CN106930466B - A kind of electromagnetic shielding wallboard and its manufacturing method - Google Patents

A kind of electromagnetic shielding wallboard and its manufacturing method Download PDF

Info

Publication number
CN106930466B
CN106930466B CN201710166783.4A CN201710166783A CN106930466B CN 106930466 B CN106930466 B CN 106930466B CN 201710166783 A CN201710166783 A CN 201710166783A CN 106930466 B CN106930466 B CN 106930466B
Authority
CN
China
Prior art keywords
parts
hole pattern
nickel alloy
temperature
thin plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710166783.4A
Other languages
Chinese (zh)
Other versions
CN106930466A (en
Inventor
肖文华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Automobile Industry Engineering Co Ltd
Original Assignee
China Automobile Industry Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Automobile Industry Engineering Co Ltd filed Critical China Automobile Industry Engineering Co Ltd
Priority to CN201710166783.4A priority Critical patent/CN106930466B/en
Priority to CN201811447001.5A priority patent/CN109440958B/en
Publication of CN106930466A publication Critical patent/CN106930466A/en
Application granted granted Critical
Publication of CN106930466B publication Critical patent/CN106930466B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/288Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and concrete, stone or stone-like material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/023Alloys based on nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/292Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and sheet metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0862Nickel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B2001/925Protection against harmful electro-magnetic or radio-active radiations, e.g. X-rays

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electromagnetism (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Finishing Walls (AREA)
  • Building Environments (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)

Abstract

A kind of electromagnetic shielding wallboard and its manufacturing method, being electromagnetically shielded wallboard includes concrete prefabricated substrate, one side is stained with nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, screen rubber coating is coated outside plastering sand pulp layer, butadiene rubber shielding coating provided by the present invention, uses polyurethane resin and styrene-acrylic emulsion as organic carrier.Compared with traditional epoxy resin solvent based coating, which obtains more preferably shield effectiveness, blanc fixe, carbon black and nickel powder, is dispersed in overlapped in coating, to form close conductive network, electric conductivity is greatly improved.Additionally due to long-term electromagenetic wave radiation can damage coating organic binder matter, coating cracks, and butadiene rubber can effectively improve the toughness of coating, increases coating life.

Description

A kind of electromagnetic shielding wallboard and its manufacturing method
Technical field
The present invention relates to a kind of electromagnetic shielding wallboard and its manufacturing method, belongs to the field of building materials.
Background technique
It is well known that with the rapid development and its extensive use of electronic technology, when electromagnetic radiation pollution public hazards are no without It is not present outside.Around TV and Radio Service underfooting, microwave station and radar station in city, signal centre nearby, electric railway Building by two sides, radio-frequency apparatus surrounding and overlooking road is all the heavier area of far zone field electromagnetic radiation pollution, furthermore indoor The electromagnetic wave that electric appliance generates is also the human body harm that can not ignore.The wall of common building object is to stop not living electromagnetic radiation; Therefore, it is necessary to take corresponding shielding measure.The prior art is unable to satisfy real needs, anxious wait find with electro-magnetic screen function Wallboard.
Summary of the invention
In order to solve the problems, such as that prior art deadlight electromagnetic shielding performance is lower in the prior art, offer one of the invention Kind electromagnetic shielding wallboard and its manufacturing method, to solve the above problem.
A kind of manufacturing method being electromagnetically shielded wallboard, electromagnetic shielding wallboard include concrete prefabricated substrate, one side adherency There is nickel alloy hole pattern thin plate, be plastering sand pulp layer outside nickel alloy hole pattern thin plate, coat screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 70-80 parts of polyurethane resin, 10-20 parts of styrene-acrylic emulsion, 20-25 parts of butadiene rubber, second 60-100 parts of acetoacetic ester, 20-40 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm, After mixing, after blanc fixe 10-15 parts of addition, 10-15 parts of white carbon black powder and 20-30 parts of nickel powder, 30 DEG C of heat preservations are cooled to 20 minutes, it is then added dibutyl tin dilaurate 2-5 parts, 2-4 parts and isocyanates 1-2 parts of dipropylene glycol methyl ether stir evenly Screen rubber paint is obtained,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 5-8 ﹪, Zn 3-4 ﹪, Zr 0.8- 1 ﹪, Pb 0.5-0.6 ﹪, Ba 0.5-0.6 ﹪, Ag 0.3-0.4 ﹪, Ti 0.1-0.2 ﹪, Nb 0.1-0.2 ﹪, Mn Raw material, is put into vacuum melting furnace, smelting temperature is by 0.05-0.06 ﹪, W 0.02-0.03 ﹪, surplus Ni according to the proportion 1530-1550 DEG C, after being completely melt, temperature is down to 1480-1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, is cast Ingot casting is then put into heat-treatment furnace and is heated to 1200-1250 DEG C by ingot, and heat preservation is forged after 10-15 minutes, upsetting pull repeatedly At least twice, forging is kept the temperature 1-2 hours at 980-1000 DEG C later and naturally cools to room by 1100-1120 DEG C of final forging temperature Forging is heated to 1000-1050 DEG C of progress roughing again later by temperature, and roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate keeps the temperature 30 minutes at 850-880 DEG C, carries out essence to roughing plate later It rolls, for the control of finish rolling start rolling temperature at 820-840 DEG C, finishing speeds are 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, essence Plate thin thickness 0.5-1mm is rolled, planished sheet is punched out using numerical control stamping hole pattern machine, it is the nickel of 5-10mm that obtaining, which has aperture, Alloy hole pattern sheet billet, aperture 5-10mm as needed cut nickel alloy hole pattern sheet billet, and the nickel of well cutting is closed Golden hole pattern thin plate heating keeps the temperature 30-40 minutes, final nickel alloy hole pattern thin plate is obtained, by nickel alloy hole pattern to 750-800 DEG C Thin plate is covered on concrete prefabricated substrate using adhesive, and plastering mortar and water are stirred evenly, plastering mortar and water quality Than are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate and forms plastering sand pulp layer, and configured screen rubber paint is sprayed Screen rubber coating is formed in plastering sand pulp layer, obtains electromagnetic shielding wallboard.
A kind of manufacturing method of electromagnetic shielding wallboard, plastering mortar and water quality ratio are as follows: 1:0.3-0.5.
A kind of manufacturing method of electromagnetic shielding wallboard, the round hole that punching obtains, aperture 8mm.
A kind of manufacturing method of electromagnetic shielding wallboard, the control of finish rolling start rolling temperature are in 830 DEG C, mill speed 0.8 meter per second, finishing temperature are 710-720 DEG C.
A kind of manufacturing method of the electromagnetic shielding wallboard, 1120 DEG C of final forging temperature.
A kind of manufacturing method of electromagnetic shielding wallboard, plastering mortar include (mass parts): sulphate aluminium cement 100-150 parts, 10-20 parts of gypsum, 100-120 parts of sand, 10-30 parts of steel fibre, 10-15 parts of lead powder, 5-10 parts of iron powder, bismuthine 5-7 parts of powder, 3-4 parts of borax, 2-5 parts of polyvinyl alcohol.
A kind of manufacturing method of electromagnetic shielding wallboard, plastering mortar include (mass parts): sulphate aluminium cement 120 Part, 16 parts of gypsum, 110 parts of sand, 25 parts of steel fibre, lead powder 10,8 parts of iron powder, 5 parts of bismuthine powder, 4 parts of borax, polyvinyl alcohol 3 Part.
A kind of manufacturing method of the electromagnetic shielding wallboard, it is 14 parts of styrene-acrylic emulsion, suitable first by 75 parts of polyurethane resin 22 parts of buna, 80 parts of ethyl acetate, 35 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300- 400rpm after 12 parts of blanc fixe of addition, 10 parts of white carbon black powder and 25 parts of nickel powder, is cooled to 30 DEG C of heat preservations 20 after mixing Minute, 2 parts of dibutyl tin dilaurate are then added, 3 parts and 1 part of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain shielding Rubberbase paint.
A kind of electromagnetic shielding wallboard, electromagnetic shielding wallboard includes concrete prefabricated substrate, and one side is stained with nickel alloy hole Net thin plate, nickel alloy hole pattern thin plate are plastering sand pulp layer outside, coat screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 70-80 parts of polyurethane resin, 10-20 parts of styrene-acrylic emulsion, 20-25 parts of butadiene rubber, second 60-100 parts of acetoacetic ester, 20-40 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm, After mixing, after blanc fixe 10-15 parts of addition, 10-15 parts of white carbon black powder and 20-30 parts of nickel powder, 30 DEG C of heat preservations are cooled to 20 minutes, it is then added dibutyl tin dilaurate 2-5 parts, 2-4 parts and isocyanates 1-2 parts of dipropylene glycol methyl ether stir evenly Screen rubber paint is obtained,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 5-8 ﹪, Zn 3-4 ﹪, Zr 0.8- 1 ﹪, Pb 0.5-0.6 ﹪, Ba 0.5-0.6 ﹪, Ag 0.3-0.4 ﹪, Ti 0.1-0.2 ﹪, Nb 0.1-0.2 ﹪, Mn Raw material, is put into vacuum melting furnace, smelting temperature is by 0.05-0.06 ﹪, W 0.02-0.03 ﹪, surplus Ni according to the proportion 1530-1550 DEG C, after being completely melt, temperature is down to 1480-1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, is cast Ingot casting is then put into heat-treatment furnace and is heated to 1200-1250 DEG C by ingot, and heat preservation is forged after 10-15 minutes, upsetting pull repeatedly At least twice, forging is kept the temperature 1-2 hours at 980-1000 DEG C later and naturally cools to room by 1100-1120 DEG C of final forging temperature Forging is heated to 1000-1050 DEG C of progress roughing again later by temperature, and roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate keeps the temperature 30 minutes at 850-880 DEG C, carries out essence to roughing plate later It rolls, for the control of finish rolling start rolling temperature at 820-840 DEG C, finishing speeds are 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, essence Plate thin thickness 0.5-1mm is rolled, planished sheet is punched out using numerical control stamping hole pattern machine, it is the nickel of 5-10mm that obtaining, which has aperture, Alloy hole pattern sheet billet, aperture 5-10mm as needed cut nickel alloy hole pattern sheet billet, and the nickel of well cutting is closed Golden hole pattern thin plate heating keeps the temperature 30-40 minutes, final nickel alloy hole pattern thin plate is obtained, by nickel alloy hole pattern to 750-800 DEG C Thin plate is covered on concrete prefabricated substrate using adhesive, and plastering mortar and water are stirred evenly, plastering mortar and water quality Than are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate and forms plastering sand pulp layer, and configured screen rubber paint is sprayed Screen rubber coating is formed in plastering sand pulp layer, obtains electromagnetic shielding wallboard.
Plastering mortar includes: 100-150 parts of sulphate aluminium cement, and 10-20 parts of gypsum, 100-120 parts of sand, steel fibre 10- 30 parts, 10-15 parts of lead powder, 5-10 parts of iron powder, 5-7 parts of bismuthine powder, 3-4 parts of borax, 2-5 parts of polyvinyl alcohol,
The concrete prefabricated substrate other side can also have insulating layer of external wall or decorative coveringn.
Butadiene rubber shielding coating provided by the present invention, uses polyurethane resin and styrene-acrylic emulsion as organic carrier. Compared with traditional epoxy resin solvent based coating, which obtains more preferably shield effectiveness, blanc fixe, carbon black and nickel Powder, is dispersed in overlapped in coating, to form close conductive network, electric conductivity is greatly improved.Additionally due to long-term Electromagenetic wave radiation can damage coating organic binder matter, and coating cracks, and butadiene rubber can effectively improve coating Toughness, increase coating life.Plastering mortar of the present invention is reached by superfine lead powder, iron powder, bismuthine powder, borax collective effect Shielding action, effectively weaken radioactive radiation, and by shielding network, lead powder, bismuthine by being formed by steel fibre Powder, borax are filled it, form equally distributed shielding solid space between component, improve shield effectiveness, nickel of the present invention Alloying component makes nickel alloy hole pattern thin plate have good electric conductivity, and roughing+finish rolling+heat treatment process makes nickel alloy tissue More uniform, there is not coarse phenomenon in crystal grain, and cellular structure meets shielding requirements, and the ventilative effect of the entirety for reaching wall Fruit, thin plate hardness with higher increase wall overall mechanical strength.The present invention passes through nickel alloy hole pattern thin plate from the inside to the outside, Coat of plaster, shielding coating, which cooperates with, has integrally all reached the slave low frequency for improving wall to high frequency shield effectiveness.
Detailed description of the invention
Fig. 1 is electromagnetic shielding panel cross section schematic diagram.
Specific embodiment
As shown in Figure 1, a kind of manufacturing method for being electromagnetically shielded wallboard, electromagnetic shielding wallboard includes concrete prefabricated substrate 1, One side is stained with nickel alloy hole pattern thin plate 2, is plastering sand pulp layer 3 outside nickel alloy hole pattern thin plate, screen is coated outside plastering sand pulp layer Rubber coating 4 is covered,
Embodiment 1
A kind of electromagnetic shielding wallboard and its manufacturing method, electromagnetic shielding wallboard include concrete prefabricated substrate, and one side is viscous With nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, coats screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 73 parts of polyurethane resin, 12 parts of styrene-acrylic emulsion, 21 parts of butadiene rubber, ethyl acetate 80 Part, 25 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm is added after mixing After 10-15 parts of blanc fixe, 14 parts of white carbon black powder and 20 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 minutes, two laurels are then added 5 parts of sour dibutyl tin, 2 parts and 1 part of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 6 ﹪, Zn 3 ﹪, Zr 0.8 ﹪, Pb 0.55 ﹪, Ba 0.6 ﹪, Ag 0.35 ﹪, Ti 0.15 ﹪, Nb 0.1 ﹪, Mn 0.055 ﹪, W 0.025 ﹪, surplus Ni, Raw material is put into vacuum melting furnace according to the proportion, smelting temperature is 1530-1550 DEG C, and after being completely melt, temperature is down to 1480- It 1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, then ingot casting is put into heat-treatment furnace and is heated to 1200-1250 DEG C, heat preservation 10-15 minutes after forged, repeatedly upsetting pull at least twice, 1100-1120 DEG C of final forging temperature, later Forging is kept the temperature into 1-2 hours cooled to room temperatures at 980-1000 DEG C, forging is heated to 1000-1050 DEG C again later Roughing is carried out, roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate 30 minutes are kept the temperature at 850-880 DEG C, finish rolling is carried out to roughing plate later, for the control of finish rolling start rolling temperature at 820-840 DEG C, finish rolling is fast Degree is 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, finish rolling plate thin thickness 0.5-1mm, using numerical control stamping hole pattern machine to essence It rolls thin plate to be punched out, it is the nickel alloy hole pattern sheet billet of 5-10mm that obtaining, which has aperture, and aperture 5-10mm is right as needed Nickel alloy hole pattern sheet billet is cut, by the nickel alloy hole pattern thin plate heating of well cutting to 750-800 DEG C, 30-40 points of heat preservation Clock, obtains final nickel alloy hole pattern thin plate, and nickel alloy hole pattern thin plate is covered on concrete prefabricated substrate using adhesive, Plastering mortar and water are stirred evenly, plastering mortar and water quality ratio are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate Plastering sand pulp layer is formed, configured screen rubber paint is sprayed on formation screen rubber coating in plastering sand pulp layer, obtains electricity Magnetic screen wallboard,
Plastering mortar includes: 130 parts of sulphate aluminium cement, and 18 parts of gypsum, 115 parts of sand, 20 parts of steel fibre, 12 parts of lead powder, 6 parts of iron powder, 6 parts of bismuthine powder, 3.5 parts of borax, 3 parts of polyvinyl alcohol.
Embodiment 2
A kind of electromagnetic shielding wallboard and its manufacturing method, electromagnetic shielding wallboard include concrete prefabricated substrate, and one side is viscous With nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, coats screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 73 parts of polyurethane resin, 18 parts of styrene-acrylic emulsion, 25 parts of butadiene rubber, ethyl acetate 90 Part, 30 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm is added after mixing After 11 parts of blanc fixe, 14 parts of white carbon black powder and 29 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 minutes, tin dilaurate two is then added 4 parts of butyl tin, 3 parts and 2 parts of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 7 ﹪, Zn 4 ﹪, Zr 1 ﹪, Pb 0.55 ﹪, Ba 0.6 ﹪, Ag 0.4 ﹪, Ti 0.15 ﹪, Nb 0.15 ﹪, Mn 0.06 ﹪, W 0.02 ﹪, surplus Ni are pressed Raw material is put into vacuum melting furnace according to proportion, smelting temperature is 1530-1550 DEG C, and after being completely melt, temperature is down to 1480- It 1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, then ingot casting is put into heat-treatment furnace and is heated to 1200-1250 DEG C, heat preservation 10-15 minutes after forged, repeatedly upsetting pull at least twice, 1100-1120 DEG C of final forging temperature, later Forging is kept the temperature into 1-2 hours cooled to room temperatures at 980-1000 DEG C, forging is heated to 1000-1050 DEG C again later Roughing is carried out, roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate 30 minutes are kept the temperature at 850-880 DEG C, finish rolling is carried out to roughing plate later, for the control of finish rolling start rolling temperature at 820-840 DEG C, finish rolling is fast Degree is 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, finish rolling plate thin thickness 0.5-1mm, using numerical control stamping hole pattern machine to essence It rolls thin plate to be punched out, it is the nickel alloy hole pattern sheet billet of 5-10mm that obtaining, which has aperture, and aperture 5-10mm is right as needed Nickel alloy hole pattern sheet billet is cut, by the nickel alloy hole pattern thin plate heating of well cutting to 750-800 DEG C, 30-40 points of heat preservation Clock, obtains final nickel alloy hole pattern thin plate, and nickel alloy hole pattern thin plate is covered on concrete prefabricated substrate using adhesive, Plastering mortar and water are stirred evenly, plastering mortar and water quality ratio are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate Plastering sand pulp layer is formed, configured screen rubber paint is sprayed on formation screen rubber coating in plastering sand pulp layer, obtains electricity Magnetic screen wallboard,
Plastering mortar includes: 140 parts of sulphate aluminium cement, and 12 parts of gypsum, 115 parts of sand, 15 parts of steel fibre, 13 parts of lead powder, 6 parts of iron powder, 7 parts of bismuthine powder, 4 parts of borax, 5 parts of polyvinyl alcohol.
Embodiment 3
A kind of electromagnetic shielding wallboard and its manufacturing method, electromagnetic shielding wallboard include concrete prefabricated substrate, and one side is viscous With nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, coats screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 77 parts of polyurethane resin, 18 parts of styrene-acrylic emulsion, 22 parts of butadiene rubber, ethyl acetate 80 Part, 35 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm is added after mixing After 11 parts of blanc fixe, 12 parts of white carbon black powder and 26 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 minutes, tin dilaurate two is then added 5 parts of butyl tin, 2 parts and 1 part of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 5 ﹪, Zn 4 ﹪, Zr 0.85 ﹪, Pb 0.55 ﹪, Ba 0.6 ﹪, Ag 0.3 ﹪, Ti 0.2 ﹪, Nb 0.1 ﹪, Mn 0.05 ﹪, W 0.03 ﹪, surplus Ni, according to Raw material is put into vacuum melting furnace by proportion, and smelting temperature is 1530-1550 DEG C, and after being completely melt, temperature is down to 1480-1490 DEG C, it is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, then ingot casting is put into heat-treatment furnace and is heated to 1200- 1250 DEG C, heat preservation is forged after 10-15 minutes, and upsetting pull at least twice, 1100-1120 DEG C of final forging temperature, later will forging repeatedly Part keeps the temperature 1-2 hours cooled to room temperatures at 980-1000 DEG C, and forging is heated to 1000-1050 DEG C of progress again later Roughing, roughing speed are 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, and roughing plate thickness 1.5-2.5mm, roughing plate exists 850-880 DEG C keeps the temperature 30 minutes, carries out finish rolling to roughing plate later, the control of finish rolling start rolling temperature is at 820-840 DEG C, finishing speeds For 0.7-0.9 meter per second, finishing temperature is 710-720 DEG C, finish rolling plate thin thickness 0.5-1mm, using numerical control stamping hole pattern machine to finish rolling Thin plate is punched out, and it is the nickel alloy hole pattern sheet billet of 5-10mm, aperture 5-10mm, as needed to nickel that obtaining, which has aperture, Alloy hole pattern sheet billet is cut, and by the nickel alloy hole pattern thin plate heating of well cutting to 750-800 DEG C, keeps the temperature 30-40 minutes, Final nickel alloy hole pattern thin plate is obtained, nickel alloy hole pattern thin plate is covered on concrete prefabricated substrate using adhesive, it will Plastering mortar is stirred evenly with water, plastering mortar and water quality ratio are as follows: 1:0.3-0.5 is coated on shape on nickel alloy hole pattern thin plate At plastering sand pulp layer, configured screen rubber paint is sprayed on formation screen rubber coating in plastering sand pulp layer, obtains electromagnetism Wallboard is shielded,
Plastering mortar includes: 150 parts of sulphate aluminium cement, and 15 parts of gypsum, 105 parts of sand, 15 parts of steel fibre, 14 parts of lead powder, 9 parts of iron powder, 6 parts of bismuthine powder, 4 parts of borax, 2 parts of polyvinyl alcohol.
Embodiment 4
A kind of electromagnetic shielding wallboard and its manufacturing method, electromagnetic shielding wallboard include concrete prefabricated substrate, and one side is viscous With nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, coats screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 75 parts of polyurethane resin, 13 parts of styrene-acrylic emulsion, 24 parts of butadiene rubber, ethyl acetate 65 Part, 28 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm is added after mixing After 12 parts of blanc fixe, 11 parts of white carbon black powder and 24 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 minutes, tin dilaurate two is then added 3 parts of butyl tin, 2 parts and 2 parts of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 6 ﹪, Zn 3 ﹪, Zr 0.8 ﹪, Pb 0.55 ﹪, Ba 0.5 ﹪, Ag 0.35 ﹪, Ti 0.1 ﹪, Nb 0.1 ﹪, Mn 0.05 ﹪, W 0.02 ﹪, surplus Ni are pressed Raw material is put into vacuum melting furnace according to proportion, smelting temperature is 1530-1550 DEG C, and after being completely melt, temperature is down to 1480- It 1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, then ingot casting is put into heat-treatment furnace and is heated to 1200-1250 DEG C, heat preservation 10-15 minutes after forged, repeatedly upsetting pull at least twice, 1100-1120 DEG C of final forging temperature, later Forging is kept the temperature into 1-2 hours cooled to room temperatures at 980-1000 DEG C, forging is heated to 1000-1050 DEG C again later Roughing is carried out, roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate 30 minutes are kept the temperature at 850-880 DEG C, finish rolling is carried out to roughing plate later, for the control of finish rolling start rolling temperature at 820-840 DEG C, finish rolling is fast Degree is 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, finish rolling plate thin thickness 0.5-1mm, using numerical control stamping hole pattern machine to essence It rolls thin plate to be punched out, it is the nickel alloy hole pattern sheet billet of 5-10mm that obtaining, which has aperture, and aperture 5-10mm is right as needed Nickel alloy hole pattern sheet billet is cut, by the nickel alloy hole pattern thin plate heating of well cutting to 750-800 DEG C, 30-40 points of heat preservation Clock, obtains final nickel alloy hole pattern thin plate, and nickel alloy hole pattern thin plate is covered on concrete prefabricated substrate using adhesive, Plastering mortar and water are stirred evenly, plastering mortar and water quality ratio are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate Plastering sand pulp layer is formed, configured screen rubber paint is sprayed on formation screen rubber coating in plastering sand pulp layer, obtains electricity Magnetic screen wallboard,
Plastering mortar includes: 140 parts of sulphate aluminium cement, and 13 parts of gypsum, 110 parts of sand, 17 parts of steel fibre, 13 parts of lead powder, 6 parts of iron powder, 7 parts of bismuthine powder, 3 parts of borax, 3 parts of polyvinyl alcohol.
Embodiment 5
A kind of electromagnetic shielding wallboard and its manufacturing method, electromagnetic shielding wallboard include concrete prefabricated substrate, and one side is viscous With nickel alloy hole pattern thin plate, it is plastering sand pulp layer outside nickel alloy hole pattern thin plate, coats screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 73 parts of polyurethane resin, 20 parts of styrene-acrylic emulsion, 22 parts of butadiene rubber, ethyl acetate 80 Part, 28 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm is added after mixing After 13 parts of blanc fixe, 15 parts of white carbon black powder and 22 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 minutes, tin dilaurate two is then added 3 parts of butyl tin, 3 parts and 1 part of isocyanates of dipropylene glycol methyl ether are uniformly mixing to obtain screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 6 ﹪, Zn 0.9 ﹪ of 3.5 ﹪, Zr, Pb 0.5 ﹪, Ba 0.6 ﹪, Ag 0.35 ﹪, Ti 0.15 ﹪, Nb 0.2 ﹪, Mn 0.05 ﹪, W 0.03 ﹪, surplus Ni, Raw material is put into vacuum melting furnace according to the proportion, smelting temperature is 1530-1550 DEG C, and after being completely melt, temperature is down to 1480- It 1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, then ingot casting is put into heat-treatment furnace and is heated to 1200-1250 DEG C, heat preservation 10-15 minutes after forged, repeatedly upsetting pull at least twice, 1100-1120 DEG C of final forging temperature, later Forging is kept the temperature into 1-2 hours cooled to room temperatures at 980-1000 DEG C, forging is heated to 1000-1050 DEG C again later Roughing is carried out, roughing speed is 0.5-1 meter per second, and finishing temperature is 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate 30 minutes are kept the temperature at 850-880 DEG C, finish rolling is carried out to roughing plate later, for the control of finish rolling start rolling temperature at 820-840 DEG C, finish rolling is fast Degree is 0.7-0.9 meter per second, and finishing temperature is 710-720 DEG C, finish rolling plate thin thickness 0.5-1mm, using numerical control stamping hole pattern machine to essence It rolls thin plate to be punched out, it is the nickel alloy hole pattern sheet billet of 5-10mm that obtaining, which has aperture, and aperture 5-10mm is right as needed Nickel alloy hole pattern sheet billet is cut, by the nickel alloy hole pattern thin plate heating of well cutting to 750-800 DEG C, 30-40 points of heat preservation Clock, obtains final nickel alloy hole pattern thin plate, and nickel alloy hole pattern thin plate is covered on concrete prefabricated substrate using adhesive, Plastering mortar and water are stirred evenly, plastering mortar and water quality ratio are as follows: 1:0.3-0.5 is coated on nickel alloy hole pattern thin plate Plastering sand pulp layer is formed, configured screen rubber paint is sprayed on formation screen rubber coating in plastering sand pulp layer, obtains electricity Magnetic screen wallboard,
Plastering mortar includes: 100 parts of sulphate aluminium cement, and 15 parts of gypsum, 115 parts of sand, 12 parts of steel fibre, 14 parts of lead powder, 6 parts of iron powder, 5 parts of bismuthine powder, 4 parts of borax, 3 parts of polyvinyl alcohol.
By the relevant regulations of MIL-STD-285:1956 " the electromagnetic shielding environmental attenuation method for electronic test ", pass through Simulation test tests the wallboard in the present invention using medium wave, shortwave, ultrashort wave, microwave, such as the following table 1:
Test frequency (MHz) Wallboard shield effectiveness SE (dB) of the present invention The common wallboard shield effectiveness SE (dB) of the prior art
0.8 55.6 6
20 54.2 6
100 52.4 6
200 51.5 5
800 47.6 4
1500 45.2 2
3000 42.4 2
Table 2: shielding coating performance test
Test item Testing standard Test result
Adhesive force (grade) GB/T1720-79 1
Hardness (pencil) GB/T6739-1996 2H
Weatherability GB/T1865 Not blistering no removing in 800 hours
Water resistance, soak 48h GB/T1733-93 Without significant change
Flexibility, mm GB/T1731-93 2
Impact resistance kg/cm GB/T1732-93 50
Table 3: plastering mortar performance test
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Thermal coefficient W/ (mK) 0.37 0.40 0.39 0.40 0.42
Shrinking percentage, % 0.20 0.19 0.21 0.22 0.21
28 days adhesion strength MPa 0.45 0.44 0.42 0.40 0.51
Compression strength, MPa 2.74 2.67 2.63 2.64 2.60
Table 4: nickel alloy hole pattern thin plate performance test
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Hardness number (HV) 85 90 82 80 74
Resistivity is Ω mm2/m. 0.054 0.042 0.047 0.052 0.047
Butadiene rubber shielding coating provided by the present invention, uses polyurethane resin and styrene-acrylic emulsion as organic carrier. Compared with traditional epoxy resin solvent based coating, which obtains more preferably shield effectiveness, blanc fixe, carbon black and nickel Powder, is dispersed in overlapped in coating, to form close conductive network, electric conductivity is greatly improved.Additionally due to long-term Electromagenetic wave radiation can damage coating organic binder matter, and coating cracks, and butadiene rubber can effectively improve coating Toughness, increase coating life.Plastering mortar of the present invention is reached by superfine lead powder, iron powder, bismuthine powder, borax collective effect Shielding action, effectively weaken radioactive radiation, and by shielding network, lead powder, bismuthine by being formed by steel fibre Powder, borax are filled it, form equally distributed shielding solid space between component, improve shield effectiveness, nickel of the present invention Alloying component makes nickel alloy hole pattern thin plate have good electric conductivity, and roughing+finish rolling+heat treatment process makes nickel alloy tissue More uniform, there is not coarse phenomenon in crystal grain, and cellular structure meets shielding requirements, and the ventilative effect of the entirety for reaching wall Fruit, thin plate hardness with higher increase wall overall mechanical strength.The present invention passes through nickel alloy hole pattern thin plate from the inside to the outside, Coat of plaster, shielding coating, which cooperates with, has integrally all reached the slave low frequency for improving wall to high frequency shield effectiveness.

Claims (1)

1. a kind of manufacturing method for being electromagnetically shielded wallboard, electromagnetic shielding wallboard includes concrete prefabricated substrate, and one side is stained with Nickel alloy hole pattern thin plate, nickel alloy hole pattern thin plate are plastering sand pulp layer outside, coat screen rubber coating outside plastering sand pulp layer,
Be electromagnetically shielded wallboard manufacturing method the following steps are included:
First, in accordance with parts by weight by 70-80 parts of polyurethane resin, 10-20 parts of styrene-acrylic emulsion, 20-25 parts of butadiene rubber, acetic acid second 60-100 parts of ester, 20-40 parts of dimethylbenzene be put into blender and be warming up to 35 DEG C and mixed, mixing speed 300-400rpm, mixing After uniformly, after blanc fixe 10-15 parts of addition, 10-15 parts of white carbon black powder and 20-30 parts of nickel powder, it is cooled to 30 DEG C and keeps the temperature 20 points Clock is then added dibutyl tin dilaurate 2-5 parts, and 2-4 parts and isocyanates 1-2 parts of dipropylene glycol methyl ether are uniformly mixing to obtain Screen rubber paint,
Nickel alloy hole pattern thin plate includes following element mass percentage ingredient: Sn 5-8 ﹪, Zn 3-4 ﹪, Zr 0.8-1 ﹪, Pb 0.5-0.6 ﹪, Ba 0.5-0.6 ﹪, Ag 0.3-0.4 ﹪, Ti 0.1-0.2 ﹪, Nb 0.1-0.2 ﹪, Mn 0.05- Raw material is put into vacuum melting furnace by 0.06 ﹪, W 0.02-0.03 ﹪, surplus Ni according to the proportion, smelting temperature 1530- 1550 DEG C, after being completely melt, temperature is down to 1480-1490 DEG C, is kept for furnace temperature 15 minutes, is then poured, obtains ingot casting, with Ingot casting is put into heat-treatment furnace afterwards and is heated to 1200-1250 DEG C, heat preservation is forged after 10-15 minutes, and upsetting pull is at least repeatedly Twice, forging is kept the temperature 1-2 hours cooled to room temperatures by 1100-1120 DEG C of final forging temperature at 980-1000 DEG C later, it Forging is heated to 1000-1050 DEG C of progress roughing again afterwards, roughing speed is 0.5-1 meter per second, finishing temperature 900-920 DEG C, roughing plate thickness 1.5-2.5mm, roughing plate keeps the temperature 30 minutes at 850-880 DEG C, carries out finish rolling, finish rolling to roughing plate later At 820-840 DEG C, finishing speeds are 0.7-0.9 meter per second for start rolling temperature control, and finishing temperature is 710-720 DEG C, finish rolling plate thin and thick 0.5-1mm is spent, planished sheet is punched out using numerical control stamping hole pattern machine, it is the nickel alloy hole pattern of 5-10mm that obtaining, which has aperture, Sheet billet, aperture 5-10mm as needed cut nickel alloy hole pattern sheet billet, and the nickel alloy hole pattern of well cutting is thin Plate is heated to 750-800 DEG C, keeps the temperature 30-40 minutes, obtains final nickel alloy hole pattern thin plate, and nickel alloy hole pattern thin plate is used Adhesive covers on concrete prefabricated substrate, and plastering mortar and water are stirred evenly, plastering mortar and water quality ratio are as follows: 1: 0.3-0.5 is coated on nickel alloy hole pattern thin plate and forms plastering sand pulp layer, configured screen rubber paint is sprayed on plastering sand Screen rubber coating is formed in pulp layer, obtains electromagnetic shielding wallboard.
CN201710166783.4A 2017-03-20 2017-03-20 A kind of electromagnetic shielding wallboard and its manufacturing method Active CN106930466B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710166783.4A CN106930466B (en) 2017-03-20 2017-03-20 A kind of electromagnetic shielding wallboard and its manufacturing method
CN201811447001.5A CN109440958B (en) 2017-03-20 2017-03-20 Electromagnetic shielding wallboard

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710166783.4A CN106930466B (en) 2017-03-20 2017-03-20 A kind of electromagnetic shielding wallboard and its manufacturing method

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201811447001.5A Division CN109440958B (en) 2017-03-20 2017-03-20 Electromagnetic shielding wallboard

Publications (2)

Publication Number Publication Date
CN106930466A CN106930466A (en) 2017-07-07
CN106930466B true CN106930466B (en) 2019-03-12

Family

ID=59432422

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201811447001.5A Expired - Fee Related CN109440958B (en) 2017-03-20 2017-03-20 Electromagnetic shielding wallboard
CN201710166783.4A Active CN106930466B (en) 2017-03-20 2017-03-20 A kind of electromagnetic shielding wallboard and its manufacturing method

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201811447001.5A Expired - Fee Related CN109440958B (en) 2017-03-20 2017-03-20 Electromagnetic shielding wallboard

Country Status (1)

Country Link
CN (2) CN109440958B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108756053B (en) * 2018-06-22 2021-08-27 江苏东尚住宅工业有限公司 Prefabricated slab with electromagnetic shielding layer and manufacturing method thereof
CN109618548B (en) * 2018-09-29 2020-09-15 镇江华核装备有限公司 Composite shielding material for special vehicle

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2198324Y (en) * 1994-05-14 1995-05-24 吕新华 Combined electromagnet wave isolation room
JP4356235B2 (en) * 2000-12-07 2009-11-04 清水建設株式会社 Electromagnetic shielding wall joint structure
CN100476013C (en) * 2006-03-31 2009-04-08 江苏爱富希新型建材有限公司 Method for machining electromagnetic shielding plate for construction
KR100679307B1 (en) * 2006-06-23 2007-02-06 조용래 Construcrion element having metal layer and manufacturing method of thereof
CN102584124A (en) * 2012-02-21 2012-07-18 陕西理工学院 Technology for preparing zeolite-containing inorganic insulation mortar
CN104674977A (en) * 2013-11-27 2015-06-03 贵阳铝镁设计研究院有限公司 Electromagnetic shielding wall and construction method thereof
CN203766151U (en) * 2014-04-16 2014-08-13 浙江阿鲁特新型材料有限公司 Electromagnetic-radiation-resisting aluminum-plastic panel
CN204920316U (en) * 2015-07-02 2015-12-30 ***通信集团设计院有限公司 Computer lab with electromagnetic wave shielding structure
CN205637315U (en) * 2016-03-29 2016-10-12 北新集团建材股份有限公司 Composite sheet wall body of protecting against radiation
CN205642156U (en) * 2016-05-13 2016-10-12 天诺光电材料股份有限公司 Electromagnetic shield shelter wallboard
CN106045415A (en) * 2016-05-30 2016-10-26 李青 Anticorrosion concrete
CN205742722U (en) * 2016-06-14 2016-11-30 江苏吉福新材料股份有限公司 A kind of electromagnetic isolation density board
CN106380164B (en) * 2016-11-17 2019-01-04 中国人民解放军总参谋部工程兵第四设计研究院 Tempest concrete and the combined wall built up using it and its construction method

Also Published As

Publication number Publication date
CN109440958A (en) 2019-03-08
CN109440958B (en) 2020-11-13
CN106930466A (en) 2017-07-07

Similar Documents

Publication Publication Date Title
CN106930466B (en) A kind of electromagnetic shielding wallboard and its manufacturing method
CN103247403B (en) A kind of preparation method of metal soft magnetic powder core
CN108947376A (en) A kind of cement mortar and preparation method thereof
CN104065774B (en) A kind of Antiradiation mobile phone shell with signal enhancing function and preparation method thereof
CN110982421A (en) High-temperature-resistant wave-absorbing coating and preparation method thereof
CN113135775B (en) Stealth material for compatible inhibition of ultrahigh-temperature electromagnetic scattering and infrared radiation and preparation method thereof
CN106735245A (en) The method that powder forming prepares foam aluminum sandwich
CN102041439A (en) Method for improving mechanical properties of low-carbon aluminum killed steel continuous annealing product for automobile
CN112164488B (en) Silver paste for ceramic filter and preparation method thereof
CN103745791A (en) Production method of ultrahigh magnetic permeability of iron-based nanocrystalline magnetic powder core
CN106205935A (en) A kind of amorphous state soft magnetism composite magnetic powder core and preparation method thereof
CN104376942A (en) Prndfeb magnetic wave absorbing material and preparation method thereof
CN107424706A (en) Silicon steel powder core and preparation method thereof
CN104868409A (en) Anti-corrosion high-heat conduction composite cable bridge and manufacturing process thereof
CN108424609A (en) A kind of automobile electronics electromagnetic shielding material
CN107864603A (en) A kind of communication base station electrical control cabinet
CN106116398B (en) A kind of radiation protection health plasterboard
CN109265127B (en) Preparation method of high-strength high-toughness electromagnetic protection material for 3D printing
US20190264041A1 (en) Water-based high-temperature-resistant titanium-steel anti-bonding coating and use thereof
CN104293008B (en) A kind of preparation method of high silicon steel environmental protection half organic insulation coating
CN110713661A (en) Low-frequency P-band wave-absorbing material and preparation method thereof
CN103757505B (en) Standing-seam roofing tile aldural colour coated plate band and production method thereof
CN103771701B (en) Glass material of a kind of shock resistance Resisting fractre and preparation method thereof
CN113979724B (en) Sintered brick and preparation method and application thereof
EP3218322A1 (en) Building material for shielding against electromagnetic waves, method for producing the same and use thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20190202

Address after: 300193 No. 591 Changjiang Road, Nankai District, Tianjin

Applicant after: AUTOMOBILE ENGINEERING CORPORATION

Address before: 071065 Baoding Construction Materials Company, No. 64 Jianbei Road, Qingyuan District, Baoding City, Hebei Province

Applicant before: Xiao Wenhua

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant