CN106835716A - For processing wool or smooth brightening agent containing wool fabric and preparation method thereof - Google Patents
For processing wool or smooth brightening agent containing wool fabric and preparation method thereof Download PDFInfo
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- CN106835716A CN106835716A CN201710115027.9A CN201710115027A CN106835716A CN 106835716 A CN106835716 A CN 106835716A CN 201710115027 A CN201710115027 A CN 201710115027A CN 106835716 A CN106835716 A CN 106835716A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention discloses a kind of for processing wool or smooth brightening agent containing wool fabric, it is characterised in that the concrete component of the smooth brightening agent is as follows：Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammoniums 5% 8%, APEO 8,810 5% 10%, polyethers 6% 9%, silane coupler KN 550 3% 5%, polyester 2% 5%, D4 octamethylcy-clotetrasiloxanes 23% 26%, catalyst 1.5 2%, cold acetic acid 0.5% 1.5%, balance of deionized water.The preparation method of the smooth brightening agent is that raw material is weighed by formula rate, make of the invention to improve wool or the smooth of wool fabric, soft feel for processing wool or smooth brightening agent containing wool fabric using interim stirring, heating response, used in wool fabric post-treatment, serve the effect that good increasing is deep, increasing is gorgeous, add lustre to.
Description
Technical field
It is more particularly to a kind of for processing wool or flat containing wool fabric the present invention relates to articles for washing technical field
Sliding brightening agent and preparation method thereof.
Background technology
The Wool Textile Industry of China is the third-largest weaving pillar industry after cotton spinning and chemical fibre in textile industry, is
Produce the industry of grade textiles.China's woolen industry holds a safe lead in world's wool industry at present, and scouring of wool ability, wool top add
Work, spinning and weaving, garment production row first place in the world.China is maximum raw wool importer and country of consumption in the world, in state
Border wool in the market occupies the critical role of price leadership, with the continuous appearance of wool fabric new product, textile auxiliary market
To also develop rapidly, therefore, the demand to textile auxiliary also can accordingly increase.At present, dye industry is by national supervisor portion
Door is defined as heavy polluted industry, and textile auxiliary can not be ignored in production and application process to the influence that environment and zoology come,
So Devoting Major Efforts To Developing meets the environmentally friendly auxiliary agent of ecodevelopment, to improving auxiliary industry whole competitiveness, the product of textile auxiliary is lifted
Quality and technical merit are particularly important, meanwhile, as people are increasingly paid close attention to Green Textiles and environmental and ecological protection, ring
Guarantor's type textile auxiliary has turned into the Main way of current textile auxiliary development.International Textile ecological study and inspection association are
It is distinctly claimed, textile auxiliary also needs to meet in addition to possessing necessary use technique applicability, application performance and firm performance
The requirement of environment-friendly quality.
At present, a large amount of appearance of largely using due to domestic dyestuff, and new structure fabric, in actual production process
In, the fabric color after dyeing is not bright-coloured enough, burnt hair obfuscation, and causing the class of fabric product reduces, and competitiveness declines, and contaminates in fact
Color depth is higher, and light fastness is also better, and during dye light color, light fastness is often unqualified.And the existing organic silicon of in the market
Or though non-silicon class deep-dyeing agent, brightening agent can make moderate progress to shade fabric, the deep brightening effect of increasing is poor, increases the general feux rouges of dark light,
Fabrics smooth, soft feel are poor, product stability shortcoming, can not still reach promising result, and fabric color after repeatedly washing
Pool is decreased obviously, and loses efficiency.With the rapid growth of increasingly increase and the domestic consumption market of textile exports amount, textile industry
Demand to this product is also increasing, while also proposing the requirement for meeting environmental protection to product.Therefore, the country must increase
Research and development to fabric brightening agent auxiliary agent, develop high-effect, and environmentally friendly, durability is strong, and has to fabric feeling
The corresponding product for being improved.
The content of the invention
For defect present in prior art or deficiency, the present invention innovatively propose it is a kind of for process wool or
Smooth brightening agent containing wool fabric and preparation method thereof, the brightening agent improves smooth, the soft hand of wool or wool fabric
Sense, uses in wool fabric post-treatment, serves the effect that good increasing is deep, increasing is gorgeous, add lustre to.
The technical proposal of the invention is realized in this way：
It is a kind of for processing wool or smooth brightening agent containing wool fabric, it is characterised in that the brightening agent is by following weight hundred
Divide the component composition of ratio：Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；The 5%-10% of APEO 8810；
Polyethers 6%-9%；Silane coupler KN-550 3%-5%；Polyester 2%-5%；D4 octamethylcy-clotetrasiloxanes 23%-26%；Catalyst
1.5%-2%；Cold acetic acid 0.5%-1.5%；Deionized water surplus.
Preferably, the specific percentage by weight of the finishing agent component is as follows：Double fatty alkyl ester group hydroxyethyl methyl Methylsulfates
Ammonium 6%；APEO 88108.5%；Polyethers 8%；Silane coupler KN-550 4%；Polyester 3%；The silica of D4 prestoxs ring four
Alkane 25%；Catalyst 1.8%；Cold acetic acid 1%；Deionized water surplus.
Preferably, the catalyst is sodium hydrate aqueous solution.
A kind of preparation method for processing wool or smooth brightening agent containing wool fabric, comprises the following steps：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 45-50 DEG C by the temperature adjustment of reactor,
After temperature stabilization, by percentage by weight for the D4 octamethylcy-clotetrasiloxanes of 23%-26% are added to reactor, stirring dress is opened
Put, agitating device rotating speed is 100-200rpm, and mixing time is 30-50min, to stirring, in whipping process, by reactor
Temperature be warming up to 95 DEG C；
（3）, stirring terminate after, continue by temperature of reaction kettle control at 95 DEG C, successively by percentage by weight for 5%-10% polyoxy
The polyethers of vinethene 8810,6%-9% is added to reactor, opens agitating device, and agitating device rotating speed is 150-200rpm, is stirred
The time is mixed for 20-30min, to stirring；
（4）, by percentage by weight for 3%-5% silane coupler KN-550, by instill in the way of at the uniform velocity drop in reactor,
The whole process used time is maintained at 40min；Simultaneously by percentage by weight as the sodium hydrate aqueous solution of 1.5%-2% in the way of instilling
At the uniform velocity drop in reactor, the time control of dropwise addition is in 15-25 min；
（5）, by percentage by weight for the polyester of 2%-5% is added to reactor, 95 DEG C of reactor constant temperature opens agitating device,
Agitating device rotating speed is 200-300rpm, and mixing time is 20-30min；
（6）, temperature of reaction kettle is cooled to 45-55 DEG C after, just percentage by weight for 5%-8% double fatty alkyl ester group hydroxyl second
Ylmethyl sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 200-350rpm, during stirring
Between be 20-25min, to after stirring, filtering and discharging；
（7）, with percentage by weight be 0.5%-1.5% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 7-9, is obtained
To the muddy emulsion with gold-tinted, as finished product.
Preferably, a kind of preparation method for processing wool or smooth brightening agent containing wool fabric, including following step
Suddenly：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 47 DEG C by the temperature adjustment of reactor, temperature
After degree stabilization, the D4 octamethylcy-clotetrasiloxanes that percentage by weight is 25% are added to reactor, open agitating device, stirred
Device rotary speed is mixed for 150rpm, mixing time is 40min, to stirring, in whipping process, the temperature of reactor is warming up to
95℃；
（3）, after stirring terminates, continue temperature of reaction kettle control at 95 DEG C, successively by polyoxy second that percentage by weight is 8.5%
The polyethers of alkene ether 8810,8% is added to reactor, opens agitating device, and agitating device rotating speed is 180rpm, and mixing time is
25min, to stirring；
（4）, by percentage by weight be 4% silane coupler KN-550, at the uniform velocity dropped in reactor in the way of instilling, it is whole
The individual process used time is maintained at 40min；Simultaneously in the way of instilling by sodium hydrate aqueous solution that percentage by weight is 1.8% at the uniform velocity
Drop in reactor, the time control of dropwise addition is in 20min；
（5）, be that 3% polyester is added to reactor by percentage by weight, 95 DEG C of reactor constant temperature opens agitating device, stirring
Device rotary speed is 260rpm, and mixing time is 25min；
（6）, temperature of reaction kettle is cooled to 50 DEG C after, just percentage by weight is 6% double fatty alkyl ester group hydroxyethyl methyls
Sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 300rpm, and mixing time is 23min, extremely
After stirring, filtering and discharging；
（7）, with percentage by weight be 1% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 8, is obtained with gold-tinted
Muddy emulsion, as finished product.
Compared with prior art, the beneficial effects of the present invention are：
The invention discloses a kind of for processing wool or smooth brightening agent containing wool fabric and preparation method thereof, the brightening agent
Used in wool fabric post-treatment, serve the effect that good increasing is deep, increasing is gorgeous, add lustre to, increase dark difference up to △ E ≈
1.29-2.46, the depth for showing increases 16.83-29.33%, reduces the consumption of dyestuff, left equivalent to amount of dye 15% is increased
The right side, the color fastness of fabric is not influenceed, hence it is evident that more than half grade of the fastness to wet rubbing of lifting fabric.
Smooth brightening agent of the invention improves wool or the smooth of wool fabric, soft feel, wool or wool fabric
Washability it is splendid, by repeatedly washing after, fabric can still keep not washing preceding more than 90% color and luster；The product is without even
The group of the unfavorable environmental protection such as nitrogen, phenol, wool fabric fabric is high to brightening agent absorptivity, and without discharge contact scar, itself is biological
Degradability is good, can also directly reduce dye for fabrics consumption, meets very much environmental requirement.
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammoniums in brightening agent of the present invention are a kind of novel cation tables
Face activating agent, with excellent soft, antistatic property, yellowing-resistant.Without APEO, formaldehyde, easily biological-degradable, environmental protection.
Consumption is few, and effect is good, prepares convenient, and integrated cost is low, with high cost performance；Sodium hydrate aqueous solution synthesis when, from
Sub- uniform diameter, product quality stabilization.
Specific embodiment
With reference to specific embodiment, technical scheme is clearly and completely described, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
It is a kind of for processing wool or smooth brightening agent containing wool fabric, it is characterised in that the brightening agent by weighing as follows
Measure the component composition of percentage：Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；The 5%- of APEO 8810
10%；Polyethers 6%-9%；Silane coupler KN-550 3%-5%；Polyester 2%-5%；D4 octamethylcy-clotetrasiloxanes 23%-26%；Urge
Agent 1.5%-2%；Cold acetic acid 0.5%-1.5%；Deionized water surplus.
Preferably, the specific percentage by weight of the finishing agent component is as follows：Double fatty alkyl ester group hydroxyethyl methyl Methylsulfates
Ammonium 6%；APEO 8,810 8.5%；Polyethers 8%；Silane coupler KN-550 4%；Polyester 3%；The silica of D4 prestoxs ring four
Alkane 25%；Catalyst 1.8%；Cold acetic acid 1%；Deionized water surplus.
Preferably, the catalyst is sodium hydrate aqueous solution.
Embodiment one：
A kind of preparation method for processing wool or smooth brightening agent containing wool fabric, comprises the following steps：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 45 DEG C by the temperature adjustment of reactor, temperature
After degree stabilization, the D4 octamethylcy-clotetrasiloxanes that percentage by weight is 23% are added to reactor, open agitating device, stirred
Device rotary speed is mixed for 100rpm, mixing time is 30min, to stirring, in whipping process, the temperature of reactor is warming up to
95℃；
（3）, after stirring terminates, continue temperature of reaction kettle control at 95 DEG C, successively by polyoxyethylene that percentage by weight is 5%
The polyethers of ether 8810,6% is added to reactor, opens agitating device, and agitating device rotating speed is 150rpm, and mixing time is
20min, to stirring；
（4）, by percentage by weight be 3% silane coupler KN-550, at the uniform velocity dropped in reactor in the way of instilling, it is whole
The individual process used time is maintained at 40min；Simultaneously in the way of instilling by sodium hydrate aqueous solution that percentage by weight is 1.5% at the uniform velocity
Drop in reactor, the time control of dropwise addition is in 15min；
（5）, be that 2% polyester is added to reactor by percentage by weight, 95 DEG C of reactor constant temperature opens agitating device, stirring
Device rotary speed is 200rpm, and mixing time is 20min；
（6）, temperature of reaction kettle is cooled to 45 DEG C after, just percentage by weight is 5% double fatty alkyl ester group hydroxyethyl methyls
Sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 200rpm, and mixing time is 20min, extremely
After stirring, filtering and discharging；
（7）, with percentage by weight be 0.5% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 7, is obtained with Huang
The muddy emulsion of light, as finished product.
Embodiment two：
A kind of preparation method for processing wool or smooth brightening agent containing wool fabric, comprises the following steps：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 47 DEG C by the temperature adjustment of reactor, temperature
After degree stabilization, the D4 octamethylcy-clotetrasiloxanes that percentage by weight is 25% are added to reactor, open agitating device, stirred
Device rotary speed is mixed for 150rpm, mixing time is 40min, to stirring, in whipping process, the temperature of reactor is warming up to
95℃；
（3）, after stirring terminates, continue temperature of reaction kettle control at 95 DEG C, successively by polyoxy second that percentage by weight is 8.5%
The polyethers of alkene ether 8810,8% is added to reactor, opens agitating device, and agitating device rotating speed is 180rpm, and mixing time is
25min, to stirring；
（4）, by percentage by weight be 4% silane coupler KN-550, at the uniform velocity dropped in reactor in the way of instilling, it is whole
The individual process used time is maintained at 40min；Simultaneously in the way of instilling by sodium hydrate aqueous solution that percentage by weight is 1.8% at the uniform velocity
Drop in reactor, the time control of dropwise addition is in 20min；
（5）, be that 3% polyester is added to reactor by percentage by weight, 95 DEG C of reactor constant temperature opens agitating device, stirring
Device rotary speed is 260rpm, and mixing time is 25min；
（6）, temperature of reaction kettle is cooled to 50 DEG C after, just percentage by weight is 6% double fatty alkyl ester group hydroxyethyl methyls
Sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 300rpm, and mixing time is 23min, extremely
After stirring, filtering and discharging；
（7）, with percentage by weight be 1% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 8, is obtained with gold-tinted
Muddy emulsion, as finished product.
Embodiment three：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 50 DEG C by the temperature adjustment of reactor, temperature
After degree stabilization, the D4 octamethylcy-clotetrasiloxanes that percentage by weight is 26% are added to reactor, open agitating device, stirred
Device rotary speed is mixed for 200rpm, mixing time is 50min, to stirring, in whipping process, the temperature of reactor is warming up to
95℃；
（3）, after stirring terminates, continue temperature of reaction kettle control at 95 DEG C, successively by polyoxyethylene that percentage by weight is 10%
The polyethers of ether 8810,9% is added to reactor, opens agitating device, and agitating device rotating speed is 200rpm, and mixing time is
30min, to stirring；
（4）, by percentage by weight be 5% silane coupler KN-550, at the uniform velocity dropped in reactor in the way of instilling, it is whole
The individual process used time is maintained at 40min；The sodium hydrate aqueous solution that percentage by weight is 2% is at the uniform velocity dripped in the way of instilling simultaneously
Add in reactor, the time control of dropwise addition is in 25 min；
（5）, be that 5% polyester is added to reactor by percentage by weight, 95 DEG C of reactor constant temperature opens agitating device, stirring
Device rotary speed is 300rpm, and mixing time is 30min；
（6）, temperature of reaction kettle is cooled to 55 DEG C after, just percentage by weight is 8% double fatty alkyl ester group hydroxyethyl methyls
Sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 350rpm, and mixing time is 25min, extremely
After stirring, filtering and discharging；
（7）, with percentage by weight be 1.5% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 9, is obtained with Huang
The muddy emulsion of light, as finished product.
The preferred embodiment of invention is the foregoing is only, is not intended to limit the invention, it is all in spirit of the invention
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (5)
1. it is a kind of for processing wool or smooth brightening agent containing wool fabric, it is characterised in that the brightening agent is by following weight
The component composition of percentage：
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；
The 5%-10% of APEO 8810；
Polyethers 6%-9%；
Silane coupler KN-550 3%-5%；
Polyester 2%-5%；
D4 octamethylcy-clotetrasiloxanes 23%-26%；
Catalyst 1.5%-2%；
Cold acetic acid 0.5%-1.5%；
Deionized water surplus.
2. it is according to claim 1 for processing wool or smooth brightening agent containing wool fabric, it is characterised in that this is whole
The specific percentage by weight for managing agent component is as follows：
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammoniums 6%；
APEO 8,810 8.5%；
Polyethers 8%；
Silane coupler KN-550 4%；
Polyester 3%；
D4 octamethylcy-clotetrasiloxanes 25%；
Catalyst 1.8%；
Cold acetic acid 1%；
Deionized water surplus.
3. according to any one of claim 1 or 2 for processing wool or smooth brightening agent containing wool fabric, it is special
Levy and be, the catalyst is sodium hydrate aqueous solution.
4. the preparation side for processing wool or smooth brightening agent containing wool fabric according to claim any one of 1-3
Method, it is characterised in that comprise the following steps：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 45-50 DEG C by the temperature adjustment of reactor,
After temperature stabilization, by percentage by weight for the D4 octamethylcy-clotetrasiloxanes of 23%-26% are added to reactor, stirring dress is opened
Put, agitating device rotating speed is 100-200rpm, and mixing time is 30-50min, to stirring, in whipping process, by reactor
Temperature be warming up to 95 DEG C；
（3）, stirring terminate after, continue by temperature of reaction kettle control at 95 DEG C, successively by percentage by weight for 5%-10% polyoxy
The polyethers of vinethene 8810,6%-9% is added to reactor, opens agitating device, and agitating device rotating speed is 150-200rpm, is stirred
The time is mixed for 20-30min, to stirring；
（4）, by percentage by weight for 3%-5% silane coupler KN-550, by instill in the way of at the uniform velocity drop in reactor,
The whole process used time is maintained at 40min；Simultaneously by percentage by weight as the sodium hydrate aqueous solution of 1.5%-2% in the way of instilling
At the uniform velocity drop in reactor, the time control of dropwise addition is in 15-25 min；
（5）, by percentage by weight for the polyester of 2%-5% is added to reactor, 95 DEG C of reactor constant temperature opens agitating device,
Agitating device rotating speed is 200-300rpm, and mixing time is 20-30min；
（6）, temperature of reaction kettle is cooled to 45-55 DEG C after, just percentage by weight for 5%-8% double fatty alkyl ester group hydroxyl second
Ylmethyl sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 200-350rpm, mixing time
It is 20-25min, to after stirring, filtering and discharging；
（7）, with percentage by weight be 0.5%-1.5% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 7-9, is obtained
To the muddy emulsion with gold-tinted, as finished product.
5. the preparation method for processing wool or smooth brightening agent containing wool fabric according to claim 4, it is special
Levy and be, comprise the following steps：
（1）, weigh：Various raw materials are checked as requested, according to standby after the formula rate various raw materials of weighing；
（2）, deionization book is added in the reactor for being configured with agitating device, be 47 DEG C by the temperature adjustment of reactor, temperature
After degree stabilization, the D4 octamethylcy-clotetrasiloxanes that percentage by weight is 25% are added to reactor, open agitating device, stirred
Device rotary speed is mixed for 150rpm, mixing time is 40min, to stirring, in whipping process, the temperature of reactor is warming up to
95℃；
（3）, after stirring terminates, continue temperature of reaction kettle control at 95 DEG C, successively by polyoxy second that percentage by weight is 8.5%
The polyethers of alkene ether 8810,8% is added to reactor, opens agitating device, and agitating device rotating speed is 180rpm, and mixing time is
25min, to stirring；
（4）, by percentage by weight be 4% silane coupler KN-550, at the uniform velocity dropped in reactor in the way of instilling, it is whole
The individual process used time is maintained at 40min；Simultaneously in the way of instilling by sodium hydrate aqueous solution that percentage by weight is 1.8% at the uniform velocity
Drop in reactor, the time control of dropwise addition is in 20min；
（5）, be that 3% polyester is added to reactor by percentage by weight, 95 DEG C of reactor constant temperature opens agitating device, stirring
Device rotary speed is 260rpm, and mixing time is 25min；
（6）, temperature of reaction kettle is cooled to 50 DEG C after, just percentage by weight is 6% double fatty alkyl ester group hydroxyethyl methyls
Sulfate methyl ammonium is added to reactor, opens agitating device, and agitating device rotating speed is 300rpm, and mixing time is 23min, extremely
After stirring, filtering and discharging；
（7）, with percentage by weight be 1% glacial acetic acid debugging step（6）The pH value that mixing liquid is obtained is 8, is obtained with gold-tinted
Muddy emulsion, as finished product.
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| CN109537293A (en) * | 2018-11-27 | 2019-03-29 | 纤化（上海）生物化工股份有限公司 | A kind of all-round brightener and its preparation method and application for denim fabric |
| CN111101379A (en) * | 2019-12-30 | 2020-05-05 | 无锡太平针织有限公司 | Super-soft antistatic auxiliary agent and application thereof in bionic fiber product |
| CN113186740A (en) * | 2021-05-26 | 2021-07-30 | 德州竹洋洗涤科技有限公司 | Fabric brightening agent |
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