, and fish and aquatic animals and plants death produce peculiar smell, and destruction periphery is ecological, triggers
Society, economy, environment aspect a series of problems, so must remove with toxigenic algae.To prevent the generation of blue-green algae
The nutrient salts in domestic water must be purified, prevent that it from flowing into rivers sea.Therefore in rivers, the effective plant of river lake plantation
Thing, it is particularly important to reach removing algae to absorb nutrient salts.But the hardly possible completion of domestic water is fully cleaned up, and together
Cross and plant effective plant absorbing, remove prevention algae and be also impossible to complete.Another method is in river, lake, marine site
Loess is sowed during blue algae bloom, so as to carry out adsorbing the nutrient salts for causing water quality deterioration reaching removing algae purpose, but this
Plant method effect not good.
Korean patent No. discloses a kind of method using inorganic material as water treatment agent for 2000-0053716, and this is inorganic
Material includes porphyry, desulfurated plaster and flyash etc., however, containing the materials such as heavy metal in desulfurated plaster and flyash, not only
It is harmful, and easily cause the secondary pollution of water quality.
Korean patent No. is that to disclose one kind in temperature be 1100- by loess, kaolin, diatomite to 2001-0036795
Burnt under conditions of 1200 DEG C, so as to produce the method for inorganic drainage agent.But, high cost needed for the inorganic drainage agent is produced,
For cost input, its sewage treating efficiency is extremely low.
China Patent No. discloses a kind of sewage-treating agent containing natural mineral matter for CN104276670A, will tiltedly send out boiling
Stone, kaolinite, the clay mineral of high-cation exchange capacity, quartz sand, volcanic ash and medical stone are crushed, in temperature after mixing
Heating and separating twice under conditions of 160-170 DEG C.It is not comprehensive rich in species but it is made up of mineral completely, to water quality
Catharsis is not comprehensive.
The problems such as water treatment field is also faced with technological innovation, the demand of development in itself, develops low toxicity, even nontoxic
Environmental protection water treatment technology with environment-friendly green water treatment product and rationally, economic, safe, is current water process
The active demand in field.In consideration of it, research one kind need not set up other water treatment facilities and can be produced at low cost, with letter
Single operating type sow can be carried out operation in reservoir, municipal sewage canal, natural lake, so as to provide in water
Various pollutant flocculations, the environmental protection for also decomposition of floating simultaneously, active natural materials water treatment agent, are that the present invention is urgently solved
Certainly the problem of.
The content of the invention
Therefore, the technical problems to be solved by the invention are to overcome technological deficiency of the prior art, so as to provide one
Plant environmental protection, active natural materials water treatment agent.
Therefore, the present invention provides a kind of organic environmental-protection water quality cleansing agent, include the raw material of following percetage by weight:
Clinoptilolite 25-35%, rock-forming mineral 3-7%, clay mineral 3-7%, volcanic ash 5-15%, green tea 20-30%,
Oak Tree 20-30%.
Further, the raw material of following percetage by weight is included:Clinoptilolite 30%, rock-forming mineral 5%, clay mineral 5%,
Volcanic ash 10%, green tea 25%, Oak Tree 25%.
Further, the natural clinoptilolite, rock-forming mineral, high clay mineral, the particle diameter of volcanic ash are 200 mesh.
Further, the Oak Tree, the particle diameter of green tea are 200 mesh.
Present invention also offers a kind of preparation method of organic environmental-protection water quality cleansing agent, including:
A, by natural clinoptilolite, rock-forming mineral, clay mineral, volcanic ash mineral, be processed into the following mineral powder of 200 mesh
End;
B, by the mineral dust being processed into by being sufficiently mixed, be heated to 150 DEG C and dissolve natural minerals with warm water dilution
Composition, obtains natural minerals gel;
C, Oak Tree, green tea cleaned with water, after cleaning drying remove moisture be processed into the following powder of 200 mesh be diluted with water it is molten
Solution, obtains natural disinfection component liquids;
D, by natural minerals gel and natural disinfection component liquids, by volume 1:1 accurate mixing is produced.
Include the raw material of following percetage by weight:
Further, by weight percentage, wherein clinoptilolite 25-35%, rock-forming mineral 3-7%, clay mineral 3-
7%th, volcanic ash 5-15%, green tea 20-30%, Oak Tree 20-30%.
Further, the raw material of following percetage by weight is included:Clinoptilolite 30%, rock-forming mineral 5%, clay mineral 5%,
Volcanic ash 10%, green tea 25%, Oak Tree 25%.
Further, the natural clinoptilolite, rock-forming mineral, high clay mineral, the particle diameter of volcanic ash are 200 mesh.
Further, the Oak Tree, the particle diameter of green tea are 200 mesh.
Wherein, clinoptilolite refers to sodium aqueous in zeolite race, potassium, the stone of the aluminium silicate mineral of calcium, and crystal is generally
Transparent plate, the function can after dehydration with molecular sieve, can selectively extract nitrogen from air and make oxygen coalescence.With suction
The performances such as attached property, ion exchangeable, catalysis and acidproof heat-proof, can be used as adsorbent, ion-exchanger and catalyst, for sewage
In terms of processing, with extensive market application foreground.
Rock-forming mineral is the mineral for constituting magmatic rock, is present in igneous rock, is largely silicate mineral and carbonate
Mineral.Common rock-forming mineral includes quartz, potassium feldspar, plagioclase, mica, hornblend, pyroxene and olivine.This seven kinds of mineral are
The main component of crustal rock.
Water in clay mineral exists in the form of adsorbing water, intermediary water and constitution water.Constitution water is only tied at high temperature
Structure just loses when destroying, but the zeolite water in absorption water, intermediary water and sepiolite structure hole is all water at low temperature, through low temperature
It can deviate from after (100~150 DEG C) heating, while as can be with rehydration after the mineral dehydration of smectite race, this be one important
Feature.The features such as dilatancy produced by the effect of clay mineral and water, scattered and coherency, viscosity, thixotropy and plasticity
Industrially it is used widely.
Volcanic ash refers to be gone out by volcanic eruption and rubble and mineral particles of the diameter less than 2 millimeters.In fulminant fire
In the motion of mountain, solid stone and molten slurry are broken down into trickle particle and form volcanic ash.In normal temperature and can in the case of having water
Hyrate of the generation with hydraulic cement ability is reacted with lime (CaO).
Green tea is the not fermented tea being made, and remains the natural materials of fresh leaf, the Tea Polyphenols that contains, catechin, Ye Lv
Element, caffeine, amino acid, vitamins and other nutritious components are also more.These natural nutrition compositions in green tea are to anti-aging, anti-
Cancer, anticancer, sterilization, anti-inflammatory etc. have special-effect.
Oak Tree strong stress resistance, resistance to drying, high temperature and water are wet, frost resistance and city environmental pollution, and wind resistance is strong, and happiness draining is good
Good soil, but can also be grown in heavy soil.Oak Tree likes sandy loam or well-drained subacidity soil, and resistance to environment is dirty
Dye, it is adaptable to barren, arid, slant acidity or basicity soil.The Oak Tree speed of growth is medium, moist, well-drained
Grown tall 60 centimetres every year on soil.Many alveolate textures are flooded with inside it, cellular inside is air-saturated, so cork
It is elastic fine, belong to a kind of pure natural material, to human body, environment without any harm.
The applicant is by the discovery that studies for a long period of time, by natural clinoptilolite, rock-forming mineral, clay mineral, volcanic ash as in vain
The water treatment agent that the mixing of the natural plants such as mica mineral, green tea, Oak Tree concentrate is constituted, with flocculating, sink to water pollutant
Form sediment, on float and maximum improve the effect of water transparency.Using natural minerals and natural plant composition as main material, to aquatic animals and plants
Without large scale equipment while influence minimum, water quality can be improved by simply sowing operation.The water correction agent of the present invention contains
It is key element to have clinoptilolite and cation to replace capacity very big high clay mineral, and the anion on its surface can actively be replaced very much
Substantial amounts of cation is changed, is mixed with the sterilized concentrate of the natural plants such as natural minerals concentrate and green tea, Oak Tree and is made as spy
Point.
The above-mentioned technical proposal of the present invention has advantages below compared with prior art:
The present invention is easy to use, without extra treatment facility, it is only necessary to which organic environmental-protection water quality cleansing agent is sprayed on
The water surfaces such as reservoir, river and natural lake, by flocculation, floating, collect the various pollutants of processing, maximum improves water body
Transparency;Blue-green algae, the various pollutants of red algae cause of outbreak can be decomposed into simultaneously, body eutrophication are prevented, greatly
Improve water quality and the habitat of aquatic animals and plants, self detergent power of recovery lake water ecosystem, without setting up at other water
Reason equipment can also solve the purifying problem in water intaking source, reduce the load of existing various water treatment facilities, save newly added equipment and build
If taking and expense of maintenance and management.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.
Embodiment 1
A kind of organic environmental-protection water quality cleansing agent, includes the raw material of following percetage by weight:
Clinoptilolite 30%, rock-forming mineral 5%, clay mineral 5%, volcanic ash 10%, green tea 25%, Oak Tree 25%, its
Preparation method, including:
A, by natural clinoptilolite, rock-forming mineral, clay mineral, volcanic ash mineral, be processed into the following mineral powder of 200 mesh
End;
B, by the mineral dust being processed into by being sufficiently mixed, be heated to 150 DEG C and dissolve natural minerals with warm water dilution
Composition, obtains natural minerals gel;
C, Oak Tree, green tea cleaned with water, after cleaning drying remove moisture be processed into the following powder of 200 mesh be diluted with water it is molten
Solution, obtains natural disinfection component liquids;
D, by natural minerals gel and natural disinfection component liquids, by volume 1:1 accurate mixing is produced.
The organic environmental-protection water quality cleansing agent that embodiment 1 is obtained is applied in the polluted water of Worker's Cultural Palace man-made lake,
Every test is carried out,
Specific test condition:On January 10th, 2016 delivers, and body contaminant water to be cleaned in lake uses organic environmental-protection water quality of the present invention
Cleanser
After analyzing water quality, test result such as table 1 below:
Project | Unit | Before processing | After processing 1 month | After processing 12 months | Clearance rate (%) |
pH | 9.23 | 8.21 | 7.58 | - | |
TOC | mg/L | 3.74 | 3.56 | 3.01 | 19.5 |
COD | mg/L | 11.4 | 9.78 | 5.6 | 50.9 |
T-N | mg/L | 1.63 | 1.51 | 1.00 | 38.7 |
T-P | mg/L | 0.033 | 0.029 | 0.005 | 84.8 |
Chl-a | % | 40.29 | 36.12 | 9.07 | 77.5 |
The organic environmental-protection water quality cleansing agent that embodiment 1 is obtained is applied in the polluted water in Qing Huilou ponds, is carried out every
Test,
Specific test condition:On January 1st, 2016 delivers, and body contaminant water to be cleaned in lake uses organic environmental-protection water quality of the present invention
Cleanser, after analyzing water quality, test result such as table 2 below:
The water quality cleansing agent that comparative example 1 is obtained is applied in the polluted water of Worker's Cultural Palace man-made lake, is carried out every
Test,
Specific test condition:On January 1st, 2014 delivers, and body contaminant water to be cleaned in lake uses water quality in comparative example 1 of the present invention
Cleanser, after analyzing water quality, test result such as table 3 below:
Project | Unit | Before processing | After processing 1 month | After processing 12 months | Clearance rate (%) |
pH | 9.54 | 8.99 | 8.77 | - | |
TOC | mg/L | 4.04 | 3.86 | 3.59 | 11.3 |
COD | mg/L | 13.5 | 11.8 | 10.9 | 19.3 |
T-N | mg/L | 1.73 | 1.67 | 1.56 | 9.8 |
T-P | mg/L | 0.043 | 0.039 | 0.028 | 34.9 |
Chl-a | % | 46.9 | 42.1 | 35.1 | 25.2 |
The organic environmental-protection water quality cleansing agent that can be seen that the present invention from upper Tables 1 and 2 has extraordinary treatment effect,
There is good improvement on indices, especially there is quick rise in performance in the water quality treated through the sewage-treating agent
Imitate and the characteristics of effect is lasting, the indices of water quality still can persistently be kept after 12 months, and water body pH substantially lowers,
TOC, COD, T-N, T-P, Chl-a, SS etc., which have, clearly to be improved, concrete numerical value may refer to Tables 1 and 2 for it is different by
The test result of the water quality of pollution.
From upper table 1 and table 3 as can be seen that the organic environmental-protection water quality cleansing agent of the present invention relative to be not added with natural disinfection into
For the water quality cleansing agent for dividing liquid, there is obvious advantage on the improvement to water body indices, journey is lowered in water body pH
The water quality cleansing agent for being not added with natural disinfection component liquids is substantially better than on degree, and TOC, COD, T-N, T-P, Chl-a, SS are clear
The water quality cleansing agents of natural disinfection component liquids is not added with except the degree of rate is also significantly better than, concrete numerical value may refer to the He of table 1
Table 3 be directed to same contaminated water body, using after different quality cleanser to test result after the purification of water quality.
Obviously, the specific species of the organic acid used in above-described embodiment is only intended to clearly illustrate example,
And the not restriction to embodiment.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.There is no necessity and possibility to exhaust all the enbodiments.And thus
Among the obvious change or variation extended out are still in the protection domain of the invention.
Claims (9)
1. a kind of organic environmental-protection water quality cleansing agent, it is characterised in that include the raw material of following percetage by weight:
Clinoptilolite 25-35%, rock-forming mineral 3-7%, clay mineral 3-7%, volcanic ash 5-15%, green tea 20-30%, Oak Tree
20-30%.
2. organic environmental-protection water quality cleansing agent according to claim 1, it is characterised in that include the original of following percetage by weight
Material:Clinoptilolite 30%, rock-forming mineral 5%, clay mineral 5%, volcanic ash 10%, green tea 25%, Oak Tree 25%.
3. the organic environmental-protection water quality cleansing agent according to claim any one of 1-2, it is characterised in that the natural tiltedly hair boiling
Stone, rock-forming mineral, high clay mineral, the particle diameter of volcanic ash are 200 mesh.
4. the organic environmental-protection water quality cleansing agent according to claim any one of 1-3, it is characterised in that the Oak Tree, green tea
Particle diameter be 200 mesh.
5. a kind of preparation method of organic environmental-protection water quality cleansing agent, it is characterised in that including:
A, by natural clinoptilolite, rock-forming mineral, clay mineral, volcanic ash mineral, be processed into the following mineral dust of 200 mesh;
B, by the mineral dust being processed into by being sufficiently mixed, be heated to 150 DEG C and dissolve natural minerals composition with warm water dilution,
Obtain natural minerals gel;
C, Oak Tree, green tea cleaned with water, drying, which removes moisture and is processed into the following powder of 200 mesh, after cleaning is diluted with water dissolving,
Obtain natural disinfection component liquids;
D, by natural minerals gel and natural disinfection component liquids, by volume 1:1 accurate mixing is produced.
6. the preparation method of organic environmental-protection water quality cleansing agent according to claim 5, it is characterised in that by weight percentage
Meter, wherein clinoptilolite 25-35%, rock-forming mineral 3-7%, clay mineral 3-7%, volcanic ash 5-15%, green tea 20-30%,
Oak Tree 20-30%.
7. the preparation method of the organic environmental-protection water quality cleansing agent according to claim any one of 5-6, it is characterised in that tiltedly send out
Zeolite 30%, rock-forming mineral 5%, clay mineral 5%, volcanic ash 10%, green tea 25%, Oak Tree 25%.
8. the preparation method of the organic environmental-protection water quality cleansing agent according to claim any one of 5-7, it is characterised in that described
Natural clinoptilolite, rock-forming mineral, high clay mineral, the particle diameter of volcanic ash are 200 mesh.
9. the preparation method of the organic environmental-protection water quality cleansing agent according to claim any one of 5-8, it is characterised in that described
Oak Tree, the particle diameter of green tea are 200 mesh.
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Cited By (3)
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CN108423803A (en) * | 2018-03-20 | 2018-08-21 | 山东广景环境科技有限公司 | A kind of natural minerals original position water remediation material |
CN108502996A (en) * | 2018-03-04 | 2018-09-07 | 国合生物科技(宜兴)有限公司 | A kind of ecological flocculant of quick processing cyanobacteria water body and preparation method thereof and processing method |
CN108946961A (en) * | 2018-08-03 | 2018-12-07 | 连云开 | A kind of improver of water quality used for aquiculture |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108502996A (en) * | 2018-03-04 | 2018-09-07 | 国合生物科技(宜兴)有限公司 | A kind of ecological flocculant of quick processing cyanobacteria water body and preparation method thereof and processing method |
CN108423803A (en) * | 2018-03-20 | 2018-08-21 | 山东广景环境科技有限公司 | A kind of natural minerals original position water remediation material |
CN108946961A (en) * | 2018-08-03 | 2018-12-07 | 连云开 | A kind of improver of water quality used for aquiculture |
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