CN106832886A - A kind of wear-resisting high-molecular composite material and preparation method thereof - Google Patents

A kind of wear-resisting high-molecular composite material and preparation method thereof Download PDF

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Publication number
CN106832886A
CN106832886A CN201710174460.XA CN201710174460A CN106832886A CN 106832886 A CN106832886 A CN 106832886A CN 201710174460 A CN201710174460 A CN 201710174460A CN 106832886 A CN106832886 A CN 106832886A
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wear
parts
composite material
powder
molecular composite
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范亚强
马露
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JINGDEZHEN BETTERWEAR NEW MATERIALS CO Ltd
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JINGDEZHEN BETTERWEAR NEW MATERIALS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/548Silicon-containing compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The present invention relates to a kind of wear-resisting high-molecular composite material and preparation method thereof, wherein, the wear-resisting high-molecular composite material is formed by the component configuration of following volume parts:10 80 parts of rubber matrix;0 25 parts of structural reinforcement material;5 80 parts of wear-resistant ceramic material;0.1 10 parts of coupling agent;0 35 parts of filler;0 20 parts of binding agent;0 30 parts of frictional property regulator.The preparation method is that homogenious charge compression is made type on a mill by each component of said ratio.It has excellent anti-wear performance and good mechanical property, while simple production process, stably, long service life is environment friendly and pollution-free, and cost performance is high, disclosure satisfy that the requirement in market for product quality.Meanwhile, it is widely used, and can be used in fields such as mine, metallurgy, ore milling apparatus, Pulp pump, oil recovery, ship, automobile, papermaking, shoemaking, wind-powered electricity generation, motor-car, nano material sand mills.

Description

A kind of wear-resisting high-molecular composite material and preparation method thereof
Technical field
The present invention relates to class wearing piece and preparation method thereof, a more particularly to class is special engineered compound with wear-resistant macromolecule Material and preparation method thereof, belongs to new material scientific domain.
Background technology
Wear-resistant macromolecule material is the material based on macromolecular compound.Macromolecular material is by relative molecular mass The material that compound higher is constituted, including rubber, plastics, fiber, coating, adhesive and polymer-based composite.
The fast development of world's Macromolecular materials industry, is on the one hand because their excellent properties make it in many fields In have found application;On the other hand also in that they are produced and the required output investment ratio other materials of application is low, metal is especially compared Material is much lower, remarkable in economical benefits.
China for polymer material science research since the fifties, the need for meeting new technology and high-tech, Have developed a large amount of special plastics, such as fluorine, polymeric silicon, arrived a little years, macromolecular material development is even more rapid, and increasingly connects The life of persons of modern times.Plastics, synthetic fibers and the synthetic rubber for being referred to as the big synthetic material of modern macromolecule three have become state People's economic construction and the essential important materials of people's daily life.
Wear-resistant macromolecule material, particularly synthetic rubber liner make it in mine, metallurgy, build in the utilization in wear-resisting field The industries such as material, electronics and chemical industry turn into indispensable equipment part, disintegrating apparatus, milling apparatus, mine chute, Pulp pump etc. Wherein liner is the main consumable part during its use, multiplex Steel material manufacture high violent so that noise is big in use, power consumption Greatly, wear and tear big.The liner produced using macromolecular material, can reach small, lightweight noise, low energy consumption, high abrasion, use week The characteristics of phase is longer.But, capacity, power ascension with associated equipment, and production scene are wanted to cost of equipment maintenance The wearability of lifting, common combined antiwear material is asked to receive baptism, if not taking at significantly more efficient wear Protection Reason, evaporating, emitting, dripping or leaking of liquid or gas accident will take place frequently, the crucial problem as restriction production, cause to change equipment part repeatedly, improve life Cost of investment is produced, labor strength is increased, normal production procedure has been had influence on.
The content of the invention
It is multiple it is an object of the invention to provide a kind of more wear-resisting macromolecule in order to overcome the deficiency of above-mentioned prior art Condensation material and preparation method thereof, is allowed to the performance indications such as wear-resistant, shock resistance, noise-reducing and greatly improves, and then reduction equipment is matched somebody with somebody The replacement frequency of part, saves investment of production cost, reduces labor strength etc..
The purpose of the present invention is achieved by the following technical programs:
A kind of wear-resisting high-molecular composite material, is formulated by the component of following volume parts:
Rubber matrix 10-80 parts;
Structural reinforcement material 0-25 parts;
Wear-resistant ceramic material 5-80 parts;
Coupling agent 0.1-10 parts;
Filler 0-35 parts;
Binding agent 0-20 parts;
Frictional property regulator 0-30 parts.
Further, the rubber matrix be isoprene rubber, butadiene-styrene rubber, neoprene, polyurethane rubber, fluorubber, Any one in ACM.
Further, the structural reinforcement material can be nylon, aramid fiber, carbon fiber, glass fibre, metallic fiber, steel Any one in silk cord, or various staple fibres or synthetic fibers.
Further, the wear-resistant ceramic material is nano aluminium oxide ceramic powder, particle or ball, and its density is in 2.6- Between 6.0g/cm3, Mohs' hardness >=5.0, alumina content purity >=60%, spherical or particle size is in 0.001-50mm.
Further, the coupling agent refer to double-[γ-(triethoxysilicane) propyl group] tetrasulfide Si69, it is double-[γ- (triethoxysilicane) propyl group] any one in tetrasulfide KH-580, γ-mercaptopropyl trimethoxysilane KH-590.
Further, the frictional property regulator be carborundum powder, crystal Firebrake ZB, crystal aluminium borate in one kind or Two kinds and thing mixed above.
Further, described filler is inorganic ceramic powder, and it can be monocrystalline silicon powder, zirconium silicate powder, zirconium oxide Any one in powder, quartzy powder, graphite powder, Graphene powder, granular boron compound.
Further, the binding agent is polymer-ceramic type high temp binding agent.
A kind of preparation method of wear-resisting high-molecular composite material, comprises the following steps:
A) rubber matrix, wear-resistant ceramic material, coupling agent, the frictional property regulator of certain number are weighed by volume, its Middle wear-resistant ceramic material is weighed respectively by two kinds of specifications of powdery and graininess;
B) rubber matrix, powdery wear-resistant ceramic material and the coupling agent that will be weighed add mill to be kneaded, and treat three Age resistor is added after well mixed, until well mixed;
C) and then by high temperature hot-rolling above-mentioned well mixed sizing material is heat-treated, and it is cold after the completion of heat treatment But;
D) frictional property regulator, powdery wear-resistant ceramic material, accelerator and vulcanization are then sequentially added on a mill Agent is kneaded, until each sizing material is well mixed;
E) sizing material vulcanizes by high pressure, is cooled to normal temperature, it is final it is machined after obtain high abrasion goods.
Further, structural reinforcement material and/or filler and/or bonding agent can also be added in the step d).
Compared with prior art, the invention has the advantages that:
Wear-resisting high-molecular composite material of the present invention, with excellent anti-wear performance and good mechanical property, while production Process is simple, product quality stabilization, long service life is environment friendly and pollution-free, and cost performance is high, disclosure satisfy that the requirement in market.Meanwhile, It is widely used, can be in mine, metallurgy, ore milling apparatus, Pulp pump, oil recovery, ship, automobile, papermaking, shoemaking, wind-powered electricity generation, dynamic The fields such as car, nano material sand mill significantly use and promote.
Specific embodiment
According to a kind of wear-resisting high-molecular composite material that the present invention is provided, it is formulated by the component of following volume parts:
Rubber matrix 10-80 parts, preferred scope value is 20-70 parts;
Structural reinforcement material 0-25 parts, preferred scope value is 0-15 parts;
Wear-resistant ceramic material 5-80 parts, preferred scope value is 10-70 parts;
Coupling agent 0.1-10 parts, preferred scope value is 0.5-5 parts;
Filler 0-35 parts, preferred scope value is 0-20 parts;
Binding agent 0-20 parts, preferred scope value is 0-10 parts;
Frictional property regulator 0-30 parts, preferred scope value is 2-20 parts.
Preferably, the rubber matrix is isoprene rubber, butadiene-styrene rubber, neoprene, polyurethane rubber, fluorubber, third Any one in the various strong flexible polymers such as olefin(e) acid ester rubber.The structural reinforcement material can be nylon, aramid fiber, carbon fibre Any one in dimension, glass fibre, metallic fiber, all-steel cord, or various staple fibres or synthetic fibers.It is described Wear-resistant ceramic material be nano aluminium oxide ceramic powder, particle or ball, its density between 2.6-6.0g/cm3, Mohs' hardness >= 5.0, alumina content purity >=60%, spherical or particle size is in 0.001-50mm.It is described resistance to as further preferably Mill ceramic material can also be a kind of Ultra-wear-resistantalumina alumina ceramic ball described in Chinese patent 201310174278.6.
Preferably, the coupling agent refers to double-[γ-(triethoxysilicane) propyl group] tetrasulfide Si69, double-[γ-(three Ethyoxyl silicon) propyl group] any one in tetrasulfide KH-580, γ-mercaptopropyl trimethoxysilane KH-590.The friction Properties modifier is one kind or two kinds and thing mixed above in carborundum powder, crystal Firebrake ZB, crystal aluminium borate.Described filler It is inorganic ceramic powder, it can be monocrystalline silicon powder, zirconium silicate powder, zirconium oxide powder, quartzy powder, graphite powder, stone Any one in black alkene powder, granular boron compound.The binding agent is polymer-ceramic type high temp binding agent, with bonding Power is strong, and bonding interface is uniform, and good stability, thermal shock resistance can continuously work in high temperature environments, anticorrosive, anti-oxidant equivalent Really.
Wear-resisting high-molecular composite material of the present invention can do corresponding choosing according to different use environment temperature case requirements Select, than if any high rigidity, high resiliency, high abrasion, high pressure resistant, resistance to ag(e)ing, ozone resistance, oil resistivity requirement, can select poly- Urethane is obtained.If any high temperature resistant, oil resistant, chemicals-resistant, acid-alkali-corrosive-resisting requirement can select fluoride copolymers and be obtained.If any Oil resistant, resistance to combustion, resistance to oxidation and ozone proof requirement, can select chlorobutadiene polymerization and are obtained.Structural reinforcement material glass fibre Using then having good heat resistance and mechanical performance, anti-wear performance is also good, aramid fiber light weight, and specific surface area is big, strong Degree height, high temperature resistant, wear-resistant, fluffy and rubber compatibility are good.Frictional property regulator carborundum powder has good heat conduction Property, high-abrasive material can be avoided to produce localized hyperthermia.Crystal Firebrake ZB, aluminium borate can reduce local temperature, it is also possible to avoid Local temperature is too high.
A kind of preparation method of the wear-resisting high-molecular composite material provided according to the present invention, comprises the following steps:
A) rubber matrix, wear-resistant ceramic material, coupling agent, the frictional property regulator of certain number are weighed by volume, its Middle wear-resistant ceramic material is weighed respectively by two kinds of specifications of powdery and graininess;
B) rubber matrix, powdery wear-resistant ceramic material and the coupling agent that will be weighed add mill to be kneaded, and treat three Age resistor is added after well mixed, until well mixed;
C) and then by high temperature hot-rolling above-mentioned well mixed sizing material is heat-treated, and it is cold after the completion of heat treatment But;
D) frictional property regulator, powdery wear-resistant ceramic material, accelerator and vulcanization are then sequentially added on a mill Agent is kneaded, until each sizing material is well mixed;
E) sizing material vulcanizes by high pressure, is cooled to normal temperature, it is final it is machined after obtain high abrasion goods.
Preferably, structural reinforcement material and/or filler and/or bonding agent can also be added in the step d).
Present invention process formula has different formula components and processing steps for different fields of employment, below by Three specific embodiments come for example, specific as follows:
(1) as mill liner material, its formula components by polyurethane rubber, nano aluminium oxide ceramics, coupling agent Si69, Carborundum powder, monocrystalline silicon powder etc. are constituted.
Processing step is as follows:A) 35 parts of polyurethane rubber is weighed by parts by volume, 20 parts of 325 mesh of nano aluminium oxide ceramic powder, 1.5 parts of coupling agent Si69500 mesh, 30 parts of 40 mesh of nano aluminium oxide ceramic particle, 10 parts of 100 mesh of carborundum powder, monocrystalline silicon powder 10000 3.5 parts of mesh.B) polyurethane rubber, nano aluminium oxide ceramic powder and the coupling agent Si69 addition mills that will be weighed are carried out Mixing, age resistor is added after three is well mixed, until well mixed.C) and then by high temperature hot-rolling to above-mentioned well mixed Sizing material be heat-treated, and after the completion of heat treatment cool down.D) monocrystalline silicon powder, carbonization are then sequentially added on a mill Silica flour, nano aluminium oxide ceramic particle, accelerator, vulcanizing agent are kneaded, until each sizing material is well mixed.E) sizing material is through too high Pressure vulcanization, is cooled to normal temperature, it is final it is machined after obtain high abrasion goods.
The embodiment is used cooperatively due to various organic and scientific and reasonable the carrying out of inorganic material, resistance to so as to improve product Mill property, increased service life, process is simple, industrialized production is applicable, with obvious economic and social benefit.Meanwhile, its Obtained wearing piece internal bond strength is high, and adhesion strength is high, improves the mechanical strength of material, increased wearability, extension Service life.
(2) as Pulp pump line with rubber material, its formula components is by PVF rubber, nano aluminium oxide ceramics, coupling agent Si69, carborundum powder etc. are constituted.
Processing step is as follows:A) 30 parts of PVF rubber is weighed by parts by volume, 20 parts of 325 mesh of nano aluminium oxide ceramic powder, 1 part of coupling agent Si69500 mesh, 45 parts of 40 mesh of nano aluminium oxide ceramic particle, 4 parts of 100 mesh of carborundum powder.B) the poly- ammonia that will be weighed Ester rubber, nano aluminium oxide ceramic powder and coupling agent Si69 add mill to be kneaded, and are added after three is well mixed anti- Old agent, until well mixed.C) and then by high temperature hot-rolling above-mentioned well mixed sizing material is heat-treated, and in heat treatment After the completion of cool down.D) carborundum powder, nano aluminium oxide ceramic particle, accelerator, vulcanizing agent are then sequentially added on a mill Kneaded, until each sizing material is well mixed.E) sizing material vulcanizes by high pressure, is cooled to normal temperature, it is final it is machined after To high abrasion goods.
The present embodiment considers that Pulp pump conveys the particularity of slurry, special with acidproof, alkaline-resisting, resistant to elevated temperatures PVF rubber Glue, coordinates the inventive method to improve wearability, service life is increased, with obvious technical advantage, and substitutability.
(3) as sand mill agitator disk and cylinder lining material, its formula components is made pottery by polyurethane rubber, nano aluminium oxide Porcelain, coupling agent Si69, carborundum powder etc. are constituted.
Processing step is as follows:A) 30 parts of polyurethane rubber is weighed by parts by volume, 40 parts of 325 mesh of nano aluminium oxide ceramic powder, 2 parts of coupling agent Si69500 mesh, 10 parts of 40 mesh of nano aluminium oxide ceramic particle, 18 parts of 100 mesh of carborundum powder.B) it is poly- by what is weighed Urethane rubber, nano aluminium oxide ceramic powder and coupling agent Si69 add mill to be kneaded, and are added after three is well mixed Age resistor, until well mixed.C) and then by high temperature hot-rolling above-mentioned well mixed sizing material is heat-treated, and in Re Chu Cooled down after the completion of reason.D) carborundum powder, nano aluminium oxide ceramic particle, accelerator, vulcanization are then sequentially added on a mill Agent is kneaded, until each sizing material is well mixed.E) sizing material vulcanizes by high pressure, is cooled to normal temperature, it is final it is machined after Obtain high abrasion goods.
As described above, only presently preferred embodiments of the present invention, when the scope that present invention implementation can not be limited with this, The simple equivalence changes made according to scope of the present invention patent and invention description content generally and modification, all still belong to this hair In the range of bright patent covers.

Claims (10)

1. a kind of wear-resisting high-molecular composite material, it is characterised in that be formulated by the component of following volume parts:
Rubber matrix 10-80 parts;
Structural reinforcement material 0-25 parts;
Wear-resistant ceramic material 5-80 parts;
Coupling agent 0.1-10 parts;
Filler 0-35 parts;
Binding agent 0-20 parts;
Frictional property regulator 0-30 parts.
2. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The rubber matrix is isoamyl Any one in rubber, butadiene-styrene rubber, neoprene, polyurethane rubber, fluorubber, ACM.
3. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The structural reinforcement material can Be in nylon, aramid fiber, carbon fiber, glass fibre, metallic fiber, all-steel cord any one, or it is various artificial Fiber or synthetic fibers.
4. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The wear-resistant ceramic material is Nano aluminium oxide ceramic powder, particle or ball, its density is between 2.6-6.0g/cm3, and Mohs' hardness >=5.0, alumina content is pure Degree >=60%, spherical or particle size is in 0.001-50mm.
5. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The coupling agent refer to it is double- [γ-(triethoxysilicane) propyl group] tetrasulfide Si69, double-[γ-(triethoxysilicane) propyl group] tetrasulfide KH-580, γ- Any one in mercaptopropyl trimethoxysilane KH-590.
6. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The frictional property regulator It is the one kind in carborundum powder, crystal Firebrake ZB, crystal aluminium borate or two kinds and thing mixed above.
7. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:Described filler is inorganic ceramic Powder, it can be monocrystalline silicon powder, zirconium silicate powder, zirconium oxide powder, quartzy powder, graphite powder, Graphene powder, powder Any one in granular boron compound.
8. a kind of wear-resisting high-molecular composite material according to claim 1, it is characterised in that:The binding agent is made pottery for polymerization Porcelain type high temp binding agent.
9. a kind of preparation method of wear-resisting high-molecular composite material, it is characterised in that comprise the following steps:
A) rubber matrix, wear-resistant ceramic material, coupling agent, the frictional property regulator of certain number are weighed by volume, wherein resistance to Mill ceramic material is weighed respectively by two kinds of specifications of powdery and graininess;
B) rubber matrix, powdery wear-resistant ceramic material and the coupling agent that will be weighed add mill to be kneaded, and treat that three mixes Age resistor is added after uniform, until well mixed;
C) and then by high temperature hot-rolling above-mentioned well mixed sizing material is heat-treated, and is cooled down after the completion of heat treatment;
D) frictional property regulator, powdery wear-resistant ceramic material, accelerator and vulcanizing agent is then sequentially added on a mill to enter Row mixing, until each sizing material is well mixed;
E) sizing material vulcanizes by high pressure, is cooled to normal temperature, it is final it is machined after obtain high abrasion goods.
10. a kind of preparation method of wear-resisting high-molecular composite material according to claim 9, it is characterised in that:The step D) structural reinforcement material and/or filler and/or bonding agent can also be added in.
CN201710174460.XA 2017-03-22 2017-03-22 A kind of wear-resisting high-molecular composite material and preparation method thereof Pending CN106832886A (en)

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CN107353463A (en) * 2017-08-24 2017-11-17 苏州诺乐智能科技有限公司 A kind of balance car pedal
CN107574519A (en) * 2017-09-29 2018-01-12 汇鸿(南通)安全用品有限公司 A kind of anti-encapsulated yarn of cutting
CN107698963A (en) * 2017-10-13 2018-02-16 南京旭羽睿材料科技有限公司 Applied to graphene composite material for preparing textile rubber roll and preparation method thereof
CN108359226A (en) * 2018-03-12 2018-08-03 苏州经贸职业技术学院 A kind of bow arm material and preparation method thereof
CN108530703A (en) * 2018-04-02 2018-09-14 苏州耐思特塑胶有限公司 A kind of preparation method of automobile tire rubber composite material
CN110328768A (en) * 2019-07-26 2019-10-15 浙江工业大学 A kind of rubber-base composite material production method of gradient function Polishing machining method
CN114854295A (en) * 2022-04-14 2022-08-05 山西维力固科技股份有限公司 Polyurethane-based wear-resistant composite material and construction process
CN115325781A (en) * 2021-05-10 2022-11-11 苏州市宝苏矿冶设备有限公司 Acid and alkali resistant super wear-resistant wringing roller and steel plate wringing roller set

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Publication number Priority date Publication date Assignee Title
CN107353463A (en) * 2017-08-24 2017-11-17 苏州诺乐智能科技有限公司 A kind of balance car pedal
CN107574519A (en) * 2017-09-29 2018-01-12 汇鸿(南通)安全用品有限公司 A kind of anti-encapsulated yarn of cutting
CN107698963A (en) * 2017-10-13 2018-02-16 南京旭羽睿材料科技有限公司 Applied to graphene composite material for preparing textile rubber roll and preparation method thereof
CN108359226A (en) * 2018-03-12 2018-08-03 苏州经贸职业技术学院 A kind of bow arm material and preparation method thereof
CN108530703A (en) * 2018-04-02 2018-09-14 苏州耐思特塑胶有限公司 A kind of preparation method of automobile tire rubber composite material
CN110328768A (en) * 2019-07-26 2019-10-15 浙江工业大学 A kind of rubber-base composite material production method of gradient function Polishing machining method
CN110328768B (en) * 2019-07-26 2021-10-26 浙江工业大学 Method for manufacturing rubber-based composite material by using gradient function polishing processing method
CN115325781A (en) * 2021-05-10 2022-11-11 苏州市宝苏矿冶设备有限公司 Acid and alkali resistant super wear-resistant wringing roller and steel plate wringing roller set
CN114854295A (en) * 2022-04-14 2022-08-05 山西维力固科技股份有限公司 Polyurethane-based wear-resistant composite material and construction process

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