CN106848453B - 钠离子电池补钠的方法及钠离子电池 - Google Patents
钠离子电池补钠的方法及钠离子电池 Download PDFInfo
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- CN106848453B CN106848453B CN201710142916.4A CN201710142916A CN106848453B CN 106848453 B CN106848453 B CN 106848453B CN 201710142916 A CN201710142916 A CN 201710142916A CN 106848453 B CN106848453 B CN 106848453B
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- Prior art keywords
- sodium
- ion battery
- battery
- ion
- substance
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- 229910001415 sodium ion Inorganic materials 0.000 title claims abstract description 114
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 title claims abstract description 113
- 239000011734 sodium Substances 0.000 title claims abstract description 45
- 229910052708 sodium Inorganic materials 0.000 title claims abstract description 41
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 25
- 230000008901 benefit Effects 0.000 title description 8
- 239000000126 substance Substances 0.000 claims abstract description 45
- 239000002184 metal Substances 0.000 claims abstract description 43
- 229910052751 metal Inorganic materials 0.000 claims abstract description 41
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 29
- 239000000654 additive Substances 0.000 claims abstract description 27
- 230000000996 additive effect Effects 0.000 claims abstract description 27
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 14
- 239000007774 positive electrode material Substances 0.000 claims abstract description 8
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 39
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 19
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 14
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 239000003792 electrolyte Substances 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000011149 active material Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 230000005611 electricity Effects 0.000 claims description 5
- CFVBFMMHFBHNPZ-UHFFFAOYSA-N [Na].[V] Chemical compound [Na].[V] CFVBFMMHFBHNPZ-UHFFFAOYSA-N 0.000 claims description 4
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- BNBLBRISEAQIHU-UHFFFAOYSA-N disodium dioxido(dioxo)manganese Chemical compound [Na+].[Na+].[O-][Mn]([O-])(=O)=O BNBLBRISEAQIHU-UHFFFAOYSA-N 0.000 claims description 3
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- RHFUXPCCELGMFC-UHFFFAOYSA-N n-(6-cyano-3-hydroxy-2,2-dimethyl-3,4-dihydrochromen-4-yl)-n-phenylmethoxyacetamide Chemical compound OC1C(C)(C)OC2=CC=C(C#N)C=C2C1N(C(=O)C)OCC1=CC=CC=C1 RHFUXPCCELGMFC-UHFFFAOYSA-N 0.000 claims description 3
- 229960003351 prussian blue Drugs 0.000 claims description 3
- 239000013225 prussian blue Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 229910020657 Na3V2(PO4)3 Inorganic materials 0.000 description 8
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
- 238000007086 side reaction Methods 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 239000007772 electrode material Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- ZMVMBTZRIMAUPN-UHFFFAOYSA-H [Na+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Na+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZMVMBTZRIMAUPN-UHFFFAOYSA-H 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910019463 NaV2 Inorganic materials 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 229910021385 hard carbon Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 2
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 2
- 239000005955 Ferric phosphate Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910020652 Na3V2 (PO4)3 Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940032958 ferric phosphate Drugs 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4242—Regeneration of electrolyte or reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
Description
Claims (9)
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CN201710142916.4A CN106848453B (zh) | 2017-03-10 | 2017-03-10 | 钠离子电池补钠的方法及钠离子电池 |
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CN106848453A CN106848453A (zh) | 2017-06-13 |
CN106848453B true CN106848453B (zh) | 2019-02-19 |
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Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108336301A (zh) * | 2018-02-06 | 2018-07-27 | 哈尔滨工业大学 | 一种高性能钠离子电池负极及其制备方法 |
FR3083011B1 (fr) * | 2018-06-26 | 2021-04-23 | Accumulateurs Fixes | Matiere active sacrificielle d'electrode positive pour element electrochimique sodium-ion |
CN109585844B (zh) * | 2018-11-26 | 2020-09-29 | 中南大学 | 一种补钠正极活性材料、正极材料、钠离子电池及其制备和应用 |
CN111293289A (zh) * | 2018-12-10 | 2020-06-16 | 中南大学 | 一种钠氧化物复合补钠正极活性材料、正极材料、正极、钠离子电池及其电化成补钠方法 |
CN111293288B (zh) * | 2018-12-10 | 2021-06-01 | 中南大学 | 一种NaF/金属复合补钠正极活性材料、正极材料、正极及其制备和在钠电中的应用 |
CN109786660A (zh) * | 2018-12-17 | 2019-05-21 | 中国电子科技集团公司第十八研究所 | 一种可进行正极预钠化的钠离子电池电极 |
CN110165218B (zh) * | 2019-04-04 | 2021-02-19 | 中南大学 | 一种正极补钠剂在钠离子电池中的应用 |
CN113130896B (zh) * | 2019-12-30 | 2022-11-22 | 珠海冠宇电池股份有限公司 | 一种钠离子电池用正极材料及包括该正极材料的钠离子电池 |
CN111653744B (zh) * | 2020-05-21 | 2021-11-02 | 中国科学院化学研究所 | 一种钠离子电池正极补钠添加剂、钠离子电池正极片及钠离子电池 |
CN113644271B (zh) * | 2021-08-12 | 2023-03-14 | 山东玉皇新能源科技有限公司 | 一种钠离子电池负极补钠添加剂及负极材料 |
CN113793979B (zh) * | 2021-08-18 | 2022-06-24 | 江苏正力新能电池技术有限公司 | 一种二次电池及用电装置 |
CN113823856A (zh) * | 2021-09-24 | 2021-12-21 | 湖南立方新能源科技有限责任公司 | 一种钠离子电池的化成方法、制备方法和钠离子电池 |
CN114583174B (zh) * | 2022-03-21 | 2024-03-26 | 蜂巢能源科技股份有限公司 | 一种钠离子电池及其制备方法 |
CN115863542B (zh) * | 2022-12-02 | 2024-02-20 | 厦门海辰储能科技股份有限公司 | 正极极片和电化学储能装置 |
CN116706075B (zh) * | 2023-08-09 | 2024-01-26 | 深圳海辰储能控制技术有限公司 | 补钠组合物、正极极片及其制备方法、钠离子电池 |
Citations (5)
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---|---|---|---|---|
JP2000311685A (ja) * | 1999-04-27 | 2000-11-07 | Japan Metals & Chem Co Ltd | 二次電池用リチウムマンガン複合酸化物の製造方法 |
CN102694158A (zh) * | 2012-06-13 | 2012-09-26 | 上海空间电源研究所 | 一种含硅锂负极、其制备方法及包含该负极的锂硫电池 |
WO2015133692A1 (ko) * | 2014-03-05 | 2015-09-11 | 전자부품연구원 | 양극 활물질, 그를 갖는 리튬이차전지 및 그의 제조 방법 |
CN105552344A (zh) * | 2016-02-24 | 2016-05-04 | 中国科学院物理研究所 | 一种锂离子电池正极片、锂离子电池及其制备方法 |
CN105702961A (zh) * | 2014-11-27 | 2016-06-22 | 比亚迪股份有限公司 | 一种正极材料和一种锂离子电池 |
-
2017
- 2017-03-10 CN CN201710142916.4A patent/CN106848453B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000311685A (ja) * | 1999-04-27 | 2000-11-07 | Japan Metals & Chem Co Ltd | 二次電池用リチウムマンガン複合酸化物の製造方法 |
CN102694158A (zh) * | 2012-06-13 | 2012-09-26 | 上海空间电源研究所 | 一种含硅锂负极、其制备方法及包含该负极的锂硫电池 |
WO2015133692A1 (ko) * | 2014-03-05 | 2015-09-11 | 전자부품연구원 | 양극 활물질, 그를 갖는 리튬이차전지 및 그의 제조 방법 |
CN105702961A (zh) * | 2014-11-27 | 2016-06-22 | 比亚迪股份有限公司 | 一种正极材料和一种锂离子电池 |
CN105552344A (zh) * | 2016-02-24 | 2016-05-04 | 中国科学院物理研究所 | 一种锂离子电池正极片、锂离子电池及其制备方法 |
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Address after: 518000 1-2 Floor, Building A, Xinwangda Industrial Park, No. 18 Tangjianan Road, Gongming Street, Guangming New District, Shenzhen City, Guangdong Province Patentee after: Xinwangda Power Technology Co.,Ltd. Address before: 518000 1-2 Floor, Building A, Xinwangda Industrial Park, No. 18 Tangjianan Road, Gongming Street, Guangming New District, Shenzhen City, Guangdong Province Patentee before: SUNWODA ELECTRIC VEHICLE BATTERY Co.,Ltd. |
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