CN106863953B - A kind of tempered glass - Google Patents

A kind of tempered glass Download PDF

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Publication number
CN106863953B
CN106863953B CN201710115086.6A CN201710115086A CN106863953B CN 106863953 B CN106863953 B CN 106863953B CN 201710115086 A CN201710115086 A CN 201710115086A CN 106863953 B CN106863953 B CN 106863953B
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CN
China
Prior art keywords
layer
glass
toughened glass
tempered glass
perspex
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201710115086.6A
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Chinese (zh)
Other versions
CN106863953A (en
Inventor
刘杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Fly New Materials Co Ltd
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Zhejiang Fly New Materials Co Ltd
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Filing date
Publication date
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Priority to CN201710115086.6A priority Critical patent/CN106863953B/en
Publication of CN106863953A publication Critical patent/CN106863953A/en
Application granted granted Critical
Publication of CN106863953B publication Critical patent/CN106863953B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56Damping, energy absorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to glass technology fields, and in particular to a kind of tempered glass.Adhesive layer including compound steel glassy layer and for connecting each toughened glass layer, the thickness proportion of compound steel glass is 1:3-10:0.5-2, between each toughened glass layer or outside is equipped at least one layer of perspex layer, the thickness ratio of the toughened glass layer of the perspex layer and outer layer is 1:3-5, is additionally provided at least one layer of conductive layer in each toughened glass layer.Tempered glass of the invention is by combining it with multilayered structure, and with polyester buffer layer auxiliary between multilayer, improve the toughness of entire tempered glass, to reduce the generation of the self-destruction phenomenon of tempered glass caused by the external force of part, the tempered glass has excellent bending resistance anti-seismic performance, meanwhile also added conductive layer and hollow layer in the tempered glass, so that its cooperation be made to have reached corresponding function.

Description

A kind of tempered glass
Technical field
The present invention relates to glass technology fields, and in particular to a kind of tempered glass.
Background technique
Tempered glass (Tempered glass/Reinforced glass) belongs to safety glass, and tempered glass is in fact A kind of prestressed glass forms pressure in glass surface and answers for the intensity for improving glass usually using method chemically or physically Power, glass bears to offset skin stress first when external force, to improve bearing capacity, reinforcing glass itself anti-wind pressure is trembled with fear Heat, impact etc..It also has the following characteristics that safety, and when glass is destroyed by external force, fragment can be at similar cellular The broken little particle in obtuse angle, is not easy to cause serious injury human body.The tempered glass impact strength of high intensity, condition of equivalent thickness is general 3-5 times of logical glass, bending strength is 3-5 times of simple glass.Thermal stability, tempered glass have good thermal stability, The temperature difference that can be born is 3 times of simple glass, can bear 300 DEG C of difference variation.Meanwhile intensity is improved compared with simple glass Several times (bending resistance), bearing capacity increase improve frangible property, are in the fractionlet without acute angle tempered glass destroys, right The injury of human body significantly reduces.
But the tempered glass of existing traditional structure, structure is single not reasonable, in use usually due to unreasonable Structure design there is " self-destruction " phenomenon (service life is short), while the bending resistance anti-seismic performance of current tempered glass is poor, It is not able to satisfy existing construction standard requirements gradually.
Summary of the invention
The purpose of the present invention is to solve the above problems, provide a kind of tempered glass.
In order to achieve the above object of the invention, the invention adopts the following technical scheme:
A kind of tempered glass, the adhesive layer including compound steel glassy layer and for connecting each toughened glass layer, compound steel The thickness proportion for changing glass is 1:3-10:0.5-2, and between each toughened glass layer or outside is equipped at least one layer of organic glass The thickness ratio of the toughened glass layer of layer, the perspex layer and outer layer is 1:3-5, is additionally provided at least one in each toughened glass layer Layer conductive layer.
Conductive layer is bonded formation one with adhesive layer 2 first, is then bonded again to toughened glass layer.About right click glass The optimal selection of glass layer is to be equipped with one layer of perspex layer 3 in the outside of each toughened glass layer 1
The tempered glass is coupled hardness with softness, and toughness is more sufficient, be can reduce self-destruction phenomenon, is improved service life.
As a preferred option, hollow layer is equipped between the compound steel glassy layer.
As a preferred option, polyester buffer layer is equipped between the compound steel glassy layer.
As a preferred option, the polyester buffer layer with a thickness of 0.5-3mm.
As a preferred option, the conductive layer with a thickness of 0.05-0.2mm.
As a preferred option, the adhesive layer is PVB film layers.
As a preferred option, bonding is equipped with one layer of perspex layer in the toughened glass layer in the outside.
As a preferred option, it is coated with zinc oxide film in the perspex layer or outermost toughened glass layer, aoxidized Zinc layers are equipped with silicon nitride layer.
As a preferred option, it is additionally provided with hydrophobic coating.
Compared with prior art, the present invention beneficial effect is: tempered glass of the invention by by it with multilayered structure group It closes, and the toughness of entire tempered glass is improved, to reduce caused by the external force of part with polyester buffer layer auxiliary between multilayer The generation of the self-destruction phenomenon of tempered glass, the tempered glass have excellent bending resistance anti-seismic performance, meanwhile, in the tempered glass It also added conductive layer and hollow layer, so that its cooperation be made to have reached corresponding function.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of the embodiment of the present invention 2;
Fig. 3 is the structural schematic diagram of the embodiment of the present invention 3;
Fig. 4 is the structural schematic diagram of the embodiment of the present invention 4;
Fig. 5 is the structural schematic diagram of the embodiment of the present invention 5.
In figure: 1 toughened glass layer, 2 adhesive layers, 3 perspex layers, 4 conductive layers, 5 hollow layers, 6 polyester buffer layers, 7 oxygen Change zinc layers, 8 silicon nitride layers, 9 hydrophobic coatings.
Specific embodiment
Below by specific embodiment the technical scheme of the present invention will be further described explanation.
If raw material employed in the embodiment of the present invention is raw material commonly used in the art without specified otherwise, implement Method employed in example, is the conventional method of this field.
Embodiment 1:
A kind of tempered glass, the adhesive layer 2 including compound steel glassy layer 1 and for connecting each toughened glass layer 1, bonding Layer 2 is PVB film layers, and the thickness proportion of compound steel glass is 1:3-10:0.5-2, is equipped in the outside of each toughened glass layer 1 The thickness ratio of the toughened glass layer 1 of one layer of perspex layer 3, perspex layer 3 and outer layer is 1:3-5, the steel of outer layer here Change one layer in that two layers of the two sides in glass i.e. three layer.It is additionally provided with one layer of conductive layer 4 between each toughened glass layer 1, leads Electric layer 4 with a thickness of 0.05-0.2mm.A kind of mode of conductive layer 4 is to be bonded formation one with adhesive layer 2 first, then again to steel Change glassy layer to be bonded.The structure forms the thin compound steel glass structure in two sides behind centre, and such structure can be kept away The internal stress for exempting from tempered glass is excessive, so as to the generation for avoiding part from revealing, meanwhile, such structure setting improves The toughness of tempered glass makes the tempered glass couple hardness with softness, can be by its toughness by external force in the case where encountering external force Ability absorbs, and the stress equilibrium for breaking itself is avoided to lead to breakage.
Embodiment 2:
On the basis of embodiment 1, hollow layer 5 is equipped between compound steel glassy layer 1.
Embodiment 3:
On the basis of embodiment 1 or 2, polyester buffer layer 6, polyester buffer layer 6 are equipped between compound steel glassy layer 1 With a thickness of 0.5-3mm.
Embodiment 4:
On the basis of the above embodiments, it is coated with zinc oxide film 7 in perspex layer 3 or outermost toughened glass layer 1, Zinc oxide film 7 is equipped with silicon nitride layer 8.When perspex layer 3 is outermost layer, zinc oxide film 7 is located on perspex layer 3, When outermost layer is toughened glass layer 1, zinc oxide film 7 is located in toughened glass layer 1.
Embodiment 5:
On the basis of the above embodiments, it is additionally provided with hydrophobic coating 9, hydrophobic coating 9 is located at the innermost layer of tempered glass, such as As exterior wall glass in use, hydrophobic coating 9 is located at internal layer.Other are arranged such.
Embodiment 6:
A kind of material of the PVB film layers used for the various embodiments described above, the material by following components match preparation and At, 100 parts of PVB resin, 30 parts of polyvinyl formal, 8 parts of polyamidoimide, 5 parts of polyvinyl acetate, liquid MOCA 1.5 parts, 2 parts of triphenyl phosphite, 1 part of septichen phenyl ester, 0.03 part of talcum powder.
Since current compound glass is made of being bonded by PVB film, since the service life of glass is obviously big In the film service life of PVB, therefore in order to improve the physical life of compound glass, it is necessary to which the service life for improving PVB works as PVB It receives illumination or due to overlong time, will lead to light degradation or aging, the aging less serious case of PVB causes the translucency of glass to become Difference, severe one, the structural failure that will lead to compound glass cause unnecessary loss.
The PVB film layers of proportion preparation compare routine PVB film, and the service life is longer, and ageing-resistant performance is more preferable, resistance to Wait performance more preferably.
Specific test data is as follows:
Using artificial ageing condition, burn-in test, in 500h, common PVB are carried out to common PVB and PVB of the invention Start to turn to be yellow, the PVB film light transmittance being fabricated to is lower than 80%, and the jaundice of PVB material and light transmittance of the invention is lower than 80% Time is 700h;After 700h, the light transmittance of common PVB film is since aging is reduced to 60%, and light transmittance of the invention is 75%, after 800h, the light transmittance of common PVB be reduced to 50% hereinafter, at this point, the film light transmittance of the PVB material of the application still So it is greater than 70%.
About the adhesion strength of PVB film and common PVB film of the invention, when initial, intensity of the invention is common The 110-120% of PVB film adhesion strength, after 600h, the adhesion strength of common PVB film is reduced to the 80% of initial strength, And PVB film intensity of the invention is only reduced to the 93% of its initial strength.
According to above-mentioned test result it is found that PVB film of the invention than common film have better adhesion strength and Ageing-resistant performance.

Claims (1)

1. a kind of tempered glass, which is characterized in that including compound steel glassy layer (1) and for connecting each toughened glass layer (1) Adhesive layer (2), the thickness proportion of compound steel glass is 1:3-10:0.5-2, between each toughened glass layer (1) or outside Equipped at least one layer of perspex layer (3), the thickness ratio of the toughened glass layer (1) of the perspex layer (3) and outer layer is 1: 3-5 is additionally provided at least one layer of conductive layer (4) between each toughened glass layer (1);
Hollow layer (5) are equipped between the compound steel glassy layer (1);
Polyester buffer layer (6) are equipped between the compound steel glassy layer (1);
The polyester buffer layer (6) with a thickness of 0.5-3mm;
The conductive layer (4) with a thickness of 0.05-0.2mm;
The adhesive layer (2) is PVB film layers;
Bonding is equipped with one layer of perspex layer (3) in the toughened glass layer (1) in the outside;
It is coated with zinc oxide film (7) in the perspex layer (3) or outermost toughened glass layer (1), zinc oxide film is set on (7) There are silicon nitride layer (8);It is characterized in that, being additionally provided with hydrophobic coating (9);
The material of PVB film layers is prepared by following components proportion, 100 parts of PVB resin, 30 parts of polyvinyl formal, is gathered 8 parts of amide imide, 5 parts of polyvinyl acetate, 1.5 parts of liquid MOCA, 2 parts of triphenyl phosphite, septichen phenyl ester 1 part, 0.03 part of talcum powder.
CN201710115086.6A 2017-02-28 2017-02-28 A kind of tempered glass Expired - Fee Related CN106863953B (en)

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Application Number Priority Date Filing Date Title
CN201710115086.6A CN106863953B (en) 2017-02-28 2017-02-28 A kind of tempered glass

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Application Number Priority Date Filing Date Title
CN201710115086.6A CN106863953B (en) 2017-02-28 2017-02-28 A kind of tempered glass

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CN106863953B true CN106863953B (en) 2019-06-21

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109429820A (en) * 2019-01-11 2019-03-08 韩霄然 A kind of novel glass mounting structure for glasshouse

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101900908B (en) * 2009-05-27 2012-01-25 比亚迪股份有限公司 Energy-saving dimming glass
CN201685505U (en) * 2010-06-10 2010-12-29 广州兴华玻璃工业有限公司 Anti-smashing compound glass
CN201924774U (en) * 2010-11-16 2011-08-10 南车青岛四方机车车辆股份有限公司 Front glass window of rail car cab
CN205800390U (en) * 2016-07-06 2016-12-14 安徽荣程玻璃制品有限公司 A kind of safety glass
CN206493662U (en) * 2017-02-28 2017-09-15 浙江飞越汉禾坊新材料有限公司 A kind of safety glass

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Address after: 314211 388 Jie Cheng Road, Shin Dai Town, Pinghu City, Jiaxing, Zhejiang

Applicant after: ZHEJIANG FEIYUE HANHEFANG NEW MATERIAL CO.,LTD.

Address before: 314211 388 Jie Cheng Road, Shin Dai Town, Pinghu City, Jiaxing, Zhejiang

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