CN106916348A - A kind of wear-resisting high-strength degree slipper sole and its production technology and application - Google Patents

A kind of wear-resisting high-strength degree slipper sole and its production technology and application Download PDF

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Publication number
CN106916348A
CN106916348A CN201710236587.XA CN201710236587A CN106916348A CN 106916348 A CN106916348 A CN 106916348A CN 201710236587 A CN201710236587 A CN 201710236587A CN 106916348 A CN106916348 A CN 106916348A
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parts
wear
slipper sole
resisting high
strength degree
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吴国顺
吴体芳
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Deyi Cultural And Creative Group Co Ltd
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Deyi Cultural And Creative Group Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00—Characterised by the use of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2407/00—Characterised by the use of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
    • C08J2423/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention discloses a kind of wear-resisting high-strength degree slipper sole and its production technology and application, it is used as main material by using rubber, being aided with LLDPE and polyvinyl chloride carries out performance and is combined, being also added into anti-wear agent improve the anti-wear performance of product, so that final products have under the premise of favorable elasticity also with excellent anti-wear performance, double-purpose is carried out as reinforcing agent using white carbon and carbon black so that the strength character of final products is further improved, N cyclohexylthiophthalimides are also added into addition, azodicarbonamide, dioctyl phthalate, acetyl tributyl citrate, the auxiliary addition agents such as zinc oxide are adjusted formula, make it more preferable in processing characteristics, improve the yield and stability of finished product.

Description

A kind of wear-resisting high-strength degree slipper sole and its production technology and application
Technical field
The present invention relates to slipper sole field, especially a kind of wear-resisting high-strength degree slipper sole and its production technology and should With.
Background technology
Slippers as one of shoes indispensable in daily life, the increasingly pursuit with consumer to quality of the life, Requirement for the durability and snugness of fit of slippers also becomes more and more higher, because traditional plastic sandals is generally straight plastics Tap into row compression molding, and it is easily occurring areal deformation, tear and problem easy to wear using process so that slippers make Substantially reduced with life-span and comfort, and slippers are yielding so that when its surface is easily put aside dirt and causes to wear one section Between after easily there is the smelly situation in surface, the serious situation that can also make wearer the fungal infections such as tinea pedis occur.
Due to most slippers sole for plastics or rubber carry out it is hot-forming, and it is hot-forming during due to The mobile performance of raw material is different, and it easily produces internal stress when being molded moulding, once sole weares and teares in use Or partial fracture, then it is unbalance and trigger the further tear of damaged part just to easily lead to internal stress, so as to accelerate slippers Service life termination.
The content of the invention
In view of the shortcomings of the prior art, there is high-wearing feature, high intensity and production it is an object of the invention to provide one kind The wear-resisting high-strength degree slipper sole and its production technology of process is simple and application.
In order to realize above-mentioned technical purpose, the technical scheme is that：
A kind of wear-resisting high-strength degree slipper sole, it is made up of the component of following weight portion：
40~55 parts of rubber；
5~10 parts of LLDPE；
4~8 parts of polyvinyl chloride；
2~4 parts of N, N'- DTPD di tolyl p phenylenediamine；
2~4 parts of N- cyclohexylthiophthalimides；
1~3 part of azodicarbonamide；
0.5~1.5 part of dioctyl phthalate；
0.5~1.5 part of acetyl tributyl citrate；
1~1.5 part of zinc oxide；
3~6 parts of anti-wear agent；
1~1.5 part of lubricant；
0.5~1.5 part of crosslinking agent；
1~3 part of white carbon；
1~3 part of carbon black；
2~4 parts of Masterbatch.
Further, described rubber is at least one of natural rubber, butadiene rubber, isoprene rubber, brombutyl Mix.
Further, described anti-wear agent is double-[3- (triethoxysilicane) propyl group]-tetrasulfide.
Further, described crosslinking agent is polymethyl siloxane or titanate coupling agent.
Further, described lubricant is N, N'- ethylene bis stearamides.
Further, the granularity of described white carbon and carbon black is nanoscale.
Preferably, it is made up of the component of following weight portion：
45 parts of rubber；
7 parts of LLDPE；
6 parts of polyvinyl chloride；
3 parts of N, N'- DTPD di tolyl p phenylenediamine；
3 parts of N- cyclohexylthiophthalimides；
2 parts of azodicarbonamide；
1 part of dioctyl phthalate；
1 part of acetyl tributyl citrate；
1.3 parts of zinc oxide；
4 parts of anti-wear agent；
1.2 parts of lubricant；
1 part of crosslinking agent；
2 parts of white carbon；
2 parts of carbon black；
3 parts of Masterbatch.
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）Rubber, LLDPE, polyvinyl chloride, N, N'- DTPD di tolyl p phenylenediamines, N- hexamethylenes are weighed by metering Base thiophthalimide, azodicarbonamide, dioctyl phthalate, acetyl tributyl citrate, oxidation Zinc, anti-wear agent, lubricant, crosslinking agent, white carbon, carbon black, and it is sequentially added in mixer with 80~100 DEG C of temperature It is stirred 15~30min of mixing；
（2）The mixed material of above-mentioned stirring and Masterbatch are added in banbury in the lump, and with 120~140 DEG C of temperature 30~40min of banburying is carried out, the mixture after banburying is added in comminutor again then, entered at a temperature of 125~145 DEG C Row granulation is obtained master batch of the particle size in 2~4mm；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus answered, and indent storing apparatus are placed in baking oven, with 70~90 DEG C of temperature carry out heated at constant temperature 2~ 3h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Further, described described indent storing apparatus are metal material or ceramic material.
A kind of wear-resisting high-strength degree slippers, it includes wear-resisting high-strength degree slipper sole described above.
Using above-mentioned technical scheme, beneficial effects of the present invention are：It is used as main material by using rubber, is aided with linear low Density polyethylene and polyvinyl chloride carry out performance and are combined, and being also added into anti-wear agent improve the anti-wear performance of product so that most Finished product has under the premise of favorable elasticity also with excellent anti-wear performance, and double-purpose is carried out as benefit using white carbon and carbon black Strong agent causes that the strength character of final products is further improved, be also added into addition N- cyclohexylthiophthalimides, The auxiliary addition agents such as azodicarbonamide, dioctyl phthalate, acetyl tributyl citrate, zinc oxide are adjusted matching somebody with somebody Side, makes it more preferable in processing characteristics, improves the yield and stability of finished product.
Specific embodiment
A kind of wear-resisting high-strength degree slipper sole, it is made up of the component of following weight portion：
40~55 parts of rubber；
5~10 parts of LLDPE；
4~8 parts of polyvinyl chloride；
2~4 parts of N, N'- DTPD di tolyl p phenylenediamine；
2~4 parts of N- cyclohexylthiophthalimides；
1~3 part of azodicarbonamide；
0.5~1.5 part of dioctyl phthalate；
0.5~1.5 part of acetyl tributyl citrate；
1~1.5 part of zinc oxide；
3~6 parts of anti-wear agent；
1~1.5 part of lubricant；
0.5~1.5 part of crosslinking agent；
1~3 part of white carbon；
1~3 part of carbon black；
2~4 parts of Masterbatch.
Further, described rubber is at least one of natural rubber, butadiene rubber, isoprene rubber, brombutyl Mix.
Further, described anti-wear agent is double-[3- (triethoxysilicane) propyl group]-tetrasulfide.
Further, described crosslinking agent is polymethyl siloxane or titanate coupling agent.
Further, described lubricant is N, N'- ethylene bis stearamides.
Further, the granularity of described white carbon and carbon black is nanoscale.
Preferably, it is made up of the component of following weight portion：
45 parts of rubber；
7 parts of LLDPE；
6 parts of polyvinyl chloride；
3 parts of N, N'- DTPD di tolyl p phenylenediamine；
3 parts of N- cyclohexylthiophthalimides；
2 parts of azodicarbonamide；
1 part of dioctyl phthalate；
1 part of acetyl tributyl citrate；
1.3 parts of zinc oxide；
4 parts of anti-wear agent；
1.2 parts of lubricant；
1 part of crosslinking agent；
2 parts of white carbon；
2 parts of carbon black；
3 parts of Masterbatch.
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）Rubber, LLDPE, polyvinyl chloride, N, N'- DTPD di tolyl p phenylenediamines, N- hexamethylenes are weighed by metering Base thiophthalimide, azodicarbonamide, dioctyl phthalate, acetyl tributyl citrate, oxidation Zinc, anti-wear agent, lubricant, crosslinking agent, white carbon, carbon black, and it is sequentially added in mixer with 80~100 DEG C of temperature It is stirred 15~30min of mixing；
（2）The mixed material of above-mentioned stirring and Masterbatch are added in banbury in the lump, and with 120~140 DEG C of temperature 30~40min of banburying is carried out, the mixture after banburying is added in comminutor again then, entered at a temperature of 125~145 DEG C Row granulation is obtained master batch of the particle size in 2~4mm；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus answered, and indent storing apparatus are placed in baking oven, with 70~90 DEG C of temperature carry out heated at constant temperature 2~ 3h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Further, described described indent storing apparatus are metal material or ceramic material.
A kind of wear-resisting high-strength degree slippers, it includes wear-resisting high-strength degree slipper sole described above.
Embodiment 1
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）20 parts of natural rubbers, 20 parts of butadiene rubbers, 5 parts of LLDPEs, 4 parts of polyvinyl chloride, 2 are weighed by metering Part N, N'- DTPD di tolyl p phenylenediamines, 2 parts of N- cyclohexylthiophthalimides, 1 part of azodicarbonamide, 0.5 part of neighbour Dioctyl phthalate, 0.5 part of acetyl tributyl citrate, 1 part of zinc oxide, 3 parts of double-[3- (triethoxysilicane) third Base]-tetrasulfide, 1 part of N, N'- ethylene bis stearamides, 0.5 part of titanate coupling agent, 1 part of nano-scale white carbon black, 1 part of nanometer Level carbon black, and it is sequentially added in mixer with 90 DEG C of temperature be stirred mixing 20min；
（2）The mixed material of above-mentioned stirring and 2 parts of Masterbatch are added in banbury in the lump, and are entered with 130 DEG C of temperature , be added to the mixture after banburying in comminutor again then by row banburying 35min, is granulated at a temperature of 125~130 DEG C Master batch of the particle size in 2~4mm is obtained；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus of the ceramic material answered, and indent storing apparatus are placed in baking oven, constant temperature is carried out with 80 DEG C of temperature Heating 2.5h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Performance test
Slipper sole obtained above is carried out to be cut into the test bars that specification is 8cmX2cmX1.5cm, and to its progressive Can test, acquired results are：Shore hardness：52nd, tensile strength：2.3Mpa, elongation at break 240%, rebound degree：45%.
Embodiment 2
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）By metering weigh 25 parts of natural rubbers, 20 parts of isoprene rubbers, 7 parts of LLDPEs, 5 parts of polyvinyl chloride, 2.8 parts of N, N'- DTPD di tolyl p phenylenediamines, 3 parts of N- cyclohexylthiophthalimides, 1.8 parts of azodicarbonamides, 1 Part dioctyl phthalate, 1 part of acetyl tributyl citrate, 1.2 parts of zinc oxide, 4 parts of double-[3- (triethoxysilicane) Propyl group]-tetrasulfide, 1.2 parts of N, N'- ethylene bis stearamides, 0.8 part of titanate coupling agent, 1.5 parts of nano-scale white carbon blacks, 1.5 parts of nanoscale carbon blacks, and it is sequentially added in mixer with 80 DEG C of temperature be stirred mixing 30min；
（2）The mixed material of above-mentioned stirring and 2.5 parts of Masterbatch are added in banbury in the lump, and with 120 DEG C of temperature Banburying 40min is carried out, the mixture after banburying is added in comminutor again then, made at a temperature of 130~135 DEG C Master batch of the prepared particle size of grain in 2~4mm；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus of the ceramic material answered, and indent storing apparatus are placed in baking oven, constant temperature is carried out with 70 DEG C of temperature Heating 3h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Performance test
Slipper sole obtained above is carried out to be cut into the test bars that specification is 8cmX2cmX1.5cm, and to its progressive Can test, acquired results are：Shore hardness：51st, tensile strength：2.6Mpa, elongation at break 280%, rebound degree：51%.
Embodiment 3
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）By metering weigh 25 parts of natural rubbers, 20 parts of bromobutyls, 7 parts of LLDPEs, 6 parts of polyvinyl chloride, 3 parts of N, N'- DTPD di tolyl p phenylenediamines, 3 parts of N- cyclohexylthiophthalimides, 2 parts of azodicarbonamides, 1 part of neighbour Dioctyl phthalate, 1 part of acetyl tributyl citrate, 1.3 parts of zinc oxide, 4 parts of double-[3- (triethoxysilicane) third Base]-tetrasulfide, 1.2 parts of N, N'- ethylene bis stearamides, 1 part of titanate coupling agent, 2 parts of nano-scale white carbon blacks, 2 parts of nanometers Level carbon black, and it is sequentially added in mixer with 90 DEG C of temperature be stirred mixing 25min；
（2）The mixed material of above-mentioned stirring and 3 parts of Masterbatch are added in banbury in the lump, and are entered with 140 DEG C of temperature , be added to the mixture after banburying in comminutor again then by row banburying 30min, is granulated at a temperature of 135~145 DEG C Master batch of the particle size in 2~4mm is obtained；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus of the ceramic material answered, and indent storing apparatus are placed in baking oven, constant temperature is carried out with 90 DEG C of temperature Heating 2h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Performance test
Slipper sole obtained above is carried out to be cut into the test bars that specification is 8cmX2cmX1.5cm, and to its progressive Can test, acquired results are：Shore hardness：49th, tensile strength：2.4Mpa, elongation at break 264%, rebound degree：48%.
Embodiment 4
A kind of production technology of wear-resisting high-strength degree slipper sole, it comprises the following steps：
（1）55 parts of natural rubbers, 10 parts of LLDPEs, 8 parts of polyvinyl chloride, 4 parts of N, N'- dimethylbenzene are weighed by metering Base p-phenylenediamine, 4 parts of N- cyclohexylthiophthalimides, 3 parts of azodicarbonamides, 1.5 parts of phthalic acids two are pungent Ester, 1.5 parts of acetyl tributyl citrates, 1.5 parts of zinc oxide, 6 parts of double-[3- (triethoxysilicane) propyl group]-tetrasulfides, 1.5 parts of N, N'- ethylene bis stearamides, 1.5 parts of polymethyl siloxanes, 3 parts of nano-scale white carbon blacks, 3 parts of nanoscale carbon blacks, and will It is sequentially added in mixer and is stirred mixing 15min with 100 DEG C of temperature；
（2）The mixed material of above-mentioned stirring and 4 parts of Masterbatch are added in banbury in the lump, and are entered with 120 DEG C of temperature , be added to the mixture after banburying in comminutor again then by row banburying 40min, is granulated at a temperature of 130~140 DEG C Master batch of the particle size in 2~4mm is obtained；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus of the metal material answered, and indent storing apparatus are placed in baking oven, constant temperature is carried out with 80 DEG C of temperature Heating 2.5h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
Performance test
Slipper sole obtained above is carried out to be cut into the test bars that specification is 8cmX2cmX1.5cm, and to its progressive Can test, acquired results are：Shore hardness：47th, tensile strength：2.3Mpa, elongation at break 240%, rebound degree：51%.
The above is embodiments of the invention, for the ordinary skill in the art, religion of the invention Lead, without departing from the principles and spirit of the present invention all impartial changes done according to scope of the present invention patent, repair Change, replace and modification, should all belong to covering scope of the invention.

Claims (10)

1. a kind of wear-resisting high-strength degree slipper sole, it is characterised in that：It is made up of the component of following weight portion：
40~55 parts of rubber；
5~10 parts of LLDPE；
4~8 parts of polyvinyl chloride；
2~4 parts of N, N'- DTPD di tolyl p phenylenediamine；
2~4 parts of N- cyclohexylthiophthalimides；
1~3 part of azodicarbonamide；
0.5~1.5 part of dioctyl phthalate；
0.5~1.5 part of acetyl tributyl citrate；
1~1.5 part of zinc oxide；
3~6 parts of anti-wear agent；
1~1.5 part of lubricant；
0.5~1.5 part of crosslinking agent；
1~3 part of white carbon；
1~3 part of carbon black；
2~4 parts of Masterbatch.
2. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Described rubber is natural rubber At least one of glue, butadiene rubber, isoprene rubber, brombutyl are mixed.
3. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Described anti-wear agent for it is double- [3- (triethoxysilicane) propyl group]-tetrasulfide.
4. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Described crosslinking agent is poly- first Radical siloxane or titanate coupling agent.
5. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Described lubricant is N, N'- ethylene bis stearamides.
6. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Described white carbon and carbon black Granularity be nanoscale.
7. a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：Its by following weight portion group It is grouped into：
45 parts of rubber；
7 parts of LLDPE；
6 parts of polyvinyl chloride；
3 parts of N, N'- DTPD di tolyl p phenylenediamine；
3 parts of N- cyclohexylthiophthalimides；
2 parts of azodicarbonamide；
1 part of dioctyl phthalate；
1 part of acetyl tributyl citrate；
1.3 parts of zinc oxide；
4 parts of anti-wear agent；
1.2 parts of lubricant；
1 part of crosslinking agent；
2 parts of white carbon；
2 parts of carbon black；
3 parts of Masterbatch.
8. the production technology of a kind of wear-resisting high-strength degree slipper sole according to claim 1, it is characterised in that：It is included such as Lower step：
（1）Rubber, LLDPE, polyvinyl chloride, N, N'- DTPD di tolyl p phenylenediamines, N- hexamethylenes are weighed by metering Base thiophthalimide, azodicarbonamide, dioctyl phthalate, acetyl tributyl citrate, oxidation Zinc, anti-wear agent, lubricant, crosslinking agent, white carbon, carbon black, and it is sequentially added in mixer with 80~100 DEG C of temperature It is stirred 15~30min of mixing；
（2）The mixed material of above-mentioned stirring and Masterbatch are added in banbury in the lump, and with 120~140 DEG C of temperature 30~40min of banburying is carried out, the mixture after banburying is added in comminutor again then, entered at a temperature of 125~145 DEG C Row granulation is obtained master batch of the particle size in 2~4mm；
（3）Master batch obtained above is added to carries out the idiosome that pressing mold is molded into slipper sole in molding press；
（4）After the idiosome of slipper sole obtained above is carried out into deburring, place it in structure and mutually fitted with slipper sole structure In the indent storing apparatus answered, and indent storing apparatus are placed in baking oven, with 70~90 DEG C of temperature carry out heated at constant temperature 2~ 3h, after then being naturally cooled to room temperature again, you can required wear-resisting high-strength degree slipper sole is obtained.
9. the production technology of a kind of wear-resisting high-strength degree slipper sole according to claim 8, it is characterised in that：Described is interior Recessed storing apparatus are metal material or ceramic material.
10. a kind of wear-resisting high-strength degree slippers, it is characterised in that：It includes that the wear-resisting high-strength degree described in any of the above-described claim is dragged Footwear sole.
CN201710236587.XA 2017-04-12 2017-04-12 A kind of wear-resisting high-strength degree slipper sole and its production technology and application Pending CN106916348A (en)

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