CN106906639A - Cotton fabric waterproofing refuses oil corrugation finishing agent - Google Patents

Cotton fabric waterproofing refuses oil corrugation finishing agent Download PDF

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Publication number
CN106906639A
CN106906639A CN201610521848.8A CN201610521848A CN106906639A CN 106906639 A CN106906639 A CN 106906639A CN 201610521848 A CN201610521848 A CN 201610521848A CN 106906639 A CN106906639 A CN 106906639A
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China
Prior art keywords
parts
finishing agent
corrugation
cotton fabric
oil
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Pending
Application number
CN201610521848.8A
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Chinese (zh)
Inventor
陆亚洲
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Individual
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Individual
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Publication date
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Priority to CN201610521848.8A priority Critical patent/CN106906639A/en
Publication of CN106906639A publication Critical patent/CN106906639A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/47Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65Salts of oxyacids of nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/355Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358Triazines
    • D06M13/364Cyanuric acid; Isocyanuric acid; Derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01Stain or soil resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/11Oleophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45Shrinking resistance, anti-felting properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses cotton fabric waterproofing refuse oil corrugation finishing agent, including following weight portion component, 100~160 parts of dimethylol urea, 40~60 parts of magnesium chloride hexahydrate, 100~160 parts of aluminum sulfate, 80~100 parts of trimethylol melamine, 20~30 parts of lauryl methacrylate, 20~30 parts of zinc nitrate hexahydrate, 40~60 parts of poly- isobutyl ester, 20~40 parts of aluminium hydroxide, 12~24 parts of phosphotriester, 12~18 parts of antimony oxide, 10~20 parts of benzoyl peroxide, 600~800 parts of deionized water.The cotton fabric waterproofing that the present invention is provided refuses oil corrugation finishing agent, makes simple, and the raw materials for production selection of use is avirulent, the fabric processed with this finishing agent can crease and shrink resistance, fixed effect is good, exempts from flatiron, with it is well-pressed, plentiful, not dirty the features such as.

Description

Cotton fabric waterproofing refuses oil corrugation finishing agent
Technical field
The present invention relates to a kind of finishing agent technical field, and in particular to a kind of cotton fabric waterproofing refuses oil corrugation finishing agent.
Background technology
In recent years, with the improvement of people ' s living standards, under working environment with water repellent, refuse oil, soil-repellent finishing clothes need The amount of asking constantly increases, the fabric treated using finishing agent, can protect the user against splashing for water, oil, chemicals and pollutant Infringement is echoed, with protective, can be used for protective garments or work clothes etc. under the working environment of making high-quality, by people Attention and have a good application prospect;The finishing agent function of using at present is relatively simple, and using effect is poor, it is necessary to enter The improvement of one step, simple finishing agent can not meet the required of people.
The content of the invention
Oil corrugation finishing agent is refused it is an object of the invention to provide cotton fabric waterproofing, in above-mentioned prior art problem is solved Or it is multiple.
According to an aspect of the present invention, cotton fabric waterproofing refuse oil corrugation finishing agent, including following weight portion component:
100~160 parts of dimethylol urea, 40~60 parts of magnesium chloride hexahydrate, 100~160 parts of aluminum sulfate, trihydroxy methyl trimerization 80~100 parts of cyanamide, 20~30 parts of lauryl methacrylate, 20~30 parts of zinc nitrate hexahydrate, 40~60 parts of poly- isobutyl ester, hydrogen 20~40 parts of aluminum oxide, 12~24 parts of phosphotriester, 12~18 parts of antimony oxide, 10~20 parts of benzoyl peroxide, go from 600~800 parts of sub- water.
The cotton fabric waterproofing that the present invention is provided refuses oil corrugation finishing agent, makes simple, and the raw materials for production selection of use is nontoxic Property, the fabric processed with this finishing agent can crease and shrink resistance, fixed effect is good, exempts from flatiron, with Water-proof and oil-proof, well-pressed, rich Full, not dirty the features such as.
Specific embodiment
Embodiment 1
By 100 parts of dimethylol urea, 40 parts of magnesium chloride hexahydrate, 100 parts of aluminum sulfate, 80 parts of trimethylol melamine, first 20 parts of base lauryl acrylate, 20 parts of zinc nitrate hexahydrate, 40 parts of poly- isobutyl ester, 20 parts of aluminium hydroxide, 12 parts of phosphotriester, three oxygen Change 12 parts of two antimony, 10 parts of benzoyl peroxide, 600 parts of deionized water is put into reactor, is stirred continuously, heating after mixing completely To 60 DEG C, product is obtained final product after uniform stirring.
Embodiment 2
By 130 parts of dimethylol urea, 50 parts of magnesium chloride hexahydrate, 130 parts of aluminum sulfate, 90 parts of trimethylol melamine, first 25 parts of base lauryl acrylate, 25 parts of zinc nitrate hexahydrate, 50 parts of poly- isobutyl ester, 30 parts of aluminium hydroxide, 18 parts of phosphotriester, three oxygen Change 15 parts of two antimony, 15 parts of benzoyl peroxide, 700 parts of deionized water is put into reactor, is stirred continuously, heating after mixing completely To 60 DEG C, product is obtained final product after uniform stirring.
Embodiment 3
By 160 parts of dimethylol urea, 60 parts of magnesium chloride hexahydrate, 160 parts of aluminum sulfate, 100 parts of trimethylol melamine, first 30 parts of base lauryl acrylate, 30 parts of zinc nitrate hexahydrate, 60 parts of poly- isobutyl ester, 40 parts of aluminium hydroxide, 24 parts of phosphotriester, three oxygen Change 18 parts of two antimony, 20 parts of benzoyl peroxide, 800 parts of deionized water is put into reactor, is stirred continuously, heating after mixing completely To 60 DEG C, product is obtained final product after uniform stirring.
The above is only preferred embodiment of the invention, it is noted that to those skilled in the art, not On the premise of departing from the invention design, some similar deformations and improvement can also be made, these also should be regarded as the present invention Protection domain within.

Claims (1)

1. cotton fabric waterproofing refuses oil corrugation finishing agent, it is characterised in that:Component including following weight portion:
100~160 parts of dimethylol urea, 40~60 parts of magnesium chloride hexahydrate, 100~160 parts of aluminum sulfate, trimethylol melamine 80~100 parts, 20~30 parts of lauryl methacrylate, 20~30 parts of zinc nitrate hexahydrate, 40~60 parts of poly- isobutyl ester, hydroxide 20~40 parts of aluminium, 12~24 parts of phosphotriester, 12~18 parts of antimony oxide, 10~20 parts of benzoyl peroxide, deionized water 600~800 parts.
CN201610521848.8A 2016-07-01 2016-07-01 Cotton fabric waterproofing refuses oil corrugation finishing agent Pending CN106906639A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610521848.8A CN106906639A (en) 2016-07-01 2016-07-01 Cotton fabric waterproofing refuses oil corrugation finishing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610521848.8A CN106906639A (en) 2016-07-01 2016-07-01 Cotton fabric waterproofing refuses oil corrugation finishing agent

Publications (1)

Publication Number Publication Date
CN106906639A true CN106906639A (en) 2017-06-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610521848.8A Pending CN106906639A (en) 2016-07-01 2016-07-01 Cotton fabric waterproofing refuses oil corrugation finishing agent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486865A (en) * 2018-04-04 2018-09-04 安徽恒益纺织科技有限公司 A kind of inorganic agent slowing down the shrink of pure cotton clothes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1556274A (en) * 2003-12-30 2004-12-22 浙江恒逸集团有限公司 Cotton viscose fabric phosphorus silicon synergistic effect fire retarding treating liquid
CN102011305A (en) * 2009-09-08 2011-04-13 沙亚泉 Cotton fabric shrink-proof and wrinkle-proof finishing agent
CN102549212A (en) * 2009-09-26 2012-07-04 亨茨曼纺织货品(德国)有限责任公司 Composition for oil- and/or water-repellent finishing of fiber materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1556274A (en) * 2003-12-30 2004-12-22 浙江恒逸集团有限公司 Cotton viscose fabric phosphorus silicon synergistic effect fire retarding treating liquid
CN102011305A (en) * 2009-09-08 2011-04-13 沙亚泉 Cotton fabric shrink-proof and wrinkle-proof finishing agent
CN102549212A (en) * 2009-09-26 2012-07-04 亨茨曼纺织货品(德国)有限责任公司 Composition for oil- and/or water-repellent finishing of fiber materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486865A (en) * 2018-04-04 2018-09-04 安徽恒益纺织科技有限公司 A kind of inorganic agent slowing down the shrink of pure cotton clothes

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