CN106937634A - A kind of acaricide composition and its application method - Google Patents
A kind of acaricide composition and its application method Download PDFInfo
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- CN106937634A CN106937634A CN201710154870.8A CN201710154870A CN106937634A CN 106937634 A CN106937634 A CN 106937634A CN 201710154870 A CN201710154870 A CN 201710154870A CN 106937634 A CN106937634 A CN 106937634A
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- CN
- China
- Prior art keywords
- acaricide
- application method
- mite
- fluacrypyrim
- agent
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the miticide composition of a kind of mite nitrile of azoles containing second and fluacrypyrim, Spiromesifen, Hexythiazox or propargite, common formulations are made with suitable agricultural agent by active ingredient second azoles mite nitrile and fluacrypyrim, Spiromesifen, Hexythiazox or propargite.Significantly, there is notable synergistic effect, can reduce dosage in the present invention, delay the resistance to the action of a drug of single medicament, economic, efficient, environmental protection to the crop control of pest mite such as cotton spider mites effect between two medicaments.
Description
Technical field
The invention belongs to evil mite chemical prevention field, and in particular to a kind of acaricide composition and its application method.
Background technology
Second azoles mite nitrile, chemical name：(z) -2- (4- tert-butyl-phenyls) -2- cyano group -1- (1- ethyl -3- methylpyrazoles -5-
Base) vinyl-PA ester is to change pesticide chemical in Shenyang to research and develop Co., Ltd using nitrile pyrrole mite ester as guide's chemical combination
The compound with high acaricidal activity found after thing, transformation, to the low toxicities such as honeybee, bird, fish, silkworm, preventing and treating citrus red mite, apple
Fruit tetranychid, cotton spider mites and the contour effect of vegetables tetranychid.
Fluacrypyrim, belongs to low toxicity acaricide, is mitochondrial respiratory inhibitor, blocks the electronics between cytochrome b and c1 to turn
Move, be mainly used in preventing and treating the multiple mites in the fruit trees such as apple, citrus, pears.
Spiromesifen, the mechanism of action destroys the energetic supersession activity of acarid, interference to suppress the Fatty synthesis in mite class body
The biosynthesis of its fat-body, especially there is preferable activity to larval stage, while ovarian duct closure function can also be produced, drops
The fertility of low acarid, greatly reduces spawning quantity.
Hexythiazox, is non-internal-absorting acaricide, and each worm state to mite class is all effective.Quick-acting, the lasting period is long.
Propargite, with tagging and stomach poison function, without interior suction and infiltration conduction, into mite, deutonymph effectively, ovicidal effect
It is really poor.
Different type of action acaricides are compounded, and be can be very good to improve prevention effect, are expanded prevention and treatment range, economize on
Medicine cost, not yet finds that second azoles mite nitrile prevents and treats the related of evil mite to fluacrypyrim, Spiromesifen, Hexythiazox, propargite mixture at present
Report.
The content of the invention
It is an object of the invention to provide a kind of acaricide composition and its application method, complex preparation is made, for preventing and treating
Crop evil mite, effect is good, and dosage is low；And there is provided the method for preventing and treating the insects such as evil mite using said composition.
The technical solution adopted by the present invention is as follows：
A kind of acaricide composition and its application method, it is characterised in that：It is made up of effective constituents A and B and auxiliary material, wherein effectively
Composition A is second azoles mite nitrile, and active ingredient B is one kind in fluacrypyrim, Spiromesifen, Hexythiazox and propargite.
A kind of described acaricide composition and its application method, it is characterised in that：In the Compositional acaricide, effectively into
The mass ratio for dividing A and active ingredient B is 40:1-1:40.
A kind of described acaricide composition and its application method, it is characterised in that：In the Compositional acaricide, effectively into
The mass ratio for dividing A and active ingredient B is 10:1-1:10.
A kind of described acaricide composition and its application method, it is characterised in that：In the Compositional acaricide, effectively into
The mass ratio for dividing A and active ingredient B is 10:1-1:5.
A kind of described acaricide composition and its application method, it is characterised in that：The formulation of the Compositional acaricide is
Missible oil, suspending agent, water-dispersible granules, wettable powder, microcapsule suspending agent.
Application method：Said preparation both can routinely spray, atomizing, pouring root, be entered after can also diluting with machineries such as hot mist machine, aircrafts
Row large area dispenser, reduces the generation of evil mite.
Beneficial effects of the present invention：
The miticide composition of the present invention compared with prior art, produces following beneficial effect：(1) compared with single dose, said composition
To evil mite notable synergistic, hence it is evident that improve prevention effect, drug cost is significantly reduced；（2）Evil mite is not likely to produce to the medicament
The resistance to the action of a drug, while also inhibits resistance of the evil mite to other agricultural chemicals；（3）Have quick-acting and long-acting functions concurrently to evil mite；(4) may be used
Field dosage is greatly reduced, environmental pollution and residues of pesticides are effectively reduced；（5）Compared with other conventional medicaments, production and
Use cost is reduced；（6）Being controlled one medicine, a dispenser can prevent and treat various pests simultaneously, reduction prevents and treats recruitment cost more；(7) reduce
To the toxicity of other non-target organisms.
Experimental data
Using indoor bioassay method.
Co-toxicity coefficient of the built agent to cotton spider mites of different ratio is drawn by indoor bioassay first, then passes through field
Its clear and definite prevention effect of the test of pesticide effectiveness, determines the formula rate and optimum amount of built agent.
Indoor bioassay：Using slide infusion process.
Missible oil is made in the formula for having synergistic effect obtained by indoor bioassay（EC）, suspension emulsion（SE）, wettable powder
（WP）, water-dispersible granules（WDG）, microcapsule suspending agent（CS）.
Table 1, table 2, table 3, table 4 sets forth second azoles mite nitrile and fluacrypyrim, Spiromesifen, Hexythiazox, propargite to cotton
Virulence test result of the tetranychid into mite；
The virulence of the second azoles mite nitrile of table 1 and fluacrypyrim mixture to cotton spider mites
The virulence of the second azoles mite nitrile of table 2 and Spiromesifen mixture to cotton spider mites
The virulence of the second azoles mite nitrile of table 3 and Hexythiazox mixture to cotton spider mites
The virulence of the second azoles mite nitrile of table 4 and propargite mixture to cotton spider mites
It can be seen from Table 1 that second azoles mite nitrile and fluacrypyrim are 40:1~1:In the range of 40 cotton spider mites are shown with good increasing
Imitate effect.It can be seen from Table 2 that second azoles mite nitrile and Spiromesifen are 20:1~40:Cotton spider mites are shown well in the range of 1
Synergistic effect.It can be seen from Table 3 that, second azoles mite nitrile and Hexythiazox are 10:1~1:Cotton spider mites are shown very well in the range of 10
Synergistic effect.It can be seen from Table 4 that, second azoles mite nitrile and propargite are 40:1~1:Have well to cotton spider mites in the range of 40
Synergistic effect.
Embodiment：
By second azoles mite nitrile and fluacrypyrim, Spiromesifen, Hexythiazox, propargite in varing proportions, excipients, wetting agent are added, is filled out
The auxiliary agents such as agent are filled, the formulations such as missible oil, suspension emulsion, water-dispersible granules, wettable powder, microcapsule suspending agent have been made.In order to say
Obvious results really, is further illustrated with example 1 to example 4 below, but not limited to this.
(the 30% second azoles mite nitrile fluacrypyrim suspending agent of embodiment 1）
Composition of raw materials：By mass percentage
Active component second azoles mite nitrile 25%
Active component fluacrypyrim 5%
NNO 3%
BY110 2%
APE-1 2%
Xanthans 0.15%
Propane diols 1%
Octanol 0.05%
Water surplus.
Preparation method is as follows：
According to formula, component is weighed in proportion, ball mill ball milling is added 30 minutes, filtering is pumped into 3 points of dispersion tank high speed shear
It is fully ground after clock through sand mill, control solid constituent particle diameter is within 2 microns, and grinding stirs after terminating, and produces
Suspending agent product.
(the 30% second fenpyroximate Spiromesifen missible oil of embodiment 2）
Composition of raw materials：By mass percentage
Active component second fenpyroximate 5%
Active component Spiromesifen 25%
Dimethylbenzene 20%
DMF 2%
Anhydrous calcium salt 5%
Tween 80 5%
Carbon tetrachloride surplus.
Preparation method：Active component is fully dissolved in dimethylbenzene, stirred, anhydrous calcium salt and tween is added
80, content then is adjusted with solvent DMF, surplus is adjusted with carbon tetrachloride.
Embodiment 3（30% second azoles mite nitrile Hexythiazox water dispersible granules）
Active component second azoles mite nitrile 25%
Active component Hexythiazox 5%
Methyl fatty acid amides benzene sulfonic acid calcium 4%
Sodium carbonate 3%
Sodium lignin sulfonate 4%
Attapulgite surplus.
Preparation method：Second azoles mite nitrile, Hexythiazox, Methyl fatty acid amides benzene sulfonic acid calcium, sodium carbonate, attapulgite are mixed together
After closing uniformly, 5 μm of particle diameter is crushed to through airslide disintegrating mill, female powder is obtained, granulated after female powder and sodium lignin sulfonate are sufficiently mixed,
Drying, sieving, so that water-dispersible granules are made.
Embodiment 4（66% second azoles mite nitrile propargite wettable powder）
Active component second azoles mite nitrile 6%
Active component propargite 66%
Wooden sodium 3%
Amine carbonate 3%
White carbon 10%
Attapulgite surplus.
Preparation method：Above-mentioned substance is uniformly mixed, mixture is crushed through airslide disintegrating mill, wettable powder is made.
Embodiment 5（12% second azoles mite nitrile fluacrypyrim microcapsule suspending agent）
Active component second azoles mite nitrile 6%
Active component fluacrypyrim 6%
Dimethylformamide 2%
Methyl diphenylene diisocyanate 3%
Fatty acid amide N methyl taurine sodium salt 2%
Ethylenediamine 0.5%
Gum arabic 2%
Polyvinyl alcohol 2%
Water polishing is to 100%
（1）By medicament dissolution in solvent, add methyl diphenylene diisocyanate and be uniformly mixing to obtain oil phase；（2）In water
Add emulsifying agent, adjuvant and be uniformly mixing to obtain aqueous phase；（3）Aqueous phase is added in oil phase, high speed homogenizing formation oil-in-water emulsion；
（4）Under 450 revs/min of speed conditions, add ethylenediamine and participate in interface polymerization reaction, reaction temperature rises to 55 DEG C, is kept for 3 hours
Solidify encystation；（5）Dispersant, thickener are added, stirs and microcapsule suspending agent is made.
The method for preventing and treating evil mite using above-mentioned composition pesticide is to occur the phase in evil mite to add water and be made into suspension spray and use,
Prevent and treat evil mite.The present invention can routinely spray after can also the medicament of preparation be diluted by 500-5000 times, atomizing, or utilize heat
The big machineries such as mist machine, aircraft carry out large area dispenser, reduce the generation of the insect evil mites such as tetranychid.
Claims (5)
1. a kind of acaricide composition and its application method, it is characterised in that：It is made up of effective constituents A and B and auxiliary material, wherein having
It is second azoles mite nitrile to imitate composition A, and active ingredient B is one kind in fluacrypyrim, Spiromesifen, Hexythiazox and propargite.
2. a kind of acaricide composition according to claim 1 and its application method, it is characterised in that：The compound acaricide
In agent, effective constituents A and active ingredient B mass ratio are 40: 1-1: 40.
3. a kind of acaricide composition according to claim 1 and its application method, it is characterised in that：The compound acaricide
In agent, effective constituents A and active ingredient B mass ratio are 10: 1-1: 10.
4. a kind of acaricide composition according to claim 1 and its application method, it is characterised in that：The compound acaricide
In agent, effective constituents A and active ingredient B mass ratio are 10: 1-1: 5.
5. a kind of acaricide composition according to claim 1 and its application method, it is characterised in that：The compound acaricide
The formulation of agent is missible oil, suspending agent, water-dispersible granules, wettable powder, microcapsule suspending agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710154870.8A CN106937634A (en) | 2017-03-15 | 2017-03-15 | A kind of acaricide composition and its application method |
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| CN201710154870.8A CN106937634A (en) | 2017-03-15 | 2017-03-15 | A kind of acaricide composition and its application method |
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| CN106937634A true CN106937634A (en) | 2017-07-11 |
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| CN201710154870.8A Pending CN106937634A (en) | 2017-03-15 | 2017-03-15 | A kind of acaricide composition and its application method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109832279A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104663672A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing mite growth inhibitor mite-killing agent |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
| CN104663668A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide |
| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
| CN106605657A (en) * | 2015-10-24 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Pesticide combination containing SYP-9625 |
-
2017
- 2017-03-15 CN CN201710154870.8A patent/CN106937634A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104663672A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing mite growth inhibitor mite-killing agent |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
| CN104663668A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide |
| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
| CN106605657A (en) * | 2015-10-24 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Pesticide combination containing SYP-9625 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109832279A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
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