CN106830678A - A kind of preparation method of photosensitive glass-ceramics mobile phone shell - Google Patents
A kind of preparation method of photosensitive glass-ceramics mobile phone shell Download PDFInfo
- Publication number
- CN106830678A CN106830678A CN201710187666.6A CN201710187666A CN106830678A CN 106830678 A CN106830678 A CN 106830678A CN 201710187666 A CN201710187666 A CN 201710187666A CN 106830678 A CN106830678 A CN 106830678A
- Authority
- CN
- China
- Prior art keywords
- parts
- mobile phone
- phone shell
- carried out
- photosensitive glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000012043 crude product Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 11
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000292 calcium oxide Substances 0.000 claims abstract description 11
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 11
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 11
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 11
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 11
- 239000000047 product Substances 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 11
- 238000000137 annealing Methods 0.000 claims abstract description 8
- 238000005520 cutting process Methods 0.000 claims abstract description 6
- 238000013003 hot bending Methods 0.000 claims abstract description 6
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 238000005286 illumination Methods 0.000 claims abstract description 4
- 238000005498 polishing Methods 0.000 claims abstract description 4
- 238000004080 punching Methods 0.000 claims abstract description 4
- 230000004927 fusion Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007123 defense Effects 0.000 abstract description 2
- 239000011521 glass Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000006089 photosensitive glass Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/02—Re-forming glass sheets
- C03B23/023—Re-forming glass sheets by bending
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/18—Telephone sets specially adapted for use in ships, mines, or other places exposed to adverse environment
- H04M1/185—Improving the rigidity of the casing or resistance to shocks
Abstract
The invention discloses a kind of preparation method of photosensitive glass-ceramics mobile phone shell, it is related to the application of photosensitive glass-ceramics.The present invention comprises the following steps:Configured with silica, lithium carbonate, potassium nitrate, aluminum oxide, calcium oxide, zirconium as raw material, after the completion of raw material be placed in melting furnace carry out being molten into solution;Being sent at once after solution-cast is molded in annealing furnace carries out annealing for blank;Blank is carried out into specification section using commercially available wire cutting machine;Rough polishing is carried out to section and punching is processed as rectangle standard film;The side edge of rectangle standard film four is done into preset data hot bending on hot press and is processed as four flanging crude products;Crude product is carried out into photo-irradiation treatment;Crude product after illumination is carried out into Crystallizing treatment in baking furnace;Then carry out finishing polish and mobile phone shell finished product is obtained.Utilization scope of the present invention is wide, and thinness is up to 0.15mm and wear-resisting, corrosion-resistant, and electrical conductivity is high, thermal conductivity factor is big, and intensity is enough to avoid being broken into pieces, and except mobile phone shell ten thousand, the technology of the present invention applies also for wiring board, aerospace engineering, military defense project.
Description
Technical field
The present invention relates to the application of photosensitive glass-ceramics, and in particular to a kind of preparation side of photosensitive glass-ceramics mobile phone shell
Method.
Background technology
It is well known that the atomic arrangement inside simple glass is one of the reason for not having well-regulated, this is also Glass breadks easily.
Glass ceramics (i.e. devitrified glass) has the double grading of glass and ceramics, and glass ceramics is made up of as ceramics crystal,
Its atomic arrangement is very regular, therefore, glass ceramics is higher than the brightness of ceramics, stronger than glass toughness, prior art
In to have recorded using zirconium oxide be that main component makes mobile phone shell, but zirconium oxide mobile phone shell yield rate is low, bulk density is big, heat
Curved probability is poor, and crash resistance is poor, therefore generally requires to be realized plus frame on the basis of zirconium oxide, and adds after frame due to office
Portion's stress, it is easier to damage zirconium oxide body.Corning Incorporated have developed photosensitive glass-ceramics, but have no in the prior art
Photosensitive glass-ceramics perfection is agreed with into the record onto mobile phone, in addition, being processed for the hot bending treatment of devitrified glass and flanging
Technique, not successful breakthrough.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of low cost, easy processing, node index photosensitive crystallite high
The preparation method of glass mobile phone shell.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of preparation of photosensitive glass-ceramics shell
Method, it is characterised in that:Comprise the following steps:
(1) configured with silica, lithium carbonate, potassium nitrate, aluminum oxide, calcium oxide, zirconium as raw material, after the completion of by original
Material is placed in melting furnace and carries out being molten into solution;
(2) being sent at once after solution-cast is molded in annealing furnace carries out annealing for blank;
(3) blank is carried out into specification section using commercially available wire cutting machine;
(4) rough polishing is carried out to section and punching is processed as rectangle standard film;
(5) the side edge of rectangle standard film four is done into preset data hot bending on hot press and is processed as four flanging crude products;
(6) crude product is carried out into photo-irradiation treatment;
(7) crude product after illumination is carried out into Crystallizing treatment in baking furnace;
(8) and then carry out finishing polish mobile phone shell finished product is obtained.
Further technical scheme is that the raw material is formulated with following portions by weight composition:
Silica 40-60,26-38 parts of part lithium carbonate, potassium nitrate 5-20 parts, aluminum oxide 3-9 parts, calcium oxide 0.2-0.7
Part, zirconium 2.5-9 parts.
Further technical scheme is that the raw material is formulated with following portions by weight:
50 parts of silica, 32 parts of lithium carbonate, 10 parts of potassium nitrate, 4.5 parts of aluminum oxide, 0.5 part of calcium oxide, 3 parts of zirconium.
Further technical scheme is that fusion temperature is maintained at 1500-1600 DEG C in step (1).
Further technical scheme is that fusion temperature is maintained at 1580 DEG C in step (1).
It is using the beneficial effect produced by above-mentioned technical proposal:Implement the technology of the present invention and do not need special installation, only
Common industrial ceramics production equipment is needed, can be produced if melting furnace, wire cutting machine, hot press, baking furnace etc..Thrown with equipment
Money is saved, and production process is pollution-free, and added value of product is high, is a new technology being worth promoting, separately the advantages of energy-conserving and environment-protective
Outward, utilization scope of the present invention is wide, low cost, high yield rate, easy processing, and product thinness is up to 0.15mm, and wear-resisting, corrosion resistant
Erosion, high temperature resistant, electrical conductivity is high, thermal conductivity factor is big, and intensity is enough to avoid being broken into pieces, and the present invention compares the mobile phone shell of zirconium oxide,
Using integrally formed hot bending process, the effect of frame is instead of, it is very easily supporting with mobile phone, it is auxiliary without other structures
Help;, by four flangings into after mobile phone shell, outward appearance is beautiful, and performance is far longer than zirconium oxide product for this mobile phone shell photosensitive glass-ceramics.
Specific embodiment
Figure of description:
Fig. 1 is the product structure schematic diagram prepared using the method for the invention.
1st, bonnet body;2nd, flanging;3rd, hole.
With reference to the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Ground description, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Many details are elaborated in the following description in order to fully understand the present invention, but the present invention can be with
Other manner described here is different from using other to implement, those skilled in the art can be without prejudice to intension of the present invention
In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
Disclosure sets forth a kind of preparation method of photosensitive glass-ceramics mobile phone shell, it is characterised in that:Comprise the following steps:
(1) configured with silica, lithium carbonate, potassium nitrate, aluminum oxide, calcium oxide, zirconium as raw material, after the completion of mixture
Raw material is placed in melting furnace to carry out being molten into solution;
(2) being sent at once after solution-cast is molded in annealing furnace carries out annealing for blank;
(3) blank is carried out into specification section using commercially available wire cutting machine;
(4) rough polishing is carried out to section and punching is processed as rectangle standard film;
(5) the side edge of rectangle standard film four is done into preset data hot bending on hot press and is processed as four flanging crude products;
(6) crude product is carried out into photo-irradiation treatment;
(7) crude product after illumination is carried out into Crystallizing treatment in baking furnace;
(8) and then carry out finishing polish mobile phone shell finished product is obtained.
Preferably, the raw material is formulated with following portions by weight composition:
Silica 40-60,26-38 parts of part lithium carbonate, potassium nitrate 5-20 parts, aluminum oxide 3-9 parts, calcium oxide 0.2-0.7
Part, zirconium 2.5-9 parts.
Preferably, the raw material is formulated with following portions by weight:
50 parts of silica, 32 parts of lithium carbonate, 10 parts of potassium nitrate, 4.5 parts of aluminum oxide, 0.5 part of calcium oxide, 3 parts of zirconium.
Preferably, fusion temperature is maintained at 1500-1600 DEG C in step (1).
Preferably, fusion temperature is maintained at 1580 DEG C in step (1).
Embodiment, using 50 parts of silica, 32 parts of lithium carbonate, 10 parts of potassium nitrate, 4.5 parts of aluminum oxide, calcium oxide 0.5
Part, 3 parts of zirconium is the preparation that raw material carries out photosensitive glass mobile phone shell according to above-mentioned steps, and 10 samples as shown in Figure 1 are prepared altogether
Product, Experimental Mechanics performance test is carried out by each sample, uses equipment:INSTRON-5566 universal testing machines Vickers/aobvious
Micro Vickers hardness meter;Its test effect is as follows:
Implement the technology of the present invention and do not need special installation, only need common industrial ceramics production equipment, such as melting furnace, line is cut
Cutting mill, hot press, baking furnace etc. can just be produced.With low equipment investment, production process is pollution-free, and added value of product is high, energy-conservation
Environmentally friendly the advantages of, be a new technology being worth promoting, in addition, utilization scope of the present invention is wide, product thinness is reachable
0.15mm, and it is wear-resisting, corrosion-resistant, electrical conductivity is high, thermal conductivity factor is big, and intensity is enough to avoid being broken into pieces, in addition to mobile phone shell, this
Inventive technique applies also for wiring board, aerospace engineering, military defense project, and purposes is widely.
Claims (5)
1. a kind of preparation method of photosensitive glass-ceramics mobile phone shell, it is characterised in that:Comprise the following steps:
(1) configured with silica, lithium carbonate, potassium nitrate, aluminum oxide, calcium oxide, zirconium as raw material, by original after the completion of mixture
Material is placed in melting furnace and carries out being molten into solution;
(2) being sent at once after solution-cast is molded in annealing furnace carries out annealing for blank;
(3) blank is carried out into specification section using commercially available wire cutting machine;
(4) rough polishing is carried out to section and punching is processed as rectangle standard film;
(5) the side edge of rectangle standard film four is done into preset data hot bending on hot press and is processed as four flanging crude products;
(6) crude product is carried out into photo-irradiation treatment;
(7) crude product after illumination is carried out into Crystallizing treatment in baking furnace;
(8) and then carry out finishing polish mobile phone shell finished product is obtained.
2. the preparation method of a kind of photosensitive glass-ceramics mobile phone shell according to claim 1, it is characterised in that:The raw material
It is formulated with following portions by weight composition:
Silica 40-60 parts, lithium carbonate 26-38 parts, potassium nitrate 5-20 parts, aluminum oxide 3-9 parts, calcium oxide 0.2-0.7 parts, zirconium
2.5-9 parts.
3. a kind of preparation method of photosensitive glass-ceramics mobile phone shell according to claim 1, it is characterised in that:The original
Material is formulated with following portions by weight:
50 parts of silica, 32 parts of lithium carbonate, 10 parts of potassium nitrate, 4.5 parts of aluminum oxide, 0.5 part of calcium oxide, 3 parts of zirconium.
4. the preparation method of a kind of photosensitive glass-ceramics mobile phone shell according to claim 1, it is characterised in that:Step (1)
Middle fusion temperature is maintained at 1500-1600 DEG C.
5. the preparation method of a kind of photosensitive glass-ceramics mobile phone shell according to claim 1, it is characterised in that:Step (1)
Middle fusion temperature is maintained at 1580 DEG C.
Priority Applications (1)
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CN201710187666.6A CN106830678A (en) | 2017-03-27 | 2017-03-27 | A kind of preparation method of photosensitive glass-ceramics mobile phone shell |
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CN201710187666.6A CN106830678A (en) | 2017-03-27 | 2017-03-27 | A kind of preparation method of photosensitive glass-ceramics mobile phone shell |
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Publication Number | Publication Date |
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CN106830678A true CN106830678A (en) | 2017-06-13 |
Family
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CN201710187666.6A Pending CN106830678A (en) | 2017-03-27 | 2017-03-27 | A kind of preparation method of photosensitive glass-ceramics mobile phone shell |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107601900A (en) * | 2017-11-06 | 2018-01-19 | 王月辉 | A kind of photosensitive glass-ceramics shell and preparation method thereof |
CN108191244A (en) * | 2018-01-18 | 2018-06-22 | 杨霞 | A kind of glass ceramics mobile phone shell with decorative pattern and preparation method thereof |
CN108737603A (en) * | 2018-05-25 | 2018-11-02 | Oppo广东移动通信有限公司 | shell and electronic device |
CN108900658A (en) * | 2018-05-25 | 2018-11-27 | Oppo广东移动通信有限公司 | The manufacturing method of shell, electronic device and shell |
CN110963709A (en) * | 2019-12-26 | 2020-04-07 | 深圳市汇隆源科技有限公司 | Manufacturing method of precise 3D glass plate |
CN114800053A (en) * | 2022-03-30 | 2022-07-29 | 盐城牧东光电科技有限公司 | Three-dimensional mobile phone rear cover glass and preparation method thereof |
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CN1306946A (en) * | 2000-02-01 | 2001-08-08 | 株式会社小原 | Glass ceramics |
CN1872752A (en) * | 2006-06-06 | 2006-12-06 | 青岛大学 | Method for preparing polar microcrystalline glass |
CN103803803A (en) * | 2014-03-08 | 2014-05-21 | 曹小松 | High-strength nucleated glass and preparation method thereof |
CN106517800A (en) * | 2016-11-18 | 2017-03-22 | 中建材(江苏)应用技术研究院有限公司 | Glass ceramics and preparation method thereof |
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2017
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EP0233732A1 (en) * | 1986-02-13 | 1987-08-26 | Litton Systems, Inc. | Lithium-aluminum-silicate glass and glass-ceramic powders and methods of making them |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107601900A (en) * | 2017-11-06 | 2018-01-19 | 王月辉 | A kind of photosensitive glass-ceramics shell and preparation method thereof |
CN108191244A (en) * | 2018-01-18 | 2018-06-22 | 杨霞 | A kind of glass ceramics mobile phone shell with decorative pattern and preparation method thereof |
CN108737603A (en) * | 2018-05-25 | 2018-11-02 | Oppo广东移动通信有限公司 | shell and electronic device |
CN108900658A (en) * | 2018-05-25 | 2018-11-27 | Oppo广东移动通信有限公司 | The manufacturing method of shell, electronic device and shell |
CN108737603B (en) * | 2018-05-25 | 2020-09-11 | Oppo广东移动通信有限公司 | Housing and electronic device |
CN110963709A (en) * | 2019-12-26 | 2020-04-07 | 深圳市汇隆源科技有限公司 | Manufacturing method of precise 3D glass plate |
CN110963709B (en) * | 2019-12-26 | 2020-10-23 | 深圳市汇隆源科技有限公司 | Manufacturing method of precise 3D glass plate |
CN114800053A (en) * | 2022-03-30 | 2022-07-29 | 盐城牧东光电科技有限公司 | Three-dimensional mobile phone rear cover glass and preparation method thereof |
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Application publication date: 20170613 |
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