CN106883653A - A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof - Google Patents
A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof Download PDFInfo
- Publication number
- CN106883653A CN106883653A CN201710170896.1A CN201710170896A CN106883653A CN 106883653 A CN106883653 A CN 106883653A CN 201710170896 A CN201710170896 A CN 201710170896A CN 106883653 A CN106883653 A CN 106883653A
- Authority
- CN
- China
- Prior art keywords
- led
- dual cure
- moisture dual
- ultraviolet
- proofing coatings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to ultraviolet moisture dual cure three-proofing coatings of a kind of LED and preparation method thereof, belong to technical field of chemical paint.The ultraviolet moisture dual cure three-proofing coatings of LED of the invention, including following component by mass percentage：LED UV resins 20 40%, organic siliconresin 30 60%, reactive diluent 10 20%, cationic initiator 1 5%, fluorescent material 0.01 0.1%, silane coupler 1 5%, auxiliary agent 0.1 1%.The characteristics of ultraviolet moisture dual cure three-proofing coatings of LED of the invention have low energy rapid curing, high efficiency, reduce production cost；Additionally, the ultraviolet moisture dual cure three-proofing coatings of LED of the invention are also avoided that the defect that dash area or floor portions cannot solidify, the protective effect of three-proofing coating is improved.
Description
Technical field
The present invention relates to ultraviolet moisture dual cure three-proofing coatings of a kind of LED and preparation method thereof, belong to chemistry painting industry technology
Field.
Background technology
With the development of social economy and digital electronic goods, UV three-proofing coatings used for printed circuit board show quickly increasing
It is long., generally by polymerized monomer, light trigger, polymerization inhibitor etc. into being grouped into, it is in ultraviolet (UV) light action for traditional UV three-proofing coatings
Under can rapid curing, so as to printed circuit board surface formed protective layer.UV-curing technology is described as " 5E " technology, its
There is environmental protection, energy-conservation, drying time is short, glossiness is good, have a wide range of application.But, traditional UV high-pressure sodium lamps are present
Short life (generally only 1000-2000 hours), power consumption is high, and ozone can be produced during radiant light photograph, and in printing
The temperature that thing surface produces is up to 50 DEG C with first-class defect, limits the application of some thermo-responsive base materials, and tie for solid
The complicated circuit board of structure due to UV irradiate less than structure can not carry out solidifying the use that further limit UV three-proofing coatings.
LED ultraviolet sources are a kind of low energy curing light sources, its transmitting Single wavelength ultraviolet light 365nm, 375nm,
385nm、395nm、405nm.Compared to traditional UV high-pressure sodium lamps, the advantage of LED ultraviolet sources is：Long service life, reaches
By 15000-20000 hours；The power consumption of 80-90% can be saved；Ozone is not produced in Radiation Curing；Can effectively control
Stock surface temperature is below 40 DEG C.But, LED ultraviolet sources directly be applied into traditional UV three-proofing coatings carry out light to consolidate
Change, also there is the defects such as slow curing rate, dry difficulty, resist blocking and that poor performance, the high speed printing for not meeting printed circuit board (PCB) will
Ask；And the absorption difference under the ultraviolet launch wavelengths of LED of the light trigger in tradition UV three-proofing coatings, therefore, limit LED ultraviolet
Popularization and application of the photocuring in UV three-proofing coatings.
The content of the invention
It is double it is an object of the invention to provide a kind of ultraviolet moisture of the LED of environment-friendly high-efficiency in order to solve the defect of prior art
Solidify three-proofing coating and preparation method thereof again.
It is a further object to provide a kind of three-proofing coating of the ultraviolet moisture dual cures of LED, existing UV tri- is solved
Anti- paint can not provide effectively protection and because the solidification process of photocuring system is by light-initiated on complicated type wiring board
, shape, thickness for solidfied material, color have certain limitation, the shortcoming that three-proofing coating cannot solidify in dash area, in purple
Even outer light is difficult to the region irradiated, faint ultraviolet light also can solidify it, and be solidified by moisture-crosslinking, so that real
Apply the protective effect to various complicated type wiring boards.
The purpose of the present invention is achieved through the following technical solutions：
A kind of ultraviolet moisture dual cure three-proofing coatings of LED, including following component by mass percentage：The ultraviolet trees of LED
Fat 20-40%, organic siliconresin 30-60%, reactive diluent 10-20%, cationic initiator 1-5%, fluorescent material 0.01-
0.1%th, silane coupler 1-5%, auxiliary agent 0.1-1%.
Preferably, described LED UV resins are LED 9071 (Guangzhou Wuxing Material Technology Co., Ltd.), LED 9400
(Guangzhou Wuxing Material Technology Co., Ltd.), ZC7616 (Zi Cai Chemical Co., Ltd.s of Kaiping City), HU0037 (Guangdong sky brightness green woods
Material Co., Ltd) in one or more mixture.
Preferably, the organic siliconresin is neat silicone, epoxy modified silicone resin, acryl-modified silicone resin tree
One or more mixture in fat, silicon modified polyurethane acrylic acid.
Preferably, the reactive diluent is three glycerine diacrylates (TPGDA), DPG acrylate
(DPGDA), ethoxyquin -2- methyl-1,3-propanediols diacrylate (MPD2EODA), tetrahydrofuran acrylate (TFMA),
1,6- hexanediyl esters (HDDA), the third oxidation glycerol triacrylate (G3POTA), isobornyl acrylate
(IBOA), one kind in isobornyl methacrylate (IBOMA), ethoxyquin Glycerin triacrylate (TMP3EOTA)
Or two or more mixtures.
Preferably, the cationic initiator is mixed type triaryl hexafluorophosphoric acid sulfonium salt cationic initiator (VL-
3090), the fluoro- 3- pyrroles's phenyl titanocenes (784) of double 2,6- bis-, 4- (thiophenyl) phenyl diphenyl sulphur hexafluorophosphate, benzene
Double (2,4,6- trimethylbenzoyls) phosphine oxides (819) of base, 2- methyl -2- (4- first dredges base phenyl) -2 morpholinyl -1- acetone
(907), 2- hydroxy-methyls phenyl-propane -1- ketone (1173), 1- hydroxy-cyclohexyls phenyl ketone (184), benzoin dimethylether
(BDK), one or more the mixture in benzophenone (BP), the diphenyl phosphine oxides of 2,4,6- tri- (TPO).
Preferably, the fluorescent material is in distyryl biphenyl class (CBS) and double triazine amino-stilbenes class (33#)
One or two mixtures.
Preferably, the silane coupler is MTMS, MTES, methacryloxypropyl
In base propyl trimethoxy silicane, vinyltrimethoxy silane, VTES, aminopropyl triethoxysilane
One or more mixture.
Preferably, the auxiliary agent includes levelling agent and defoamer.
It is further preferred that the levelling agent includes the one kind in dimethyl silicone polymer, polyester resin change properties of organic silicon oxygen silicon
Or two kinds of mixture；The defoamer is saturated alcohols, fatty alcohol, fatty acid alcohol, higher fatty acid metal soap, sulfonated oil or has
One or more mixture in machine silicone oil.
The preparation method of the above-mentioned ultraviolet moisture dual cure three-proofing coatings of LED, comprises the following steps：
(1) will cationic initiator, fluorescent material, reactive diluent add a mixing bowl in, stirred under 300 revs/min to
Dissolving；
(2) LED UV resins, organic siliconresin, silane coupler, auxiliary agent are sequentially added, in 800 revs/min of rotating speed
Stirring 30min, you can the ultraviolet moisture dual cure three-proofing coatings of LED of the invention are obtained.
Beneficial effects of the present invention：
There is the ultraviolet moisture dual cure three-proofing coatings of LED of the invention low energy rapid curing, high efficiency, reduction to be produced into
This characteristics of；Additionally, the ultraviolet moisture dual cure three-proofing coatings of LED of the invention are also avoided that dash area or floor portions cannot
The defect of solidification, improves the protective effect of three-proofing coating.
Specific embodiment
With reference to specific embodiment, the invention will be further described.Following examples are only used for clearly illustrating
Technical scheme, and can not limit the scope of the invention.
Embodiment 1
A kind of ultraviolet moisture dual cure three-proofing coatings of LED, by weight percentage by 5% mixed type triaryl hexafluorophosphoric acid
Sulfonium salt cationic initiator (VL-3090), 0.01% distyryl biphenyl class (CBS), 15% 3 glycerine diacrylate
Ester (TPGDA) is added in a mixing bowl, and stirring is to dissolving under 300 revs/min of rotating speed, then sequentially adds by weight percentage
The resins of 32.49%LED 9071,45% epoxy modified silicone resin, 2% MTMS, 0.25% poly dimethyl
Siloxanes and 0.25% organic silicone oil, are stirred 30 minutes with 800 revs/min of rotating speed, you can the ultraviolet tides of LED of the invention are obtained
Gas dual cure three-proofing coating.
Embodiment 2
A kind of ultraviolet moisture dual cure three-proofing coatings of LED, by weight percentage by the 5% pair of fluoro- 3- pyrroles's benzene of 2,6- bis-
Base titanocenes (784), 0.01% pair of triazine amino-stilbene class (33#), 15% ethoxyquin -2- methyl-1,3-propanediols two
Acrylate (MPD2EODA) add a mixing bowl in, stirred to dissolving with 300 revs/min of rotating speed, then by weight percentage according to
Secondary addition 20%LED 9400 resins, 57.49% acryl-modified silicone resin resin, 2% methacryloxypropyl front three
TMOS, 0.25% polyester resin change properties of organic silicon oxygen silicon and 0.25% higher fatty acid metal soap, with 800 revs/min of rotating speed
Stirring 30 minutes, you can the ultraviolet moisture dual cure three-proofing coatings of LED of the invention are obtained.
Embodiment 3
A kind of ultraviolet moisture dual cure three-proofing coatings of LED, by weight percentage by 5%4- (thiophenyl) phenyl diphenyl
Sulphur hexafluorophosphate, 0.01% pair of triazine amino-stilbene class (33#), 10% tetrahydrofuran acrylate (TFMA) are added
In a mixing bowl, stirring is to dissolving under 300 revs/min of rotating speeds, then sequentially adds 37.49%ZC7616 trees by weight percentage
Fat, 45% silicon modified polyurethane acrylic acid, 2% vinyltrimethoxy silane, 0.25% dimethyl silicone polymer and 0.25%
Fatty acid alcohol, is stirred 30 minutes with 800 revs/min of rotating speed, you can the ultraviolet moisture dual cures three of LED of the invention are obtained and prevent
Paint.
Embodiment 4
A kind of ultraviolet moisture dual cure three-proofing coatings of LED, by weight percentage by double (2,4, the 6- trimethyls of 5% phenyl
Benzoyl) phosphine oxide (819), 0.01% distyryl biphenyl class (CBS), the acrylic acid of 20% ethoxyquin Glycerin three
Ester (TMP3EOTA) is added in a mixing bowl, and stirring is to dissolving under 300 revs/min of rotating speeds, then sequentially adds by weight percentage
37.49%HU0037 resins, 35% neat silicone, 2% aminopropyl triethoxysilane, 0.25% polyester resin change properties of organic silicon oxygen silicon
With 0.25% sulfonated oil, stirred 30 minutes with 800 revs/min of rotating speed, you can the ultraviolet moisture of LED of the invention is obtained dual solid
Change three-proofing coating.
Comparative example
In the case of not containing the organic siliconresin of energy moisture solidification and being unable to the LED resins of low energy solidification, one is prepared
Plant UV solidification three-proofing coatings.A kind of LED ultra-violet curings three-proofing coating, by weight percentage by 5%2- hydroxy-methyls phenyl-propane-
1- ketone (1173), 0.01% distyryl biphenyl class (CBS), 20% ethoxyquin Glycerin triacrylate
(TMP3EOTA) in, stirring is to dissolving under 300 revs/min of rotating speed, then sequentially adds 57.49% poly- ammonia by weight percentage
Ester acrylic resin, 5% pure third resin, 10% fluorine-silicon modified acrylic resin, 2% aminopropyl triethoxysilane, 0.25% gather
Ester modified organic silica silicon and 0.25% sulfonated oil, are stirred 30 minutes with 800 revs/min of rotating speed, and a kind of UV solidifications three are obtained
Anti- paint.
Comparative example and the three-proofing coating of comparative example, as a result such as following table：The performance indications of UV three-proofing coatings
The three-proofing coating of comparative example and embodiment all has good salt spray resistance and volume resistance high, and wherein embodiment has more
Good tensile strength effect, curing depth is high, curing rate is fast, the low feature of solidification energy, and because not contained in system
Its environmental-protecting performance of phosphorus flame retardant is more preferable, can be widely used for electronic component, integrated circuit, Electronic Packaging, LED encapsulation, printing electricity
In the production such as road plate, while wiring board reliability and service life can be improved.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert this
Invention is confined to these specific embodiments.For general technical staff of the technical field of the invention, do not departing from
On the premise of present inventive concept, some simple deduction or replace can also be made, be regarded as belonging to protection model of the invention
Enclose.
Claims (9)
1. ultraviolet moisture dual cure three-proofing coatings of a kind of LED, it is characterised in that comprising following component by mass percentage：
LED UV resins 20-40%, organic siliconresin 30-60%, reactive diluent 10-20%, cationic initiator 1-5%, fluorescence
Powder 0.01-0.1%, silane coupler 1-5%, auxiliary agent 0.1-1%.
2. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the LED UV resins
It is one or more the mixture in LED 9071, LED 9400, ZC7616, HU0037.
3. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the organic siliconresin
It is the one kind in neat silicone, epoxy modified silicone resin, acryl-modified silicone resin resin, silicon modified polyurethane acrylic acid
Or two or more mixtures.
4. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the reactive diluent
It is three glycerine diacrylates (TPGDA), DPG acrylate (DPGDA), ethoxyquin -2- methyl-1,3-propanediols
Diacrylate (MPD2EODA), tetrahydrofuran acrylate (TFMA), 1,6- hexanediyl esters (HDDA), the third oxidation
Glycerol triacrylate (G3POTA), isobornyl acrylate (IBOA), isobornyl methacrylate (IBOMA), ethoxy
Change one or more the mixture in Glycerin triacrylate (TMP3EOTA).
5. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the cation triggers
Agent is mixed type triaryl hexafluorophosphoric acid sulfonium salt cationic initiator (VL-3090), the fluoro- cyclopentadienyls of 3- pyrroles's phenyl two of double 2,6- bis-
Double (2,4,6- trimethylbenzoyls) phosphine oxides of titanium (784), 4- (thiophenyl) phenyl diphenyl sulphur hexafluorophosphate, phenyl
(819), 2- methyl -2- (4- first dredges base phenyl) -2 morpholinyl -1- acetone (907), 2- hydroxy-methyl phenyl-propane -1- ketone
(1173), 1- hydroxy-cyclohexyls phenyl ketone (184), benzoin dimethylether (BDK), benzophenone (BP), the hexichol of 2,4,6- tri-
One or more mixture in base phosphine oxide (TPO).
6. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the fluorescent material is two
One or two mixtures in substitutedstyrylbipcompounds (CBS) and double triazine amino-stilbenes class (33#).
7. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the silane coupler
It is MTMS, MTES, methacryloxypropyl trimethoxy silane, vinyl front three
One or more mixture in TMOS, VTES, aminopropyl triethoxysilane.
8. ultraviolet moisture dual cure three-proofing coatings of LED according to claim 1, it is characterised in that the auxiliary agent includes stream
Flat agent and defoamer, the levelling agent include dimethyl silicone polymer, polyester resin change properties of organic silicon oxygen silicon in one or two
Mixture；The defoamer is in saturated alcohols, fatty alcohol, fatty acid alcohol, higher fatty acid metal soap, sulfonated oil or organic silicone oil
One or more mixture.
9. the preparation method of the ultraviolet moisture dual cure three-proofing coatings of LED according to claim any one of 1-9, its feature exists
In comprising the following steps：
(1) by cationic initiator, fluorescent material, reactive diluent addition a mixing bowl, stirring is extremely dissolved under 300 revs/min；
(2) LED UV resins, organic siliconresin, silane coupler, auxiliary agent are sequentially added, is stirred in 800 revs/min of rotating speeds
30min, you can the ultraviolet moisture dual cure three-proofing coatings of LED of the invention are obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710170896.1A CN106883653A (en) | 2017-03-21 | 2017-03-21 | A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710170896.1A CN106883653A (en) | 2017-03-21 | 2017-03-21 | A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106883653A true CN106883653A (en) | 2017-06-23 |
Family
ID=59180794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710170896.1A Pending CN106883653A (en) | 2017-03-21 | 2017-03-21 | A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106883653A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066539A (en) * | 2019-05-27 | 2019-07-30 | 邱木生 | A kind of UVLED three proofings environmental protection paint and preparation method thereof |
| CN113444384A (en) * | 2021-07-21 | 2021-09-28 | 深圳市希顺有机硅科技有限公司 | UV-moisture dual-curing three-proofing paint and preparation method and application thereof |
| CN114409905A (en) * | 2022-01-21 | 2022-04-29 | 青岛科技大学 | Acrylate modified organic silicon resin and application thereof in UV/moisture dual-curing organic silicon three-proofing paint |
| CN115651498A (en) * | 2022-10-19 | 2023-01-31 | 深圳职业技术学院 | Novel environment-friendly water-based three-proofing paint and preparation method and construction process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559121A (en) * | 2012-02-29 | 2012-07-11 | 北京海斯迪克新材料有限公司 | Ultraviolet (UV)/moisture dual-cured laminated adhesive and preparation method thereof |
| CN104804491A (en) * | 2014-01-24 | 2015-07-29 | 程威军 | High-temperature resistance UV and moisture double-curing three-proofing lacquer |
-
2017
- 2017-03-21 CN CN201710170896.1A patent/CN106883653A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559121A (en) * | 2012-02-29 | 2012-07-11 | 北京海斯迪克新材料有限公司 | Ultraviolet (UV)/moisture dual-cured laminated adhesive and preparation method thereof |
| CN104804491A (en) * | 2014-01-24 | 2015-07-29 | 程威军 | High-temperature resistance UV and moisture double-curing three-proofing lacquer |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066539A (en) * | 2019-05-27 | 2019-07-30 | 邱木生 | A kind of UVLED three proofings environmental protection paint and preparation method thereof |
| CN113444384A (en) * | 2021-07-21 | 2021-09-28 | 深圳市希顺有机硅科技有限公司 | UV-moisture dual-curing three-proofing paint and preparation method and application thereof |
| CN114409905A (en) * | 2022-01-21 | 2022-04-29 | 青岛科技大学 | Acrylate modified organic silicon resin and application thereof in UV/moisture dual-curing organic silicon three-proofing paint |
| CN115651498A (en) * | 2022-10-19 | 2023-01-31 | 深圳职业技术学院 | Novel environment-friendly water-based three-proofing paint and preparation method and construction process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106883653A (en) | A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof | |
| CN104789039B (en) | A kind of interior raw type frosting effect glass ink and the method that frosting effect product is produced using it | |
| CN106752785B (en) | Aqueous UV silver powder coating and preparation method thereof | |
| CN103980812B (en) | A kind of UV-LED photocureable coating and preparation method thereof | |
| CN101747594B (en) | Epoxy acrylate prepolymer resin and preparation method thereof and application in photocurable coating | |
| CN105062405B (en) | Cover-plate glass base material cures no-solvent type sensitive transfer glue and preparation method thereof with LED light | |
| CN102585691B (en) | Ultraviolet-cured hydrophilic coating composition and preparation method thereof | |
| CN104710548A (en) | 3D printing core material | |
| CN102559121A (en) | Ultraviolet (UV)/moisture dual-cured laminated adhesive and preparation method thereof | |
| CN102532434B (en) | UV (Ultraviolet)/moisture double cured silicon rubber and preparation method thereof | |
| CN104946008B (en) | LED UV photocuring solder masks and preparation method thereof | |
| CN103044996A (en) | Solvent-free ultraviolet (UV) curing photodiffusion coating material, preparation method and application of solvent-free UV curing photodiffusion coating material | |
| CN103045015A (en) | Liquid photo-imageable alkali developable and anodizing resistant ink and preparation method thereof | |
| CN103540240A (en) | UV (Ultraviolet)-compound laser coating composition | |
| CN104179065B (en) | A kind of impermeable UV silk-screen paper gloss oil and preparation method thereof | |
| CN104804491A (en) | High-temperature resistance UV and moisture double-curing three-proofing lacquer | |
| CN111117341B (en) | Preparation method of UV ink film | |
| CN103232829A (en) | Light-moisture dual-curing adhesive | |
| CN105131849A (en) | Production method of ultraviolet light curing pressure-sensitive adhesive film | |
| CN103112222B (en) | Polyaniline and carbon fiber blanket composite screening material with wave absorbing function and preparation method thereof | |
| CN109897509A (en) | A kind of UV photocureable coating for aluminum-based copper-clad plate | |
| CN102719175A (en) | Adhesive-label transfer-printing composition as well as preparation method and application thereof | |
| CN102898878B (en) | Electron beam radiation cured coating of low cost, high adhesive force and preparation method thereof | |
| CN104327593A (en) | UV-curable strippable ink as well as production method and construction method of UV-curable strippable ink | |
| CN106366756A (en) | Photo-curing printing ink composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170623 |
|
| RJ01 | Rejection of invention patent application after publication |