CN106884336B - A kind of banner fabric and preparation method thereof of the anti-gas shock of waterproof - Google Patents
A kind of banner fabric and preparation method thereof of the anti-gas shock of waterproof Download PDFInfo
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- CN106884336B CN106884336B CN201710266164.2A CN201710266164A CN106884336B CN 106884336 B CN106884336 B CN 106884336B CN 201710266164 A CN201710266164 A CN 201710266164A CN 106884336 B CN106884336 B CN 106884336B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/066—Silicon polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/146—Soilproof, soil repellent
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Abstract
The present invention relates to a kind of banner fabrics and preparation method thereof of the anti-gas shock of waterproof, it is characterized in that the banner fabric is using high-strength nylon66 fiber as substrate, waterproof coating is equipped on high-strength nylon66 fiber, the raw material composition of water-repellent paint used in waterproof coating are as follows: solvent type resin class silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~3% and surplus diluent；Pattern is printed on high-strength nylon66 fiber after coating.The fabric good water-proof effect, anti-gas shock is good, and printed color is uniform, clear patterns, color fastness are high, one side print can reach double-side pattern effect.
Description
Technical field
The present invention relates to banner fabric manufacture technology field, the banner fabric of specially a kind of anti-gas shock of waterproof and its
Production method.The flag of this method production can reach waterproof, anti-gas shock and bloth printing with double-sided effect.
Background technique
In the souvenir Anti-Japanese War Victory 70 anniversary military review on the 3rd of September in 2015, a pair of colors size point of helicopter suspension
Not Wei 6m × 9m and 6m × 7.5m, 160~180 kilometers/hour of flying speed.Allow national flag, army flag cannot be random when reviewing troops
It swings, stretch straight Founder, and at all without breakage after high-speed flight, be once a great problem in preparing of reviewing troops.High-speed flight
In, the red flag being suspended on helicopter cable wire will receive huge gas shock, can especially occur in red flag tail portion violent
Shake, generates " hitting wave " more than velocity of sound, and conventional use of banner fabric is far from satisfying requirement.Generally 30 minutes left sides of flight
The right side, just breakage can't bear in flag face.
Banner fabric substrate has cotton, silk, terylene, nylon, acrylic fibers etc. at present, and is commonly mostly plain cloth, wherein with
Nylon facing material is preferred, and with good strength, wearability etc., but the nylon facing material of different size, different tissues is in the ratio of strength to weight
Upper difference is larger, therefore selection is that flag makes an important step.The production method of double-side pattern flag mostly uses discharge to print greatly
Print process requirement plate-making is pulled out in flower process production, and to super large breadth, color is complicated, is difficult to control on brightly painted web process.
Present printing technique does not all carry out water-proofing treatment, cause rainfall or meet water sprinkle flag in situation be easy to soak, it is dirty；In high wind
Or special requirement blows hit in the case of flag at high speed, existing banner fabric shake is violent, badly broken, is difficult to keep original shape
State, so needing to improve the intensity of banner fabric, tear resistance, water proof anti-soil performance.Usual flag is a kind of means of publicity,
Therefore need color it is good, it is two-sided have a decalcomania effect, the prior art has not been able to accomplish only to carry out bloth printing and occur double
Face prints figuratum effect.
Summary of the invention
In view of the deficiencies of the prior art, the technical issues of present invention intends to solve is to provide a kind of anti-gas shock of waterproof
Banner fabric and preparation method thereof.The fabric good water-proof effect, anti-gas shock is good, printed color uniformly, clear patterns, color
Fastness is high, one side print can reach double-side pattern effect (i.e. pattern color difference in front and back sides is small), is mainly used for advertisement, flag, vertically hung scroll, account
Paulin, umbrella cloth etc. require the fabric stamp processing of waterproof, double-side pattern effect.The production method selects high-strength nylon66 fiber as base
Material, while the water-repellent paint based on solvent type resin class silicone oil is selected by a large amount of experiment, it can be effectively by nylon66 fiber
It is creatively combined with thermal transfer printing, realizes the effect of above-mentioned waterproof, anti-gas shock, and front and back sides pattern color difference is small, it should
Method and process is simple, without being transformed to loom and printing equipment, is easy to industrializing implementation.
The present invention solve the fabric technical problem the technical solution adopted is that: a kind of flag of anti-gas shock of waterproof is provided
Flag fabric, it is characterised in that nylon fiber long filament of the banner fabric using fineness no more than 100D practices calico as raw material, in nylon
It is equipped with waterproof coating, the raw material composition of water-repellent paint used in waterproof coating are as follows: solvent type resin class silicone oil 30~35%, toluene
25~30%, the diluent of curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~3% and surplus；After coating
Nylon practice calico on be printed on pattern；The spray rating of the fabric is 4 grades, and colorfastness to rubbing is 4-5 grades, and color fastness to light is not low
In 4 grades, splice mutual dyefastness 4-5 grades；The tearing brute force of the fabric is that nylon practices the three times of calico tearing brute force or more.
The present invention solve the production method technical problem the technical solution adopted is that: a kind of above-mentioned anti-gas of waterproof is provided
Flow impact banner fabric production method, the production method the following steps are included:
1) the nylon fiber long filament using fineness no more than 100D makes nylon fabric as raw material, then carries out practicing white and drying
Sizing obtains nylon and practices calico；
2) coating treatment:
Water-repellent paint, the raw material composition of the water-repellent paint are as follows: solvent type resin class silicone oil 30~35%, first are deployed first
Benzene 25~30%, curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~3% and surplus diluent；Then exist
The nylon that step 1) obtains, which is practiced, coats deployed water-repellent paint, then drying and shaping on calico, i.e., formed on the surface layer for practicing calico
Waterproof coating；
3) thermal transfer printing:
According to required flag pattern, designed decalcomania is printed onto transfer paper using disperse dyes, and
Clot obtains printing figuratum transfer paper；Again on heat-transfering printing machine by the pattern thermal transfer in transfer paper in coating treatment
On white silk calico afterwards, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min；
4) fabric that will be obtained after step 3) thermal transfer printing carries out clot to get the anti-gas shock of waterproof is arrived
Banner fabric.
The present invention also protects a kind of using flag made of above-mentioned fabric.
Compared with prior art, the beneficial effects of the present invention are:
Present invention substantive distinguishing features outstanding are: the fabric is equipped with waterproof coating, which not only acts as waterproof
Effect, moreover it is possible to the dyestuff color yield for improving nylon facing material improves the tear resistance of nylon facing material, make fabric encounter rainfall or
It meets water to sprinkle in situation, can not exclusively soak, not get wet, keep good extended state.The production method uses high-strength nylon
For fiber as substrate, the ratio of strength to weight is high, while selecting specific silicone oil water-repellent paint, makes to can be realized heat transfer on nylon facing material
Stamp, while the tear resistance of fabric entirety is significantly improved, overcoming cannot carry out in nylon fabric in the prior art
The technical problem of thermal transfer printing, and reach a face stamp after thermal transfer printing and double-side pattern effect occur.
Marked improvement of the invention is:
1. the service performance of banner fabric, the heat transfer of nylon facing material print can be significantly improved using production method of the present invention
Flower performance has reached good printing quality, waterproof effect after coating treatment, improves the tear resistance, ageing-resistant of fabric
Performance.
2. production method of the present invention uses thermal transfer printing technique, the thermal transfer temperature in strict control thermal transfer printing is
200 DEG C~240 DEG C, while strict control thermal transfer speed, make that fabric color yield is obviously improved, color fastness significantly improves, can obtain
To the effect of a face printed double-sided pattern, when making banner fabric, color fastness and color difference index are all satisfied national mark after printing and dyeing
Related request in standard, and thermal transfer printing process is easy to operate, does not need complicated plate-making, energy-saving and emission-reduction meet environmental protection and want
It asks.And production method of the present invention can be suitably used for the production of complicated, the brightly painted banner fabric of super large breadth, color.
3. after tested, the flag of production method production of the present invention is 160~180km/h, wind speed 8m/s in flying speed, fly
Normal use is remained under conditions of about 300 meters of row height, i.e. the tear resistance of banner fabric is stronger；It is waterproof, antifouling simultaneously,
Rainfall or chance water sprinkle flag in situation and are still able to maintain the expansion straight Founder of posture, ensure that the effect that flag is shown in the sky, mention
The use value of high flag.
Specific embodiment
The present invention will be further described with reference to embodiments.It should be understood that these embodiments are to be used to explain the present invention
Rather than the protection scope of limitation the claims in the present invention.Implementation condition used in the examples can be according to specific producer
Condition does further adjustment, and the implementation condition being not specified is usually the condition in routine experiment.
The banner fabric (abbreviation fabric) of the anti-gas shock of waterproof of the present invention is not more than 100D with fineness, and single wire fracture is strong
Degree is that the nylon fiber long filament of 5.0~9.0CN/dtex is raw material, practices in nylon and is equipped with waterproof coating, waterproof coating institute on calico
Formed with the raw material of water-repellent paint are as follows: solvent type resin class silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%,
The diluent of silane coupling agent 3~5%, catalyst 1~3% and surplus；It is white by the nylon white silk of thermal transfer printing after coating
Pattern is printed on cloth；The spray rating of the fabric is 4 grades, and colorfastness to rubbing is 4-5 grades, and color fastness to light is greater than 4 grades, and splicing is mutual
4-5 grades of dyefastness；The tearing brute force of the fabric is that nylon practices the three times of calico tearing brute force or more；The fabric bloth printing can
Obtain the effect of double-side pattern.
It is high-strength nylon 66 fiber, high-strength nylon 66 fiber that fabric of the present invention, which is further characterized by the nylon fiber,
With higher toughness, be conducive to the tear resistance for further increasing nylon fabric.
The production method (abbreviation production method or method) of the banner fabric of the above-mentioned anti-gas shock of waterproof includes following step
It is rapid:
1) fabric pre-processes:
Fineness is not more than 100D, and the nylon fiber long filament that single wire fracture intensity is 5.0~9.0CN/dtex is raw material, is adopted
With plain weave two-wire lattice weave, nylon fabric is made, then carries out the white and drying and shaping of conventional white silk, nylon is obtained and practices calico；
2) coating treatment:
Water-repellent paint, the raw material composition of the water-repellent paint are as follows: solvent type resin class silicone oil 30~35%, first are deployed first
Benzene 25~30%, curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~3% and surplus diluent；Then exist
The nylon that step 1) obtains, which is practiced, coats deployed water-repellent paint, then drying and shaping on calico, i.e., formed on the surface layer for practicing calico
Waterproof coating；The difference of the specific ingredient and content of the raw material composition of water-repellent paint can have shadow to the color of final stamp
It rings, coloured light also has a minor change, but all preferable in the color using this water-repellent paint stamp on the whole；
3) thermal transfer printing:
According to required flag pattern, using disperse dyes in 150~230 DEG C of sublimation characteristics by designed stamp
Pattern is printed onto transfer paper, if practicing calico breadth is less than flag pattern dimension, just needs for flag pattern to be divided into
Fritter is spliced into global pattern when sewing flag on graphic-print to fabric after segmentation again；Then clot obtains being printed on figure
The transfer paper of case；White silk calico on heat-transfering printing machine by the pattern thermal transfer in transfer paper after step 2) coating treatment again
On, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min, different thermal transfer temperature and speed
Setting, the shade of stamp can be had an impact；
4) fabric that will be obtained after step 3) thermal transfer printing carries out clot to get the anti-gas shock of waterproof is arrived
Banner fabric.
The fineness that production method of the present invention is further characterized by the high-strength nylon fiber long filament is 15D~70D, this
Fabric made of kind raw material is frivolous and the ratio of strength to weight is high.
The fabric construction that production method of the present invention is further characterized by nylon66 fiber fabric is plain weave two-wire lattice tissue, double
The area of each grid of line lattice is not more than 1 square centimeter, and the size of grid can be 2.5mm × 2.5mm, 3mm × 3mm, 4mm
× 4mm, 3mm × 5mm, 5mm × 5mm etc., grid size will affect tear resistance, and grid uses rib weave, form grid
Effect can significantly improve the tear resistance of fabric.
Production method of the present invention is further characterized by preferably 220~230 DEG C of the thermal transfer temperature.
It is white that production method of the present invention is further characterized by white silk of the pattern thermal transfer after coating treatment in transfer paper
In the one side of the waterproof coating of cloth.Production method of the present invention can be coated in coating treatment with single side, can also with dual coating,
The white silk calico of one side with waterproof coating carries out thermal transfer printing, and the front and back sides color difference of obtained fabric is smaller, color more light
It is bright.
The breadth of the banner fabric of the anti-gas shock of the waterproof that production method of the present invention is obtained through step 4) clot is not more than
1.9 rice.Specific breadth is related with the width of fabric woven design, depending on the width of coating processing, specific size with to be made
Size at flag finished product is related.If the flag size of production is especially huge, such as 6 × 9 meters of the national flag of reviewing troops, fabric breadth
Bigger, the road number of flag splicing is fewer.Currently, it is 3.2 meters that maximum breadth is processed in thermal transfer printing, fabric breadth maximum can be arrived
3.2 meters, but the maximum width of coating processing is 1.9 meters or so, so the maximum width of the method for the invention finished fabric is not
Greater than the maximum width of coating processing.The method of the invention is different from conventional rotary scream printing, PLATE SCREAM PRINTING, discharge printing,
It can be more flexible design design, flower pattern ruler width, color it is richer more true to nature.
The technological principle of production method of the present invention is: practicing calico to nylon before thermal transfer printing and carries out coating treatment, warp
Waterproof can be achieved the effect that by crossing material behind coating treatment, and can change nylon fabric molecule link number, significantly improve fabric
Color yield, dyestuff can effectively penetrate into the back side, achieve the effect that double-side pattern occurs in a face stamp.
Although production method of the present invention solidifies various influence factors by repetition test, it is determined that related process parameters,
In actual production because of ink-jet board difference, transfer interpreter temporary parking, the initial transfer state of booting and continuously transfer printing state etc.
Factor influence still has micro variation, so as to cause color difference.Using the flag same continuous air brushing of printing device, a migration volume
Paper corresponds to flag, and entire volume fabric has once printed when thermal transfer printing, and appropriate adjustment transfer speed, transfer temperature can mitigate
Color difference.The thermal transfer printing is exactly to be transferred to the pattern on transfer printing paper on fabric by heat transfer machine, wherein shifting
The production method of calico paper has numerial code spray drawing method, roller printing method etc., and the numerial code spray drawing method of use can produce various patterns
Banner fabric, and simple process is convenient.
Banner fabric made from production method of the present invention can form duplex pringing effect by a thermal transfer printing
Fruit, color yield reach 90% or more；Have the function of good water proof anti-soil, so that flag is coped with the bad weathers such as rainwater, significantly
The blowing-resistant for improving flag hits ability.The present invention can use nylon66 fiber of the fineness no more than 100D as raw material or use
Nylon 6 is raw material, and when selecting high-strength nylon66 fiber as raw material, fabric has higher intensity and tear resistance.System of the present invention
Make the fabric that method can be used to make various advertisement flags, various countries' national flag, coloured flag, sandy beach flag, Gua Qi, tent cloth, umbrella cloth, is applicable in
Range is wide.
Embodiment 1
The present embodiment makes jumbo red flag fabric, and specific production method is:
1) fabric pre-processes:
It using high-strength nylon 66 fiber long filament as raw material, is weaved using two-wire lattice plain weave, production nylon66 fiber fabric, then into
Row is conventional to practice white and drying and shaping, obtains nylon and practices calico；
2) coating treatment:
Formula components are mixed in proportion first to obtain water-repellent paint, the raw material composition of the water-repellent paint are as follows: molten
Dosage form resinae silicone oil 34%, toluene 26%, curing agent 0.8%, silane coupling agent 3.5%, catalyst 1.5% and surplus it is dilute
Release agent；Then deployed water-repellent paint is coated on the fabric that step 1) obtains, and is coated for single side, then drying and shaping, i.e.,
Waterproof coating is formed on the surface layer for practicing calico；Water-repellent paint needs to use in 24 hours after deployed；
3) thermal transfer printing:
According to the pattern of required jumbo red flag, designed decalcomania is printed onto transfer paper using disperse dyes
On, and clot, it obtains printing figuratum transfer paper；Pattern in transfer paper is aligned with the coat side of fabric, then in heat
On transfer printing machine by the pattern thermal transfer in transfer paper on the white silk calico after step 2) coating treatment, thermal transfer temperature is
230 DEG C, thermal transfer speed is 6m/min；
4) fabric that will be obtained after step 3) thermal transfer printing carries out clot to get the anti-gas shock of waterproof is arrived
Banner fabric, the present embodiment be required jumbo red flag fabric.
It is 32g/m that the high-strength nylon 66 fiber long filament of this in the present embodiment, which is square meter grammes per square metre,2Nylon66 fiber practice white silk tartan, carefully
Degree is 29D, and single wire fracture intensity is 7.5CN/dtex；Grid size is 2.5mm × 2.5mm.Figure when thermal transfer, in transfer paper
Case is imprinted in the one side of the waterproof coating of the white silk calico after coating treatment.
Jumbo red flag fabric made from above-mentioned production method is tested for the property, is detected by third party testing agency,
The tearing resistance of jumbo red flag fabric made from the present embodiment is significantly increased, and greatly improves fabric and resists air-flow and blows the energy hit
Power.Meanwhile the color fastness of fabric stamp can be significantly improved using this method, it realizes a face stamp and the effect of double-side pattern occurs
Fruit has a great deal of practical meanings for banner fabric.The spray rating of jumbo red flag fabric made from the present embodiment is 4
Grade, the colorfastness to rubbing of fabric are 4-5 grades, and color fastness to light is greater than 4 grades, splices 4-5 grades of mutual dyefastness (staining), front and back sides
4-5 grades of color difference.Result of practical application proves, the 6m × 9m flag made of the material is hung under helicopter, with 160~
180 kilometers/hour of speed flight Shi Changyue 2 hours, after flight, only generates about 3 × 5cm or so in the flag lower right corner
Flash.And the flag of conventional material in the market, comparable applications condition, flight about half an hour, flag just breakage fall four/
Three or so.Under drizzle or moderate rain meteorological condition, straight Founder is unfolded in helicopter suspension flight, flag face, and flag face itself is not soaked, no
Shirring, remaining a small amount of droplet can also be fallen after shaking from flag emaciated face.And the flag of other fabrics, comparable applications condition, flag face
It soaks, shirring.
Embodiment 2
The present embodiment makes a kind of banner fabric of anti-gas shock of waterproof, specific production method with embodiment 1, difference
Being in that the high-strength nylon 66 fiber long filament is square meter grammes per square metre in this present embodiment is 39g/m2Nylon66 fiber practice white silk tartan, fineness
For 30D；Grid size is 3 × 5mm；The raw material of the water-repellent paint forms are as follows: solvent type resin class silicone oil 32%, toluene
27%, the diluent of curing agent 0.8%, silane coupling agent 4%, catalyst 1.2% and surplus；Thermal transfer temperature is 223 DEG C, heat
Transfer speed is 5.6m/min.
The banner fabric of the anti-gas shock of waterproof made from the present embodiment is denoted as fabric A.To the mechanics of fabric A, waterproof, color
The performance indicators such as fastness are tested, as a result are as follows: (1) tearing brute force: through to 142N, broadwise 139N；(2) colorfastness to rubbing is 4-
5 grades；(3) front and back sides color difference is 4-5 grades；(4) spray rating is 4 grades.
Comparative example
Selected raw material and production method be with embodiment 2 in comparative example, the difference is that, painting is eliminated in the production process
Layer treatment process directly carries out thermal transfer printing technique, finished product fabric after step 1) processing, which is denoted as fabric
B。
Fabric A made from embodiment 2 and comparative example and fabric B is subjected to correlated performance test and comparison, after testing, fabric
A and fabric B the difference is that: (1) tearing brute force: the tearing brute force of fabric A is through to 142N, broadwise 139N；Tearing for fabric B is strong
Power is through to 20N, broadwise 19N；(2) colorfastness to rubbing: fabric A is 4-5 grades, and fabric B is 1-2 grades；(3) front and back sides color difference: face
Expect that A is 4-5 grades, fabric B is 3 grades.(4) fabric A spray rating is 4 grades, and fabric B spray rating is 1 grade.
In addition, (under the meteorological condition of drizzle or moderate rain, helicopter is flown with the speed of 160~180km/h under the same conditions
Row 2h) it makes a flight test, it is shaken acutely in the flag flight course of comparative example, sound is huge, and flag face is integrally soaked, and surface has
Large area shirring, though there is improvement after the exhibition of stretching, shirring is still obvious, has seriously affected the beauty of flag.And the flag of embodiment 2
Founder that flag airborne launch posture is straight, unfolded state is hardly influenced by rainy weather, and after flight, on inspection, flag face is not
It soaks, not shirring, remaining a small amount of droplet can also be fallen after shaking from flag emaciated face, and the pattern printed and dyed on red flag is in rainwash
Under, there is not the problems such as any dizzy dye, decoloration, colour fading, splicing mutually contaminate.
Embodiment 3
The present embodiment makes a kind of banner fabric of anti-gas shock of waterproof, specific production method with embodiment 1, difference
It is in and selects nylon 6 fiber long filament for raw material in this present embodiment, square meter grammes per square metre is 73g/m2, fineness 70D, grid size is
2×2mm。
The performance indicators such as mechanics, waterproof, the color fastness of banner fabric to the anti-gas shock of waterproof made from the present embodiment
It is tested, as a result are as follows: (1) tearing brute force: through to 213N, broadwise 204N；(2) colorfastness to rubbing is 4-5 grades；(3) front and back sides
Color difference is 4 grades；(4) spray rating is 4 grades；(5) 4 grades of color fastness to light.The tearing brute force of the fabric is practiced compared with the present embodiment nylon
The tearing brute force of calico (tearing brute force: is significantly promoted through having to 114N, broadwise 48.1N).
Embodiment 4
The present embodiment makes banner fabric, in coating treatment, carries out dual coating.
Embodiment 5
The present embodiment is a kind of advertisement flag of the anti-gas shock of waterproof, and having a size of 1.35m × 6m, the fabric of the advertisement flag is
The production method of embodiment 2 obtains.
The processes such as white silk according to the present invention is white, drying and shaping, clot are the prior art.
The present invention does not address place and is suitable for the prior art.
Claims (7)
1. a kind of banner fabric of the anti-gas shock of waterproof, it is characterised in that the banner fabric is not more than the nylon of 100D with fineness
Fiber filament is raw material, practices in nylon and is equipped with waterproof coating on calico, the raw material composition of water-repellent paint used in waterproof coating are as follows: molten
Dosage form resinae silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~
3% and surplus diluent；Nylon after coating, which is practiced, is printed on pattern on calico；The spray rating of the fabric is 4 grades, and rub color
Fastness is 4-5 grades, and color fastness to light is not less than 4 grades, splices mutual dyefastness 4-5 grades；The tearing brute force of the fabric is practiced for nylon
Twice or more of calico tearing brute force；
The production method of the banner fabric of the anti-gas shock of the waterproof, the production method the following steps are included:
1) fabric pre-processes:
Nylon fiber long filament using fineness no more than 100D makes nylon fabric as raw material, then carries out practicing white and drying and shaping, obtains
Practice calico to nylon；
2) coating treatment:
Water-repellent paint, the raw material composition of the water-repellent paint are as follows: solvent type resin class silicone oil 30~35%, toluene 25 are deployed first
~30%, the diluent of curing agent 0.5~1%, silane coupling agent 3~5%, catalyst 1~3% and surplus；Then in step
1) nylon obtained, which is practiced, coats deployed water-repellent paint, then drying and shaping on calico, i.e., form waterproof on the surface layer for practicing calico
Coating；
3) thermal transfer printing:
According to required flag pattern, designed decalcomania is printed onto transfer paper using disperse dyes, and clot,
It obtains printing figuratum transfer paper；Again by white silk of the pattern thermal transfer after coating treatment in transfer paper on heat-transfering printing machine
On calico, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min；
4) fabric that will be obtained after step 3) thermal transfer printing carries out clot to get the flag of the anti-gas shock of waterproof is arrived
Flag fabric.
2. the banner fabric of the anti-gas shock of waterproof according to claim 1, it is characterised in that the nylon fiber is height
Strong nylon 66 fiber.
3. banner fabric according to claim 1, it is characterised in that the fineness of the nylon fiber long filament is 15D~70D.
4. banner fabric according to claim 1, it is characterised in that the thermal transfer temperature is 220~230 DEG C.
5. banner fabric according to claim 1, it is characterised in that the pattern thermal transfer in transfer paper is after coating treatment
White silk calico waterproof coating one side on.
6. -5 any banner fabric according to claim 1, it is characterised in that the fabric construction of the nylon fabric is flat
Line two-wire lattice tissue.
7. a kind of flag, it is characterised in that the flag is made of fabric described in claim 1.
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| CN201710266164.2A CN106884336B (en) | 2017-04-21 | 2017-04-21 | A kind of banner fabric and preparation method thereof of the anti-gas shock of waterproof |
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| CN201710266164.2A CN106884336B (en) | 2017-04-21 | 2017-04-21 | A kind of banner fabric and preparation method thereof of the anti-gas shock of waterproof |
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| CN109371709A (en) * | 2018-09-28 | 2019-02-22 | 深圳特朗商实业有限公司 | Anti-dropout thickening agent and its preparation process on a kind of waterproof coating fabric |
| CN111851086A (en) * | 2020-07-06 | 2020-10-30 | 安徽拓扑数码新材料有限公司 | Production method of high-weather-resistance flag fabric |
| CN112339466A (en) * | 2020-11-07 | 2021-02-09 | 泗阳捷锋帽业有限公司 | Reflective film thermal transfer printing method |
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| US3922399A (en) * | 1974-06-21 | 1975-11-25 | Arnold G Ochsner | Dual surface textiles |
| CN101372813A (en) * | 2008-10-17 | 2009-02-25 | 仪征新天地织物面料实业有限公司 | Waterproof breathable environment-protective facing material and production method thereof |
| CN104499288A (en) * | 2014-11-30 | 2015-04-08 | 盐城市华普轻纺机械有限公司 | High-waterproof non-woven fabric for tent |
| CN104453350A (en) * | 2014-11-30 | 2015-03-25 | 盐城市华普轻纺机械有限公司 | Non-woven fabric for tent |
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