CN106884174A - A kind of industrial cleaning agent based on nanometer oyster shell whiting and preparation method thereof - Google Patents
A kind of industrial cleaning agent based on nanometer oyster shell whiting and preparation method thereof Download PDFInfo
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- CN106884174A CN106884174A CN201710086176.7A CN201710086176A CN106884174A CN 106884174 A CN106884174 A CN 106884174A CN 201710086176 A CN201710086176 A CN 201710086176A CN 106884174 A CN106884174 A CN 106884174A
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- oyster shell
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
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Abstract
The present invention provides a kind of industrial cleaning agent based on nanometer oyster shell whiting and preparation method thereof, including following weight portion composition：2 ~ 8 parts of 25 ~ 40 parts of oyster shell whiting of nanometer, 2 ~ 6 parts of alkali, 1 ~ 6 part of washing assisant, 0.1 ~ 1 part of preservative, 0.4 ~ 2 part of antirust agent, 0.2 ~ 1.6 part of essential oil, 30 ~ 50 parts of deionized water, 1 ~ 5 part of aminopterin and ethane thiol.Treated immersion bubble will be crushed after oyster shell whiting cleaning, drying and high-temperature calcination is expanded is finally mixed with remaining composition.Preservative, antirust agent, essential oil are added with the present invention makes cleaning agent form anti-corrosion, anti-corrosion, antifouling and fire-retardant protective film to scavenger surface in cleaning process; washing assisant, aminopterin and ethane thiol effectively lift cleaning efficiency and cleaning performance is better than prior art; easy to use, simple production process of the invention, can lift anti-corrosive properties, rust-preventing characteristic and the anti-flammability of metal and cleaning performance is excellent.
Description
Technical field
The invention belongs to industrial cleaning agent field, and in particular to a kind of industrial cleaning agent and its system based on nanometer oyster shell whiting
Preparation Method.
Background technology
The metal major part for industrially using at present is easier to get rusty, and metal surface dirt is more, due to metal
The factors such as environment, weather, the medium of contact of work cause metal to get rusty or surface sediment dirt, in order to extend metal
Service life and improve operating efficiency, it is necessary to cleaned using cleaning agent, industrially use for removing dirt
Chemistry or biological agent are referred to as industrial cleaning agent.
Prior art provides various cleaning agents, for example, Chinese invention granted patent document, a kind of industrial metal plate is clear
Public number of lotion preparation mandate：A kind of Industrial metal plate cleaner preparation methods of the B of CN 102995031, including with
Lower step：（1）Add 2.3-5.6% AEOs, 1.2-2.7% second by weight percentage successively in mixer
Alcohol, 0.5-1.3 % sodium metasilicate, 0.2-1.6 % citric acids, 1.1-2.0% Sodium Benzoates, 2.2-3.4% detergent alkylates
Sodium sulfonate, 0.3-0.9% sodium molybdates, 0.1-0.5% oleic acid, 0.2-0.5 disodium hydrogen phosphates, 1.2-6.6% ethylenediamine tetra-acetic acids,
3.1-3.6% BTAs, 2.5-3.5% isopropanols；Being eventually adding deionized water makes total weight percent be 100%；（2）
Stir to obtain cleaning agent finished product.Prepared cleaning agent can quickly remove the dirt of metal sheet surface, and will not corrode metallic plate,
The smooth light of the metal sheet surface after cleaning can be made, cleaning efficiency is more than 99%, effect is significant.
Prior art can be realized quickly removing metal surface dirt, and cleaning efficiency is higher, but antirust, anti-corrosion for metal
Performance boost aspect has been short of and cleaning performance has much room for improvement.
The content of the invention
The present invention provides a kind of industrial cleaning agent based on nanometer oyster shell whiting and its preparation side to solve above-mentioned technical problem
Method, can lift the anti-corrosive properties and rust-preventing characteristic of metal and cleaning performance is excellent.
The present invention is for the solution scheme taken of above-mentioned technical problem：A kind of industrial cleaning agent based on nanometer oyster shell whiting
It is made up of the composition of following weight portion：Nanometer 25 ~ 40 parts of oyster shell whiting, 2 ~ 6 parts of alkali, 1 ~ 6 part of washing assisant, 0.1 ~ 1 part of preservative,
2 ~ 8 parts of 0.4 ~ 2 part of antirust agent, 0.2 ~ 1.6 part of essential oil, 30 ~ 50 parts of deionized water, 1 ~ 5 part of aminopterin and ethane thiol.
Above-mentioned cleaning agent first adsorbs dirt simultaneously to the quick flocculating setting of dirt when in use, can be fast after flocculating setting
Speed allows dirt dissolving cleanser to be easily accomplished cleaning, and cleaning performance is excellent and due to prior art, and dirt residual is few,
The smooth non-corroding in metal surface after the completion of cleaning, cleaning agent can form many to being cleaned metal surface while cleaning
The fire-retardant, anti-corrosion of layer, the diaphragm of antirust, and cleanser's skin is not injured.
A kind of preparation process of the preparation method of the industrial cleaning agent based on nanometer oyster shell whiting is as follows：
1）Crush:Shell is cleaned using 0.5% hydrochloric acid, can effectively be removed shell surface dirt and be avoided impurity screening in subsequent treatment
The step of, after cleaning after clean with distilled water guarantee shell again without being dried after dirt, crushed using pulverizer and obtain 60 ~ 220 purposes
Oyster shell whiting；
2）Immersion:The oyster shell whiting of 60 ~ 220 mesh is immersed in treatment fluid, is soaked resolvability material in oyster shell whiting by treatment fluid
Bubble out clean to carry out filtering again；
3）Calcining：Oyster shell whiting is placed in preferably 1000 ~ 1500 DEG C carries out high-temperature calcination expanded preferably 4 ~ 8 hours, makes in oyster shell whiting
Combustible species burn off；
4）Mixing：Oyster shell whiting is crushed the nanometer oyster shell whiting of 100 ~ 200nm of acquisition again by pulverizer；By nanometer oyster shell whiting with
After deionized water mixing, then addition alkali, washing assisant, preservative, antirust agent, essential oil, aminopterin and ethane thiol are stirred successively
Mix and to form that mobility is strong and uniform cleaning agent.
Treatment fluid is made up of following component and its percentage：Ethanol 60 ~ 80%, 4- butanediols 10 ~ 20%, methyl acetate 15 ~
20%th, 1-hydroxy ethylidene-1,1-diphosphonic acid 2 ~ 7%, sodium carbonate 1 ~ 3%, cellulase 0.2 ~ 3%, sodium isoascorbate 0.08 ~ 0.5%, iso-amylene
Pyrophosphoric acid 0.1 ~ 2%, glyceraldehyde-3-phosphate 0.5 ~ 1.5%.The dissolubility and dissolution velocity for the treatment of fluid are higher, to can in oyster shell whiting
The solute effect of dissolved matter is excellent.
Washing assisant is made up of following component and its percentage：AEO AEO-9 10 ~ 20%, fatty alcohol
APEO AEO-3 10 ~ 20%, cocoanut fatty acid diethanolamide 3 ~ 5%, triethanolamine 0.5 ~ 2%, ethylene glycol monobutyl ether
3 ~ 5%, C12/C15 fatty alcohols PO-EO block polyethers 1 ~ 5%, ethanol 5 ~ 8%, 2- methyl -2,4- pentanediols 5 ~ 10%, sodium citrate 1
~ 4%, Purafect 4000L liquid basified proteases 0.5 ~ 1.5%, maleic acid-acrylic acid copolymer 0.5 ~ 2%, essence 0.1 ~
0.5%th, beta Amino isobutyric acid 1 ~ 1.5%, mevalonic acid 0.2 ~ 1.5%, deionized water 30 ~ 45%.Washing assisant effect is significantly improved,
After washing assisant is added to cleaning agent, cleaning agent dissolving spot, dirt-removing power tool are had a distinct increment.
Preservative is made up of following component and its percentage：Dichloromethane 10 ~ 25%, a fluorine dichloroethanes 1 ~ 20%, solvent
Oil 0.5 ~ 10%, tetrachloro-ethylene 50 ~ 70%, lead oxide 1 ~ 5% and potassium acid sulfate 1 ~ 3%.It is right in cleaning agent is to metal cleaning process
To prevent, metal from being corroded the preservative protective film of metal formation layer after cleaning and antiseptic effect is excellent.
Antirust agent is water-based antirust, forms the antirust of layer to metal during cleaning agent is cleaned to metal
Diaphragm is to prevent metal to be subject to corrosion after cleaning, and rust-proof effect is substantially lasting.
Essential oil is lemon, and cleaning agent cleaning performance in cleaning process is lifted and forms one layer in metal surface to be had
Antifouling fire-retardant diaphragm, and protection cleanser's skin is from cleaning agent chemistry injury.
Beneficial effect：Preservative, antirust agent, essential oil are added with using shell as raw material environmental protection, in cleaning agent to be made
Cleaning agent forms multilayer protective film in cleaning process to scavenger surface, and these protective films can lift the anti-of cleaned material
Corruption, anti-corrosion, antifouling and fire-retardant performance, washing assisant, aminopterin and ethane thiol effectively lift the cleaning effect of cleaning agent
Dirt residual is few after rate and cleaning, and cleaning performance is better than prior art, and easy to use, simple production process of the invention can be carried
Rise anti-corrosive properties, rust-preventing characteristic and the anti-flammability of metal and cleaning performance is excellent.
Specific embodiment
It is described in further detail with reference to embodiments：
Embodiment 1：
A kind of industrial cleaning agent based on nanometer oyster shell whiting and preparation method thereof, is made up of the composition of following weight portion：Namibe
25 ~ 40 parts of shell powder, 2 ~ 6 parts of alkali, 1 ~ 6 part of washing assisant, 0.1 ~ 1 part of preservative, 0.4 ~ 2 part of antirust agent, 0.2 ~ 1.6 part of essential oil,
2 ~ 8 parts of 30 ~ 50 parts of deionized water, 1 ~ 5 part of aminopterin and ethane thiol.
Above-mentioned cleaning agent first adsorbs dirt simultaneously to the quick flocculating setting of dirt when in use, can be fast after flocculating setting
Speed allows dirt dissolving cleanser to be easily accomplished cleaning, and cleaning performance is excellent and due to prior art, and dirt residual is few,
The smooth non-corroding in metal surface after the completion of cleaning, cleaning agent can form many to being cleaned metal surface while cleaning
The fire-retardant, anti-corrosion of layer, the diaphragm of antirust, and cleanser's skin is not injured.
A kind of preparation process of the preparation method of the industrial cleaning agent based on nanometer oyster shell whiting is as follows：
1）Crush:Shell is cleaned using 0.5% hydrochloric acid, can effectively be removed shell surface dirt and be avoided impurity screening in subsequent treatment
The step of, after cleaning after clean with distilled water guarantee shell again without being dried after dirt, crushed using pulverizer and obtain 60 ~ 220 purposes
Oyster shell whiting；
2）Immersion:The oyster shell whiting of 60 ~ 220 mesh is immersed in treatment fluid, is soaked resolvability material in oyster shell whiting by treatment fluid
Bubble out clean to carry out filtering again；
3）Calcining：Oyster shell whiting is placed in preferably 1300 DEG C carries out high-temperature calcination expanded preferably 6 hours, makes incendivity thing in oyster shell whiting
Matter burn off；
4）Mixing：Oyster shell whiting is crushed the nanometer oyster shell whiting of 100 ~ 200nm of acquisition again by pulverizer；By nanometer oyster shell whiting with
After deionized water mixing, then addition alkali, washing assisant, preservative, antirust agent, essential oil, aminopterin and ethane thiol are stirred successively
Mix and to form that mobility is strong and uniform cleaning agent.
Treatment fluid is made up of following component and its percentage：Ethanol 60 ~ 80%, 4- butanediols 10 ~ 20%, methyl acetate 15 ~
20%th, 1-hydroxy ethylidene-1,1-diphosphonic acid 2 ~ 7%, sodium carbonate 1 ~ 3%, cellulase 0.2 ~ 3%, sodium isoascorbate 0.08 ~ 0.5%, iso-amylene
Pyrophosphoric acid 0.1 ~ 2%, glyceraldehyde-3-phosphate 0.5 ~ 1.5%.The dissolubility and speed for the treatment of fluid are higher, to be can dissolve in oyster shell whiting
The solute effect of property material is excellent.
Washing assisant is made up of following component and its percentage：AEO AEO-9 10 ~ 20%, fatty alcohol
APEO AEO-3 10 ~ 20%, cocoanut fatty acid diethanolamide 3 ~ 5%, triethanolamine 0.5 ~ 2%, ethylene glycol monobutyl ether
3 ~ 5%, C12/C15 fatty alcohols PO-EO block polyethers 1 ~ 5%, ethanol 5 ~ 8%, 2- methyl -2,4- pentanediols 5 ~ 10%, sodium citrate 1
~ 4%, Purafect 4000L liquid basified proteases 0.5 ~ 1.5%, maleic acid-acrylic acid copolymer 0.5 ~ 2%, essence 0.1 ~
0.5%th, beta Amino isobutyric acid 1 ~ 1.5%, mevalonic acid 0.2 ~ 1.5%, deionized water 30 ~ 45%.Washing assisant effect significantly improves excellent
It is above-mentioned to effectively improve cleaning performance, washing assisant addition containing beta Amino isobutyric acid, mevalonic acid composition in prior art
After entering cleaning agent, cleaning agent dissolving spot, dirt-removing power tool are had a distinct increment.
Preservative is made up of following component and its percentage：Dichloromethane 10 ~ 25%, a fluorine dichloroethanes 1 ~ 20%, solvent
Oil 0.5 ~ 10%, tetrachloro-ethylene 50 ~ 70%, lead oxide 1 ~ 5% and potassium acid sulfate 1 ~ 3%.It is right in cleaning agent is to metal cleaning process
To prevent, metal from being corroded the preservative protective film of metal formation layer after cleaning and antiseptic effect is excellent.
Antirust agent is water-based antirust, forms the antirust of layer to metal during cleaning agent is cleaned to metal
Diaphragm is to prevent metal to be subject to corrosion after cleaning, and rust-proof effect is substantially lasting.
Essential oil is lemon, and cleaning agent cleaning performance in cleaning process is lifted and forms one layer in metal surface to be had
Antifouling fire-retardant diaphragm, and protection cleanser's skin is from cleaning agent chemistry injury.
Embodiment 2：
The present invention is from shell as raw material, such as shell such as mussel, oyster, conch, scallop, abalone, pearl shell.
A kind of preparation process of the preparation method of the industrial cleaning agent based on nanometer oyster shell whiting is as follows：
1）Crush:Shell is cleaned using 0.5% hydrochloric acid, can effectively be removed shell surface dirt and be avoided impurity screening in subsequent treatment
The step of, after cleaning after clean with distilled water guarantee shell again without being dried after dirt, crushed using pulverizer and obtain 60 ~ 220 purposes
Oyster shell whiting；
2）Immersion:The oyster shell whiting of 60 ~ 220 mesh is immersed in treatment fluid, is soaked resolvability material in oyster shell whiting by treatment fluid
Bubble out clean to carry out filtering again；
3）Calcining：Oyster shell whiting is placed in preferably 1300 DEG C carries out high-temperature calcination expanded preferably 6 hours, makes incendivity thing in oyster shell whiting
Matter burn off；
4）Mixing：Oyster shell whiting is crushed the nanometer oyster shell whiting of 100 ~ 200nm of acquisition again by pulverizer；By nanometer oyster shell whiting with
After deionized water mixing, then addition alkali, washing assisant, preservative, antirust agent, essential oil, aminopterin and ethane thiol are stirred successively
Mix and to form that mobility is strong and uniform cleaning agent.
Above-mentioned cleaning agent is made up of the composition of following weight portion：It is preferred that 35 parts of nanometer oyster shell whiting, preferably 5 parts of alkali, preferably washing
Wash 5 parts of auxiliary agent, preferably 0.8 part of preferred preservative, 2 parts of antirust agent, preferably 1.5 parts of essential oil, preferably 40 parts of deionized water, preferably ammonia
6 parts of 4 parts of base pterin and preferred ethane thiol.；
Above-mentioned cleaning agent first adsorbs dirt simultaneously to the quick flocculating setting of dirt when in use, can quickly make after flocculating setting
Dirt dissolving cleanser can be easily accomplished cleaning, and cleaning performance is excellent and due to prior art, and dirt residual is few, clear
The smooth non-corroding in metal surface after the completion of washing, cleaning agent can form multilayer resistance to being cleaned metal surface while cleaning
Combustion, anti-corrosion, the diaphragm of antirust, and cleanser's skin is not injured.
Treatment fluid is made up of following component and its percentage：Preferred alcohol 64.7%, preferably 4- butanediols 10%, preferably acetic acid
Methyl esters 15%, preferably 1-hydroxy ethylidene-1,1-diphosphonic acid 2%, preferably sodium carbonate 3%, preferably preferred cellulose enzyme 1.5%, sodium isoascorbate 0.3
%, preferably isopentenylpyrophosphate 2%, preferably glycerine aldehyde -3- phosphatase 11s .5%.The dissolubility and speed for the treatment of fluid are higher, to oyster shell whiting
The solute effect of interior resolvability material is excellent.
Washing assisant is made up of following component and its percentage：Preferred fat alcohol APEO AEO-9 10%, preferably fat
Fat alcohol APEO AEO-3 20%, preferably cocoanut fatty acid diethanolamide 5%, preferably triethanolamine 1%, preferably second two
Alcohol monobutyl ether 4%, preferably C12/C15 fatty alcohols PO-EO block polyethers 4%, preferred alcohol 7%, preferably 2- methyl -2,4- pentanediols
8%th, optimization citric acid sodium 3%, preferably Purafect 4000L liquid basified proteases 1%, preferably maleic acid-acrylic acid copolymer
1.5%th, preferably essence 0.5%, preferably beta Amino isobutyric acid 1%, preferably mevalonic acid 1%, preferably deionized water 33%.Washing assisant is imitated
Fruit significantly improves, and after washing assisant is added to cleaning agent, cleaning agent dissolving spot, dirt-removing power tool is had a distinct increment.
Preservative is constituted by with composition and its percentage：It is preferred that dichloromethane 15%, preferably a fluorine dichloroethanes 18%, preferably
Solvent naphtha 8%, preferably tetrachloro-ethylene 51%, preferably lead oxide 5% and preferably sulfuric acid hydrogen potassium 3%, in cleaning agent to metal cleaning process
In the preservative protective film of layer is formed to metal to prevent metal from being corroded and antiseptic effect is excellent after cleaning.
Antirust agent is water-based antirust, forms the antirust of layer to metal during cleaning agent is cleaned to metal
Diaphragm is to prevent metal to be subject to corrosion after cleaning, and rust-proof effect is substantially lasting.
Essential oil is lemon, and cleaning agent cleaning performance in cleaning process is lifted and forms one layer in metal surface to be had
Antifouling fire-retardant diaphragm, and protection cleanser's skin is from cleaning agent chemistry injury.
Using other shells in embodiment, can reach and embodiment identical technique effect.
The present invention is added with preservative, antirust agent, essential oil as raw material environmental protection, in cleaning agent using shell makes cleaning
Agent in cleaning process to scavenger surface formed multilayer protective film, these protective films can be lifted cleaned material anti-corrosion,
Anti-corrosion, antifouling and fire-retardant performance, washing assisant, aminopterin and ethane thiol effectively lifted cleaning agent cleaning efficiency and
Dirt residual is few after cleaning, and cleaning performance is better than prior art, and easy to use, simple production process of the invention can lift gold
The anti-corrosive properties of category, rust-preventing characteristic and anti-flammability and cleaning performance is excellent.
Embodiment of above is merely to illustrate the present invention, and not limitation of the present invention, the ordinary skill people of this area
Member, without departing from the spirit and scope of the present invention, can also make a variety of changes and modification.Therefore, it is all equivalent
Technical scheme fall within scope of the invention, scope of patent protection of the invention should be defined by the claims.
Claims (9)
1. a kind of industrial cleaning agent based on nanometer oyster shell whiting, it is characterised in that：Composition and its weight portion are：Nanometer oyster shell whiting 25
~ 40 parts, 2 ~ 6 parts of alkali, 1 ~ 6 part of washing assisant, 0.1 ~ 1 part of preservative, 0.4 ~ 2 part of antirust agent, 0.2 ~ 1.6 part of essential oil, deionization
2 ~ 8 parts of 30 ~ 50 parts of water, 1 ~ 5 part of aminopterin and ethane thiol.
2. a kind of preparation method of industrial cleaning agent based on nanometer oyster shell whiting according to claim 1, its preparation process
It is as follows：
1）Crush：Shell is dried after cleaning out, and is crushed after drying and is obtained oyster shell whiting；
2）Immersion：Oyster shell whiting is immersed in treatment fluid, is filtered after the completion of immersion and cleaned；
3）Calcining：Oyster shell whiting is carried out into high-temperature calcination expanded；
4）Mixing：Oyster shell whiting is crushed by pulverizer and obtains nanometer oyster shell whiting, nanometer oyster shell whiting and deionized water, alkali, washing
Auxiliary agent, preservative, antirust agent, essential oil, aminopterin and ethane thiol stir to form cleaning agent.
3. the preparation method of a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 2, it is characterised in that：
Described treatment fluid is made up of following component and its percentage：Ethanol 60 ~ 80%, 4- butanediols 10 ~ 20%, methyl acetate 15 ~
20%th, 1-hydroxy ethylidene-1,1-diphosphonic acid 2 ~ 7%, sodium carbonate 1 ~ 3%, cellulase 0.2 ~ 3%, sodium isoascorbate 0.08 ~ 0.5%, iso-amylene
Pyrophosphoric acid 0.1 ~ 2%, glyceraldehyde-3-phosphate 0.5 ~ 1.5%.
4. a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 1, it is characterised in that：The washing is helped
Agent is made up of following component and its percentage：AEO AEO-9 10 ~ 20%, AEO AEO-3
10 ~ 20%, cocoanut fatty acid diethanolamide 3 ~ 5%, triethanolamine 0.5 ~ 2%, ethylene glycol monobutyl ether 3 ~ 5%, C12/C15 fat
Alcohol PO-EO block polyethers 1 ~ 5%, ethanol 5 ~ 8%, 2- methyl -2,4- pentanediols 5 ~ 10%, sodium citrate 1 ~ 4%, Purafect
4000L liquid basified proteases 0.5 ~ 1.5%, maleic acid-acrylic acid copolymer 0.5 ~ 2%, essence 0.1 ~ 0.5%, β aminoisobutyrics
Acid 1 ~ 1.5%, mevalonic acid 0.2 ~ 1.5%, deionized water 30 ~ 45%.
5. a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 1, it is characterised in that：The preservative
It is made up of following component and its percentage：Dichloromethane 10 ~ 25%, a fluorine dichloroethanes 1 ~ 20%, solvent naphtha 0.5 ~ 10%, tetrachloro
Ethene 50 ~ 70%, lead oxide 1 ~ 5% and potassium acid sulfate 1 ~ 3%.
6. a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 1, it is characterised in that：The antirust agent
It is water-based antirust.
7. a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 1, it is characterised in that：The essential oil is lemon
Lemon essential oil.
8. a kind of preparation method of the industrial cleaning agent based on nanometer oyster shell whiting according to claim 2, it is characterised in that：Institute
Shell is using dries pulverizing after being cleaned with distilled water again after the cleaning of 0.5% hydrochloric acid in stating step 1.
9. the preparation method of a kind of industrial cleaning agent based on nanometer oyster shell whiting according to claim 2, it is characterised in that：
Oyster shell whiting is crushed to 100 ~ 200nm by nano grinder in the step 4.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710086176.7A CN106884174B (en) | 2017-02-17 | 2017-02-17 | A kind of industrial cleaning agent and preparation method thereof based on nanometer conch meal |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710086176.7A CN106884174B (en) | 2017-02-17 | 2017-02-17 | A kind of industrial cleaning agent and preparation method thereof based on nanometer conch meal |
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| CN106884174A true CN106884174A (en) | 2017-06-23 |
| CN106884174B CN106884174B (en) | 2019-09-10 |
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| WO2001067866A1 (en) * | 2000-03-13 | 2001-09-20 | Surfcera Co., Ltd. | Antibacterial agent comprising shell, method for purifying water by using the antibacterial agent and method for washing farm product by using the antibacterial agent |
| US20120165236A1 (en) * | 2010-07-23 | 2012-06-28 | Shoichi Nakamura | Cleansing agent |
| CN103897888A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Residue-free detergent |
| CN104877808A (en) * | 2015-06-26 | 2015-09-02 | 浙江海洋学院 | Method for preparing aquatic product cleaning agent based on shell powder |
| CN105087173A (en) * | 2015-09-11 | 2015-11-25 | 舟山赛莱特海洋科技有限公司 | Green sea fruit and vegetable antibacterial cleaning agent and preparation method thereof |
| CN105132208A (en) * | 2015-09-11 | 2015-12-09 | 舟山赛莱特海洋科技有限公司 | Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof |
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2017
- 2017-02-17 CN CN201710086176.7A patent/CN106884174B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001067866A1 (en) * | 2000-03-13 | 2001-09-20 | Surfcera Co., Ltd. | Antibacterial agent comprising shell, method for purifying water by using the antibacterial agent and method for washing farm product by using the antibacterial agent |
| US20120165236A1 (en) * | 2010-07-23 | 2012-06-28 | Shoichi Nakamura | Cleansing agent |
| CN103897888A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Residue-free detergent |
| CN104877808A (en) * | 2015-06-26 | 2015-09-02 | 浙江海洋学院 | Method for preparing aquatic product cleaning agent based on shell powder |
| CN105087173A (en) * | 2015-09-11 | 2015-11-25 | 舟山赛莱特海洋科技有限公司 | Green sea fruit and vegetable antibacterial cleaning agent and preparation method thereof |
| CN105132208A (en) * | 2015-09-11 | 2015-12-09 | 舟山赛莱特海洋科技有限公司 | Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof |
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|---|---|
| CN106884174B (en) | 2019-09-10 |
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