CN106928832A - A kind of high temperature resistant anti-infrared radiation energy-saving coating - Google Patents
A kind of high temperature resistant anti-infrared radiation energy-saving coating Download PDFInfo
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- CN106928832A CN106928832A CN201710267047.8A CN201710267047A CN106928832A CN 106928832 A CN106928832 A CN 106928832A CN 201710267047 A CN201710267047 A CN 201710267047A CN 106928832 A CN106928832 A CN 106928832A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2251—Oxides; Hydroxides of metals of chromium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2262—Oxides; Hydroxides of metals of manganese
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2293—Oxides; Hydroxides of metals of nickel
Abstract
The invention discloses a kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, the coating is made up of the component of following weight portion：0.05 0.15 parts of high temperature 30 40 parts of powder of radiation high, 10 20 parts of silica flour, 5 10 parts of superhigh temperature additive, 30 50 parts of bonding agent, 10 20 parts of solvent, 0.1 0.2 parts of dispersant, 0.15 0.3 parts of coupling agent and defoamer.A kind of ternary structural of stabilization is formed present invention aims to coat inside, hinder coating is growed using crystal inside at high temperature for a long time, on the one hand can reduce because crystal is grown up the decay of caused coating infrared emittance, on the other hand the phenomenons such as cracking, chip off-falling that coating produced due to sintering shrinkage can be prevented, increase service life, effectively prevent infrared emittance from decaying.
Description
Technical field
The invention belongs to high-temperature energy-saving coating material field, and in particular to a kind of high temperature resistant anti-infrared radiance decay energy-conservation is applied
Material.
Background technology
World today's mineral resources energy worsening shortages, seriously threaten the development of world industry, and Industrial Stoves consume energy about
The 25%~40% of total energy consumption is accounted for, and the average thermal efficiency of kiln is only 32% or so.Pass through mainly due to one side heat
Furnace lining and furnace outer wall lose, and the efficiency of utilization of another aspect kiln and boiler is relatively low so that heat can not effectively utilize and
It is discharged, causes the huge waste of the energy.High temperature resistant High Radiant Rate Coating is that a class has good heat radiation and heat-absorption properties
New energy-saving material, the effect of radiation efficiency, augmentation of heat transfer can be improved used in Industrial Stoves inner lining surface；Used in industry
The metal tube skin of boiler, can strengthen absorbability of the boiler tube to heat, improve heat transfer efficiency, thermal loss be reduced, to reach
To the purpose for improving heat utilization efficiency and energy saving.
In recent years, the R and D of high-radiation energy-saving coating make some progress, in Industrial Boiler and kiln
Application above have received good energy-saving effect, the patent of invention of Application No. 201410055343.8 discloses a kind of high emission
Rate high-temperature nano ceramic coating, it mainly prepares coating from nano-powder for raw material, and coatings emissivity is not less than 0.94, but
It is that easy-sintering is shunk nano-powder at high temperature, crystal is grown up, on the one hand can makes coating infrared emittance reduction at high temperature
So as to influence the energy-saving effect of coating, another aspect crystal ambassador's coating shrinkage long to be likely to result in the cracking of coating greatly and take off
Fall.The patent of invention of Application No. 201310361422.7 discloses a kind of preparation method of energy-saving coatings, micro- from aluminum oxide
Powder, jakobsite, zirconium mullite, ferropicotite and gahnite are primary raw material, and finally prepared energy-saving coatings are complete
Wave band emissivity be 0.94, formd in coating it is polynary mix system, increased impurity energy level, the infrared of coating can be effectively improved
Radiance.But coating at high temperature if long-term use due to its be it is polynary mix system, lattice is more active, and crystal is easily long
Ambassador's coating sintering shrinkage, the infrared emittance for ultimately resulting in coating is gradually decayed, and coating cracking is will result in when shrinking excessive
So as to influence the service life of coating.
At present, the preparation of energy-saving coatings product is mostly raw material from micro-nano powder, because smaller its ratio of diameter of particle
Surface more large radiation rate is higher；Or from the polynary system material that mixes for raw material, the complication for improving internal crystal structure is entered
And the red hair radiance of material is improved, micro-nano raw material and diversification are mixed when system raw material is used at high temperature for a long time and can all be deposited
Grown up in crystal the problem of sintering shrinkage, thus causing the activity of crystal reduces so that the infrared emittance of coating gradually declines
Subtract, when coating shrinkage to a certain extent when occur cracking, decortication phenomenon so that influence coating using effect.If can protect
There is card coating long-time applied at elevated temperature crystal on the premise of high radiant rate not grow up or only slightly grow up, coating do not shrink or
Person shrinks smaller, will effectively prevent the decay of the infrared emittance of coating, and the service life of coating is greatly improved, and improves stove
The energy-saving efficiency and maintenance period of kiln.
The content of the invention
In view of this, the purpose of the present invention is directed to the deficiencies in the prior art, there is provided a kind of high temperature resistant anti-infrared radiance
Decay energy-saving coatings, solve that service life under energy-saving coatings hot conditions is short or coating infrared emittance in use
Decay problem.
The purpose of the present invention is achieved through the following technical solutions：
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, the coating is made up of the component of following weight portion：High temperature
Height 30-40 parts of powder of radiation, silica flour 10-20 parts, 5-10 parts of superhigh temperature additive, bonding agent 30-50 parts, solvent 10-20 parts,
Dispersant 0.1-0.2 parts, coupling agent 0.15-0.3 parts and defoamer 0.05-0.15 parts.
Further, high temperature radiation powder high is by di-iron trioxide, cupric oxide, manganese oxide, chromium oxide and nickel oxide
The several of one or more constitute in any proportion；The granularity of the radiation powder high is respectively less than 10 μm.
Further, the superhigh temperature additive is electric-melting zirconia micro mist, and powder size is 1-5 μm.
Further, the bonding agent is by one or more in waterborne polyurethane resin, waterglass and Ludox
Several constitute in any proportion.
Further, the solvent is water.
Further, the dispersant is sodium tripolyphosphate, calgon or polyethylene glycol type water reducer FS10.
Further, the coupling agent is trimethoxysilane coupling agent.
Further, the defoamer is the G60 defoamers of Sima Chemical Manufacture.
Gained coating of the invention conventionally mixes, stirs compounding.
Used raw material can be commercially available easily in the present invention, the compound national or professional standard of specification.
The features of the present invention：It is compound from micro-nano di-iron trioxide, cupric oxide, manganese oxide, chromium oxide and nickel oxide
Powder is radiating powder raw material high, and these height radiation raw materials form the material of composite spinelle structure at high temperature, with higher
High temp, infrared radiation rate, the introducing of electric-melting zirconia micro mist can hinder growing up for spinel crystal, coat inside is formed three
First interface effect, it helps improve the infrared emittance of coating, the in addition introducing of zirconium oxide micro mist also contributes to improve
The thermal shock resistance of coating.
The beneficial effects of the invention are as follows：
A kind of ternary structural of stabilization is formed present invention aims to coat inside, hinder coating is for a long time in high temperature
Lower use crystal inside is growed, and on the one hand can be reduced because crystal is grown up the decay of caused coating infrared emittance, separately
On the one hand the phenomenons such as cracking, chip off-falling that coating produced due to sintering shrinkage can be prevented.It is infrared that material at high temperature is improved in general
The method of radiance has two kinds, and one kind is to use ultra-fine micro-nano powder for raw material to prepare radiation powder high, and another kind is to apply
Expect the Composite of composition, the radiance of single object is after all limited, because the monochromatic absorption index of object is with radiated wave
Wavelength difference and be continually changing, the radiation characteristic of object also all shows certain selectivity.Solve the method for this problem
It is exactly using multiple material composition Composite, to enable object mutual with radiation characteristic in different wavelength range at different temperatures
Mend and mutually strengthen.The present invention is exactly to combine both approaches to prepare infrared radiating powder high, but selects both sides
It is as coating is used for a long time at high temperature, in coating that method prepare high temperature high-radiation energy-saving coating to have a common problem
Crystal ambassador's coating material long in portion's loses original property, so as to influence the infrared emittance and energy-saving efficiency of coating.
The present invention adds superhigh temperature additive electric-melting zirconia micro mist, electric-melting zirconia on the basis of original design concept
It is to found to form by the superhigh temperature more than 3,000 degree Celsius, crystal activity is low and is not easy to other materials and reacts, and
And the infrared emittance of zirconium oxide is also higher, electric-melting zirconia micro mist is incorporated into coating, on the one hand can be with hinder coating
Crystal is grown up refinement crystal grain, on the other hand can also improve the infrared emittance of coating.The high temperature resistant energy of electric-melting zirconia
Power is stronger, therefore coating uses in the case of relative low temperature (less than 1400 DEG C) and influence will not be produced on it.
Specific embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 30 high
Part, 10 parts of silica flour, 5 parts of electric-melting zirconia micro mist, 50 parts of waterborne polyurethane resin, 5 parts of water, 0.1 part of sodium tripolyphosphate, front three
0.05 part of the G60 defoamers of 0.15 part of TMOS coupling agent and Sima Chemical Manufacture.
Embodiment 2
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 40 high
Part, 10 parts of silica flour, 10 parts of electric-melting zirconia micro mist, 30 parts of waterglass, 10 parts of water, 0.2 part of calgon, trimethoxy silicon
0.15 part of the G60 defoamers of 0.3 part of alkane coupling agent and Sima Chemical Manufacture.
Embodiment 3
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 30 high
Part, 20 parts of silica flour, 8 parts of electric-melting zirconia micro mist, 10 parts of 20 parts of waterborne polyurethane resin and Ludox, 12 parts of water, poly- second
0.15 part of diol type water reducer FS10 dispersants, the Sima Chemical Manufacture that 0.2 part and 0.1 part of trimethoxysilane coupling agent
G60 defoamers.
Embodiment 4
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 35 high
Part, 10 parts of silica flour, 5 parts of electric-melting zirconia micro mist, 35 parts of Ludox, 15 parts of water, 0.1 part of calgon, trimethoxy silicon
0.05 part of the G60 defoamers of 0.3 part of alkane coupling agent and Sima Chemical Manufacture.
Embodiment 5
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 30 high
Part, 15 parts of silica flour, 5 parts of electric-melting zirconia micro mist, 30 parts of waterglass, 20 parts of water.Additional 0.1 part of sodium tripolyphosphate, front three
0.15 part of the G60 defoamers of 0.25 part of TMOS coupling agent and Sima Chemical Manufacture.
Embodiment 6
A kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, consist of the following parts by weight, high temperature radiation powder 38 high
Part, 12 parts of silica flour, 10 parts of electric-melting zirconia micro mist, 15 parts of waterborne polyurethane resin and 15 parts of Ludox, 10 parts of water, ethylene glycol
The G60 defoamers of 0.15 part of type water reducer FS10 dispersants, 0.2 part of trimethoxysilane coupling agent and Sima Chemical Manufacture
0.05 part.
The performance parameter such as following table of embodiment 1-6 gained coating
The performance parameter of the present invention gained coating of table 1.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, this area is common
Other modifications or equivalent that technical staff is made to technical scheme, without departing from technical solution of the present invention
Spirit and scope, all should cover in the middle of scope of the presently claimed invention.
Claims (8)
1. a kind of high temperature resistant anti-infrared radiance decay energy-saving coatings, it is characterised in that the coating by following weight portion component
Composition：High temperature 30-40 parts of powder of radiation high, silica flour 10-20 parts, 5-10 parts of superhigh temperature additive is bonding agent 30-50 parts, molten
Agent 10-20 parts, dispersant 0.1-0.2 parts, coupling agent 0.15-0.3 parts and defoamer 0.05-0.15 parts.
2. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the high temperature is high
Radiation powder is by one or more several by any in di-iron trioxide, cupric oxide, manganese oxide, chromium oxide and nickel oxide
Ratio is constituted；The granularity of the radiation powder high is respectively less than 10 μm.
3. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the superhigh temperature
Additive is electric-melting zirconia micro mist, and powder size is 1-5 μm.
4. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the bonding agent
It is made up of in any proportion the several of one or more in waterborne polyurethane resin, waterglass and Ludox.
5. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the solvent is
Water.
6. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the dispersant
It is sodium tripolyphosphate, calgon or polyethylene glycol type water reducer FS10.
7. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the coupling agent
It is trimethoxysilane coupling agent.
8. high temperature resistant anti-infrared radiance according to claim 1 decay energy-saving coatings, it is characterised in that the defoamer
It is the G60 defoamers of Sima Chemical Manufacture.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459849A (en) * | 2017-08-25 | 2017-12-12 | 洛阳嘉德节能科技有限公司 | A kind of infrared high-radiation energy-saving coating of high temperature resistant lint efflorescence and preparation method |
| CN107474723A (en) * | 2017-08-17 | 2017-12-15 | 宁波双屹节能环保科技有限公司 | A kind of industrial kiln high-performance infrared radiation coating |
| CN107573731A (en) * | 2017-10-24 | 2018-01-12 | 中国科学院理化技术研究所 | A kind of Temperature Infra red Radiation Coatings and its preparation method and application |
| CN107815148A (en) * | 2017-11-13 | 2018-03-20 | 苏州锐特捷化工制品有限公司 | A kind of high temperature resistant infrared radiative energy-saving coating and preparation method thereof |
| CN109535984A (en) * | 2018-12-27 | 2019-03-29 | 中钢集团洛阳耐火材料研究院有限公司 | A kind of superhigh temperature infra-red radiation heat preservation energy-saving coating |
| CN110066598A (en) * | 2019-05-28 | 2019-07-30 | 河南嘉和节能科技有限公司 | A kind of high temperature anti-dropout infrared radiative energy-saving coating |
| CN110117457A (en) * | 2019-05-28 | 2019-08-13 | 河南嘉和节能科技有限公司 | A kind of high temperature resistant anti-infrared attenuation energy-saving coatings |
| CN111073503A (en) * | 2019-12-24 | 2020-04-28 | 洛阳嘉德节能科技有限公司 | High-temperature-resistant high-emissivity anticorrosive paint |
| CN112830769A (en) * | 2021-01-20 | 2021-05-25 | 中国科学院金属研究所 | High-emissivity high-entropy ceramic powder material and coating preparation method |
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| CN107474723A (en) * | 2017-08-17 | 2017-12-15 | 宁波双屹节能环保科技有限公司 | A kind of industrial kiln high-performance infrared radiation coating |
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Effective date of registration: 20180928 Address after: 467000 miner Middle Road No. 21, Henan Province, Pingdingshan Applicant after: China Pingmei Shenma Energy Chemical Group Co., Ltd. Applicant after: Henan Jiahe Energy Saving Technology Co., Ltd. Address before: 450000 No. 25, 1 unit, 1 building, South Road West, North Station, Shangdu Road, Zheng Dong New District, Zhengzhou, Henan, China No. 25009 Applicant before: Henan Jiahe Energy Saving Technology Co., Ltd. |
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Inventor after: Zhang Dengyue Inventor after: Zhou Yunhui Inventor after: Wang Zhengwei Inventor after: Jin Peng Inventor after: Li Fei Inventor after: Shi Shujie Inventor after: Wang Xufeng Inventor after: Gu Xiaohu Inventor before: Wang Zhengwei Inventor before: Zhang Wei |
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