CN1068174C - Plant germicide and producing method thereof - Google Patents
Plant germicide and producing method thereof Download PDFInfo
- Publication number
- CN1068174C CN1068174C CN95113910A CN95113910A CN1068174C CN 1068174 C CN1068174 C CN 1068174C CN 95113910 A CN95113910 A CN 95113910A CN 95113910 A CN95113910 A CN 95113910A CN 1068174 C CN1068174 C CN 1068174C
- Authority
- CN
- China
- Prior art keywords
- germicide
- copper
- plant
- aliette
- butene dioic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 9
- 230000002070 germicidal effect Effects 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 claims abstract description 16
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 15
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 claims abstract description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000001954 sterilising effect Effects 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 241000233866 Fungi Species 0.000 claims abstract description 5
- 201000010099 disease Diseases 0.000 claims abstract description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000004327 boric acid Substances 0.000 claims description 9
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 8
- 238000004659 sterilization and disinfection Methods 0.000 claims description 8
- 239000002351 wastewater Substances 0.000 claims description 8
- 239000003905 agrochemical Substances 0.000 claims description 4
- 230000001580 bacterial effect Effects 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 3
- UGWKCNDTYUOTQZ-UHFFFAOYSA-N copper;sulfuric acid Chemical compound [Cu].OS(O)(=O)=O UGWKCNDTYUOTQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 14
- 235000016068 Berberis vulgaris Nutrition 0.000 abstract description 5
- 241000335053 Beta vulgaris Species 0.000 abstract description 5
- -1 copper butenedioic acid Chemical compound 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 238000003306 harvesting Methods 0.000 abstract description 2
- 244000052616 bacterial pathogen Species 0.000 abstract 2
- 229960002645 boric acid Drugs 0.000 abstract 2
- 235000010338 boric acid Nutrition 0.000 abstract 2
- 239000010842 industrial wastewater Substances 0.000 abstract 2
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 2
- 241000233679 Peronosporaceae Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a plant germicide and a preparing method thereof. The plant germicide is mainly used on beet, fruit trees, etc. for eliminating, preventing and controlling diseases caused by germs and fungi, has the advantages of favorable effect of killing germs, no residual toxicity and low cost of products and benefits the high yield and the abundant harvest of plants. The plant germicide of the present invention is a composition at least containing copper butenedioic acid, aliette and boracic acid. The preparation method mainly comprises: adding copper sulfate to industrial waste water containing butenedioic acid from the production of benzoic anhydride to obtain copper butenedioic acid; then, mixing the copper butenedioic acid, the aliette and the boracic acid, and grinding the mixture into powder of more than 300 meshes. In the present invention, industrial waste water is utilized to prepare the germicide with excellent sterilizing effect; therefore, industrial pollution is reduced, and the cost of the germicide is reduced. Tryouts on beet in large area show that the plant germicide has obvious effect of high yield.
Description
The invention belongs to a kind of composition pesticide and manufacture method thereof that is used to prevent and treat because of fungi and germ plant disease.
Crops are because of fungi, and germ disease is during agriculture and forestry are produced, and has a strong impact on the subject matter of high yield good harvest.General this class agricultural chemicals is with strong points, the plant variety or the bacterial classification narrow range that are suitable for.
The object of the invention is to disclose a kind of plant sterilization composition, and it belongs to a kind of broad-spectrum sterilization composition, is applicable to agriculture and forestry plants such as fruit tree beet.A kind of method of producing this bactericidal composition that is exclusively used in is disclosed simultaneously.
Plant sterilization composition of the present invention.It is a kind of composition that comprises butene dioic acid copper, aliette, boric acid, and wherein butene dioic acid copper, 80% aliette, boric acid three weight ratio are 17-20: 32.5-37.5: 36-49.
The manufacture method of described plant sterilization composition, form by following steps:
A, from the phthalic anhydride waste water that contains butene dioic acid, produce butene dioic acid ketone:
1, phthalic anhydride waste water filters through plate and frame filter press;
2, filtrate adds caustic soda, and being neutralized to pH value is 5.5:
3, in jacket reactor, add industrial sulphuric acid copper, be warmed to 80-95 ℃.React and generated butene dioic acid copper in 1-4 hour;
4, cool off above-mentioned product, vacuum suction filter gets decorating film;
5, dry butene dioic acid copper decorating film.
B, get agricultural chemicals type 80% aliette and industrial goods boric acid.
C, three are milled to the 300-400 order and become pulvis by weight being that 17-20: 32.5-37.5: 36-49 mixes in ball mill.
Embodiment 1
Get the phthalic anhydride waste water that contains butene dioic acid about 20 it is combined to DT, be i.e. butene dioic acid copper molecule formula C
4H
4CuO
4At first filter phthalic anhydride waste water through plate and frame filter press, adding the pH value that caustic soda makes filtrate is 5.5, adds copper sulphate and heats to 90 ℃, reacted 2 hours, stop heating, the cooling back uses vacuum suction filter, its decorating film to be the body material DT of bactericide of the present invention after vacuum drying.
Getting agricultural chemicals type aliette (containing 80% active ingredient) and industrial goods boric acid three mixes.Its ratio is＜weight ratio〉butene dioic acid copper 20, aliette 37.5, boric acid 42.5.Mixture is worn into 300 order powder on ball mill, promptly form the broad spectrum type bactericide that directly can use.
Embodiment 2
Get butene dioic acid copper 17, aliette 32, boric acid 49 grinds into 300 order powder.
The present invention is a kind of broad spectrum type plant sterilization composition, can be useful for multiple agriculture forestry planting thing, if tree, beet etc.By fungi and bacterial plant disease and downy mildew remarkable prevention effect is arranged to multiple.Try out through the beet ground large tracts of land that the harm of northerly germ is maximum, its effect of increasing production is fabulous, and the manufacture method of bactericidal composition of the present invention is to be raw material with phthalic anhydride waste water, reduces cost to greatest extent, and a kind of processing phthalic anhydride waste water new method is provided.Economic benefit and obvious social benefit.
Claims (2)
1, a kind of plant sterilization composition, be used to kill and prevent and treat by fungi and bacterial plant disease, it is the composition that comprises butene dioic acid copper, aliette, boric acid, and wherein butene dioic acid copper, aliette, boric acid three weight ratio are 17-20: 26-30: 36-49.
2, a kind of manufacture method that is exclusively used in the described plant sterilization composition of claim 1, form by following steps:
A, from the phthalic anhydride waste water that contains butene dioic acid, produce butene dioic acid copper;
1, phthalic anhydride waste water filters through the sheet frame filter;
2, filtrate adds caustic soda, and being neutralized to pH value is 5.5;
3, in jacket reactor, add industrial sulphuric acid copper, heat, react 1-4 hour generation butenyldione copper to 80-95 ℃,
4, cool off above-mentioned product, vacuum suction filter gets decorating film,
5, dry butene dioic acid copper decorating film.
B, get agricultural chemicals type 80% aliette and industrial goods boric acid,
C, three are milled to the 300-400 order and become pulvis by weight being that 17-20: 32.5-37.5: 36-49 mixes in ball mill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113910A CN1068174C (en) | 1995-11-09 | 1995-11-09 | Plant germicide and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113910A CN1068174C (en) | 1995-11-09 | 1995-11-09 | Plant germicide and producing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1149960A CN1149960A (en) | 1997-05-21 |
| CN1068174C true CN1068174C (en) | 2001-07-11 |
Family
ID=5080118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95113910A Expired - Fee Related CN1068174C (en) | 1995-11-09 | 1995-11-09 | Plant germicide and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1068174C (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61233606A (en) * | 1986-01-24 | 1986-10-17 | Rikagaku Kenkyusho | Fungicide composition for agricultural and horticultural use |
| ZA868201B (en) * | 1985-10-29 | 1988-09-28 | Hans Merensky Holdings Proprie | Boron treatment of avocado trees |
-
1995
- 1995-11-09 CN CN95113910A patent/CN1068174C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA868201B (en) * | 1985-10-29 | 1988-09-28 | Hans Merensky Holdings Proprie | Boron treatment of avocado trees |
| JPS61233606A (en) * | 1986-01-24 | 1986-10-17 | Rikagaku Kenkyusho | Fungicide composition for agricultural and horticultural use |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1149960A (en) | 1997-05-21 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: HARBIN LVHAI BIOCHEMICAL CO., LTD. Free format text: FORMER OWNER: CHEN FENGZHI Effective date: 20080815 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20080815 Address after: Heilongjiang city of Harbin province Daoli District Qun Li Xiang Wang Jia Dian Patentee after: Harbin lvhai Biological Chemical Co. Ltd. Address before: Harbin City, Heilongjiang province zone haping road power room 313 No. 91-6 Patentee before: Chen Fengzhi |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20010711 Termination date: 20141109 |
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| EXPY | Termination of patent right or utility model |