CN106834797B - A kind of formula and preparation method thereof of adonic dusty material - Google Patents

A kind of formula and preparation method thereof of adonic dusty material Download PDF

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Publication number
CN106834797B
CN106834797B CN201610930991.2A CN201610930991A CN106834797B CN 106834797 B CN106834797 B CN 106834797B CN 201610930991 A CN201610930991 A CN 201610930991A CN 106834797 B CN106834797 B CN 106834797B
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adonic
copper
preparation
dusty material
tin
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CN106834797A (en
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张嘉峰
张福生
罗涛
吴棕洋
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ZHEJIANG XUDE NEW MATERIAL Co Ltd
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ZHEJIANG XUDE NEW MATERIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/02Alloys based on copper with tin as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/0848Melting process before atomisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/088Fluid nozzles, e.g. angle, distance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a kind of formulas and preparation method thereof of adonic dusty material, and wherein method includes the following steps, the first step:Melting selects mass percent for 95~97% copper, and 1.5~3% nickel, 1~2.5% tin is heated to 1085~1100 DEG C, adds nickel and tin, forms aluminium alloy, 1250~1350 DEG C of smelting temperature, smelting time 20~25 minutes;Second step:Composition Control is cooled to 1200~1250 DEG C after detection is qualified;Third walks:Atomization, is injected bottom pour ladle by aluminium alloy after slagging-off, restraint-type circumferential weld nozzle is used to be atomized with 0.8~1.2Mpa air pressures, and high pressure draught smashes aluminium alloy and forms alloy powder;4th step:Screening, the finished product adonic dusty material of 120 mesh is prepared into using spin vibration sieve.The alloy powder that the present invention is prepared using melting aerosolization method, can be satisfied with the requirement for preparing bimetal sliding bearing.

Description

A kind of formula and preparation method thereof of adonic dusty material
Technical field
The invention belongs to alloy powder preparing technical fields, and in particular to a kind of formula of adonic dusty material and Preparation method.
Background technology
Bimetal sliding bearing be on the steel plate direct sintering bronze powder at being rolled after bimetal bearing material, lead by It is low, easy to stick in its hardness to echo preferable seizure resistance, so being widely used in sliding bearing part.Existing sliding bearing is used Often contain a large amount of lead, such as CuPb10Sn10, CuPb24Sn, CuPb24Sn4 etc. in bronze based self-lubricating material.
Lead is a kind of toxic heavy metal, toxic to human body, has pollution to environment, lead and its compound are to human body each group It knits toxic.Developed country has put into effect many relevant regulations, such as European Union《Electrically, it is limited using certain in electronic equipment Harmful substance》Middle regulation must not contain the harmful substances such as lead for the new electronics and electrical equipment that put goods on the market.With mankind's ring Protect enhancing and the raising sought of own health of consciousness, and production and daily life tool is universal, it is desirable to be used Tool and component be environmentally friendly machine.Therefore, manufacture sliding bearing copper alloy powder powder material is unleaded imperative.
Invention content
The technical problem to be solved in the present invention is to provide a kind of formulas and preparation method thereof of adonic dusty material.
In order to solve the above technical problems, the present invention adopts the following technical scheme that:
A kind of preparation method of adonic dusty material, includes the following steps,
The first step:Melting selects mass percent for 95~97% copper, 1.5~3% nickel, 1~2.5% tin Raw material, by copper be added smelting furnace in, 1085~1100 DEG C are heated in air atmosphere, after copper fusing after add nickel and Tin, melting form aluminium alloy, 1250~1350 DEG C of smelting temperature, smelting time 20~25 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject, it is cooled to 1200 after composition detection qualification~ 1250℃;
Third walks:Atomization is added glass and removes the gred with charcoal, drags for net bits, aluminium alloy is injected bottom pour ladle, using restraint-type ring Seam nozzle is atomized with 0.8~1.2Mpa air pressures under air, and high pressure draught smashes aluminium alloy and forms alloy powder;
4th step:Screening, the finished product adonic dusty material of -120 mesh is prepared into using spin vibration sieve.
Preferably, in third step, the copper liquid poured out for the first time in atomization is used as wash heat stove converter nose, need to be connect with container Firmly, it is utilized when lower stove melting.
Preferably, in third step, the height of intermediate bottom pour ladle copper liquid is kept to be not less than 20cm in atomization process.
Preferably, the leakage eye of bottom pour ladle bottom surface is 1, leaks a diameter of 3.5-5mm of eye.
Preferably, the jet apex angle of restraint-type circumferential weld nozzle is 20-35 degree.
Preferably, the slit width of restraint-type circumferential weld nozzle is 0.5-2mm.
Preferably, a diameter of 1m of the sieve of spin vibration sieve.
Preferably, the apparent density of alloy powder is 4.5~5.5g/cm3
Preferably, the mobility of alloy powder is 12~19s/50g.
Preferably, 99% or more the alloy powder is spherical or ellipse.
A kind of formula of adonic dusty material, according to above-mentioned preparation method be made, by weight percentage by with Lower ingredient is constituted:Copper 95~97%, nickel 1.5~3%, tin 1~2.5%.
There is following advantageous effect using the present invention:
1, the present invention adds nickel and tin as alloying element in copper, compared with fine copper, improves alloy strength;With copper-lead Tin series alloy is compared, and alloy powder of the invention has good plasticity, and is controlled lead content and be less than 0.1%, is realized Bimetal sliding bearing material it is unleaded.
2, the present invention adds nickel in copper, is conducive to the corrosion resistance for improving alloy, can keep steady in corrosive medium Fixed, the present invention adds tin in formula, and when Theil indices are less than 10%, tin is added with the intensity for being conducive to improve final finished.
3, opposite water atomization, the present invention is not aqueous by the powder that melting-aerosolization produces, need not be for a long time after atomization Drying, can directly sieve, shorten production procedure.
4, the present invention uses restraint-type circumferential weld nozzle, aluminium alloy to be broken in nozzle exit, and nozzle is transmitted to metal Energy it is big, be conducive to improve alloy powder flour extraction, the powder made of above technical scheme, 90% or more powder Pattern be rendered as more regular spherical shape, surface texture is smooth, there is no pit or poroid tissue, consistency Good, the apparent density of powder is 4.5~5.5g/cm3, mobility is 12~19s/50g.
5, using the bimetal sliding bearing of the unleaded powder sintered production of adonic, wearability and bond strength Requirement can be reached, can be used for Engineering Machinery Components and auto parts and components, leaded metal material is eliminated and using It is the ideal material for realizing that bimetal sliding bearing is unleaded to the influence of human and environment in journey.
Description of the drawings
Fig. 1 is a kind of flow chart of the preparation method of copper and tin nickel alloy powder powder material of the embodiment of the present invention.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are some of the embodiments of the present invention, instead of all the embodiments.Based on this hair Embodiment in bright, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment 1
As shown in FIG. 1, FIG. 1 is a kind of flow charts of the preparation method of adonic dusty material of the present invention, including Following steps:
The first step:Melting selects mass percent for 95% copper, and copper is added 3% nickel, the raw material of 2% tin In smelting furnace, it is heated to 1085 DEG C in air atmosphere, nickel and tin are added after copper fusing, melting forms aluminium alloy, melting 1350 DEG C of temperature, smelting time 23 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject is cooled to 1250 DEG C after composition detection qualification;
In the present embodiment, impurity includes silicon, aluminium, magnesium etc.;
Third walks:Atomization is added glass and removes the gred with charcoal, drags for net bits, aluminium alloy is injected bottom pour ladle, the leakage of bottom pour ladle bottom surface Eye is 1, leaks a diameter of 3.5mm of eye, restraint-type circumferential weld nozzle is used to be atomized under air with 0.8Mpa air pressures, is limited The jet apex angle of formula circumferential weld nozzle is 22 degree, and the slit width of restraint-type circumferential weld nozzle is 1mm, and high pressure draught smashes aluminium alloy and forms conjunction Bronze end, the copper liquid poured out for the first time in atomization are used as wash heat stove converter nose, need to be caught with container, sharp when lower stove melting With it is 23cm to keep the height of intermediate bottom pour ladle copper liquid in atomization process.
4th step:Screening, the finished product adonic dusty material of -120 mesh, the sieve of spin vibration sieve are prepared into using spin vibration sieve Net a diameter of 1m.
A kind of formula of adonic dusty material, according to above-mentioned preparation method be made, by weight percentage by with Lower ingredient is constituted:Copper 95%, nickel 3%, tin 2%.The adonic powder being prepared according to above-mentioned formula and preparation method Apparent density be 5.5g/cm3, the mobility of alloy powder is 14s/50g, and 99% with above-mentioned alloy powder is spherical or ellipse Circle is sintered on steel matrix and forms antifriction alloy layer, and wearability and bond strength can reach requirement, can be used for Engineering Machinery Components and auto parts and components are the ideal materials for realizing that bimetal sliding bearing is unleaded.
Embodiment 2
As shown in FIG. 1, FIG. 1 is a kind of flow charts of the preparation method of adonic dusty material of the present invention, including Following steps:
The first step:Melting, it is 97% copper, 1.5% nickel, the raw material of 1.5% tin, by copper to select mass percent It being added in smelting furnace, 1100 DEG C is heated in air atmosphere, nickel and tin are added after copper fusing, melting forms aluminium alloy, 1270 DEG C of smelting temperature, smelting time 20 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject is cooled to 1210 DEG C after composition detection qualification;
In the present embodiment, impurity includes silicon, aluminium, magnesium etc.;
Third walks:Atomization is added glass and removes the gred with charcoal, drags for net bits, aluminium alloy is injected bottom pour ladle, the leakage of bottom pour ladle bottom surface Eye is 1, leaks a diameter of 5mm of eye, uses restraint-type circumferential weld nozzle to be atomized under air with 1.2Mpa air pressures, restraint-type The jet apex angle of circumferential weld nozzle is 20 degree, and the slit width of restraint-type circumferential weld nozzle is 1mm, and high pressure draught smashes aluminium alloy and forms alloy Powder, the copper liquid poured out for the first time in atomization are used as wash heat stove converter nose, need to be caught with container, sharp when lower stove melting With it is 20cm to keep the height of intermediate bottom pour ladle copper liquid in atomization process.
4th step:Screening, the finished product adonic dusty material of -120 mesh, the sieve of spin vibration sieve are prepared into using spin vibration sieve Net a diameter of 1m.
A kind of formula of adonic dusty material, according to above-mentioned preparation method be made, by weight percentage by with Lower ingredient is constituted:Copper 97%, nickel 1.5%, tin 1.5%.The adonic being prepared according to above-mentioned formula and preparation method The apparent density of powder is 4.5g/cm3, the mobility of alloy powder is 16s/50g, 99% or more alloy powder be it is spherical or Person's ellipse is sintered on steel matrix and forms antifriction alloy layer, and wearability and bond strength can reach requirement, can It is the ideal material for realizing that bimetal sliding bearing is unleaded for Engineering Machinery Components and auto parts and components.
Embodiment 3
As shown in FIG. 1, FIG. 1 is a kind of flow charts of the preparation method of adonic dusty material of the present invention, including Following steps:
The first step:Melting selects mass percent for 96% copper, and copper is added 3% nickel, the raw material of 1% tin In smelting furnace, it is heated to 1090 DEG C in air atmosphere, nickel and tin are added after copper fusing, melting forms aluminium alloy, melting 1250 DEG C of temperature, smelting time 25 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject is cooled to 1200 DEG C after composition detection qualification;
In the present embodiment, impurity includes silicon, aluminium, magnesium etc.;
Third walks:Atomization is added glass and removes the gred with charcoal, drags for net bits, aluminium alloy is injected bottom pour ladle, the leakage of bottom pour ladle bottom surface Eye is 1, leaks a diameter of 3.5mm of eye, restraint-type circumferential weld nozzle is used to be atomized under air with 1.1Mpa air pressures, is limited The jet apex angle of formula circumferential weld nozzle is 35 degree, and the slit width of restraint-type circumferential weld nozzle is 0.5mm, and high pressure draught smashes aluminium alloy and formed Alloy powder, the copper liquid poured out for the first time in atomization are used as wash heat stove converter nose, need to be caught with container, when lower stove melting It utilizes, it is 21cm that the height of intermediate bottom pour ladle copper liquid is kept in atomization process.
4th step:Screening, the finished product adonic dusty material of -120 mesh, the sieve of spin vibration sieve are prepared into using spin vibration sieve Net a diameter of 1m.
A kind of formula of adonic dusty material, according to above-mentioned preparation method be made, by weight percentage by with Lower ingredient is constituted:Copper 96%, nickel 3%, tin 1%.The adonic powder being prepared according to above-mentioned formula and preparation method Apparent density be 4.8g/cm3, the mobility of alloy powder is 12s/50g, and 99% or more alloy powder is spherical or ellipse Circle is sintered on steel matrix and forms antifriction alloy layer, and wearability and bond strength can reach requirement, can be used for Engineering Machinery Components and auto parts and components are the ideal materials for realizing that bimetal sliding bearing is unleaded.
Embodiment 4
As shown in FIG. 1, FIG. 1 is a kind of flow charts of the preparation method of adonic dusty material of the present invention, including Following steps:
The first step:Melting, it is 95% copper, 2.5% nickel, the raw material of 2.5% tin, by copper to select mass percent It being added in smelting furnace, 1090 DEG C is heated in air atmosphere, nickel and tin are added after copper fusing, melting forms aluminium alloy, 1320 DEG C of smelting temperature, smelting time 22 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject is cooled to 1230 DEG C after composition detection qualification;
In the present embodiment, impurity includes silicon, aluminium, magnesium etc.;
Third walks:Atomization is added glass and removes the gred with charcoal, drags for net bits, aluminium alloy is injected bottom pour ladle, the leakage of bottom pour ladle bottom surface Eye is 1, leaks a diameter of 5mm of eye, uses restraint-type circumferential weld nozzle to be atomized under air with 1.2Mpa air pressures, restraint-type The jet apex angle of circumferential weld nozzle is 34 degree, and the slit width of restraint-type circumferential weld nozzle is 2mm, and high pressure draught smashes aluminium alloy and forms alloy Powder, the copper liquid poured out for the first time in atomization are used as wash heat stove converter nose, need to be caught with container, sharp when lower stove melting With it is 22cm to keep the height of intermediate bottom pour ladle copper liquid in atomization process.
4th step:Screening, the finished product adonic dusty material of -120 mesh, the sieve of spin vibration sieve are prepared into using spin vibration sieve Net a diameter of 1m.
A kind of formula of adonic dusty material, according to above-mentioned preparation method be made, by weight percentage by with Lower ingredient is constituted:Copper 95%, nickel 2.5%, tin 2.5%.The adonic being prepared according to above-mentioned formula and preparation method The apparent density of powder is 5.0g/cm3, the mobility of alloy powder is 19s/50g, 99% or more alloy powder be it is spherical or Person's ellipse is sintered on steel matrix and forms antifriction alloy layer, and wearability and bond strength can reach requirement, can It is the ideal material for realizing that bimetal sliding bearing is unleaded for Engineering Machinery Components and auto parts and components.
It should be appreciated that exemplary embodiment as described herein is illustrative and be not restrictive.Although being retouched in conjunction with attached drawing One or more embodiments of the invention is stated, it should be understood by one skilled in the art that not departing from through appended right In the case of the spirit and scope of the present invention defined by it is required that, the change of various forms and details can be made.

Claims (8)

1. a kind of preparation method of adonic dusty material, which is characterized in that include the following steps,
The first step:Melting, it is 95~97% copper, 1.5~3% nickel, the former material of 1~2.5% tin to select mass percent Copper is added in smelting furnace, 1085~1100 DEG C is heated in air atmosphere by material, adds nickel and tin after copper fusing, melts Refining forms aluminium alloy, 1250~1350 DEG C of smelting temperature, smelting time 20~25 minutes;
Second step:Composition Control, composition detection control is in copper 95~97%, nickel 1.5 after the aluminium alloy is carried out liquid level slagging-off ~3%, tin 1~2.5%, inevitable or impurity≤0.5% that can not reject, it is cooled to 1200 after composition detection qualification~ 1250℃;
Third walks:Atomization is added glass and removes the gred with charcoal, drag for net bits, the aluminium alloy injected bottom pour ladle, using restraint-type ring Seam nozzle is atomized with 0.8~1.2Mpa air pressures under air, and high pressure draught smashes the aluminium alloy and forms alloy powder;Institute It states and the height of intermediate bottom pour ladle copper liquid is kept to be not less than 20cm in atomization process;The jet apex angle of the restraint-type circumferential weld nozzle is 20-35 degree;
4th step:Screening, the finished product adonic dusty material of -120 mesh is prepared into using spin vibration sieve.
2. the preparation method of adonic dusty material described in accordance with the claim 1, which is characterized in that walked in the third In, the copper liquid poured out for the first time in atomization is used as wash heat stove converter nose, need to be caught with container, be utilized when lower stove melting.
3. the preparation method of adonic dusty material described in accordance with the claim 1, which is characterized in that the bottom pour ladle bottom surface Leakage eye be 1, it is described leakage eye a diameter of 3.5-5mm.
4. the preparation method of adonic dusty material described in accordance with the claim 1, which is characterized in that the restraint-type ring The slit width for stitching nozzle is 0.5-2mm.
5. the preparation method of adonic dusty material described in accordance with the claim 1, which is characterized in that the spin vibration sieve The a diameter of 1m of sieve.
6. the preparation method of adonic dusty material described in accordance with the claim 1, which is characterized in that the alloy powder Apparent density be 4.5~5.5g/cm3, the mobility of alloy powder is 12~19s/50g.
7. according to the preparation method of claim 1-6 any one of them adonic dusty materials, which is characterized in that 99% Above alloy powder is spherical or ellipse.
8. a kind of formula of adonic dusty material, which is characterized in that according to any preparation sides claim 1-7 Method is made, and is made of by weight percentage following component:Copper 95~97%, nickel 1.5~3%, tin 1~2.5%.
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Inventor after: Zhang Jiafeng

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Inventor after: Luo Tao

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Denomination of invention: Formula and preparation method of a copper nickel tin alloy powder material

Effective date of registration: 20231121

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