CN106916652A - Environment-friendly cleaning agent - Google Patents
Environment-friendly cleaning agent Download PDFInfo
- Publication number
- CN106916652A CN106916652A CN201511014307.8A CN201511014307A CN106916652A CN 106916652 A CN106916652 A CN 106916652A CN 201511014307 A CN201511014307 A CN 201511014307A CN 106916652 A CN106916652 A CN 106916652A
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- Prior art keywords
- environment
- cleaning agent
- friendly cleaning
- low
- friendly
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/267—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/28—Organic compounds containing halogen
- C11D7/30—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of environment-friendly cleaning agent, wherein, the environment-friendly cleaning agent includes：Raw material are by using gauge, n-Propyl Bromide 94%-95%；Normal propyl alcohol 3%-4%；Nitromethane 0.2%；DOX 0.8%；Epoxy butane 0.7%；BHT0.3%.The present invention has ozone layer destroying index low, global warming effect is low, and environment protecting is good, cleaning effect is high, and penetration is high, micropore material can also be cleaned easily, rate of drying is fast, without flashing point, degree of hydrolysis be low, liquid phase change is stable, be applicable to steam and clean and the advantages of Distillation recovery.
Description
Technical field
The present invention relates to a kind of cleaning agent, and in particular to a kind of environment-friendly cleaning agent.
Background technology
In recent years, with the continuous improvement of people's living standard and industrial technology level, various metallic articles, electronics,
The products such as accurate industry are widely used in the middle of industrial production and daily life, and market demand also compares
It is larger.In various metallic article process and after shaping, to carry out the cleaning on surface, and metallic article, electronics,
The surface of the products such as accurate industry and recess need to be cleaned., it is necessary to using to various types of during cleaning
The cleaning agent of type.
During dirt of the cleaning agent on body surface is washed, the surface-active of water can be changed, decontamination, de-sludging effect is improved
Material.Environment-friendly cleaning agent is for general cleaning agent, because the activating agent contained in cleaning agent and various
Auxiliary agent turns into environment-friendly cleaning agent because of biodegradable or environmental pollution very little, also known as environment-friendly cleaning agent.
Current each state all develops Environment protection cleaning technology in all one's effort, in the hope of reducing energy consumption, excess destruction of the choke suppress to environment.
In the U.S., each scientific research institution is especially focused on the research and development of green technology, and large quantities of high-tech enterprises release phase in nearly 2 years successively
New technology is closed, causes the world to be gazed at.China to this new technology at present also progressively drawing close, but also larger difference
Away from domestic user is mostly based on use foreign technology.
In the cleaning agent of prior art, n-Propyl Bromide is similar with trichloro ethylene due to its chemical constitution and physicochemical property,
With the equivalent cleaning force of same trichloro ethylene, (earth is warmed up for low ODP (ozone layer destroying index) values and low GWP in addition
Change effect) value, so being already widely used on Europe, Japan, the U.S. and other places.Its maximum technical barrier is
Pure n-Propyl Bromide is heated to tens degree of generations HBr (hydrobromic acid) that will decompose, and forms HBr acid so as to corrode work
Industry metal is due to American-European technology blockage and monopolization, and product sudden huge profits, domestic enterprise's existence is extremely difficult.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, low it is an object of the invention to provide a kind of ozone layer destroying index, the earth is warmed up
Change effect is low, and environment protecting is good, cleaning effect is high, and penetration is high, and micropore material also can easily be cleaned, speed is dried
Degree is fast, without flashing point, degree of hydrolysis be low, liquid phase change is stable, applicable what steam is cleaned and the advantages of Distillation recovery
Environment-friendly cleaning agent.
In order to achieve the above object, the technical solution used in the present invention is as follows：
A kind of environment-friendly cleaning agent, wherein, the environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 94%-95%；
Normal propyl alcohol 3%-4%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%.
Above-mentioned design of the invention, the environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 95%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%.
Above-mentioned design of the invention, the environment-friendly cleaning agent includes：
N-Propyl Bromide 94.885%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%；
BTA (BTA) 0.1%；
Triethanolamine 0.015%.
The beneficial effects of the present invention are：
1st, ozone layer destroying index is low (ODP=0.019-0.027), and global warming effect (GWP) is low, meets environmental requirement.
2nd, cleaning effect is high, and penetration is high, and micropore material can also be cleaned easily.
3rd, rate of drying is fast.
4th, without flashing point (flashpoint).
5th, degree of hydrolysis is low, even if the corrosivity of generation hydrobromic acid, also the hydrochloric acid than chlorinating agent is low.
6th, liquid phase change is stable, and applicable what steam is cleaned and Distillation recovery.
7th, toxicity data there is no toxicity control in SARA313.
8th, can be trichloro ethylene extensively using the cleaning method of the industries such as the various metals of what, electronics, accurate industry,
The ideal environmental protection substitute of the tradition ODS class cleaning agents such as trichloroethanes, boiling Lyons -113.
The range of application of environment-friendly cleaning agent of the invention is：1, various metal cleaner/degreasing agents, ultrasonic drilling machine cleaning
Substitute trichloro ethylene etc..2, precision cleaning.3, electronics industry cleaning scaling powder.4, surface is scrubbed and cold wash or steaming
Purposes.5, other greasy dirts or dirty clean, normal temperature or heating are cleaned, immersion or by hand scouring
Specific embodiment
In order to further illustrate principle of the invention and structure, now to a preferred embodiment of the present invention will be described in detail,
But the embodiment is only to provide explanation to be used with explanation, it is impossible to for limiting scope of patent protection of the invention.
Embodiment 1：
A kind of environment-friendly cleaning agent, wherein, the environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 94%-95%；
Normal propyl alcohol 3%-4%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%.
Embodiment：2：
A kind of environment-friendly cleaning agent, the environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 95%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%.
Embodiment 3：
A kind of environment-friendly cleaning agent, the environment-friendly cleaning agent includes：
N-Propyl Bromide 94.885%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT (2,6- di-tert-butyl-4-methy phenol) 0.3%；
BTA (BTA) 0.1%；
Triethanolamine 0.015%.
The physicochemical property of environment-friendly cleaning agent of the invention：
71 degree of boiling point, proportion 1.35, viscosity 0.49cps (25 degree), vapour pressure 110.8 (20 degree), specific heat 0.27 (25
Degree), latent heat 58.8cal/g, solubility 0.24g/100gh20, water-soluble 0.05g/100g solvents, surface
Power 25.9dyne/cm.20 degree, flash-point is without the limit (pure oxygen) 4-7.8% is burnt in burning.
The range of application of environment-friendly cleaning agent of the invention：
1st, various metal cleaner/degreasing agents, ultrasonic drilling machine cleaning substitutes trichloro ethylene etc..
2nd, precision cleaning.
3rd, electronics industry cleaning scaling powder.
4th, surface is scrubbed and cold wash or steaming purposes.
5th, other greasy dirts or dirty clean, normal temperature or heating cleaning, by hand immersion or scouring.
Principle of the invention and beneficial effect are：
1st, ozone layer destroying index is low (0DP=0.019-0.027), and global warming effect (GWP) is low, meets environmental requirement.
2nd, cleaning effect is high, and penetration is high, and micropore material can also be cleaned easily.
3rd, rate of drying is fast.
4th, without flashing point (flashpoint).
5th, degree of hydrolysis is low, even if the corrosivity of generation hydrobromic acid, also the hydrochloric acid than chlorinating agent is low.
6th, liquid phase change is stable, and applicable what steam is cleaned and Distillation recovery.
7th, toxicity data there is no toxicity control in SARA313.
8th, can be trichloro ethylene extensively using the cleaning method of the industries such as the various metals of what, electronics, accurate industry,
The ideal environmental protection substitute of the tradition ODS class cleaning agents such as trichloroethanes, boiling Lyons -113.
Disclosed content, is several for preferred embodiment, as long as partial alteration, change, or to this hair
The modification of bright disclosed technology contents, and come from technological thought of the invention and be not added with to be familiar with the people of this skill
Creative thinking is easy to what is deduced, does not all depart from patent right category of the invention.
Claims (3)
1. a kind of environment-friendly cleaning agent, it is characterised in that：
The environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 94%-95%；
Normal propyl alcohol 3%-4%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT0.3%.
2. a kind of environment-friendly cleaning agent as claimed in claim 1, it is characterised in that：
The environment-friendly cleaning agent includes：
Raw material by using gauge,
N-Propyl Bromide 95%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT0.3%.
3. a kind of environment-friendly cleaning agent as claimed in claim 1, it is characterised in that：
The environment-friendly cleaning agent includes：
N-Propyl Bromide 94.885%；
Normal propyl alcohol 3%；
Nitromethane 0.2%；
DOX 0.8%；
Epoxy butane 0.7%；
BHT0.3%；
BTA0.1%；
Triethanolamine 0.015%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511014307.8A CN106916652A (en) | 2015-12-28 | 2015-12-28 | Environment-friendly cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511014307.8A CN106916652A (en) | 2015-12-28 | 2015-12-28 | Environment-friendly cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106916652A true CN106916652A (en) | 2017-07-04 |
Family
ID=59456131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511014307.8A Pending CN106916652A (en) | 2015-12-28 | 2015-12-28 | Environment-friendly cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106916652A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674787A (en) * | 2017-11-28 | 2018-02-09 | 苏州锐耐洁电子科技新材料有限公司 | A kind of novel environment friendly cleaning agent |
| CN111088125A (en) * | 2019-12-31 | 2020-05-01 | 南京市检捷生物信息科技有限公司 | Cleaning agent for laboratory optical instrument and cleaning method thereof |
| CN112111340A (en) * | 2020-08-31 | 2020-12-22 | 山东旭锐新材有限公司 | Environment-friendly cleaning agent with low VOCs content |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101784650A (en) * | 2007-08-23 | 2010-07-21 | 纳幕尔杜邦公司 | The Azeotrope compositions that comprises fluorinated olefin that is used for cleaning applications |
| CN101982544A (en) * | 2010-11-04 | 2011-03-02 | 西北工业大学 | Electrical equipment cleaning agent and preparation method |
| CN102304443A (en) * | 2011-08-01 | 2012-01-04 | 合肥华清金属表面处理有限责任公司 | Environmental-protection low-sensitization low-toxicity industrial cleaning agent |
| CN102936542A (en) * | 2011-11-22 | 2013-02-20 | 东莞市洛加斯润滑油有限公司 | Environment-friendly cleaning agent |
-
2015
- 2015-12-28 CN CN201511014307.8A patent/CN106916652A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101784650A (en) * | 2007-08-23 | 2010-07-21 | 纳幕尔杜邦公司 | The Azeotrope compositions that comprises fluorinated olefin that is used for cleaning applications |
| CN101982544A (en) * | 2010-11-04 | 2011-03-02 | 西北工业大学 | Electrical equipment cleaning agent and preparation method |
| CN102304443A (en) * | 2011-08-01 | 2012-01-04 | 合肥华清金属表面处理有限责任公司 | Environmental-protection low-sensitization low-toxicity industrial cleaning agent |
| CN102936542A (en) * | 2011-11-22 | 2013-02-20 | 东莞市洛加斯润滑油有限公司 | Environment-friendly cleaning agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674787A (en) * | 2017-11-28 | 2018-02-09 | 苏州锐耐洁电子科技新材料有限公司 | A kind of novel environment friendly cleaning agent |
| CN111088125A (en) * | 2019-12-31 | 2020-05-01 | 南京市检捷生物信息科技有限公司 | Cleaning agent for laboratory optical instrument and cleaning method thereof |
| CN112111340A (en) * | 2020-08-31 | 2020-12-22 | 山东旭锐新材有限公司 | Environment-friendly cleaning agent with low VOCs content |
| CN112111340B (en) * | 2020-08-31 | 2021-10-01 | 山东旭锐新材有限公司 | Environment-friendly cleaning agent with low VOCs content |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170704 |
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| WD01 | Invention patent application deemed withdrawn after publication |