CN106861299A - A kind of chromium-containing waste gas processing unit - Google Patents

A kind of chromium-containing waste gas processing unit Download PDF

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Publication number
CN106861299A
CN106861299A CN201710267803.7A CN201710267803A CN106861299A CN 106861299 A CN106861299 A CN 106861299A CN 201710267803 A CN201710267803 A CN 201710267803A CN 106861299 A CN106861299 A CN 106861299A
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China
Prior art keywords
pipeline
detector
wire
collection device
medicament
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Granted
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CN201710267803.7A
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Chinese (zh)
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CN106861299B (en
Inventor
赵子宁
钟建筑
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Nantong Zhongyi Chemical Co ltd
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Individual
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Priority to CN201810132453.8A priority Critical patent/CN108236837B/en
Priority to CN201710267803.7A priority patent/CN106861299B/en
Publication of CN106861299A publication Critical patent/CN106861299A/en
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Publication of CN106861299B publication Critical patent/CN106861299B/en
Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/346Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/42Basic components
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/70Treatment of water, waste water, or sewage by reduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • C02F2101/22Chromium or chromium compounds, e.g. chromates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A kind of chromium-containing waste gas processing unit, belong to industrial waste gas processing technology field, the filter is connected by wire with power supply, the filter is connected with particle collection device and PH detector respectively by pipeline, valve is installed between the filter and particle collection device, the PH detector is connected with acid fog collection device and alkali mist collection device respectively by pipeline, the acid fog collection device and alkali mist collection device are connected with PH detector respectively, the PH detector is connected by wire with controller, the controller is connected with cryogenic system by wire, the cryogenic system is connected with liquid waste treating apparatus by wire, the liquid waste treating apparatus are connected by pipeline with absorbent charcoal adsorber, the absorbent charcoal adsorber is connected by pipeline with detector.The usefulness of the invention is:So that the treatment of chromium-containing waste gas is more automated, meet the principle of green production.

Description

A kind of chromium-containing waste gas processing unit
Technical field
The present invention relates to a kind of chromium-containing waste gas processing unit, specifically using waste gas holding vessel, filter, PH detections Device, acid mist treatment device, alkali mist processing unit, controller composition belongs to industrial waste gas processing technology field.
Background technology
With the development of the modern industry, increasing factory rises sheer from level ground, and various fresh products enter people successively Life, bring unprecedented convenience to us, at the same time, the pollution that industrial production is brought also increasingly causes people Attention.Especially to health, environment has very big harm to industrial waste gas, and waste gas can be by different approach respiratory tracts Into the internal of people, it is detrimental to health, the World Health Organization claims, air pollution in 2012 causes about 7,000,000 people dead, also It is just have one in every eight the dead in the whole world.Secondly, industrial waste gas can be reduced to the solar radiation up to ground, and the time is long to lead People and animals and plants are caused to be grown due to a lack of sunlight bad, due to containing carbon dioxide and other sour gas in industrial waste gas Body, can cause atmospheric temperature to raise, or even deacidification rain, therefore, increase and country's discharge mark is reached to the dynamics of exhaust-gas treatment Standard, the slogan of response national green production turns into the top priority of current Chemical Manufacture.
The content of the invention
For above-mentioned deficiency, the invention provides a kind of chromium-containing waste gas processing unit.
The present invention is achieved by the following technical solutions:A kind of chromium-containing waste gas processing unit, by waste gas holding vessel, filtering Device, PH detector, acid mist treatment device, alkali mist processing unit, controller, cryogenic system, particle collection device, pipeline, valve, Liquid waste treating apparatus, absorbent charcoal adsorber, detector, air compressor, tower top kettle, reflux ratio controller, power supply, lead Line, condenser, waste liquid holding vessel, standby pool, precipitation storage pond, medicament sedimentation basin, amberplex, medicament reduction pond, master control Room processed, kinetic pump, alarm composition, it is mainly characterized by:The waste gas holding vessel is connected by pipe-and-filter, described Filter is connected by wire with power supply, and the filter is connected with particle collection device and PH detector respectively by pipeline Connect, valve be installed between the filter and particle collection device, the PH detector by pipeline respectively with acid mist collecting Device is connected with alkali mist collection device, and the acid fog collection device and alkali mist collection device are connected with PH detector respectively, The PH detector is connected by wire with controller, and the controller is connected with cryogenic system by wire, the depth Device for cooling is connected with liquid waste treating apparatus by wire, and the liquid waste treating apparatus pass through pipeline and absorbent charcoal adsorber phase Connection, the absorbent charcoal adsorber is connected by pipeline with detector.
Cryogenic system includes air compressor, tower top kettle, reflux ratio controller, power supply, wire, condenser, waste liquid storage Tank;In cryogenic system, the power supply is connected by wire with kinetic pump, and the kinetic pump passes through pipeline and air compressor It is connected, the air compressor is connected with tower top kettle by pipeline, the tower top kettle is connected by pipeline with condenser, The condenser is connected by pipeline with reflux ratio controller, the reflux ratio controller by pipeline respectively with tower top kettle and Waste liquid holding vessel is connected.
Liquid waste treating apparatus include standby pool, and precipitation storage pond, medicament sedimentation basin, amberplex, medicament reduction pond is main Control room, PH detector, particle collection device, wire;In liquid waste treating apparatus, the amberplex is distinguished by pipeline It is connected with particle collection device and medicament reduction pond, the medicament reduction pond is connected by pipeline with medicament sedimentation basin, institute State medicament sedimentation basin to be connected with precipitation storage pond and standby pool respectively by pipeline, PH inspections are installed in the medicament sedimentation basin Device is surveyed, the PH detector is connected by wire with alarm, and the alarm is connected to main control room by radio link.
The usefulness of the invention is:Waste gas is removed by acid-base property by emission-control equipment, will be useless by cryogenic system Gas becomes waste liquid, so as to directly be processed chromate waste water using medicament reduction precipitation method, final waste gas is filled by charcoal absorption Put to adsorb last waste residue and cause that the treatment of chromium-containing waste gas is more automated and facilitate, while reduction operation cost, accords with Close the principle of green production.
Brief description of the drawings
Fig. 1 is a kind of front view of chromium-containing waste gas processing unit;
Fig. 2 is a kind of cryogenic system figure of chromium-containing waste gas processing unit;
Fig. 3 is a kind of liquid waste treating apparatus figure of chromium-containing waste gas processing unit;
Fig. 4 is a kind of partial view of chromium-containing waste gas processing unit.
In figure, 1, waste gas holding vessel, 2, filter, 3, PH detector, 4, acid mist treatment device, 5, alkali mist processing unit, 6th, controller, 7, cryogenic system, 8, particle collection device, 9, pipeline, 10, valve, 11, liquid waste treating apparatus, 12, activated carbon inhales Adsorption device, 13, detector, 14, air compressor, 15, tower top kettle, 16, reflux ratio controller, 17, power supply, 18, wire, 19th, condenser, 20, waste liquid holding vessel, 21, standby pool, 22, precipitation storage pond, 23, medicament sedimentation basin, 24, amberplex, 25th, medicament reduction pond, 26, main control room, 27, kinetic pump, 28, alarm.
Specific embodiment
A kind of chromium-containing waste gas processing unit, by waste gas holding vessel 1, filter 2, PH detector 3, acid mist treatment device 4, alkali Mist processing unit 5, controller 6, cryogenic system 7, particle collection device 8, pipeline 9, valve 10, liquid waste treating apparatus 11, activity Charcoal adsorbent equipment 12, detector 13, air compressor 14, tower top kettle 15, reflux ratio controller 16, power supply 17, wire 18, Condenser 19, waste liquid holding vessel 20, standby pool 21, precipitation storage pond 22, medicament sedimentation basin 23, amberplex 24, medicament are also Former pond 25, main control room 26, kinetic pump 27, alarm 28 are constituted, and it is mainly characterized by:The waste gas holding vessel 1 passes through pipeline 9 It is connected with filter 2, the filter 2 is connected by wire 18 with power supply 17, the filter 2 is distinguished by pipeline 9 It is connected with particle collection device 8 and PH detector 3, valve 10 is installed between the filter 2 and particle collection device 8, The PH detector 3 is connected with acid fog collection device and alkali mist collection device respectively by pipeline 9, the acid fog collection device It is connected with PH detector 3 respectively with alkali mist collection device, the PH detector 3 is connected by wire 18 with controller 6, institute State controller 6 to be connected by wire 18 with cryogenic system 7, the cryogenic system 7 passes through wire 18 with liquid waste treating apparatus 11 It is connected, the liquid waste treating apparatus 11 are connected by pipeline 9 with absorbent charcoal adsorber 12, the absorbent charcoal adsorber 12 are connected by pipeline 9 with detector 13.
Cryogenic system 7 includes air compressor 14, tower top kettle 15, reflux ratio controller 16, power supply 17, wire 18, condensation Device 19, waste liquid holding vessel 20;In cryogenic system 7, the power supply 17 is connected by wire 18 with kinetic pump 27, the power Pump 27 is connected by pipeline 9 with air compressor 14, and the air compressor 14 is connected with tower top kettle 15 by pipeline 9, The tower top kettle 15 is connected by pipeline 9 with condenser 19, and the condenser 19 passes through pipeline 9 and the phase of reflux ratio controller 16 Connection, the reflux ratio controller 16 is connected with tower top kettle 15 and waste liquid holding vessel 20 respectively by pipeline 9.
Liquid waste treating apparatus 11 include standby pool 21, precipitation storage pond 22, medicament sedimentation basin 23, amberplex 24, medicine Agent reduces pond 25, main control room 26, PH detector 3, particle collection device 8, wire 18;It is described in liquid waste treating apparatus 11 Amberplex 24 reduces pond 25 and is connected with particle collection device 8 and medicament respectively by pipeline 9, and the medicament reduces pond 25 Be connected with medicament sedimentation basin 23 by pipeline 9, the medicament sedimentation basin 23 by pipeline 9 respectively with precipitation storage pond 22 and standby It is connected with pond 21, PH detector 3 is installed in the medicament sedimentation basin 23, the PH detector 3 is by wire 18 and alarm Device 28 is connected, and the alarm 28 is connected to main control room 26 by radio link.
During work:The chromium-containing waste gas of the storage of waste gas holding vessel 1 are delivered to filter 2 and separate large particulate matter, point After a period of time, opening valve 10 is by collecting material in particle collection device 8;Waste gas after filtering passes through PH detector 3 Detection acid-base property, selectivity disposes acid mist or alkali mist into acid mist or alkali mist processing unit, the gas after treatment again by PH detector 3 is tested, and when PH concentration is not up to standard, squeezed into again in acid mist or alkali mist processing unit and is processed, until PH concentration reaches Mark, controller 6 is passed to by electric signal, and waste gas is delivered to cryogenic system 7 by controller 6.In cryogenic system 7, by power Be delivered to waste gas in air compressor 14 waste gas be compressed into required pressure by pump 27, thoroughly remove aerial vapor with Carbon dioxide, heat exchange is carried out subsequently into tower top kettle 15 with the waste gas for backflowing;Waste gas into being condensed into liquid after condenser 19, By reflux ratio controller 16 by liquid with 5:1 ratio is delivered in waste liquid holding vessel 20 and tower top kettle 15 respectively, so follows All waste gases are all become waste liquid by ring.Waste liquid enters liquid waste treating apparatus 11 from after the treatment of cryogenic system 7, by amberplex Finely ground particle substance is separated and is collected into particle collection device 8 by 24;Waste liquid after treatment is delivered to medicament reduction pond In 25, hexavalent chromium is reduced into trivalent chromic ion by the effect of reducing agent;Medicament sedimentation basin 23 is next moved to, Lime or NaOH are added in sedimentation basin, it is generated chromium hydroxide precipitation in the basic conditions, so as to remove chromium ion; PH detector 3 in medicament sedimentation basin 23 detect PH concentration be not enough to precipitation chromium ion when, electric signal is passed into master control Room processed 26, opens valve 10 and the liquid in sedimentation basin is delivered into standby pool 21, while chromium hydroxide precipitation is stored to medicament Sedimentation basin 23, medicament sedimentation basin 23 is conveyed back after medicament is prepared and precipitation process is complete and is proceeded with one's work.After treatment Be changed into waste gas and adsorbed into absorbent charcoal adsorber 12 after waste liquid decompression, through detector 13 it is qualified after just can be emitted into In air, if unqualified into the circulation work of absorbent charcoal adsorber 12 untill qualified.
For the ordinary skill in the art, teaching of the invention, do not depart from principle of the invention with In the case of spirit, the changes, modifications that are carried out to implementation method, replace and modification still fall within protection scope of the present invention it It is interior.

Claims (3)

1. a kind of chromium-containing waste gas processing unit, is processed by waste gas holding vessel, filter, PH detector, acid mist treatment device, alkali mist Device, controller, cryogenic system, particle collection device, pipeline, valve, liquid waste treating apparatus, absorbent charcoal adsorber, gas Detector, air compressor, tower top kettle, reflux ratio controller, power supply, wire, condenser, waste liquid holding vessel, standby pool, precipitation Storage pond, medicament sedimentation basin, amberplex, medicament reduction pond, main control room, kinetic pump, alarm composition, its principal character It is:The waste gas holding vessel is connected by pipe-and-filter, and the filter is connected by wire with power supply, the mistake Filter is connected with particle collection device and PH detector respectively by pipeline, is pacified between the filter and particle collection device Equipped with valve, the PH detector is connected with acid fog collection device and alkali mist collection device respectively by pipeline, the acid mist Collection device and alkali mist collection device are connected with PH detector respectively, and the PH detector is connected by wire with controller Connect, the controller is connected with cryogenic system by wire, the cryogenic system is connected with liquid waste treating apparatus by wire Connect, the liquid waste treating apparatus are connected by pipeline with absorbent charcoal adsorber, the absorbent charcoal adsorber passes through pipeline It is connected with detector.
2. a kind of chromium-containing waste gas processing unit according to claim 1, it is characterised in that:Cryogenic system compresses including air Device, tower top kettle, reflux ratio controller, power supply, wire, condenser, waste liquid holding vessel, in cryogenic system, the power supply passes through Wire is connected with kinetic pump, and the kinetic pump is connected by pipeline with air compressor, the air compressor and tower top Kettle is connected by pipeline, and the tower top kettle is connected by pipeline with condenser, and the condenser passes through pipeline and reflux ratio Controller is connected, and the reflux ratio controller is connected with tower top kettle and waste liquid holding vessel respectively by pipeline.
3. a kind of chromium-containing waste gas processing unit according to claim 1, it is characterised in that:Liquid waste treating apparatus include standby Pond, precipitation storage pond, medicament sedimentation basin, amberplex, medicament reduction pond, main control room, PH detector, powder collection dress Put, wire, in liquid waste treating apparatus, the amberplex reduces pond with particle collection device and medicament respectively by pipeline Be connected, medicament reduction pond is connected by pipeline with medicament sedimentation basin, the medicament sedimentation basin pass through pipeline respectively with Precipitation storage pond is connected with standby pool, and PH detector is provided with the medicament sedimentation basin, and the PH detector passes through wire It is connected with alarm, the alarm is connected to main control room by radio link.
CN201710267803.7A 2017-04-21 2017-04-21 A kind of chromium-containing waste gas processing unit Expired - Fee Related CN106861299B (en)

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CN201810132453.8A CN108236837B (en) 2017-04-21 2017-04-21 Chromium-containing waste gas treatment device
CN201710267803.7A CN106861299B (en) 2017-04-21 2017-04-21 A kind of chromium-containing waste gas processing unit

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CN110801721A (en) * 2019-09-30 2020-02-18 江苏华洋新思路能源装备股份有限公司 Waste gas treatment system for coal chemical industry
CN112504962A (en) * 2020-12-04 2021-03-16 江苏源泉智能装备科技有限公司 Portable electroplating workshop chromic acid fog automatic checkout device

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CN109289759B (en) * 2018-11-23 2021-06-18 张少强 Solid alkali adsorbent and integrated device for synchronously treating acid gas and organic waste gas
CN111068414A (en) * 2019-12-17 2020-04-28 一汽解放汽车有限公司 Air filtering system and filtering method
CN111129547A (en) * 2019-12-31 2020-05-08 一汽解放汽车有限公司 Identification control device and method for gas quality of cathode air filter of hydrogen fuel cell

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Publication number Priority date Publication date Assignee Title
CN110801721A (en) * 2019-09-30 2020-02-18 江苏华洋新思路能源装备股份有限公司 Waste gas treatment system for coal chemical industry
CN112504962A (en) * 2020-12-04 2021-03-16 江苏源泉智能装备科技有限公司 Portable electroplating workshop chromic acid fog automatic checkout device
CN112504962B (en) * 2020-12-04 2022-09-20 江苏源泉智能装备科技有限公司 Portable electroplating workshop chromic acid fog automatic checkout device

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CN108236837A (en) 2018-07-03
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