CN106905663A - A kind of cable material and preparation method thereof - Google Patents

A kind of cable material and preparation method thereof Download PDF

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Publication number
CN106905663A
CN106905663A CN201710181069.2A CN201710181069A CN106905663A CN 106905663 A CN106905663 A CN 106905663A CN 201710181069 A CN201710181069 A CN 201710181069A CN 106905663 A CN106905663 A CN 106905663A
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China
Prior art keywords
parts
cable material
epoxy resin
halogen
cable
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CN201710181069.2A
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Chinese (zh)
Inventor
武行峰
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Hefei Yizhen Electric Power Equipment Co Ltd
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Hefei Yizhen Electric Power Equipment Co Ltd
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Priority to CN201710181069.2A priority Critical patent/CN106905663A/en
Publication of CN106905663A publication Critical patent/CN106905663A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention discloses a kind of cable material, including following weight portion component:20~30 parts of epoxy resin, 15~20 parts of vistanex, 15~35 parts of glass fibre, 5~8 parts of ceramic Firebrake ZB, 15~35 parts of halogen-free expansion fire retardant, 3~7 parts of compatilizer, 0.1~0.2 part of anti-dripping agent, 4~7 parts of silicone oil, 2~3 parts of lubricant, 0.5~2 part of antioxidant, 1~2 part of antiseptic, the each component is that can obtain the cable material by techniques such as kneading, extruding pelletization, dryings, the cable material has good anti-flammability and fire resistance, and excellent moisture resistance and water absorption resistance.

Description

A kind of cable material and preparation method thereof
Technical field
The invention belongs to field of cable technology, and in particular to a kind of cable material and preparation method thereof.
Background technology
Existing domestic and international fire-resisting cable mainly has magnesium oxide mineral insulated fireproof cable and Mica tape inorganic insulation Fire-resisting cable.Though mineral insulated cable has good fire resistance, its manufacturing process is complicated, production cost is high, Factory length is limited, and cable is stone cannot bend, and joint is complicated, and difficulty of construction is very high, it is difficult to extensive use.Mica tape Although wrapped fire-resisting cable work process is simple, factory length is unrestricted, one shortcoming of mica tape generally existing, high temperature combustion The mechanical strength of mica tape is greatly lowered after burning, becomes fragile, and by easy powder of detached after strenuous vibration, causes fire resisting effect not It is good.And because of easy dry linting when mica tape rubs, cause wrapped live a large amount of dust to the health care belt of operating personnel to threaten.In recent years To there is scientific research personnel's exploratory development ceramic silicon rubber insulating flame-resistant cable, but because needing special mixing in cable making process Refine, extrude and vulcanizing equipment, complex process, and be difficult to obtain balance, ceramic journey between isolation layer intensity and fire resistance Degree is difficult to be tested by the resistance to extreme misery of fire-resisting cable.
The content of the invention
The invention provides a kind of cable material and preparation method thereof, the cable material has good anti-flammability and fire resisting Property, and excellent moisture resistance and water absorption resistance.
In order to solve the problems, such as prior art, adopt the following technical scheme that:
A kind of cable material, including following weight portion component:20~30 parts of epoxy resin, 15~20 parts of vistanex, glass 15~35 parts of glass fiber, 5~8 parts of ceramic Firebrake ZB, 15~35 parts of halogen-free expansion fire retardant, 3~7 parts of compatilizer, anti-drop Fall 0.1~0.2 part of agent, 4~7 parts of silicone oil, 2~3 parts of lubricant, 0.5~2 part of antioxidant, 1~2 part of antiseptic.
Preferably, the cable material, including following weight portion component:24~27 parts of epoxy resin, vistanex 17~19 parts, 25~30 parts of glass fibre, 6~7 parts of ceramic Firebrake ZB, 24~27 parts of halogen-free expansion fire retardant, compatilizer 3 ~5 parts, 0.1~0.2 part of anti-dripping agent, 5~6 parts of silicone oil, 2~3 parts of lubricant, 0.5~1 part of antioxidant, 1~2 part of antiseptic.
Preferably, the cable material, including following weight portion component:25 parts of epoxy resin, 18 parts of vistanex, 27 parts of glass fibre, 6 parts of ceramic Firebrake ZB, 26 parts of halogen-free expansion fire retardant, 4 parts of compatilizer, 0.1 part of anti-dripping agent, silicon 5 parts of oil, 2 parts of lubricant, 0.6 part of antioxidant, 1.2 parts of antiseptic.
Preferably, the epoxy resin is modified epoxy.
Preferably, the preparation method of the modified epoxy is as follows:25~37 parts of epoxy resin are added by weight In 100 parts of toluene, 17 parts of bromoacetic acids are stirring evenly and then adding into, 100 parts of methyl alcohol are added after 15~20h of reaction is stirred at room temperature In, through precipitating, filtering, be dried to obtain material A;By weight by 13 parts of material As 45 parts of toluene of addition, it is stirring evenly and then adding into 40 parts of triphenylphosphines, are stirred at room temperature concentration of reaction solution after 33~37h, are subsequently adding in 100 parts of petroleum ethers, through precipitation, mistake Filter, be dried to obtain the modified epoxy.
Preferably, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 65~85 DEG C, Smelting time is 30~50 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization;
(3)Hot wind flow during the material for completing is put into 80~85 DEG C of environment will be granulated to dry 2~3 hours, you can obtain the electricity Cable material.
Preferably, the temperature range of the extruding and pelletizing process is 100~140 DEG C.
Compared with prior art, it has the advantages that the present invention:
Cable material of the present invention, with good flexibility and elasticity, and excellent moisture resistance and water absorption resistance, burning The material of ceramic-like afterwards, forms continuous using ceramic Firebrake ZB at high temperature in hard, uniform cellular housing Glass ceramics tunic, such object has excellent insulating properties, thermal insulation, fire insulation fire resistance, while can also withstand shocks And vibrations, and the infiltration for preventing water;While the antiseptic by adding proper ratio so that the cable material of preparation both had Antimycotic effect, while influenceing the performance of original cable material without the addition because of antiseptic;The present invention with the addition of and change Property epoxy resin, coordinate with vistanex, glass fibre and improve the insulating properties of cable material.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of cable material, including following weight portion component:20 parts of epoxy resin, vistanex 15 Part, 15 parts of glass fibre, 5 parts of ceramic Firebrake ZB, 15 parts of halogen-free expansion fire retardant, 3 parts of compatilizer, 0.1 part of anti-dripping agent, 4 parts of silicone oil, 2 parts of lubricant, 0.5 part of antioxidant, 1 part of antiseptic.
Wherein, the epoxy resin is modified epoxy, and the preparation method of the modified epoxy is as follows:By weight Part adds 25 parts of epoxy resin in 100 parts of toluene, is stirring evenly and then adding into 17 parts of bromoacetic acids, and reaction 15h is stirred at room temperature Afterwards in 100 parts of methyl alcohol of addition, through precipitating, filtering, be dried to obtain material A;13 parts of material As are added into 45 parts of toluene by weight In, 40 parts of triphenylphosphines are stirring evenly and then adding into, concentration of reaction solution after 33h is stirred at room temperature, it is subsequently adding 100 parts of petroleum ethers In, through precipitating, filtering, being dried to obtain the modified epoxy.
Wherein, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 65 DEG C, melting Time is 30 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization, temperature is 100 DEG C;
(3)Hot wind flow during the material for completing is put into 80 DEG C of environment will be granulated to dry 2 hours, you can obtain the cable material.
Embodiment 2
The present embodiment is related to a kind of cable material, including following weight portion component:30 parts of epoxy resin, vistanex 20 Part, 35 parts of glass fibre, 8 parts of ceramic Firebrake ZB, 35 parts of halogen-free expansion fire retardant, 7 parts of compatilizer, 0.2 part of anti-dripping agent, 7 parts of silicone oil, 3 parts of lubricant, 2 parts of antioxidant, 2 parts of antiseptic.
Wherein, the epoxy resin is modified epoxy, and the preparation method of the modified epoxy is as follows:By weight Part adds 37 parts of epoxy resin in 100 parts of toluene, is stirring evenly and then adding into 17 parts of bromoacetic acids, and reaction 20h is stirred at room temperature Afterwards in 100 parts of methyl alcohol of addition, through precipitating, filtering, be dried to obtain material A;13 parts of material As are added into 45 parts of toluene by weight In, 40 parts of triphenylphosphines are stirring evenly and then adding into, concentration of reaction solution after 37h is stirred at room temperature, it is subsequently adding 100 parts of petroleum ethers In, through precipitating, filtering, being dried to obtain the modified epoxy.
Wherein, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 85 DEG C, melting Time is 50 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization, temperature is 140 DEG C;
(3)Hot wind flow during the material for completing is put into 85 DEG C of environment will be granulated to dry 3 hours, you can obtain the cable material.
Embodiment 3
The present embodiment is related to a kind of cable material, including following weight portion component:24 parts of epoxy resin, vistanex 17 Part, 25 parts of glass fibre, 6 parts of ceramic Firebrake ZB, 24 parts of halogen-free expansion fire retardant, 3 parts of compatilizer, 0.1 part of anti-dripping agent, 5 parts of silicone oil, 2 parts of lubricant, 0.5 part of antioxidant, 1 part of antiseptic.
Wherein, the epoxy resin is modified epoxy, and the preparation method of the modified epoxy is as follows:By weight Part adds 25 parts of epoxy resin in 100 parts of toluene, is stirring evenly and then adding into 17 parts of bromoacetic acids, and reaction 15h is stirred at room temperature Afterwards in 100 parts of methyl alcohol of addition, through precipitating, filtering, be dried to obtain material A;13 parts of material As are added into 45 parts of toluene by weight In, 40 parts of triphenylphosphines are stirring evenly and then adding into, concentration of reaction solution after 33h is stirred at room temperature, it is subsequently adding 100 parts of petroleum ethers In, through precipitating, filtering, being dried to obtain the modified epoxy.
Wherein, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 65 DEG C, melting Time is 30 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization, temperature is 100 DEG C;
(3)Hot wind flow during the material for completing is put into 80 DEG C of environment will be granulated to dry 2 hours, you can obtain the cable material.
Embodiment 4
The present embodiment is related to a kind of cable material, including following weight portion component:27 parts of epoxy resin, vistanex 19 Part, 30 parts of glass fibre, 7 parts of ceramic Firebrake ZB, 27 parts of halogen-free expansion fire retardant, 5 parts of compatilizer, 0.2 part of anti-dripping agent, 6 parts of silicone oil, 3 parts of lubricant, 1 part of antioxidant, 2 parts of antiseptic.
Wherein, the epoxy resin is modified epoxy, and the preparation method of the modified epoxy is as follows:By weight Part adds 37 parts of epoxy resin in 100 parts of toluene, is stirring evenly and then adding into 17 parts of bromoacetic acids, and reaction 20h is stirred at room temperature Afterwards in 100 parts of methyl alcohol of addition, through precipitating, filtering, be dried to obtain material A;13 parts of material As are added into 45 parts of toluene by weight In, 40 parts of triphenylphosphines are stirring evenly and then adding into, concentration of reaction solution after 37h is stirred at room temperature, it is subsequently adding 100 parts of petroleum ethers In, through precipitating, filtering, being dried to obtain the modified epoxy.
Wherein, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 85 DEG C, melting Time is 50 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization, temperature is 140 DEG C;
(3)Hot wind flow during the material for completing is put into 85 DEG C of environment will be granulated to dry 3 hours, you can obtain the cable material.
Embodiment 5
The present embodiment is related to a kind of cable material, including following weight portion component:25 parts of epoxy resin, vistanex 18 Part, 27 parts of glass fibre, 6 parts of ceramic Firebrake ZB, 26 parts of halogen-free expansion fire retardant, 4 parts of compatilizer, 0.1 part of anti-dripping agent, 5 parts of silicone oil, 2 parts of lubricant, 0.6 part of antioxidant, 1.2 parts of antiseptic.
Wherein, the epoxy resin is modified epoxy, and the preparation method of the modified epoxy is as follows:By weight Part adds 37 parts of epoxy resin in 100 parts of toluene, is stirring evenly and then adding into 17 parts of bromoacetic acids, and reaction 20h is stirred at room temperature Afterwards in 100 parts of methyl alcohol of addition, through precipitating, filtering, be dried to obtain material A;13 parts of material As are added into 45 parts of toluene by weight In, 40 parts of triphenylphosphines are stirring evenly and then adding into, concentration of reaction solution after 37h is stirred at room temperature, it is subsequently adding 100 parts of petroleum ethers In, through precipitating, filtering, being dried to obtain the modified epoxy.
Wherein, the halogen-free expansion fire retardant is phosphor nitrogen combustion inhibitor.
A kind of method for preparing the cable material, comprises the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 85 DEG C, melting Time is 50 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization, temperature is 140 DEG C;
(3)Hot wind flow during the material for completing is put into 85 DEG C of environment will be granulated to dry 3 hours, you can obtain the cable material.
From above-described embodiment as can be seen that cable material of the present invention, with good flexibility and elasticity, Yi Jiyou Different moisture resistance and water absorption resistance, the material of the ceramic-like after burning is in hard, uniform cellular housing, using ceramic Firebrake ZB at high temperature, forms continuous glass ceramics tunic, and such object has excellent insulating properties, thermal insulation, fire insulation Fire resistance, while can also withstand shocks and shake, and prevents the infiltration of water;While the antibacterial by adding proper ratio Agent so that the cable material of preparation both has antimycotic effect, while influenceing original electricity without the addition because of antiseptic The performance of cable material;The present invention with the addition of modified epoxy, coordinates with vistanex, glass fibre and improves cable material Insulating properties.
Specific embodiment of the invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can within the scope of the claims make various deformations or amendments, this not shadow Sound substance of the invention.

Claims (8)

1. a kind of cable material, it is characterised in that the component including following weight portion:20~30 parts of epoxy resin, polyolefin tree It is 15~20 parts of fat, 15~35 parts of glass fibre, 5~8 parts of ceramic Firebrake ZB, 15~35 parts of halogen-free expansion fire retardant, compatible 3~7 parts of agent, 0.1~0.2 part of anti-dripping agent, 4~7 parts of silicone oil, 2~3 parts of lubricant, 0.5~2 part of antioxidant, antiseptic 1~2 Part.
2. cable material according to claim 1, it is characterised in that the component including following weight portion:Epoxy resin 24 ~27 parts, 17~19 parts of vistanex, 25~30 parts of glass fibre, 6~7 parts of ceramic Firebrake ZB, halogen-free expansion type flame-proof 24~27 parts of agent, 3~5 parts of compatilizer, 0.1~0.2 part of anti-dripping agent, 5~6 parts of silicone oil, 2~3 parts of lubricant, antioxidant 0.5 ~1 part, 1~2 part of antiseptic.
3. cable material according to claim 1, it is characterised in that the component including following weight portion:Epoxy resin 25 Part, 18 parts of vistanex, 27 parts of glass fibre, 6 parts of ceramic Firebrake ZB, 26 parts of halogen-free expansion fire retardant, compatilizer 4 Part, 0.1 part of anti-dripping agent, 5 parts of silicone oil, 2 parts of lubricant, 0.6 part of antioxidant, 1.2 parts of antiseptic.
4. cable material according to claim 1, it is characterised in that the epoxy resin is modified epoxy.
5. cable material according to claim 4, it is characterised in that the preparation method of the modified epoxy is as follows: By weight by 25~37 parts of epoxy resin 100 parts of toluene of addition, 17 parts of bromoacetic acids are stirring evenly and then adding into, stirred at room temperature Mixing in add after 15~20h of reaction 100 parts of methyl alcohol, through precipitating, filtering, be dried to obtain material A;By weight by 13 parts of material As Add in 45 parts of toluene, be stirring evenly and then adding into 40 parts of triphenylphosphines, concentration of reaction solution after 33~37h is stirred at room temperature, so Afterwards in 100 parts of petroleum ethers of addition, through precipitating, filtering, being dried to obtain the modified epoxy.
6. cable material according to claim 1, it is characterised in that the halogen-free expansion fire retardant is that phosphorus nitrogen is fire-retardant Agent.
7. a kind of method for preparing cable material described in any one of claim 1~6, it is characterised in that comprise the following steps:
(1)It is well mixed after weighing various raw materials by formula, is put into melting machine and is mediated, smelting temperature is 65~85 DEG C, Smelting time is 30~50 minutes;
(2)By the step(1)Mediate the material for completing and be put into double screw extruder extruding pelletization;
(3)Hot wind flow during the material for completing is put into 80~85 DEG C of environment will be granulated to dry 2~3 hours, you can obtain the electricity Cable material.
8. preparation method according to claim 7, it is characterised in that the temperature range of the extruding and pelletizing process is 100 ~140 DEG C.
CN201710181069.2A 2017-03-24 2017-03-24 A kind of cable material and preparation method thereof Withdrawn CN106905663A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107573555A (en) * 2017-11-01 2018-01-12 安徽美腾特种电缆材料有限公司 A kind of high performance cable material
CN107674275A (en) * 2017-11-01 2018-02-09 安徽美腾特种电缆材料有限公司 A kind of flame-proof anti-aging cable material
CN108003411A (en) * 2017-12-21 2018-05-08 扬州市金鑫电缆有限公司 Can be into porcelain low-smoke halogen-free polyolefin cable material and preparation method thereof
CN108467556A (en) * 2018-04-14 2018-08-31 长沙小新新能源科技有限公司 A kind of elastomer flexible cable and preparation method thereof
CN113773633A (en) * 2021-10-29 2021-12-10 扬州本之源高分子材料科技有限公司 High-weather-resistance anti-cracking modified polyurethane photovoltaic cable and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103524845A (en) * 2013-09-30 2014-01-22 芜湖航天特种电缆厂 Halogen-free flame-retardant thermoplastic polyolefin cable material
CN105741947A (en) * 2016-03-31 2016-07-06 安徽富悦达电子有限公司 Antibacterial and high-flame-retardant cable
CN106024167A (en) * 2016-06-12 2016-10-12 安徽天元电缆有限公司 Flame retardant and fire resistant cable material
CN106349634A (en) * 2016-08-30 2017-01-25 聚威工程塑料(上海)有限公司 Extrusion grade elastomer used for wire and cable of charging pile for new energy automobile

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524845A (en) * 2013-09-30 2014-01-22 芜湖航天特种电缆厂 Halogen-free flame-retardant thermoplastic polyolefin cable material
CN105741947A (en) * 2016-03-31 2016-07-06 安徽富悦达电子有限公司 Antibacterial and high-flame-retardant cable
CN106024167A (en) * 2016-06-12 2016-10-12 安徽天元电缆有限公司 Flame retardant and fire resistant cable material
CN106349634A (en) * 2016-08-30 2017-01-25 聚威工程塑料(上海)有限公司 Extrusion grade elastomer used for wire and cable of charging pile for new energy automobile

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107573555A (en) * 2017-11-01 2018-01-12 安徽美腾特种电缆材料有限公司 A kind of high performance cable material
CN107674275A (en) * 2017-11-01 2018-02-09 安徽美腾特种电缆材料有限公司 A kind of flame-proof anti-aging cable material
CN108003411A (en) * 2017-12-21 2018-05-08 扬州市金鑫电缆有限公司 Can be into porcelain low-smoke halogen-free polyolefin cable material and preparation method thereof
CN108467556A (en) * 2018-04-14 2018-08-31 长沙小新新能源科技有限公司 A kind of elastomer flexible cable and preparation method thereof
CN113773633A (en) * 2021-10-29 2021-12-10 扬州本之源高分子材料科技有限公司 High-weather-resistance anti-cracking modified polyurethane photovoltaic cable and preparation method thereof

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Application publication date: 20170630