CN106834568A - A kind of mould proof leather maintaining agent - Google Patents

A kind of mould proof leather maintaining agent Download PDF

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Publication number
CN106834568A
CN106834568A CN201710013241.3A CN201710013241A CN106834568A CN 106834568 A CN106834568 A CN 106834568A CN 201710013241 A CN201710013241 A CN 201710013241A CN 106834568 A CN106834568 A CN 106834568A
Authority
CN
China
Prior art keywords
parts
mould
leather
mould proof
maintaining agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710013241.3A
Other languages
Chinese (zh)
Inventor
李军章
杨毅华
魏云辉
齐欢欢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Ditai Auto Parts Co Ltd
Hebei University of Science and Technology
Original Assignee
Hebei Ditai Auto Parts Co Ltd
Hebei University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Ditai Auto Parts Co Ltd, Hebei University of Science and Technology filed Critical Hebei Ditai Auto Parts Co Ltd
Priority to CN201710013241.3A priority Critical patent/CN106834568A/en
Publication of CN106834568A publication Critical patent/CN106834568A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The present invention provides a kind of mould proof leather maintaining agent, including the following component in terms of mass fraction:100 120 parts of 30 40 parts of palm wax, 30 40 parts of sulfosuccinate, 20 25 parts of triglycerides, 58 parts of emulsifying agent, 8 15 parts of mould inhibitor and distilled water.Above-mentioned sealing compound is the protection of safe and efficient leather, maintenance preparation, prevents the harmful microbes such as mould from growing while curing leather product.

Description

A kind of mould proof leather maintaining agent
Technical field
The present invention relates to leather agent technical field, especially a kind of preparation for leather.
Background technology
In daily life people often in contact with to leather and fur products such as leather shoes, fur clothing, corium sofa and seats, leather is by moving The rawhide of thing is used by depilation, tanning etc. be chemical and mechanical means is processed into flexible and permeability product Surface will tarnish because contamination dust and dirt lack maintenance again, wrinkle after a period of time, and serious even occurs out The situation split, and because raw material skin has animal dirt and various miscellaneous bacterias in itself, the environment of moist moistening is such as placed on for a long time In easily mould growth, have a strong impact on the quality and performance of leather and fur products.And existing Leather mildew-proof preparation is generally benzene class Or aldehydes matter, with certain toxicity and environmental pollution being caused, the patent of such as Application No. 2013103120513 describes one Kind of shoe polish mould inhibitor, is made up of the ketoconazole of 40-60% Sodium Benzoates and 40-60%, be dissolved in glycerine be made it is active Anti-mildew granules, wherein Sodium Benzoate have toxicity, should not be contacted with skin for a long time.
The content of the invention
The main object of the present invention is to provide a kind of mould proof leather maintaining agent;Its technical problem to be solved is to carry For a kind of safe and effective leather protection, maintenance preparation, the harmful microbes such as mould are prevented while curing leather product Grow.
And the technical scheme of its solve problem is:
A kind of mould proof leather maintaining agent, including the following component in terms of mass fraction:Palm wax 30-40 parts, sulfosuccinic Acid esters 30-40 parts, triglycerides 20-25 parts, emulsifying agent 5-8 parts, mould inhibitor 8-15 parts and distilled water 50-70 parts.
Above-mentioned mould proof leather maintaining agent, the mould inhibitor is ethoxyquinoline.
Above-mentioned mould proof leather maintaining agent, the emulsifying agent is APES or lauryl alcohol polyethylene glycol oxide Ether.
Above-mentioned mould proof leather maintaining agent, including the following component in terms of mass fraction:36 parts of palm wax, sulfosuccinic 34 parts of acid esters, 23 parts of triglycerides, 5 parts of APES, 12 parts of ethoxyquinoline, 50 parts of distilled water.
The present invention is coated in leather surface and forms layer protective layer, makes that leather is smooth, fine and smooth, glossiness is good, resist bending is rich It is flexible, assign leather surface good grease sense of touch and glossiness.Because the microorganism polluted on leather is based on mould, this The leather maintaining agent of invention can effectively prevent mould from growing while leather is maintained, the raw materials used low toxicity of sealing compound, safety Property is good.
Specific embodiment
Technical scheme is clearly and completely described with reference to embodiment.Explain in the following description Many details have been stated in order to fully understand the present invention, but the present invention can also be using other different from described here Other manner is implemented, and those skilled in the art can do similar popularization, therefore this in the case of without prejudice to intension of the present invention Invention is not limited by following public specific embodiment.
The present invention includes the following component in terms of mass fraction:It is palm wax 30-40 parts, sulfosuccinate 30-40 parts, sweet Ester 20-25 parts, emulsifying agent 5-8 parts, mould inhibitor 8-15 parts and distilled water 50-70 parts of oil three, the emulsifying agent is alkyl phenol polyoxy Vinethene or ethoxylated dodecyl alcohol, mould inhibitor are ethoxyquinoline.
Currently preferred formula is(In terms of mass fraction):36 parts of palm wax, 34 parts of sulfosuccinate, triglycerides 23 parts, 5 parts of APES, 12 parts of ethoxyquinoline, 50 parts of distilled water.
Palm wax has nursing and upper light ability well, and sulfosuccinate can make palm fibre as bleeding agent and lubricant The oil components such as palmitic acid wax, triglycerides are preferably penetrated into leather, make its more high resilience, increase bend resistance ability.It is anti- Mould dose of ethoxyquinoline not only has inhibitory action as the antioxidant of food-grade to the growth of mould, and toxicity is far smaller than to make It is the mould inhibitor that medicament is used, and the quality of oil component can be kept as antioxidant, prevent from becoming sour, further carries The stability of high product.APES, two kinds of emulsifying agents of ethoxylated dodecyl alcohol can make mould inhibitor ethyoxyl Quinoline is uniform, be dispersed stably in the lotion of sealing compound, be conducive to playing persistently, the anti-mold effect of stabilization.
Preparation method:During reactor first will be put into by the formula emulsifying agent, triglycerides and the distilled water that weigh, 60 DEG C are warming up to Stirring forms premixed liquid for 30 minutes, and premixed liquid is warming up to 80-90 DEG C, adds palm wax, ethoxyquinoline and sulfosuccinate Mixing, stirs in high speed homogenization mixer.
Embodiment 1
During triglycerides 23kg, APES 5kg and distilled water 50kg put into reactor, 60 DEG C are warming up to Stirring forms premixed liquid for 30 minutes, and premixed liquid is warming up to 85 DEG C, adds palm wax 36kg, ethoxyquinoline 12kg and sulfosuccinic Acid esters 34kg mixes, and is stirred in high speed homogenization mixer, filling into finished product.
Embodiment 2
During triglycerides 21kg, ethoxylated dodecyl alcohol 6kg and distilled water 60kg put into reactor, it is warming up to 60 DEG C and stirs Mix and form within 30 minutes premixed liquid, premixed liquid is warming up to 89 DEG C, adds palm wax 37kg, ethoxyquinoline 10kg and sulfosuccinic acid Ester 35kg mixes, and is stirred in high speed homogenization mixer, filling into finished product.
Embodiment 3
During triglycerides 25kg, APES 7kg and distilled water 70kg put into reactor, it is warming up to 60 DEG C and stirs Mix and form within 30 minutes premixed liquid, premixed liquid is warming up to 82 DEG C, adds palm wax 31kg, ethoxyquinoline 15kg and sulfosuccinic acid Ester 32kg mixes, and is stirred in high speed homogenization mixer, you can filling into finished product.
Effect example
The leather maintaining agent that inspection embodiment 1 is produced presses down mycostatic performance,
Strain is common mould-aspergillus niger, aspergillus flavus and the Penicillium notatum for infecting leather, and the reference culture of above-mentioned strain is taken respectively Enrichment culture is carried out, mould medium is mixed and added into access test tube after culture, be made spore pregnant solution.
Leather sample is by the ox-hide sample of tanning.
Ox-hide sample is cut into formed objects, ox-hide surface uniformly coats the sealing compound of embodiment 1, the amount of coating respectively It is the 0% of ox-hide weight(Control group)、0.1%(Group one)、0.15%(Group two)With 0.2%(Group three).By spore pregnant solution at four groups Inoculation one is dripped on sample.Vaccinated sample is placed in culture dish, is placed between 25 DEG C, the culture of humidity 60% and is cultivated 15 days, The growing state of mould is observed and records, and it is interior as outward appearance control group that one piece of ox-hide sample is placed directly in culture.It is real Test result as shown in table 1.
The growing state of the sample ox musty on the flesh of table 1
Result shows, in the case of normal usage amount, the sample for being coated with sealing compound does not have fungus growth.It is not coated with maintenance During the sample of agent is directly placed between culture, surface produces microgroove, and the sample outward appearance for being coated with sealing compound is not changed in.
Content described above is only present pre-ferred embodiments, it is clear that described embodiment is only of the invention one Section Example, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not doing Go out the every other embodiment obtained under the premise of creative work, belong to the scope of protection of the invention.

Claims (4)

1. a kind of mould proof leather maintaining agent, it is characterised in that:Including the following component in terms of mass fraction:Palm wax 30- 40 parts, sulfosuccinate 30-40 parts, triglycerides 20-25 parts, emulsifying agent 5-8 parts, mould inhibitor 8-15 parts and distilled water 50- 70 parts.
2. mould proof leather maintaining agent according to claim 1, it is characterised in that:The mould inhibitor is ethoxyquin Quinoline.
3. mould proof leather maintaining agent according to claim 2, it is characterised in that:The emulsifying agent is alkyl phenol polyoxy Vinethene or ethoxylated dodecyl alcohol.
4. mould proof leather maintaining agent according to claim 3, it is characterised in that:Including as follows in terms of mass fraction Component:36 parts of palm wax, 34 parts of sulfosuccinate, 23 parts of triglycerides, 5 parts of APES, ethoxyquinoline 12 parts, 50 parts of distilled water.
CN201710013241.3A 2017-01-09 2017-01-09 A kind of mould proof leather maintaining agent Pending CN106834568A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710013241.3A CN106834568A (en) 2017-01-09 2017-01-09 A kind of mould proof leather maintaining agent

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Application Number Priority Date Filing Date Title
CN201710013241.3A CN106834568A (en) 2017-01-09 2017-01-09 A kind of mould proof leather maintaining agent

Publications (1)

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CN106834568A true CN106834568A (en) 2017-06-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108165060A (en) * 2017-12-11 2018-06-15 安徽省定远县劲牛球业有限公司 A kind of football nurses agent prescription
CN108484874A (en) * 2018-03-23 2018-09-04 惠州市远安新材料有限公司 A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103388037A (en) * 2012-05-08 2013-11-13 赵霞 Sheepskin product cleaning maintenance cream
CN103725202A (en) * 2013-12-20 2014-04-16 苏州市澄湖工贸有限公司 Leather brightener
CN105200169A (en) * 2014-06-18 2015-12-30 沈阳创达技术交易市场有限公司 Leather repairing agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103388037A (en) * 2012-05-08 2013-11-13 赵霞 Sheepskin product cleaning maintenance cream
CN103725202A (en) * 2013-12-20 2014-04-16 苏州市澄湖工贸有限公司 Leather brightener
CN105200169A (en) * 2014-06-18 2015-12-30 沈阳创达技术交易市场有限公司 Leather repairing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108165060A (en) * 2017-12-11 2018-06-15 安徽省定远县劲牛球业有限公司 A kind of football nurses agent prescription
CN108484874A (en) * 2018-03-23 2018-09-04 惠州市远安新材料有限公司 A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof

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Application publication date: 20170613