CN106890478A - High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment - Google Patents

High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment Download PDF

Info

Publication number
CN106890478A
CN106890478A CN201510965438.8A CN201510965438A CN106890478A CN 106890478 A CN106890478 A CN 106890478A CN 201510965438 A CN201510965438 A CN 201510965438A CN 106890478 A CN106890478 A CN 106890478A
Authority
CN
China
Prior art keywords
acetonitrile
adsorbent
adsorption tanks
outlet
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510965438.8A
Other languages
Chinese (zh)
Inventor
赵志峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Xinlanjing Chemical and Industrial Company Limited
Original Assignee
赵志峰
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 赵志峰 filed Critical 赵志峰
Priority to CN201510965438.8A priority Critical patent/CN106890478A/en
Publication of CN106890478A publication Critical patent/CN106890478A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/32Separation; Purification; Stabilisation; Use of additives
    • C07C253/34Separation; Purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

High purity reagent acetonitrile removes aldehyde type impurities adsorbent and adsorbent equipment, the device is made up of lightness-removing column kettle surge tank, acetonitrile adsorption tanks, acetonitrile absorption groove, the part of adsorbent reactivation tank four, lightness-removing column kettle surge tank adsorbs feed pump and is connected with acetonitrile adsorption tanks by acetonitrile, the material outlet of acetonitrile absorption pot bottom is divided into two branch roads, one branch road adsorbs groove and is connected as acetonitrile material outlet, by acetonitrile material outlet valve and acetonitrile.Another branch road is connected by adsorbent outlet valve as adsorbent outlet with adsorbent reactivation tank.Exhaust outlet, adsorbent import, visor, pure water inlet and acetonitrile material inlet are arranged at the specially treated adsorbent of filling in acetonitrile adsorption tanks, acetonitrile adsorption tanks top, and liquid distribution trough is provided with acetonitrile material inlet.Wherein, exhaust outlet, adsorbent import, visor are shared.Acetonitrile absorption pot bottom has nitrogen inlet, and material outlet is provided with stainless steel filtering net.

Description

High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment
Technical field
The invention belongs to high purity reagent acetonitrile production and processing technical field, it is related to a kind of high purity reagent acetonitrile to remove formaldehyde, acetaldehyde adsorbent equipment.
Background technology
The production of high purity reagent acetonitrile is the process of rectifying purifying, and traditional handicraft is that the impurity such as the formaldehyde in grade acetonitrile, acetaldehyde, propionitrile, acrylonitrile are removed by rectifying mode, obtains ethane nitrile content >=99.9% high purity reagent acetonitrile.But, the light component impurity such as formaldehyde, acetaldehyde cannot completely be removed by rectifying, formaldehyde, acetaldehyde total content≤0.0004% after rectifying, such high purity reagent are only capable of meeting low-end applications field(Separation, extraction such as medicine)Demand, the use requirement of new drug development and semicon industry cannot be met, and new drug development and semicon industry occupy the market of high purity reagent 80 ~ 85%, at present, new drug development and semicon industry high purity reagent are monopolized by import brand, and the removal of the impurity such as formaldehyde, acetaldehyde turns into the technical bottleneck of domestic high purity reagent production.
The content of the invention
The present invention is in high purity reagent acetonitrile production technology, the trace impurities such as formaldehyde, acetaldehyde cannot be completely removed by rectifying, causing high purity reagent cannot meet the phenomenon of new drug development and semicon industry demand, there is provided a kind of high purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment.The device is by lightness-removing column kettle surge tank (1), acetonitrile adsorption tanks(3), acetonitrile absorption groove(14), adsorbent reactivation tank(15)Four parts are constituted, lightness-removing column kettle surge tank(1)Feed pump is adsorbed by acetonitrile(2)With acetonitrile adsorption tanks(3)It is connected, acetonitrile adsorption tanks(3)The material outlet of bottom(9)Be divided into two branch roads, a branch road as acetonitrile material outlet, by acetonitrile material outlet valve(12)Groove is adsorbed with acetonitrile(14)It is connected.Another branch road as adsorbent outlet, by adsorbent outlet valve(13)With adsorbent reactivation tank(15)It is connected.Acetonitrile adsorption tanks(3)The specially treated adsorbent of interior filling(16), acetonitrile adsorption tanks(3)Exhaust outlet is arranged at top(6), adsorbent import(7), visor(8), pure water inlet(5)And acetonitrile material inlet(4), acetonitrile material inlet(4)On liquid distribution trough is installed(17).Wherein, exhaust outlet(6), adsorbent import(7), visor(8)Share.Acetonitrile adsorption tanks(3)Nitrogen inlet is arranged at bottom(10), material outlet(9)Stainless steel filtering net is installed(11).
Using above-mentioned technical proposal, under high pure nitrogen protection, by by the adsorbent of specially treated(16)It is filled to acetonitrile adsorption tanks(3)80% volume.Lightness-removing column kettle surge tank(1)The acetonitrile material of trace formaldehyde, acetaldehyde impurities is contained within, feed pump is adsorbed by acetonitrile(2), by lightness-removing column kettle surge tank(1)Interior acetonitrile material is delivered to acetonitrile adsorption tanks(3)The acetonitrile material inlet at top(4), acetonitrile material is by liquid distribution trough(17)It is evenly distributed on acetonitrile adsorption tanks(3)It is interior, from top to bottom with adsorbent(16)It is fully contacted, from acetonitrile adsorption tanks(3)The material outlet of bottom(9)Through stainless steel filtering net(11)Filtering, through acetonitrile material outlet valve(12), groove is adsorbed into acetonitrile(14).Acetonitrile adsorption tanks(3)Interior adsorbent(16)Reach when saturation is adsorbed, it is necessary to change acetonitrile adsorption tanks(3)Interior adsorbent(16), stop the turnover of acetonitrile material, open acetonitrile adsorption tanks(3)Bottoms material is exported(9), remove stainless steel filtering net(11), open adsorbent outlet valve(13), by adsorbent(16)Together with acetonitrile discharge of materials to adsorbent reactivation tank(15), the adsorbent of failure(16)In adsorbent reactivation tank(15)Inside regenerated.Open acetonitrile adsorption tanks(3)The pure water inlet at top(5), by acetonitrile adsorption tanks(3)Rinse well, open acetonitrile adsorption tanks(3)Bottom high pure nitrogen import(10), by acetonitrile adsorption tanks(3)After drying, under nitrogen protection, effective adsorbent is loaded(16).By after said apparatus treatment, formaldehyde, acetaldehyde in acetonitrile material can be removed completely, can produce the high purity reagent acetonitrile of high-quality.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Specific embodiment:
Embodiment:A kind of high purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment.The device is by lightness-removing column kettle surge tank (1), acetonitrile adsorption tanks(3), acetonitrile absorption groove(14), adsorbent reactivation tank(15)Four parts are constituted, lightness-removing column kettle surge tank(1)Feed pump is adsorbed by acetonitrile(2)With acetonitrile adsorption tanks(3)It is connected, acetonitrile adsorption tanks(3)The material outlet of bottom(9)Be divided into two branch roads, a branch road as acetonitrile material outlet, by acetonitrile material outlet valve(12)Groove is adsorbed with acetonitrile(14)It is connected.Another branch road as adsorbent outlet, by adsorbent outlet valve(13)With adsorbent reactivation tank(15)It is connected.Acetonitrile adsorption tanks(3)The specially treated adsorbent of interior filling(16), acetonitrile adsorption tanks(3)Exhaust outlet is arranged at top(6), adsorbent import(7), visor(8), pure water inlet(5)And acetonitrile material inlet(4), acetonitrile material inlet(4)On liquid distribution trough is installed(17).Wherein, exhaust outlet(6), adsorbent import(7), visor(8)Share.Acetonitrile adsorption tanks(3)Nitrogen inlet is arranged at bottom(10), material outlet(9)Stainless steel filtering net is installed(11).
Under high pure nitrogen protection, by by the adsorbent of specially treated(16)It is filled to acetonitrile adsorption tanks(3)80% volume.Lightness-removing column kettle surge tank(1)The acetonitrile material of trace formaldehyde, acetaldehyde impurities is contained within, feed pump is adsorbed by acetonitrile(2), by lightness-removing column kettle surge tank(1)Interior acetonitrile material is delivered to acetonitrile adsorption tanks(3)The acetonitrile material inlet at top(4), acetonitrile material is by liquid distribution trough(17)It is evenly distributed on acetonitrile adsorption tanks(3)It is interior, from top to bottom with adsorbent(16)It is fully contacted, from acetonitrile adsorption tanks(3)The material outlet of bottom(9)Through stainless steel filtering net(11)Filtering, through acetonitrile material outlet valve(12), groove is adsorbed into acetonitrile(14).Acetonitrile adsorption tanks(3)Interior adsorbent(16)Reach when saturation is adsorbed, it is necessary to change acetonitrile adsorption tanks(3)Interior adsorbent(16), stop the turnover of acetonitrile material, open acetonitrile adsorption tanks(3)Bottoms material is exported(9), remove stainless steel filtering net(11), open adsorbent outlet valve(13), by adsorbent(16)Together with acetonitrile discharge of materials to adsorbent reactivation tank(15), the adsorbent of failure(16)In adsorbent reactivation tank(15)Inside regenerated.Open acetonitrile adsorption tanks(3)The pure water inlet at top(5), by acetonitrile adsorption tanks(3)Rinse well, open acetonitrile adsorption tanks(3)Bottom high pure nitrogen import(10), by acetonitrile adsorption tanks(3)After drying, under nitrogen protection, effective adsorbent is loaded(16).

Claims (3)

1. high purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment, and the device is by lightness-removing column kettle surge tank (1), acetonitrile adsorption tanks(3), acetonitrile absorption groove(14), adsorbent reactivation tank(15)Four parts are constituted, lightness-removing column kettle surge tank(1)Feed pump is adsorbed by acetonitrile(2)With acetonitrile adsorption tanks(3)It is connected, acetonitrile adsorption tanks(3)The material outlet of bottom(9)Be divided into two branch roads, a branch road as acetonitrile material outlet, by acetonitrile material outlet valve(12)Groove is adsorbed with acetonitrile(14)Be connected, another branch road as adsorbent outlet, by adsorbent outlet valve(13)With adsorbent reactivation tank(15)It is connected, acetonitrile adsorption tanks(3)The specially treated adsorbent of interior filling(16), acetonitrile adsorption tanks(3)Exhaust outlet is arranged at top(6), adsorbent import(7), visor(8), pure water inlet(5)And acetonitrile material inlet(4), acetonitrile material inlet(4)On liquid distribution trough is installed(17), wherein, exhaust outlet(6), adsorbent import(7), visor(8)Share, acetonitrile adsorption tanks(3)Nitrogen inlet is arranged at bottom(10), material outlet(9)Stainless steel filtering net is installed(11).
2. high purity reagent acetonitrile as claimed in claim 1 removes formaldehyde, acetaldehyde adsorbent equipment, it is characterised in that:Under high pure nitrogen protection, by by the adsorbent of specially treated(16)It is filled to acetonitrile adsorption tanks(3)80% volume, lightness-removing column kettle surge tank(1)The acetonitrile material of trace formaldehyde, acetaldehyde impurities is contained within, feed pump is adsorbed by acetonitrile(2), by lightness-removing column kettle surge tank(1)Interior acetonitrile material is delivered to acetonitrile adsorption tanks(3)The acetonitrile material inlet at top(4), acetonitrile material is by liquid distribution trough(17)It is evenly distributed on acetonitrile adsorption tanks(3)It is interior, from top to bottom with adsorbent(16)It is fully contacted, from acetonitrile adsorption tanks(3)The material outlet of bottom(9)Through stainless steel filtering net(11)Filtering, through acetonitrile material outlet valve(12), groove is adsorbed into acetonitrile(14).
3. high purity reagent acetonitrile as claimed in claim 2 removes formaldehyde, acetaldehyde adsorbent equipment, it is characterised in that:Acetonitrile adsorption tanks(3)Interior adsorbent(16)Reach when saturation is adsorbed, it is necessary to change acetonitrile adsorption tanks(3)Interior adsorbent(16), stop the turnover of acetonitrile material, open acetonitrile adsorption tanks(3)Bottoms material is exported(9), remove stainless steel filtering net(11), open adsorbent outlet valve(13), by adsorbent(16)Together with acetonitrile discharge of materials to adsorbent reactivation tank(15), the adsorbent of failure(16)In adsorbent reactivation tank(15)Inside regenerated, opened acetonitrile adsorption tanks(3)The pure water inlet at top(5), by acetonitrile adsorption tanks(3)Rinse well, open acetonitrile adsorption tanks(3)Bottom high pure nitrogen import(10), by acetonitrile adsorption tanks(3)After drying, under nitrogen protection, effective adsorbent is loaded(16).
CN201510965438.8A 2015-12-21 2015-12-21 High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment Pending CN106890478A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510965438.8A CN106890478A (en) 2015-12-21 2015-12-21 High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510965438.8A CN106890478A (en) 2015-12-21 2015-12-21 High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment

Publications (1)

Publication Number Publication Date
CN106890478A true CN106890478A (en) 2017-06-27

Family

ID=59190313

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510965438.8A Pending CN106890478A (en) 2015-12-21 2015-12-21 High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment

Country Status (1)

Country Link
CN (1) CN106890478A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109085260A (en) * 2018-07-16 2018-12-25 广东工业大学 A method of the purifying residual grade acetonitrile of agriculture

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1173489A (en) * 1996-06-20 1998-02-18 日东化学工业株式会社 Purification of nitrile
US20120264662A1 (en) * 2011-03-24 2012-10-18 Dibiase Stephen A Functionalized monomers
CN102746189A (en) * 2012-07-24 2012-10-24 国药集团化学试剂有限公司 Method for preparing chromatographically pure acetonitrile
CN103772234A (en) * 2013-12-25 2014-05-07 中国石油集团东北炼化工程有限公司吉林设计院 Acetonitrile refining process
CN205549679U (en) * 2015-12-21 2016-09-07 赵志峰 High purity reagent acetonitrile formaldehyde removal , acetaldehyde adsorption equipment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1173489A (en) * 1996-06-20 1998-02-18 日东化学工业株式会社 Purification of nitrile
US20120264662A1 (en) * 2011-03-24 2012-10-18 Dibiase Stephen A Functionalized monomers
CN102746189A (en) * 2012-07-24 2012-10-24 国药集团化学试剂有限公司 Method for preparing chromatographically pure acetonitrile
CN103772234A (en) * 2013-12-25 2014-05-07 中国石油集团东北炼化工程有限公司吉林设计院 Acetonitrile refining process
CN205549679U (en) * 2015-12-21 2016-09-07 赵志峰 High purity reagent acetonitrile formaldehyde removal , acetaldehyde adsorption equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109085260A (en) * 2018-07-16 2018-12-25 广东工业大学 A method of the purifying residual grade acetonitrile of agriculture

Similar Documents

Publication Publication Date Title
CA2863910A1 (en) An extraction column and process for use thereof
CN101940289B (en) Method for separating discolored chili extract from chili pigment in crude products of chili extract
CN104860460A (en) Processing device for aniline intermediate production waste water
CN106890478A (en) High purity reagent acetonitrile removes formaldehyde, acetaldehyde adsorbent equipment
CN205549679U (en) High purity reagent acetonitrile formaldehyde removal , acetaldehyde adsorption equipment
CN107556161A (en) Chromatographic Pure Methanol and preparation method thereof, production system
CN102827045B (en) Method and apparatus for removing impurity in secondary methionine mother liquor
CN102060674A (en) Method for purifying high-purity organic solvent diethyl ether
CN205500996U (en) Laboratory waste water adsorbs processing apparatus
CN210419813U (en) Acetonitrile purification device
JP2015150559A5 (en)
CN207680093U (en) A kind of resin-column of absorption parachloroanilinum
CN104276724B (en) A kind of high salt is containing sodium chloride and glycerol recovery method in glycerol high concentrated organic wastewater
CN108379873B (en) Device for recovering ethanol in traditional Chinese medicine extraction process
CN102040496A (en) Purification method of high-purity organic solvent 4-methyl-2-pentanone
CN105217724B (en) A kind of technique and equipment for removing Nitrate In Drinking Water
CN206381677U (en) A kind of battery electrolyte Purifying Device for Organic Solvent
CN204918232U (en) Laboratory waste water treatment bucket
CN103083965A (en) Wastewater filter
CN204401139U (en) A kind of pcb board carbon treatment trough of improvement
CN104003859A (en) Method for purifying cyclohexanone through distillation adsorption
CN205164248U (en) Clout divides formula of arranging diatomaceous earth filter
CN108128837A (en) One inter-species diethyl object produces the processing method of waste water
CN203694672U (en) Resin column
CN202191726U (en) Resin separating column

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20200131

Address after: 653100 middle section of Chunhui Road, high tech Industrial Development Zone, Yuxi City, Yunnan Province

Applicant after: Yunnan Xinlanjing Chemical and Industrial Company Limited

Address before: High tech Zone in Yunnan city of Yuxi province Chunhui road 653100 Yunnan Chemical Industry Co. Ltd.

Applicant before: Zhao Zhifeng

TA01 Transfer of patent application right
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170627

WD01 Invention patent application deemed withdrawn after publication