CN106863575A - A kind of former made for air entrained concrete and its method of work - Google Patents
A kind of former made for air entrained concrete and its method of work Download PDFInfo
- Publication number
- CN106863575A CN106863575A CN201611198755.2A CN201611198755A CN106863575A CN 106863575 A CN106863575 A CN 106863575A CN 201611198755 A CN201611198755 A CN 201611198755A CN 106863575 A CN106863575 A CN 106863575A
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- Prior art keywords
- control system
- methyl
- balling drum
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- parts
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Links
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000012544 monitoring process Methods 0.000 claims abstract description 16
- 238000012423 maintenance Methods 0.000 claims abstract description 7
- 239000003082 abrasive agent Substances 0.000 claims description 55
- 239000000463 material Substances 0.000 claims description 43
- 239000002994 raw material Substances 0.000 claims description 40
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 21
- 238000000227 grinding Methods 0.000 claims description 21
- 241000534944 Thia Species 0.000 claims description 19
- 239000011163 secondary particle Substances 0.000 claims description 19
- 238000005259 measurement Methods 0.000 claims description 17
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 16
- 238000003780 insertion Methods 0.000 claims description 15
- 230000037431 insertion Effects 0.000 claims description 15
- -1 2- cyclohexyloxy Chemical group 0.000 claims description 14
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 14
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical compound OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 14
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 14
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 238000005192 partition Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000009413 insulation Methods 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000005864 Sulphur Substances 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 8
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- NNJVILVZKWQKPM-UHFFFAOYSA-N Lidocaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=CC=C1C NNJVILVZKWQKPM-UHFFFAOYSA-N 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- 125000004494 ethyl ester group Chemical group 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 claims description 7
- 125000000267 glycino group Chemical group [H]N([*])C([H])([H])C(=O)O[H] 0.000 claims description 7
- 229960004194 lidocaine Drugs 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 claims description 7
- 229960003742 phenol Drugs 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims description 7
- 229940080818 propionamide Drugs 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 239000004299 sodium benzoate Substances 0.000 claims description 7
- 229910052712 strontium Inorganic materials 0.000 claims description 7
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 7
- YNVOMSDITJMNET-UHFFFAOYSA-N thiophene-3-carboxylic acid Chemical compound OC(=O)C=1C=CSC=1 YNVOMSDITJMNET-UHFFFAOYSA-N 0.000 claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- SCNWTQPZTZMXBG-UHFFFAOYSA-N 2-methyloct-2-enoic acid Chemical class CCCCCC=C(C)C(O)=O SCNWTQPZTZMXBG-UHFFFAOYSA-N 0.000 claims description 5
- 125000000440 benzylamino group Chemical group [H]N(*)C([H])([H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 5
- 230000032050 esterification Effects 0.000 claims description 5
- 238000005886 esterification reaction Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000011812 mixed powder Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 150000003217 pyrazoles Chemical class 0.000 claims description 5
- 229910052704 radon Inorganic materials 0.000 claims description 5
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 claims description 5
- 230000004044 response Effects 0.000 claims description 5
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 5
- 239000012498 ultrapure water Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 4
- QELUYTUMUWHWMC-UHFFFAOYSA-N edaravone Chemical class O=C1CC(C)=NN1C1=CC=CC=C1 QELUYTUMUWHWMC-UHFFFAOYSA-N 0.000 claims description 4
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims description 3
- 230000005260 alpha ray Effects 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 239000000523 sample Substances 0.000 claims description 3
- 229930192474 thiophene Natural products 0.000 claims description 3
- GOYDNIKZWGIXJT-UHFFFAOYSA-N 1,2-difluorobenzene Chemical class FC1=CC=CC=C1F GOYDNIKZWGIXJT-UHFFFAOYSA-N 0.000 claims description 2
- ILPBINAXDRFYPL-UHFFFAOYSA-N 2-octene Chemical class CCCCCC=CC ILPBINAXDRFYPL-UHFFFAOYSA-N 0.000 claims description 2
- NACMZLGGHMPMKQ-UHFFFAOYSA-N 5-nitrothiophene-3-carbonitrile Chemical class [O-][N+](=O)C1=CC(C#N)=CS1 NACMZLGGHMPMKQ-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 claims description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- ZBPYTVBKHKUNHG-UHFFFAOYSA-N non-3-enoic acid Chemical compound CCCCCC=CCC(O)=O ZBPYTVBKHKUNHG-UHFFFAOYSA-N 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 125000006000 trichloroethyl group Chemical group 0.000 claims description 2
- 230000005622 photoelectricity Effects 0.000 claims 2
- 238000013016 damping Methods 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 5
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 28
- 238000010586 diagram Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010881 fly ash Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002956 ash Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B15/00—General arrangement or layout of plant ; Industrial outlines or plant installations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C17/00—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
- B02C17/10—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls with one or a few disintegrating members arranged in the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/50—Producing shaped prefabricated articles from the material specially adapted for producing articles of expanded material, e.g. cellular concrete
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B17/00—Details of, or accessories for, apparatus for shaping the material; Auxiliary measures taken in connection with such shaping
- B28B17/0063—Control arrangements
- B28B17/0081—Process control
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Food Science & Technology (AREA)
- Automation & Control Theory (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Air Transport Of Granular Materials (AREA)
Abstract
The invention discloses a kind of former made for air entrained concrete and its method of work, it is made up of screw feeder, Support bracket, one-level air inlet pipeline, balling drum, secondary inlet pipeline, maintenance door, pneumatic discharge gate, rotary electric machine, rotation cam, damper pulley, control system;Screw feeder is arranged in balling drum side;Rotation cam is arranged at balling drum opposite side;Rotary electric machine is connected by damper pulley with rotation cam;One-level air inlet pipeline is located at balling drum upper side;Secondary inlet pipeline is located at balling drum top opposite side;Pneumatic discharge gate is arranged at the side-lower of balling drum one.A kind of former made for air entrained concrete of the present invention, the device can automatically adjust putty situation, be provided with highly sensitive putty detector, and real-time monitoring charging putty situation, timely feedback processing greatly improves equipment operating efficiency.
Description
Technical field
Application field is made the invention belongs to air entrained concrete, and in particular to a kind of shaping made for air entrained concrete
Equipment and its method of work.
Background technology
Air entrained concrete is a kind of new wall material, and it is unique in that it is a kind of very light-duty insulation
Heat-insulated novel building walling.Before air entrained concrete technology starts from 100 years, and the ratio that this technology of China starts is later, than
Foreign countries have totally fallen behind 40 years, but, the development of the air entrained concrete industry of China is strictly very fast.It is now domestic
Air entrained concrete technical matters level can reach international most advanced level.
Air entrained concrete sharpest edges are exactly to economize the land resource, without wasting substantial amounts of arable land, and its raw material
Very extensively, dust and sand, slag, flyash and gangue etc. are all the raw material for doing air entrained concrete in source.And aerating
The performance characteristics of concrete are very superior, have it is extraordinary can working ability and heat-insulated and insulating power, and plasticity
It is very strong, can Bao can saw, have extraordinary processing characteristics.
The application of air entrained concrete widely, is used primarily in materials for wall, filling in machinery plant and civil buildings
The filling enclosure wall of the load-bearing such as wall, floor and roof boarding walling and non-bearing material and surrounding.
Gradually, air entrained concrete has turned into the leading products of building material industry, and country is now to clay solid brick
Carry out forbidding stopping production, be instead exactly gradually air-entrained concrete building block, steam-pressing brisk.
The application of air entrained concrete alleviates present situation, because it is fine coal to make air-entrained concrete building block raw material
Ash, dust and sand, gangue, industrial residue etc., the big rubbish for both being from thermal power plant and artificial coal in source of these raw materials, are not having
Before having air-entrained concrete building block equipment, the flyash that former power plants generating electricity is emitted all has carried out burial treatment, does not all have
Have and pay attention to its value, nowadays the application of the equipment substantially increases waste economic circulation, and is buried in underground in the past
Flyash be re-used again, along with various regions government department to air entrained concrete industry trip encouragement policy and help political affairs
Plan, so the development prospect of air-entrained concrete building block industry is very wide.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of former made for air entrained concrete, including:
Screw feeder 1, Support bracket 2, one-level air inlet pipeline 3, balling drum 4, secondary inlet pipeline 5, maintenance door 6, it is pneumatic go out
Material gate 7, rotary electric machine 8, rotation cam 9, damper pulley 10, control system 11;The Support bracket 2 is stainless steel frame;
The balling drum 4 is fixedly mounted on the top of Support bracket 2;The screw feeder 1 is arranged in the side of balling drum 4,
Screw feeder 1 is connected with the insertion of balling drum 4;The rotation cam 9 is arranged at the opposite side of balling drum 4, rotates convex
Wheel 9 is connected with the coaxial rotating of balling drum 4;The rotary electric machine 8 is driven with rotation cam 9 by damper pulley 10 and connected
Connect;The one-level air inlet pipeline 3 is located at the upper side of balling drum 4, and the insertion of one-level air inlet pipeline 3 connects balling drum 4,
Wherein described one-level air inlet pipeline 3 is provided with one-level air inlet electromagnetic valve;The secondary inlet pipeline 5 is located on balling drum 4
Square opposite side, the insertion of secondary inlet pipeline 5 connection balling drum 4, wherein the secondary inlet pipeline 5 is provided with secondary inlet
Magnetic valve;The maintenance door 6 is arranged at the side wall of balling drum 4;The pneumatic discharge gate 7 is arranged at balling drum 4 one
Side-lower, pneumatic discharge gate 7 is connected with the insertion of balling drum 4;The control system 11 is fixedly mounted on Support bracket 2
On;
The pneumatic discharge gate 7, rotary electric machine 8 control to be connected by wire and control system 11 respectively;
The one-level air inlet electromagnetic valve, secondary inlet magnetic valve control to be connected by wire and control system 11 respectively.
Further, the screw feeder 1 includes:Variable-frequency motor 1-1, feed hopper 1-2, are fed chamber 1-3, feed rotation
Axle 1-4, pressure feeding spiral blade 1-5, photoelectric sensor 1-6, putty detector 1-7;Wherein, the feed chamber 1-3 is circle
Column construction, its external diameter is between 60cm~70cm;The feed hopper 1-2 is arranged at feed chamber 1-3 sides top, feed hopper 1-
2 are connected with feed chamber 1-3 insertions;The feed rotary shaft 1-4 is arranged inside feed chamber 1-3;The feed rotary shaft 1-4 mono-
End is installed with variable-frequency motor 1-1;The pressure feeding spiral blade 1-5 is fixedly mounted on feed rotary shaft 1-4, variable-frequency motor
1-1 drives feed rotary shaft 1-4 to do coaxial rotating motion, and pressure feeding spiral blade 1-5 is before spiral under feed rotary shaft 1-4 drives
Enter motion;The photoelectric sensor 1-6 is fixedly mounted on feed chamber 1-3 outer walls side;The putty detector 1-7 is set
In feed hopper 1-2 inwalls bottom;
The variable-frequency motor 1-1, photoelectric sensor 1-6, putty detector 1-7 are controlled by wire and control system 11 respectively
System connection.
Further, the balling drum 4 includes:Cylinder shell 4-1, abrasion-proof backing block 4-2, one-level abrasive medium 4-3,
Abrasive material chamber dividing plate 4-4, one-level droplet measurement device 4-5, secondary grinding material medium 4-6, discharge partition plate 4-7, secondary particle size detector 4-
8;Wherein, the cylinder shell 4-1 is steel plate material, and its thickness is between 5cm~8cm;The abrasion-proof backing block 4-2 dismountings connection
Inside cylinder shell 4-1;The one-level abrasive medium 4-3 and secondary grinding material medium 4-6 is steel ball, wherein one-level mill
Between 9cm~13cm, secondary grinding material medium 4-6 spheroid external diameters are between 4cm~6cm for material medium 4-3 spheroid external diameters;The mill
Material chamber dividing plate 4-4 is arranged at the middle part of balling drum 4, between abrasive material chamber dividing plate 4-4 and the feedstock direction barrel of balling drum 4
Between 50cm~80cm, space is the first abrasive material chamber, one-level abrasive medium 4- to distance between abrasive material chamber dividing plate 4-4 and the barrel
3 are positioned in the first abrasive material chamber;The one-level droplet measurement device 4-5 is fixedly mounted on the first abrasive material luminal wall surface;It is described
Discharge partition plate 4-7 is arranged at the discharging of balling drum 4 direction side, the space between discharge partition plate 4-7 and abrasive material chamber dividing plate 4-4
It is the second abrasive material chamber, the secondary grinding material medium 4-6 is positioned in the second abrasive material chamber;The secondary particle size detector 4-8 consolidates
Dingan County is mounted in the second abrasive material luminal wall surface;
The one-level droplet measurement device 4-5, secondary particle size detector 4-8 control to be connected by wire and control system 11 respectively.
Further, the abrasion-proof backing block 4-2 is molded by macromolecular material pressing mold, the constituent of abrasion-proof backing block 4-2 and
Manufacturing process is as follows:
First, abrasion-proof backing block 4-2 constituents:
Count by weight, 1- (8- azabicyclos [3.2.1] -3- octyl groups) 65~125 parts of -2- methyl isophthalic acid H- benzimidazoles,
(6R, trans) 7- amino -3- [(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] methyl -8- oxo -5- thia -1- azabicyclos
55~155 parts of [4.2.5] oct-2-ene carboxylic acid, 7- amino -3- (1- methyl isophthalic acid H- tetrazolium -5- sulphomethyls) -8- oxo -5- sulphur
Miscellaneous 95~215 parts of -1- azabicyclos [4.2.5] oct-2-ene -2- carboxylic acids, 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5-
Thia -1- azabicyclo [4.2.5] oct-2-ene-second carboxylic acid -2,2,2- 15~55 parts of trichloro ethyl esters, 4- amino -2- (benzyl ammonia
Base) 75~135 parts of -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters, 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyanogen
35~75 parts of two strontium of base -3- thiophene acetic acids, concentration is the 2- [[4- [ethyl (2- Phenoxyethyls) amino] of 25ppm~55ppm
Phenyl] azo] 55~115 parts of -5- nitro -3- cyano thiophenes, N- [2- [(bromo- 4, the 6- dinitrophenyls of 2-) azo] -5- [(2-
Cyanoethyl) ethylamino] -4- anisyls] 35~75 parts of acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azos
Base] -5- (lignocaine) phenyl] 115~145 parts of propionamide, 65~195 parts of crosslinking agent, 5- (methyl thio) -3- (2- thiophenes
Fen) 45~115 parts of -1H- pyrazoles -4- formonitrile HCNs, two [3- [4,5- dihydro -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3-
Methyl -5- oxo -1H-1- pyrazolyls]] benzsulfamide (2-)] 25~85 parts of chromic acid (1-) sodium is closed, chromic acid closes two [2- (4,5- bis-
Hydrogen -3- methyl -5- oxygen -1- phenyl -1H-4- pyrazolyls) azo] 45~135 parts of Sodium Benzoate, [the chloro- 3- of 5- [(4,5- dihydros -
3- methyl -5- oxo -1- phenyl -1H- pyrazoles -4- bases) azo] conjunction of -2- hydroxy benzene sulfonic acids root] 85~165 parts of hydroxyl chromic acid hydrogen;
The crosslinking agent is 2- cyclohexyloxy -5- iodine pyridines, 5- hexyls -2- (the own oxygen phenyl of 4-) pyrimidine, 3- (3,4- difluorobenzenes
Base) any one in pyrazoles;
2nd, the manufacturing process of abrasion-proof backing block 4-2, comprises the steps of:
1st step:1375~1645 parts of ultra-pure water for adding electrical conductivity to be 2.25 μ S/cm~4.25 μ S/cm in a kettle., starts
Agitator in reactor, rotating speed is 65rpm~125rpm, starts heat pump, reactor temperature is risen to 45 DEG C~75 DEG C;
Sequentially add 1- (8- azabicyclos [3.2.1] -3- octyl groups) -2- methyl isophthalic acid H- benzimidazoles, (6R, trans) 7- amino -3-
[(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] methyl -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes carboxylic acid, 7-
Amino -3- (1- methyl isophthalic acid H- tetrazolium -5- sulphomethyls) -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes -2-
Carboxylic acid, to being completely dissolved, regulation pH value is 3.5~6.5, and agitator speed is adjusted into 135rpm~255rpm, and temperature is for stirring
95 DEG C~135 DEG C, esterification 15~25 hours;
2nd step:Take 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5- thia -1- azabicyclo [4.2.5] oct-2-ene-second
Carboxylic acid -2,2,2- trichloro ethyl esters, 4- amino -2- (benzylamino) -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters carry out powder
Broken, powder diameter is 525~1355 mesh;Add the strontium of 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyano group -3- thiophene acetic acids two
It is well mixed, it is laid in pallet, tiling thickness is 35mm~55mm, uses the dosage to be for 3.5kGy~9.5kGy, energy
The alpha ray of 5.5MeV~14.5MeV is irradiated 65~145 minutes, and Isodose β x ray irradiation xs 55~135 minutes;
3rd step:Through the 2nd step process mixed-powder be dissolved in 2- [[4- [ethyl (2- Phenoxyethyls) amino] phenyl] azo]-
In 5- nitro -3- cyano thiophenes, reactor is added, agitator speed is 75rpm~185rpm, and temperature is 85 DEG C~165 DEG C, is opened
Dynamic vavuum pump makes the vacuum of reactor reach 1.35MPa~1.85MPa, keeps this state response 15~35 hours;Pressure release is simultaneously
Radon gas is passed through, makes reacting kettle inner pressure for 1.25MPa~1.65MPa, insulation stands 25~35 hours;Agitator speed is promoted to
155rpm~295rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add N- [2- [(the bromo- 4,6- dinitrophenyls of 2-) azo]-
5- [(2- cyanoethyls) ethylamino] -4- anisyls] acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azos
Base] -5- (lignocaine) phenyl] after propionamide is completely dissolved, add crosslinking agent stirring mixing so that reactor solution it is hydrophilic
Lipophilic balance value is 5.5~8.5, and insulation stands 25~45 hours;
4th step:When agitator speed is 145rpm~225rpm, 5- (methyl thio) -3- (2- thiophene) -1H- is sequentially added
Pyrazoles -4- formonitrile HCNs, two [3- [4,5- dihydros -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3- methyl -5- oxos -1H-
1- pyrazolyls]] benzsulfamide (2-)] close chromic acid (1-) sodium, chromic acid close two [2- (4,5- dihydro -3- methyl -5- oxygen -1- phenyl -
1H-4- pyrazolyls) azo] Sodium Benzoate and [the chloro- 3- of 5- [(4,5- dihydro -3- methyl -5- oxo -1- phenyl -1H- pyrazoles -4-
Base) azo] conjunction of -2- hydroxy benzene sulfonic acids root] hydroxyl chromic acid hydrogen, reactor pressure is lifted, 1.95MPa~2.75MPa is reached,
Temperature is 145 DEG C~265 DEG C, polymerisation 15~25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to
25 DEG C~45 DEG C, discharging enters molding press and can be prepared by abrasion-proof backing block 4-2.
Further, the invention also discloses a kind of method of work of the former made for air entrained concrete, should
Method includes following steps:
1st step:Air entrained concrete after broken is made raw material and is entered into feed hopper 1-2 with the speed of 1.5m/s, through being fed chamber
Pressure feeding spiral blade 1-5 in 1-3 is delivered in balling drum 4;
2nd step:Air entrained concrete makes raw material in course of conveying in feed chamber 1-3, and putty detector 1-7 is to feed hopper 1-2
Bottom feed situation real-time monitoring, photoelectric sensor 1-6 is to variable-frequency motor 1-1 rotating speed real-time monitorings, photoelectric whirl sensing
The variable-frequency motor 1-1 tach signals that device 1-6 will be detected are sent to control system 11, and the display module in control system 11 is real-time
Display variable-frequency motor 1-1 tach signals;When putty detector 1-7 detects feed hopper 1-2 bottoms materials density higher than 25ml/
During cm3, electric signal is sent to control system 11 by putty detector 1-7, and the control variable-frequency motor 1-1 reductions of control system 11 turn
Speed;When putty detector 1-7 detects feed hopper 1-2 bottoms materials density less than 10ml/cm3, putty detector 1-7 is by electricity
Signal is sent to control system 11, and the control variable-frequency motor of control system 11 1-1 improves rotating speed;
3rd step:After air entrained concrete making raw material enters balling drum 4, balling drum 4 does under the drive of rotary electric machine 8
Circumference rotary motion, the one-level abrasive medium 4-3 and secondary grinding material medium 4-6 in balling drum 4 is under gravity
Raw material is smashed;
4th step:During one-level abrasive medium 4-3 smashes raw material, one-level droplet measurement device 4-5 is in the first abrasive material chamber
Raw material particle size real-time monitoring, when the raw material particle size that one-level droplet measurement device 4-5 is detected in the first abrasive material chamber reaches 500 mesh,
Feedback signal is sent to control system 11, in the opening one-level of control system 11 air inlet pipeline 3 one by one-level droplet measurement device 4-5
Level air inlet electromagnetic valve, under high velocity air drive, the raw material in the first abrasive material chamber after smashing is entered by abrasive material chamber dividing plate 4-4
Enter in the second abrasive material chamber;
5th step:During secondary grinding material medium 4-6 smashes raw material, secondary particle size detector 4-8 is in the second abrasive material chamber
Raw material particle size real-time monitoring, when the raw material particle size in secondary particle size detector 4-8 detects the second abrasive material chamber reaches 1200 mesh,
Feedback signal is sent to control system 11, in the opening secondary inlet of control system 11 pipeline 5 two by secondary particle size detector 4-8
Level air inlet electromagnetic valve, meanwhile, control system 11 controls pneumatic discharge gate 7 to open, under high velocity air drive, after smashing
Raw material in second abrasive material chamber is transported in aggregate bin by discharge partition plate 4-7 through pneumatic discharge gate 7.
A kind of former made for air entrained concrete disclosed by the invention, the advantage is that:
(1) device can automatically adjust putty situation, be provided with highly sensitive putty detector, real-time monitoring charging putty
Situation, timely feedback processing greatly improves equipment operating efficiency;
(2) the device abrasion-proof backing block uses macromolecular material, and wearability is significantly better than existing product, greatly improves making for equipment
Use the time limit;
(3) apparatus structure is simple, and convenient transportation, high degree of automation is simple to operate.
A kind of former made for air entrained concrete of the present invention, the device can automatically adjust putty feelings
Condition, is provided with highly sensitive putty detector, and real-time monitoring charging putty situation, timely feedback processing greatly improves equipment
Operating efficiency.
Brief description of the drawings
Fig. 1 is a kind of heretofore described former schematic diagram made for air entrained concrete.
Fig. 2 is heretofore described screw feeder structural representation.
Fig. 3 is heretofore described balling drum structural representation.
Fig. 4 is heretofore described abrasion-proof backing block material against oxidative rate with use time variation diagram.
In figure 1 above~Fig. 3, screw feeder 1, variable-frequency motor 1-1, feed hopper 1-2 are fed chamber 1-3, are fed rotary shaft
1-4, pressure feeding spiral blade 1-5, photoelectric sensor 1-6, putty detector 1-7, Support bracket 2, one-level air inlet pipeline 3,
Balling drum 4, cylinder shell 4-1, abrasion-proof backing block 4-2, one-level abrasive medium 4-3, abrasive material chamber dividing plate 4-4, the inspection of one-level particle diameter
Survey device 4-5, secondary grinding material medium 4-6, discharge partition plate 4-7, secondary particle size detector 4-8, secondary inlet pipeline 5, maintenance door 6,
Pneumatic discharge gate 7, rotary electric machine 8, rotation cam 9, damper pulley 10, control system 11.
Specific embodiment
A kind of former made for air entrained concrete for providing the present invention with reference to the accompanying drawings and examples enters
Row is further illustrated.
As shown in figure 1, being a kind of heretofore described former schematic diagram made for air entrained concrete.From figure
Find out in 1, including:Screw feeder 1, Support bracket 2, one-level air inlet pipeline 3, balling drum 4, secondary inlet pipeline 5, inspection
Repair door 6, pneumatic discharge gate 7, rotary electric machine 8, rotation cam 9, damper pulley 10, control system 11;The Support bracket 2
It is stainless steel frame;The balling drum 4 is fixedly mounted on the top of Support bracket 2;The screw feeder 1 is arranged in ball mill
The side of roller 4, screw feeder 1 is connected with the insertion of balling drum 4;It is another that the rotation cam 9 is arranged at balling drum 4
Side, rotation cam 9 is connected with the coaxial rotating of balling drum 4;The rotary electric machine 8 passes through damper pulley 10 and rotation cam
9 drive connections;The one-level air inlet pipeline 3 is located at the upper side of balling drum 4, the insertion of one-level air inlet pipeline 3 connection ball milling
Machine cylinder 4, wherein the one-level air inlet pipeline 3 is provided with one-level air inlet electromagnetic valve;The secondary inlet pipeline 5 is located at ball mill
The top opposite side of roller 4, the insertion of secondary inlet pipeline 5 connection balling drum 4, wherein the secondary inlet pipeline 5 is provided with
Secondary inlet magnetic valve;The maintenance door 6 is arranged at the side wall of balling drum 4;The pneumatic discharge gate 7 is arranged at ball mill
The side-lower of roller 4 one, pneumatic discharge gate 7 is connected with the insertion of balling drum 4;The control system 11 is fixedly mounted on support
On bracket 2;
The pneumatic discharge gate 7, rotary electric machine 8 control to be connected by wire and control system 11 respectively;
The one-level air inlet electromagnetic valve, secondary inlet magnetic valve control to be connected by wire and control system 11 respectively.
As shown in Fig. 2 being heretofore described screw feeder structural representation.Find out from Fig. 2 or Fig. 1, spiral
Dispenser 1 includes:Variable-frequency motor 1-1, feed hopper 1-2, are fed chamber 1-3, are fed rotary shaft 1-4, pressure feeding spiral blade 1-5, light
Electric speed probe 1-6, putty detector 1-7;Wherein, the feed chamber 1-3 be cylindrical structural, its external diameter 60cm~
Between 70cm;The feed hopper 1-2 is arranged at feed chamber 1-3 sides top, and feed hopper 1-2 is connected with feed chamber 1-3 insertions;Institute
Feed rotary shaft 1-4 is stated to be arranged inside feed chamber 1-3;Described feed rotary shaft 1-4 one end is installed with variable-frequency motor 1-
1;The pressure feeding spiral blade 1-5 is fixedly mounted on feed rotary shaft 1-4, and variable-frequency motor 1-1 drives feed rotary shaft 1-4 to do
Coaxial rotating is moved, and pressure feeding spiral blade 1-5 is threadingly advanced motion in the case where feed rotary shaft 1-4 drives;The photoelectric whirl is passed
Sensor 1-6 is fixedly mounted on feed chamber 1-3 outer walls side;The putty detector 1-7 is arranged at feed hopper 1-2 inwalls bottom;
The variable-frequency motor 1-1, photoelectric sensor 1-6, putty detector 1-7 are controlled by wire and control system 11 respectively
System connection.
As shown in figure 3, being heretofore described balling drum structural representation.Find out from Fig. 3 or Fig. 1, ball milling
Machine cylinder 4 includes:Cylinder shell 4-1, abrasion-proof backing block 4-2, one-level abrasive medium 4-3, abrasive material chamber dividing plate 4-4, the inspection of one-level particle diameter
Survey device 4-5, secondary grinding material medium 4-6, discharge partition plate 4-7, secondary particle size detector 4-8;Wherein, the cylinder shell 4-1 is
Steel plate material, its thickness is between 5cm~8cm;The abrasion-proof backing block 4-2 dismountings are connected to inside cylinder shell 4-1;Described one
Level abrasive medium 4-3 and secondary grinding material medium 4-6 are steel ball, wherein one-level abrasive medium 4-3 spheroids external diameter 9cm~
Between 13cm, secondary grinding material medium 4-6 spheroid external diameters are between 4cm~6cm;The abrasive material chamber dividing plate 4-4 is arranged at ball mill
The middle part of roller 4, the distance between abrasive material chamber dividing plate 4-4 and the feedstock direction barrel of balling drum 4 grind between 50cm~80cm
Space is the first abrasive material chamber between material chamber dividing plate 4-4 and the barrel, and one-level abrasive medium 4-3 is positioned in the first abrasive material chamber;
The one-level droplet measurement device 4-5 is fixedly mounted on the first abrasive material luminal wall surface;The discharge partition plate 4-7 is arranged at ball mill
Roller 4 discharges direction side, and the space between discharge partition plate 4-7 and abrasive material chamber dividing plate 4-4 is the second abrasive material chamber, the secondary grinding
Material medium 4-6 is positioned in the second abrasive material chamber;The secondary particle size detector 4-8 is fixedly mounted on the second abrasive material cavity wall table
Face;
The one-level droplet measurement device 4-5, secondary particle size detector 4-8 control to be connected by wire and control system 11 respectively.
A kind of course of work of former for being made for air entrained concrete of the present invention is:
1st step:Air entrained concrete after broken is made raw material and is entered into feed hopper 1-2 with the speed of 1.5m/s, through being fed chamber
Pressure feeding spiral blade 1-5 in 1-3 is delivered in balling drum 4;
2nd step:Air entrained concrete makes raw material in course of conveying in feed chamber 1-3, and putty detector 1-7 is to feed hopper 1-2
Bottom feed situation real-time monitoring, photoelectric sensor 1-6 is to variable-frequency motor 1-1 rotating speed real-time monitorings, photoelectric whirl sensing
The variable-frequency motor 1-1 tach signals that device 1-6 will be detected are sent to control system 11, and the display module in control system 11 is real-time
Display variable-frequency motor 1-1 tach signals;When putty detector 1-7 detects feed hopper 1-2 bottoms materials density higher than 25ml/
During cm3, electric signal is sent to control system 11 by putty detector 1-7, and the control variable-frequency motor 1-1 reductions of control system 11 turn
Speed;When putty detector 1-7 detects feed hopper 1-2 bottoms materials density less than 10ml/cm3, putty detector 1-7 is by electricity
Signal is sent to control system 11, and the control variable-frequency motor of control system 11 1-1 improves rotating speed;
3rd step:After air entrained concrete making raw material enters balling drum 4, balling drum 4 does under the drive of rotary electric machine 8
Circumference rotary motion, the one-level abrasive medium 4-3 and secondary grinding material medium 4-6 in balling drum 4 is under gravity
Raw material is smashed;
4th step:During one-level abrasive medium 4-3 smashes raw material, one-level droplet measurement device 4-5 is in the first abrasive material chamber
Raw material particle size real-time monitoring, when the raw material particle size that one-level droplet measurement device 4-5 is detected in the first abrasive material chamber reaches 500 mesh,
Feedback signal is sent to control system 11, in the opening one-level of control system 11 air inlet pipeline 3 one by one-level droplet measurement device 4-5
Level air inlet electromagnetic valve, under high velocity air drive, the raw material in the first abrasive material chamber after smashing is entered by abrasive material chamber dividing plate 4-4
Enter in the second abrasive material chamber;
5th step:During secondary grinding material medium 4-6 smashes raw material, secondary particle size detector 4-8 is in the second abrasive material chamber
Raw material particle size real-time monitoring, when the raw material particle size in secondary particle size detector 4-8 detects the second abrasive material chamber reaches 1200 mesh,
Feedback signal is sent to control system 11, in the opening secondary inlet of control system 11 pipeline 5 two by secondary particle size detector 4-8
Level air inlet electromagnetic valve, meanwhile, control system 11 controls pneumatic discharge gate 7 to open, under high velocity air drive, after smashing
Raw material in second abrasive material chamber is transported in aggregate bin by discharge partition plate 4-7 through pneumatic discharge gate 7.
A kind of former made for air entrained concrete of the present invention, the device can automatically adjust putty feelings
Condition, is provided with highly sensitive putty detector, and real-time monitoring charging putty situation, timely feedback processing greatly improves equipment
Operating efficiency.
The following is the embodiment of the manufacturing process of abrasion-proof backing block 4-2 of the present invention, embodiment is to further illustrate
Present disclosure, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, to this
Modification and replacement that inventive method, step or condition are made, belong to the scope of the present invention.
If not specializing, the conventional meanses that technological means used is well known to those skilled in the art in embodiment.
Embodiment 1
Abrasion-proof backing block 4-2 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:1375 parts of the ultra-pure water that electrical conductivity is 2.25 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 65rpm, starts heat pump, reactor temperature is risen to 45 DEG C;Sequentially add 1- (8- azabicyclos [3.2.1] -3-
Octyl group) 65 parts of -2- methyl isophthalic acid H- benzimidazoles, (6R, trans) 7- amino -3- [(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] first
55 parts of base -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes carboxylic acid, 7- amino -3- (1- methyl isophthalic acid H- tetrazoliums -5-
Sulphomethyl) 95 parts of -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-ene -2- carboxylic acids, stir to being completely dissolved, adjust
Section pH value is 3.5, and agitator speed is adjusted into 135rpm, and temperature is 95 DEG C, esterification 15 hours;
2nd step:Take 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5- thia -1- azabicyclo [4.2.5] oct-2-ene-second
15 parts of carboxylic acid -2,2,2- trichloro ethyl esters, 4- amino -2- (benzylamino) -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters 75
Part is crushed, and powder diameter is 525 mesh;Add 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyano group -3- thiophene acetic acids two
35 parts of strontium is well mixed, and is laid in pallet, and tiling thickness is 35mm, uses dosage for 3.5kGy, energy for the α of 5.5MeV is penetrated
Line is irradiated 65 minutes, and Isodose β x ray irradiation xs 55 minutes;
3rd step:Through the 2nd step concentration for the treatment of for the mixed-powder of 25ppm is dissolved in 2- [[4- [ethyl (2- Phenoxyethyls) amino]
Phenyl] azo] in 55 parts of -5- nitro -3- cyano thiophenes, reactor is added, agitator speed is 75rpm, and temperature is 85 DEG C, is opened
Dynamic vavuum pump makes the vacuum of reactor reach 1.35MPa, keeps this state response 15 hours;Pressure release is simultaneously passed through radon gas, makes anti-
It is 1.25MPa to answer pressure in kettle, and insulation stands 25 hours;Agitator speed is promoted to 155rpm, and the pressure release of simultaneous reactions kettle is extremely
0MPa;Sequentially add N- [2- [(the bromo- 4,6- dinitrophenyls of 2-) azo] -5- [(2- cyanoethyls) ethylamino] -4- methoxy benzene
Base] 35 parts of acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azo group] -5- (lignocaine) phenyl] propionamide
After 115 parts are completely dissolved, 65 parts of stirring mixing of crosslinking agent are added so that the hydrophilic lipophilic balance of reactor solution is 5.5, is protected
Temperature stands 25 hours;
4th step:When agitator speed is 145rpm, 5- (methyl thio) -3- (2- thiophene) -1H- pyrazoles -4- first is sequentially added
45 parts of nitrile, two [3- [4,5- dihydros -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3- methyl -5- oxo -1H-1- pyrazoles
Base]] benzsulfamide (2-)] close 25 parts of chromic acid (1-) sodium, two [2- (4,5- dihydro -3- methyl -5- oxygen -1- phenyl -1H- of chromic acid conjunction
4- pyrazolyls) azo] 45 parts of Sodium Benzoate and [the chloro- 3- of 5- [(4,5- dihydro -3- methyl -5- oxo -1- phenyl -1H- pyrazoles -
4- yls) azo] conjunction of -2- hydroxy benzene sulfonic acids root] 85 parts of hydroxyl chromic acid hydrogen, reactor pressure is lifted, 1.95MPa is reached, temperature
It is 145 DEG C to spend, polymerisation 15 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 25 DEG C are cooled to, discharging enters
Molding press can be prepared by abrasion-proof backing block 4-2;
The crosslinking agent is 2- cyclohexyloxy -5- iodine pyridines.
Embodiment 2
Abrasion-proof backing block 4-2 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:1645 parts of the ultra-pure water that electrical conductivity is 4.25 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 125rpm, starts heat pump, reactor temperature is risen to 75 DEG C;Sequentially add 1- (8- azabicyclos [3.2.1]-
3- octyl groups) 125 parts of -2- methyl isophthalic acid H- benzimidazoles, (6R, trans) 7- amino -3- [(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur]
155 parts of methyl -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes carboxylic acid, 7- amino -3- (1- methyl isophthalic acids H- tetra-
Azoles -5- sulphomethyls) 215 parts of -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-ene -2- carboxylic acids, stirring is to complete
Dissolving, regulation pH value is 6.5, and agitator speed is adjusted into 255rpm, and temperature is 135 DEG C, esterification 25 hours;
2nd step:Take 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5- thia -1- azabicyclo [4.2.5] oct-2-ene-second
55 parts of carboxylic acid -2,2,2- trichloro ethyl esters, 4- amino -2- (benzylamino) -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters
135 parts are crushed, and powder diameter is 1355 mesh;Add 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyano group -3- thiophene second
75 parts of sour two strontium is well mixed, and is laid in pallet, and tiling thickness is 55mm, and it is 14.5MeV for 9.5kGy, energy to use dosage
Alpha ray irradiate 145 minutes, and Isodose β x ray irradiation xs 135 minutes;
3rd step:Through the 2nd step concentration for the treatment of for the mixed-powder of 55ppm is dissolved in 2- [[4- [ethyl (2- Phenoxyethyls) amino]
Phenyl] azo] in 115 parts of -5- nitro -3- cyano thiophenes, reactor is added, agitator speed is 185rpm, and temperature is 165
DEG C, starting vavuum pump makes the vacuum of reactor reach 1.85MPa, keeps this state response 35 hours;Pressure release is simultaneously passed through radon gas,
Make reacting kettle inner pressure for 1.65MPa, insulation stands 35 hours;Agitator speed is promoted to 295rpm, simultaneous reactions kettle pressure release
To 0MPa;Sequentially add N- [2- [(the bromo- 4,6- dinitrophenyls of 2-) azo] -5- [(2- cyanoethyls) ethylamino] -4- methoxy benzene
Base] 75 parts of acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azo group] -5- (lignocaine) phenyl] propionamide
After 145 parts are completely dissolved, 195 parts of stirring mixing of crosslinking agent are added so that the hydrophilic lipophilic balance of reactor solution is 8.5,
Insulation stands 45 hours;
4th step:When agitator speed is 225rpm, 5- (methyl thio) -3- (2- thiophene) -1H- pyrazoles -4- first is sequentially added
115 parts of nitrile, two [3- [4,5- dihydros -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3- methyl -5- oxo -1H-1- pyrroles
Oxazolyl]] benzsulfamide (2-)] close 85 parts of chromic acid (1-) sodium, chromic acid close two [2- (4,5- dihydro -3- methyl -5- oxygen -1- phenyl -
1H-4- pyrazolyls) azo] 135 parts of Sodium Benzoate and [the chloro- 3- of 5- [(4,5- dihydro -3- methyl -5- oxo -1- phenyl -1H- pyrroles
Azoles -4- bases) azo] conjunction of -2- hydroxy benzene sulfonic acids root] 165 parts of hydroxyl chromic acid hydrogen, reactor pressure is lifted, reach
2.75MPa, temperature is 265 DEG C, polymerisation 25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 45 are cooled to
DEG C, discharging enters molding press and can be prepared by abrasion-proof backing block 4-2;
The crosslinking agent is 5- hexyls -2- (the own oxygen phenyl of 4-) pyrimidine.
Embodiment 3
Abrasion-proof backing block 4-2 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:1445 parts of the ultra-pure water that electrical conductivity is 3.25 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 95rpm, starts heat pump, reactor temperature is risen to 65 DEG C;Sequentially add 1- (8- azabicyclos [3.2.1] -3-
Octyl group) 85 parts of -2- methyl isophthalic acid H- benzimidazoles, (6R, trans) 7- amino -3- [(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] first
135 parts of base -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes carboxylic acid, 7- amino -3- (1- methyl isophthalic acid H- tetrazoliums -
5- sulphomethyls) 185 parts of -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-ene -2- carboxylic acids, stirring to completely it is molten
Solution, regulation pH value is 4.5, and agitator speed is adjusted into 195rpm, and temperature is 115 DEG C, esterification 18 hours;
2nd step:Take 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5- thia -1- azabicyclo [4.2.5] oct-2-ene-second
35 parts of carboxylic acid -2,2,2- trichloro ethyl esters, 4- amino -2- (benzylamino) -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters 85
Part is crushed, and powder diameter is 955 mesh;Add 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyano group -3- thiophene acetic acids two
55 parts of strontium is well mixed, and is laid in pallet, and tiling thickness is 45mm, uses dosage for 6.5kGy, energy for the α of 9.5MeV is penetrated
Line is irradiated 115 minutes, and Isodose β x ray irradiation xs 85 minutes;
3rd step:Through the 2nd step concentration for the treatment of for the mixed-powder of 45ppm is dissolved in 2- [[4- [ethyl (2- Phenoxyethyls) amino]
Phenyl] azo] in 75 parts of -5- nitro -3- cyano thiophenes, reactor is added, agitator speed is 125rpm, and temperature is 135 DEG C,
Starting vavuum pump makes the vacuum of reactor reach 1.15MPa, keeps this state response 25 hours;Pressure release is simultaneously passed through radon gas, makes
Reacting kettle inner pressure is 1.45MPa, and insulation stands 29 hours;Agitator speed is promoted to 195rpm, and the pressure release of simultaneous reactions kettle is extremely
0MPa;Sequentially add N- [2- [(the bromo- 4,6- dinitrophenyls of 2-) azo] -5- [(2- cyanoethyls) ethylamino] -4- methoxy benzene
Base] 55 parts of acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azo group] -5- (lignocaine) phenyl] propionamide
After 125 parts are completely dissolved, 135 parts of stirring mixing of crosslinking agent are added so that the hydrophilic lipophilic balance of reactor solution is 6.5,
Insulation stands 35 hours;
4th step:When agitator speed is 175rpm, 5- (methyl thio) -3- (2- thiophene) -1H- pyrazoles -4- first is sequentially added
85 parts of nitrile, two [3- [4,5- dihydros -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3- methyl -5- oxo -1H-1- pyrazoles
Base]] benzsulfamide (2-)] close 65 parts of chromic acid (1-) sodium, two [2- (4,5- dihydro -3- methyl -5- oxygen -1- phenyl -1H- of chromic acid conjunction
4- pyrazolyls) azo] 115 parts of Sodium Benzoate and [the chloro- 3- of 5- [(4,5- dihydro -3- methyl -5- oxo -1- phenyl -1H- pyrazoles -
4- yls) azo] conjunction of -2- hydroxy benzene sulfonic acids root] 145 parts of hydroxyl chromic acid hydrogen, reactor pressure is lifted, 2.25MPa is reached, temperature
It is 225 DEG C to spend, polymerisation 20 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 35 DEG C are cooled to, discharging enters
Molding press can be prepared by abrasion-proof backing block 4-2;
The crosslinking agent is 3- (3,4- difluorophenyls) pyrazoles.
Reference examples
Reference examples are the abrasion-proof backing block of commercially available certain brand.
Embodiment 4
The abrasion-proof backing block described in abrasion-proof backing block 4-2 and reference examples that embodiment 1~3 is prepared carries out using effect contrast.
The two abrasion resistance, compression strength, hardness, deformation ratio are counted, as a result as shown in table 1.
As seen from Table 1, the indexs such as abrasion-proof backing block 4-2 of the present invention, its abrasion resistance, compression strength, hardness, deformation ratio
It is superior to the product of prior art production.
Additionally, as shown in figure 4, being that abrasion-proof backing block 4-2 material against oxidative rate of the present invention changes with use time
Statistics.Find out in figure, abrasion-proof backing block 4-2 used by embodiment 1~3, its material against oxidative rate with use time intensity of variation significantly
Better than existing product.
Claims (5)
1. it is a kind of for air entrained concrete make former, including:Screw feeder (1), Support bracket (2), one is grading
Air pipe (3), balling drum (4), secondary inlet pipeline (5), maintenance door (6), pneumatic discharge gate (7), rotary electric machine
(8), rotation cam (9), damper pulley (10), control system (11);Characterized in that, the Support bracket (2) is stainless
Steelframe;The balling drum (4) is fixedly mounted on Support bracket (2) top;The screw feeder (1) is arranged in ball mill
Roller (4) side, screw feeder (1) is connected with balling drum (4) insertion;The rotation cam (9) is arranged at ball mill
Roller (4) opposite side, rotation cam (9) is connected with balling drum (4) coaxial rotating;The rotary electric machine (8) is by damping
Belt pulley (10) is connected with rotation cam (9);The one-level air inlet pipeline (3) positioned at balling drum (4) upper side,
One-level air inlet pipeline (3) insertion connects balling drum (4), wherein the one-level air inlet pipeline (3) is provided with one-level and enters pneumoelectric
Magnet valve;The secondary inlet pipeline (5) is positioned at balling drum (4) top opposite side, secondary inlet pipeline (5) insertion connected ball
Grinding machine roller (4), wherein the secondary inlet pipeline (5) is provided with secondary inlet magnetic valve;The maintenance door (6) is arranged at ball
Grinding machine roller (4) side wall;The pneumatic discharge gate (7) is arranged at the side-lower of balling drum (4), pneumatic discharge gate
(7) it is connected with balling drum (4) insertion;The control system (11) is fixedly mounted on Support bracket (2);
The pneumatic discharge gate (7), rotary electric machine (8) control to be connected by wire and control system (11) respectively;
The one-level air inlet electromagnetic valve, secondary inlet magnetic valve control to be connected by wire and control system (11) respectively.
2. it is according to claim 1 it is a kind of for air entrained concrete make former, it is characterised in that the spiral
Dispenser (1) includes:Variable-frequency motor (1-1), feed hopper (1-2) is fed chamber (1-3), feed rotary shaft (1-4), pressure feeding spiral
Blade (1-5), photoelectric sensor (1-6), putty detector (1-7);Wherein, the feed chamber (1-3) is cylinder knot
Structure, its external diameter is between 60cm~70cm;The feed hopper (1-2) is arranged at feed chamber (1-3) side top, feed hopper (1-
2) it is connected with feed chamber (1-3) insertion;It is internal that feed rotary shaft (1-4) is arranged at feed chamber (1-3);The feed rotation
Axle (1-4) one end is installed with variable-frequency motor (1-1);The pressure feeding spiral blade (1-5) is fixedly mounted on feed rotary shaft
On (1-4), variable-frequency motor (1-1) drives feed rotary shaft (1-4) to do coaxial rotating motion, and pressure feeding spiral blade (1-5) is being given
Material rotary shaft (1-4) is threadingly advanced motion under driving;The photoelectric sensor (1-6) is fixedly mounted on feed chamber (1-3)
Outer wall side;The putty detector (1-7) is arranged at feed hopper (1-2) inwall bottom;The variable-frequency motor (1-1), photoelectricity
Speed probe (1-6), putty detector (1-7) control to be connected by wire and control system (11) respectively.
3. it is according to claim 1 it is a kind of for air entrained concrete make former, it is characterised in that the ball milling
Machine cylinder (4) includes:Cylinder shell (4-1), abrasion-proof backing block (4-2), one-level abrasive medium (4-3), abrasive material chamber dividing plate (4-4),
One-level droplet measurement device (4-5), secondary grinding material medium (4-6), discharge partition plate (4-7), secondary particle size detector (4-8);Wherein,
The cylinder shell (4-1) is steel plate material, and its thickness is between 5cm~8cm;Abrasion-proof backing block (4-2) dismounting is connected to
Cylinder shell (4-1) is internal;The one-level abrasive medium (4-3) is steel ball with secondary grinding material medium (4-6), wherein one
Level abrasive medium (4-3) spheroid external diameter between 9cm~13cm, secondary grinding material medium (4-6) spheroid external diameter 4cm~6cm it
Between;Abrasive material chamber dividing plate (4-4) is arranged at balling drum (4) middle part, abrasive material chamber dividing plate (4-4) and balling drum (4)
Between 50cm~80cm, space is first to the distance between feedstock direction barrel between abrasive material chamber dividing plate (4-4) and the barrel
Abrasive material chamber, one-level abrasive medium (4-3) is positioned in the first abrasive material chamber;One-level droplet measurement device (4-5) fixed installation
In the first abrasive material luminal wall surface;The discharge partition plate (4-7) be arranged at balling drum (4) discharging direction side, discharging every
Space between plate (4-7) and abrasive material chamber dividing plate (4-4) is the second abrasive material chamber, and the secondary grinding material medium (4-6) is positioned over this
In second abrasive material chamber;The secondary particle size detector (4-8) is fixedly mounted on the second abrasive material luminal wall surface;
The one-level droplet measurement device (4-5), secondary particle size detector (4-8) are controlled by wire and control system (11) respectively
Connection.
4. it is according to claim 3 it is a kind of for air entrained concrete make former, it is characterised in that it is described wear-resisting
Liner plate (4-2) is molded by macromolecular material pressing mold, and the constituent and manufacturing process of abrasion-proof backing block (4-2) are as follows:
First, abrasion-proof backing block (4-2) constituent:
Count by weight, 1- (8- azabicyclos [3.2.1] -3- octyl groups) 65~125 parts of -2- methyl isophthalic acid H- benzimidazoles,
(6R, trans) 7- amino -3- [(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] methyl -8- oxo -5- thia -1- azabicyclos
55~155 parts of [4.2.5] oct-2-ene carboxylic acid, 7- amino -3- (1- methyl isophthalic acid H- tetrazolium -5- sulphomethyls) -8- oxo -5- sulphur
Miscellaneous 95~215 parts of -1- azabicyclos [4.2.5] oct-2-ene -2- carboxylic acids, 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5-
Thia -1- azabicyclo [4.2.5] oct-2-ene-second carboxylic acid -2,2,2- 15~55 parts of trichloro ethyl esters, 4- amino -2- (benzyl ammonia
Base) 75~135 parts of -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters, 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyanogen
35~75 parts of two strontium of base -3- thiophene acetic acids, concentration is the 2- [[4- [ethyl (2- Phenoxyethyls) amino] of 25ppm~55ppm
Phenyl] azo] 55~115 parts of -5- nitro -3- cyano thiophenes, N- [2- [(bromo- 4, the 6- dinitrophenyls of 2-) azo] -5- [(2-
Cyanoethyl) ethylamino] -4- anisyls] 35~75 parts of acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azos
Base] -5- (lignocaine) phenyl] 115~145 parts of propionamide, 65~195 parts of crosslinking agent, 5- (methyl thio) -3- (2- thiophenes
Fen) 45~115 parts of -1H- pyrazoles -4- formonitrile HCNs, two [3- [4,5- dihydro -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3-
Methyl -5- oxo -1H-1- pyrazolyls]] benzsulfamide (2-)] 25~85 parts of chromic acid (1-) sodium is closed, chromic acid closes two [2- (4,5- bis-
Hydrogen -3- methyl -5- oxygen -1- phenyl -1H-4- pyrazolyls) azo] 45~135 parts of Sodium Benzoate, [the chloro- 3- of 5- [(4,5- dihydros -
3- methyl -5- oxo -1- phenyl -1H- pyrazoles -4- bases) azo] conjunction of -2- hydroxy benzene sulfonic acids root] 85~165 parts of hydroxyl chromic acid hydrogen;
The crosslinking agent is 2- cyclohexyloxy -5- iodine pyridines, 5- hexyls -2- (the own oxygen phenyl of 4-) pyrimidine, 3- (3,4- difluorobenzenes
Base) any one in pyrazoles;
2nd, the manufacturing process of abrasion-proof backing block (4-2), comprises the steps of:
1st step:1375~1645 parts of ultra-pure water for adding electrical conductivity to be 2.25 μ S/cm~4.25 μ S/cm in a kettle., starts
Agitator in reactor, rotating speed is 65rpm~125rpm, starts heat pump, reactor temperature is risen to 45 DEG C~75 DEG C;
Sequentially add 1- (8- azabicyclos [3.2.1] -3- octyl groups) -2- methyl isophthalic acid H- benzimidazoles, (6R, trans) 7- amino -3-
[(1- methyl isophthalic acid H- tetrazole -5- bases) sulphur] methyl -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes carboxylic acid, 7-
Amino -3- (1- methyl isophthalic acid H- tetrazolium -5- sulphomethyls) -8- oxo -5- thia -1- azabicyclo [4.2.5] oct-2-enes -2-
Carboxylic acid, to being completely dissolved, regulation pH value is 3.5~6.5, and agitator speed is adjusted into 135rpm~255rpm, and temperature is for stirring
95 DEG C~135 DEG C, esterification 15~25 hours;
2nd step:Take 3- methyl -8- oxos -7- (2- phenylacetylaminos) -5- thia -1- azabicyclo [4.2.5] oct-2-ene-second
Carboxylic acid -2,2,2- trichloro ethyl esters, 4- amino -2- (benzylamino) -5- (4- benzoyl bromides) thiophene -3- carboxylic acid, ethyl esters carry out powder
Broken, powder diameter is 525~1355 mesh;Add the strontium of 5- [double (carboxymethyl) amino] -2- carboxyl -4- cyano group -3- thiophene acetic acids two
It is well mixed, it is laid in pallet, tiling thickness is 35mm~55mm, uses the dosage to be for 3.5kGy~9.5kGy, energy
The alpha ray of 5.5MeV~14.5MeV is irradiated 65~145 minutes, and Isodose β x ray irradiation xs 55~135 minutes;
3rd step:Through the 2nd step process mixed-powder be dissolved in 2- [[4- [ethyl (2- Phenoxyethyls) amino] phenyl] azo]-
In 5- nitro -3- cyano thiophenes, reactor is added, agitator speed is 75rpm~185rpm, and temperature is 85 DEG C~165 DEG C, is opened
Dynamic vavuum pump makes the vacuum of reactor reach 1.35MPa~1.85MPa, keeps this state response 15~35 hours;Pressure release is simultaneously
Radon gas is passed through, makes reacting kettle inner pressure for 1.25MPa~1.65MPa, insulation stands 25~35 hours;Agitator speed is promoted to
155rpm~295rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add N- [2- [(the bromo- 4,6- dinitrophenyls of 2-) azo]-
5- [(2- cyanoethyls) ethylamino] -4- anisyls] acetamide, (E)-N- [2- [(the bromo- 6- cyano group -4- nitrobenzene of 2-) azos
Base] -5- (lignocaine) phenyl] after propionamide is completely dissolved, add crosslinking agent stirring mixing so that reactor solution it is hydrophilic
Lipophilic balance value is 5.5~8.5, and insulation stands 25~45 hours;
4th step:When agitator speed is 145rpm~225rpm, 5- (methyl thio) -3- (2- thiophene) -1H- is sequentially added
Pyrazoles -4- formonitrile HCNs, two [3- [4,5- dihydros -4- [(2- hydroxy-5-methyl base -3- nitrobenzene) azo -3- methyl -5- oxos -1H-
1- pyrazolyls]] benzsulfamide (2-)] close chromic acid (1-) sodium, chromic acid close two [2- (4,5- dihydro -3- methyl -5- oxygen -1- phenyl -
1H-4- pyrazolyls) azo] Sodium Benzoate and [the chloro- 3- of 5- [(4,5- dihydro -3- methyl -5- oxo -1- phenyl -1H- pyrazoles -4-
Base) azo] conjunction of -2- hydroxy benzene sulfonic acids root] hydroxyl chromic acid hydrogen, reactor pressure is lifted, 1.95MPa~2.75MPa is reached,
Temperature is 145 DEG C~265 DEG C, polymerisation 15~25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to
25 DEG C~45 DEG C, discharging enters molding press and can be prepared by abrasion-proof backing block (4-2).
5. it is a kind of for air entrained concrete make former method of work, it is characterised in that the method include it is following several
Individual step:
1st step:Air entrained concrete after broken is made raw material and is entered into feed hopper (1-2) with the speed of 1.5m/s, through feed
Pressure feeding spiral blade (1-5) in chamber (1-3) is delivered in balling drum (4);
2nd step:Air entrained concrete makes raw material in chamber (1-3) interior course of conveying is fed, and putty detector (1-7) is to feed hopper
(1-2) bottom feed situation real-time monitoring, photoelectric sensor (1-6) is to variable-frequency motor (1-1) rotating speed real-time monitoring, photoelectricity
Variable-frequency motor (1-1) tach signal that speed probe (1-6) will be detected is sent to control system (11), control system (11)
Interior display module shows variable-frequency motor (1-1) tach signal in real time;When putty detector (1-7) detects feed hopper (1-2)
When bottoms material density is higher than 25ml/cm3, electric signal is sent to control system (11), control system by putty detector (1-7)
(11) control variable-frequency motor (1-1) reduces rotating speed;When putty detector (1-7) detects feed hopper (1-2) bottoms material density
During less than 10ml/cm3, electric signal is sent to control system (11), control system (11) control frequency conversion by putty detector (1-7)
Motor (1-1) improves rotating speed;
3rd step:After air entrained concrete making raw material enters balling drum (4), balling drum (4) is in rotary electric machine (8) band
Circumference rotary motion is done under dynamic, the one-level abrasive medium (4-3) in balling drum (4) and secondary grinding material medium (4-6)
Raw material is smashed under gravity;
4th step:During one-level abrasive medium (4-3) smashes raw material, one-level droplet measurement device (4-5) is to the first abrasive material chamber
Interior raw material particle size real-time monitoring, 500 are reached when one-level droplet measurement device (4-5) detects the raw material particle size in the first abrasive material chamber
During mesh, feedback signal is sent to control system (11) by one-level droplet measurement device (4-5), and control system (11) opens one-level air inlet
One-level air inlet electromagnetic valve in pipeline (3), under high velocity air drive, the raw material in the first abrasive material chamber after smashing is by mill
Material chamber dividing plate (4-4) is entered into the second abrasive material chamber;
5th step:During secondary grinding material medium (4-6) smashes raw material, secondary particle size detector (4-8) is to the second abrasive material chamber
Interior raw material particle size real-time monitoring, reaches when secondary particle size detector (4-8) detects the raw material particle size in the second abrasive material chamber
During 1200 mesh, feedback signal is sent to control system (11) by secondary particle size detector (4-8), and control system (11) opens two grades
Secondary inlet magnetic valve in air inlet pipeline (5), meanwhile, control system (11) controls pneumatic discharge gate (7) to open, at a high speed
Under air-flow drives, the raw material in the second abrasive material chamber after smashing is conveyed by discharge partition plate (4-7) through pneumatic discharge gate (7)
To in aggregate bin.
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CN107866902A (en) * | 2017-11-07 | 2018-04-03 | 南昌叁润科技有限公司 | One kind building mixed mud agitating device |
CN108579623A (en) * | 2018-04-13 | 2018-09-28 | 浙江工业大学 | A kind of mixed intensified medium of ball-type strengthens the reaction unit and method of mixed continuous production dimeric dibasic acid |
CN109622155A (en) * | 2019-01-18 | 2019-04-16 | 深圳粤通应用材料有限公司 | A kind of self cooling self-cleaning high-performance ball mill of silver paste processing |
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CN113368972A (en) * | 2020-11-03 | 2021-09-10 | 东莞市华汇精密机械有限公司 | Double dynamical no screen cloth intelligence nanometer sand mill |
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CN113585269B (en) * | 2021-09-27 | 2021-12-17 | 国能大渡河大数据服务有限公司 | Construction safety monitoring method and system for hydropower engineering |
CN115182777A (en) * | 2022-07-04 | 2022-10-14 | 中勘资源勘探科技股份有限公司 | Coal gangue processing and treating device for grouting filling |
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