CN106894027A - A kind of STAINLESS STEEL WIRE cleaning agent - Google Patents
A kind of STAINLESS STEEL WIRE cleaning agent Download PDFInfo
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- CN106894027A CN106894027A CN201710180597.6A CN201710180597A CN106894027A CN 106894027 A CN106894027 A CN 106894027A CN 201710180597 A CN201710180597 A CN 201710180597A CN 106894027 A CN106894027 A CN 106894027A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The invention belongs to the preparation field of stainless steel, a kind of STAINLESS STEEL WIRE cleaning agent is disclosed, be made up of the component of following parts by weight:12 15 parts of sodium thiosulfate, 14 parts of citric acid, 0.7 1.5 parts of oxalic acid, 0.9 1.4 parts of sodium molybdate, 12 14 parts of sodium acetate, 10 14 parts of tartaric acid, 16 parts of hexa, 100 120 parts of water.Without strong acid, environment-friendly and green, addition hexa with synergy inorganic acid and the cleaning effect of weak acid, can improve the service efficiency and using effect of cleaning agent to the cleaning agent as one of the active ingredient of cleaning agent.
Description
Technical field
The invention belongs to stainless steel applied technical field, the more particularly to preparation method of STAINLESS STEEL WIRE cleaning agent.
Background technology
At present, STAINLESS STEEL WIRE various types, it is difficult to clean, especially the trade mark be Y309L, ER309L, Y316L,
The STAINLESS STEEL WIRE of ER30L, SSUVY308 and SUS304HC etc. six.Traditional cleaning agent formula be by nitric acid, hydrofluoric acid, hydrochloric acid and
Water by mass percentage 5:4:3:90 DEG C -95 DEG C are heated up to after 8 mixing, STAINLESS STEEL WIRE to be cleaned soaks 4-4.5 hours
Can treatment it is clean, can only clean within 8 hours STAINLESS STEEL WIRE 40-45 tons, it is inefficient, and due to nitric acid, hydrofluoric acid and hydrochloric acid
Acid mist is produced by heating, is had to human body and is greatly endangered, severe contamination air, also severe contamination water is provided for the discharge of waste acid water
Source.Application No. 201410337986.1 it is entitled《Environment-friendly type tax base metal cleaner and preparation method thereof》Disclose a kind of master
Including:Water, silicic acid lipoid substance and triethanolamine, sodium carbonate, one or four butanediol copolymers, triethanolamine, base phenol polyoxy
Vinethene RF-10, alkylolamides phosphate, azelaic acid, polyethylene glycol, ether defoaming agent SPG-70 and antimildew disinfectant KF88's
Cleaning agent, can be used to be machined the cleaning of metal parts inter process and the antirust of manufacturing.The program is with strong points, to operation
Between antirust oil act on well, cannot but be applied to other aspect.
The content of the invention
The present invention provides following technical scheme:
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
Sodium thiosulfate 12-15 parts,
Citric acid 1-4 parts,
Oxalic acid 0.7-1.5 parts,
Sodium molybdate 0.9-1.4 parts,
Sodium acetate 12-14 parts,
Tartaric acid 10-14 parts,
Hexa 1-6 parts,
Water 100-120 parts.
Preferably, it is made up of the component of following parts by weight:
Sodium thiosulfate 12-13 parts,
Citric acid 1.8-4 parts,
Oxalic acid 0.7-1.0 parts,
Sodium molybdate 0.9-1.2 parts,
Sodium acetate 12-13.5 parts,
Tartaric acid 12-14 parts,
Hexa 2-6 parts,
Water 100-115 parts.
Preferably, it is made up of the component of following parts by weight:
12.5 parts of sodium thiosulfate,
3.3 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of sodium molybdate,
13 parts of sodium acetate,
12.5 parts of tartaric acid,
4 parts of hexa,
109 parts of water.
Preferably, it is made up of the component of following parts by weight:
12.9 parts of sodium thiosulfate,
2.8 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of molybdenum,
12.5 parts of sodium acetate,
14 parts of tartaric acid,
5.4 parts of hexa,
110 parts of water.
Preferably, the preparation method of the cleaning agent is comprised the following steps:
(1), under normal temperature, water is added in mixer;
(2) sodium thiosulfate, is delivered while stirring;
(3) citric acid, is delivered while stirring;
(4) oxalic acid, is delivered while stirring;
(5) sodium molybdate, is delivered while stirring;
(6) sodium acetate, is delivered while stirring;
(7) tartaric acid, is delivered while stirring;
(8) hexa, is delivered while stirring;
(9) all charging is stirred for being finished product in 20-30 minutes after finishing.
Hexa is mainly used as resin and the curing agent of plastics, the catalyst of aminoplast and foaming agent, rubber
Accelerator (Urotropinum), anti-piping compound of textile of vulcanization etc..The raw material of organic synthesis, is used for producing chlorine in medical industry
Mycin;Can be used as the disinfectant of urinary system, itself is effective to gramnegative bacterium without antibacterial action.Its 20% it is molten
Liquid can be used to treat underarm odor, sweaty feet, ringworm of the body etc..It mixes with NaOH and sodium phenate, can do the light aspiration in breathing mask
Receive agent;For manufacturing agricultural chemical insecticide.Hexa is acted on fuming nitric aicd, explosive extremely strong whirlwind can be obtained and fries
Medicine, abbreviation RDX.Hexa is alternatively arranged as determining bismuth, indium, manganese, cobalt, thorium, platinum, magnesium product, lithium, copper, uranium, beryllium, tellurium, bromination
Reagent and chromatography reagent of thing, iodide etc. etc., the vulcanization for being also used as the curing agent, rubber of resin and plastics promote
Agent (Urotropinum), the anti-piping compound of textile, and for bactericide processed, explosive etc..Aciduria is met when medicinal, after taking orally decompose product
Give birth to formaldehyde and play bactericidal action, for slight urinary tract infections;It is outer to be used to control tinea, hidroschesis, control underarm odor.It is mixed with caustic soda and sodium phenate
Close, phosgene absorbent is made for breathing mask.
Compared with prior art, its advantage is the present invention:
1. the present invention provides a kind of without heating, can clean STAINLESS STEEL WIRE and not corrode metal surface, to human body without
Harmful and free from environmental pollution STAINLESS STEEL WIRE cleaning agent and preparation method thereof.
2. present invention addition hexa can improve clear as one of the main component of STAINLESS STEEL WIRE cleaning agent
The cleaning performance of lotion, notable synergy inorganic acid reduces the usage amount of cleaning agent to the removal ability of greasy dirt.
3. without strong acid and strong base, green high-efficient can reach the cleaning effect almost consistent with strong acid to cleaning agent of the present invention
Really.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, foregoing end other objects of the invention, feature,
Aspect and advantage will be apparent, to make those skilled in the art to implement according to this with reference to specification word.
Embodiment one
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
12 parts of sodium thiosulfate,
1 part of citric acid,
0.7 part of oxalic acid,
0.9 part of sodium molybdate,
12 parts of sodium acetate,
10 parts of tartaric acid,
1 part of hexa,
100 parts of water.
Embodiment two
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
15 parts of sodium thiosulfate,
4 parts of citric acid,
1.5 parts of oxalic acid,
1.4 parts of sodium molybdate,
14 parts of sodium acetate,
14 parts of tartaric acid,
6 parts of hexa,
120 parts of water.
Embodiment three
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
12 parts of sodium thiosulfate,
1.8 parts of citric acid,
0.7 part of oxalic acid,
0.9 part of sodium molybdate,
12 parts of sodium acetate,
12 parts of tartaric acid,
2 parts of hexa,
100 parts of water.
Example IV
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
13 parts of sodium thiosulfate,
4 parts of citric acid,
1.0 parts of oxalic acid,
1.2 parts of sodium molybdate,
13.5 parts of sodium acetate,
14 parts of tartaric acid,
6 parts of hexa,
115 parts of water.
Embodiment five
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
12.5 parts of sodium thiosulfate,
3.3 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of sodium molybdate,
13 parts of sodium acetate,
12.5 parts of tartaric acid,
4 parts of hexa,
109 parts of water.
Embodiment six
A kind of STAINLESS STEEL WIRE cleaning agent, is made up of the component of following parts by weight:
12.9 parts of sodium thiosulfate,
2.8 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of molybdenum,
12.5 parts of sodium acetate,
14 parts of tartaric acid,
5.4 parts of hexa,
110 parts of water.
The preparation method of above-described embodiment is comprised the following steps:
(1), under normal temperature, water is added in mixer;
(2) sodium thiosulfate, is delivered while stirring;
(3) citric acid, is delivered while stirring;
(4) oxalic acid, is delivered while stirring;
(5) sodium molybdate, is delivered while stirring;
(6) sodium acetate, is delivered while stirring;
(7) tartaric acid, is delivered while stirring;
(8) hexa, is delivered while stirring;
(9) all charging is stirred for being finished product in 20-30 minutes after finishing.
The cleaning agent that preparation method vegetation described in embodiment is obtained is to once purged workpiece surface through light microscope
Observation, it can be seen that workpiece surface is smooth, has metallic luster, and other impurities are not observed.Prove that the cleaning agent can be effective
Removal residues in stainless steel or the iron content or the etching solution of ferrous ion of other ferrous alloy substrate surfaces.
Comparative example one:Stainless steel work-piece is cleaned instead of cleaning agent described in embodiment using clear water.
Comparative example two:Other components are identical with embodiment five in addition to hexa is not contained, preparation method with implement
Identical, the cleaning agent for preparing of example.
Comparative example three:Other components are identical with embodiment six in addition to hexa is not contained, preparation method with implement
Identical, the cleaning agent for preparing of example.
Comparative example four:Mass concentration is 10% salpeter solution.
Comparative example five:Mass concentration is 5% sulfuric acid solution.
The cleaning agent obtained with embodiment and comparative example vegetation to carrying out cleaning treatment with a collection of workpiece, cleaning dynamics and clear
It is identical to wash the time, carries out contrast test.
Contrast is compared with embodiment, it is impossible to carry out effective cleaning to stainless steel metal, it is impossible to assign metal works good
Metallic luster, cleaning performance is poor.
Claims (5)
1. a kind of STAINLESS STEEL WIRE cleaning agent, it is characterised in that:It is made up of the component of following parts by weight:
Sodium thiosulfate 12-15 parts,
Citric acid 1-4 parts,
Oxalic acid 0.7-1.5 parts,
Sodium molybdate 0.9-1.4 parts,
Sodium acetate 12-14 parts,
Tartaric acid 10-14 parts,
Hexa 1-6 parts,
Water 100-120 parts.
2. a kind of STAINLESS STEEL WIRE cleaning agent according to claim 1, it is characterised in that:
It is made up of the component of following parts by weight:
Sodium thiosulfate 12-13 parts,
Citric acid 1.8-4 parts,
Oxalic acid 0.7-1.0 parts,
Sodium molybdate 0.9-1.2 parts,
Sodium acetate 12-13.5 parts,
Tartaric acid 12-14 parts,
Hexa 2-6 parts,
Water 100-115 parts.
3. a kind of STAINLESS STEEL WIRE cleaning agent according to claim 2, it is characterised in that:
It is made up of the component of following parts by weight:
12.5 parts of sodium thiosulfate,
3.3 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of sodium molybdate,
13 parts of sodium acetate,
12.5 parts of tartaric acid,
4 parts of hexa,
109 parts of water.
4. a kind of STAINLESS STEEL WIRE cleaning agent according to claim 1, it is characterised in that:
It is made up of the component of following parts by weight:
12.9 parts of sodium thiosulfate,
2.8 parts of citric acid,
0.9 part of oxalic acid,
1.0 parts of molybdenum,
12.5 parts of sodium acetate,
14 parts of tartaric acid,
5.4 parts of hexa,
110 parts of water.
5. according to the STAINLESS STEEL WIRE cleaning agent that one of Claims 1-4 is described, it is characterised in that:
The preparation method of the cleaning agent is comprised the following steps:
(1), under normal temperature, water is added in mixer;
(2) sodium thiosulfate, is delivered while stirring;
(3) citric acid, is delivered while stirring;
(4) oxalic acid, is delivered while stirring;
(5) sodium molybdate, is delivered while stirring;
(6) sodium acetate, is delivered while stirring;
(7) tartaric acid, is delivered while stirring;
(8) hexa, is delivered while stirring;
(9) all charging is stirred for being finished product in 20-30 minutes after finishing.
Priority Applications (1)
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CN201710180597.6A CN106894027A (en) | 2017-03-24 | 2017-03-24 | A kind of STAINLESS STEEL WIRE cleaning agent |
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CN201710180597.6A CN106894027A (en) | 2017-03-24 | 2017-03-24 | A kind of STAINLESS STEEL WIRE cleaning agent |
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CN106894027A true CN106894027A (en) | 2017-06-27 |
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CN201710180597.6A Pending CN106894027A (en) | 2017-03-24 | 2017-03-24 | A kind of STAINLESS STEEL WIRE cleaning agent |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108441865A (en) * | 2018-03-09 | 2018-08-24 | 安徽金环电气设备有限责任公司 | A kind of handware recycling derusting pickle and its configuration method |
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CN102400164A (en) * | 2011-11-28 | 2012-04-04 | 常州市凯纳环保科技有限公司 | Stainless steel wire cleaning agent and preparation method thereof |
CN102400165A (en) * | 2011-11-28 | 2012-04-04 | 常州市凯纳环保科技有限公司 | Cleaning agent for stainless steel seamless stay tubes and preparation method for cleaning agent |
CN102677071A (en) * | 2011-03-11 | 2012-09-19 | 镇江市欣泰化工物资有限公司 | Metal cleaner |
CN103103541A (en) * | 2013-01-24 | 2013-05-15 | 宝山钢铁股份有限公司 | Silicon steel acid cleaning stabilizing material and application method thereof |
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2017
- 2017-03-24 CN CN201710180597.6A patent/CN106894027A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102677071A (en) * | 2011-03-11 | 2012-09-19 | 镇江市欣泰化工物资有限公司 | Metal cleaner |
CN102400164A (en) * | 2011-11-28 | 2012-04-04 | 常州市凯纳环保科技有限公司 | Stainless steel wire cleaning agent and preparation method thereof |
CN102400165A (en) * | 2011-11-28 | 2012-04-04 | 常州市凯纳环保科技有限公司 | Cleaning agent for stainless steel seamless stay tubes and preparation method for cleaning agent |
CN103103541A (en) * | 2013-01-24 | 2013-05-15 | 宝山钢铁股份有限公司 | Silicon steel acid cleaning stabilizing material and application method thereof |
Non-Patent Citations (1)
Title |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108441865A (en) * | 2018-03-09 | 2018-08-24 | 安徽金环电气设备有限责任公司 | A kind of handware recycling derusting pickle and its configuration method |
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