CN106812022B - Aqueous coating gold, silver paperboard of one kind and preparation method thereof - Google Patents

Aqueous coating gold, silver paperboard of one kind and preparation method thereof Download PDF

Info

Publication number
CN106812022B
CN106812022B CN201710024494.0A CN201710024494A CN106812022B CN 106812022 B CN106812022 B CN 106812022B CN 201710024494 A CN201710024494 A CN 201710024494A CN 106812022 B CN106812022 B CN 106812022B
Authority
CN
China
Prior art keywords
aqueous coating
paperboard
plain paper
paper substrate
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710024494.0A
Other languages
Chinese (zh)
Other versions
CN106812022A (en
Inventor
徐昶
林海晖
曹彩丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Xuan New Material Science And Technology Co Ltd
Original Assignee
Shenzhen Xuan New Material Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Xuan New Material Science And Technology Co Ltd filed Critical Shenzhen Xuan New Material Science And Technology Co Ltd
Priority to CN201710024494.0A priority Critical patent/CN106812022B/en
Publication of CN106812022A publication Critical patent/CN106812022A/en
Application granted granted Critical
Publication of CN106812022B publication Critical patent/CN106812022B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28—Colorants ; Pigments or opacifying agents
    • D21H21/285—Colorants ; Pigments or opacifying agents insoluble
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
    • D21H25/10—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with blades

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of silver foils of aqueous coating comprising：Plain paper substrate is set to the aqueous coating containing metal-like on one surface of the plain paper substrate；The aqueous coating is made by silver color blotting water paint, is formulated by the component of following weight percents content：Metallic pigments 5-10%, coalescents 5-15%, water-base resin 30-55%, levelling agent 1-3%, thickener 2-6%, water 10-50%, organic base 0.5-1.5%.The invention also discloses a kind of gold card paper of aqueous coating and its preparation methods of the paperboard of the aqueous coating.Present invention process simplifies, cost reduction.Resin used is water-base resin environmental protection, and paper is recyclable.Printable Color Range is extensive.Can there are wider array of metallic luster range, paperboard effect more glittering.

Description

Aqueous coating gold, silver paperboard of one kind and preparation method thereof
Technical field
The present invention relates to aqueous coating paper manufacture technology fields, more particularly to a kind of aqueous coating gold and silver paperboard and its system Preparation Method.
Background technology
Gold and silver paperboard is widely used mainly in color printing packaging, is suitable for cigarette, drinks, food, cosmetics, toothpaste box, medicine With the packagings such as the boxes processed of the industries such as the packaging of gift, case processed printing.The main manufacture craft of gold and silver paperboard is as follows at present：
Silver card：It is on moist compounding machine, art post paperboard or glass card, grey bottom card and aluminizer or aluminium foil glue is compound； One layer of gloss oil is applied on aluminizer or aluminium foil surface again；Then it dries, winds.
Gold card：It is on moist compounding machine, art post paperboard or glass card, grey bottom card and aluminizer or aluminium foil glue is compound； One layer of gloss oil for mixing up golden color ink is applied on aluminizer or aluminium foil surface again；Then drying tunnel drying, winding are crossed.
Since the coating on paperboard surface does not absorb ink, this gold and silver paperboard is adapted only to print using ultraviolet (UV) printing machine Brush is not suitable for common printing, such as gravure, convex print, silk-screen, flexo printing.And such gold and silver paperboard one shares four layers, system Make complex process, cost is higher, also can not recycling.
Invention content
For the present invention in order to solve the technical issues of prepared by existing gold and silver paperboard, a kind of environmental protection of proposition, printing are convenient, at low cost Honest and clean aqueous coating gold, silver paperboard and preparation method thereof.
A kind of silver foil of aqueous coating proposed by the present invention comprising：Plain paper substrate is set to the plain paper substrate The aqueous coating containing metal-like on one surface；The aqueous coating is made by silver color blotting water paint, by following The component of weight percent content is formulated：
Metallic pigments 5-10%, coalescents 5-15%, water-base resin 30-55%, levelling agent 1-3%, thickener 2- 6%, water 10-50%, organic base 0.5-1.5%.
The gold card paper of a kind of aqueous coating provided by the invention comprising plain paper substrate is set to the plain paper substrate one The aqueous coating containing metal-like on surface；The aqueous coating is made by golden blotting water paint, by following heavy The component of amount degree is formulated：
Metallic pigments 5-10%, coalescents 5-10%, water-base resin 25-50%, levelling agent 1-2%, thickener 1- 3%, water 20-50%, organic base 0.5-1%, yellow pigment mill base 5-10%, red pigment mill base 0.5-1%.
The present invention also provides a kind of preparation methods of the paperboard of the aqueous coating, and steps are as follows：
Step 1, the surface that the water paint of metal-like is uniformly applied to plain paper substrate by coating machine；Pass through Scraper controls generally 50 microns of its wet-film thickness；
Plain paper substrate equipped with water paint wet film is sent into 70 degree of drying tunnel Celsius and is dried by step 2；
It is step 3, again that the plain paper substrate steam ironing after drying is smooth, finally wind.
Compared with prior art, the present invention has the following advantages：
1, become two layers by original four layers, simplify technique, reduce production cost.
2, environmentally friendly, resin used is water-base resin, and metallic pigments are full curable type Diamond Search water-based metal particle, and paper can Recycling.
3, it is applicable in common printing, such as gravure, convex print, silk-screen, flexo printing, printable Color Range are wider.
4, can there are wider array of metallic luster range, the more large-sized full curable type Diamond Search water-based metal particle of use, effect Fruit is more glittering.
Specific implementation mode
With reference to the embodiment further instruction present invention.
The silver foil of a kind of aqueous coating provided by the invention comprising plain paper substrate is set to the plain paper substrate one The aqueous coating containing metal-like on surface；The aqueous coating is made by silver color blotting water paint, by following heavy The component of amount degree is formulated：
Metallic pigments 5-10%, coalescents 5-15%, water-base resin 30-55%, levelling agent 1-3%, thickener 2- 6%, water 20-50%, organic base 0.5-1.5%.
It according to different needs, can select, silver color blotting water paint is made in the proportioning of different component.
Silver color blotting aqueous coating formulation
The gold card paper of a kind of aqueous coating provided by the invention comprising plain paper substrate is set to the plain paper substrate one The aqueous coating containing metal-like on surface；The aqueous coating is made by golden blotting water paint, by following heavy The component of amount degree is formulated：
Metallic pigments 5-10%, coalescents 5-10%, water-base resin 25-50%, levelling agent 1-2%, thickener 1- 3%, water 20-50%, organic base 0.5-1%, yellow pigment mill base 5-10%, red pigment mill base 0.5-1%.
It can be selected according to different needs, golden blotting water paint is made in the proportioning of different component.
Golden blotting aqueous coating formulation
Wherein, the viscosity of the silver color blotting water paint or golden blotting water paint be 100-1000CPS (li Pool), the thickness of coating layer is between 25-50 microns.
The gold or silver foil of aqueous coating of the present invention, wherein metallic pigments are full curable type based aluminum pigment The grain size of grain, the aluminium pigment particle is 10-30 microns.The coalescents be alkoxide, alcohol ethers or alcohol ether esters one Kind.The water-base resin is aqueous acrylic emulsion or aqueous acrylic emulsion modified.The levelling agent is third Olefin(e) acid class levelling agent or silicone levelling agent.The thickener is the ASE polyacrylate alkali swelling type breast of non-association type Liquid.The organic base is N, one 1 monopropylene glycol of N- dimethylethanolamines or 2 one amino, one 2 monomethyl.
The preparation method of the paperboard of aqueous coating provided by the invention has：
Metal-like water paint is added in hopper, is then switched on, unreels, metal-like water paint leads to cross material roller It transmits, is applied to substrate surface, by controlling the elastic control wet-film thickness of scraper in 50 microns, then coated base Material is admitted to 70 degree of drying tunnels, preliminary to dry, and after drying tunnel comes out, by steam ironing (the same flatiron of principle), paper surface is pressed Boiling hot is smooth, finally winds.
The present invention becomes four layers of original paperboard two layers, simplifies technique, reduces production cost.Resin used is aqueous Resin, metallic pigments are full curable type Diamond Search water-based metal particle, the recyclable environmental protection of paper.Be applicable in common printing, as gravure, The printings such as convex print, silk-screen, flexo, printable Color Range are wider.Can there are wider array of metallic luster range, the bigger grain of use The full curable type Diamond Search water-based metal particle of diameter, effect are more glittering.
The present invention is had been described in detail above in association with better embodiment, but those skilled in the art Numerous variations and variation can be made to these embodiments, these change and variation should fall into the scope of protection of the invention it It is interior.

Claims (8)

1. a kind of preparation method of the paperboard of aqueous coating, includes the following steps：
Step 1, the surface that the water paint of metal-like is uniformly applied to plain paper substrate by coating machine；Pass through scraper Control generally 50 microns of its wet-film thickness；
Plain paper substrate equipped with water paint wet film is sent into 70 degree of drying tunnel Celsius and is dried by step 2；
It is step 3, again that the plain paper substrate steam ironing after drying is smooth, finally wind；
Wherein, the paperboard is silver foil comprising plain paper substrate, be set to one surface of the plain paper substrate contains gold Belong to the aqueous coating of texture；The aqueous coating is made by silver color blotting water paint, by following weight percents content Component be formulated：
Metallic pigments 5-10%, coalescents 5-15%, water-base resin 30-55%, levelling agent 1-3%, thickener 2-6%,
Water 10-50%, organic base 0.5-1.5%；
The viscosity of the silver color blotting water paint is 100-1000 cPs, and the thickness of coating layer is between 25-50 microns.
2. a kind of preparation method of the paperboard of aqueous coating, includes the following steps：
Step 1, the surface that the water paint of metal-like is uniformly applied to plain paper substrate by coating machine；Pass through scraper Control generally 50 microns of its wet-film thickness；
Plain paper substrate equipped with water paint wet film is sent into 70 degree of drying tunnel Celsius and is dried by step 2；
It is step 3, again that the plain paper substrate steam ironing after drying is smooth, finally wind；
Wherein, the paperboard is gold card paper comprising plain paper substrate, be set to one surface of the plain paper substrate contains gold Belong to the aqueous coating of texture；The aqueous coating is made by golden blotting water paint, by following weight percents content Component be formulated：
Metallic pigments 5-10%, coalescents 5-10%, water-base resin 25-50%, levelling agent 1-2%, thickener 1-3%,
Water 20-50%, organic base 0.5-1%, yellow pigment mill base 5-10%, red pigment mill base 0.5-1%；
The viscosity of the golden blotting water paint is 100-1000 cPs, and the thickness of coating layer is between 25-50 microns.
3. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the metallic pigments are The grain size of full curable type based aluminum pigment particle, the aluminium pigment particle is 10-30 microns.
4. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the coalescents are One kind of alkoxide, alcohol ethers or alcohol ether esters.
5. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the water-base resin is Aqueous acrylic emulsion or aqueous acrylic emulsion modified.
6. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the levelling agent is third Olefin(e) acid class levelling agent or silicone levelling agent.
7. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the thickener is non- The ASE polyacrylate alkali swelling type lotions of association type.
8. the preparation method of the paperboard of aqueous coating as claimed in claim 1 or 2, which is characterized in that the organic base is N, One 1 monopropylene glycol of N- dimethylethanolamines or 2 one amino, one 2 monomethyl.
CN201710024494.0A 2017-01-11 2017-01-11 Aqueous coating gold, silver paperboard of one kind and preparation method thereof Active CN106812022B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710024494.0A CN106812022B (en) 2017-01-11 2017-01-11 Aqueous coating gold, silver paperboard of one kind and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710024494.0A CN106812022B (en) 2017-01-11 2017-01-11 Aqueous coating gold, silver paperboard of one kind and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106812022A CN106812022A (en) 2017-06-09
CN106812022B true CN106812022B (en) 2018-11-13

Family

ID=59110454

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710024494.0A Active CN106812022B (en) 2017-01-11 2017-01-11 Aqueous coating gold, silver paperboard of one kind and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106812022B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109868679A (en) * 2019-02-18 2019-06-11 宁波亚洲浆纸业有限公司 The aqueous imitative glass card coating of one kind, imitative glass card and preparation method thereof
CN112175218A (en) * 2020-10-16 2021-01-05 吉安市佳泓新材料有限公司 Non-plastic water-based resin film and preparation method thereof
CN114541173B (en) * 2022-01-14 2022-10-14 浙江昶腾杰包装科技有限公司 Preparation method of gold and silver cardboard

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3784596A (en) * 1971-11-24 1974-01-08 Bergstrom Paper Co Non-aqueous paper coating compositions
CN103009860B (en) * 2012-12-27 2015-02-04 天津海华科技发展有限公司 Printing paper coated with gold-loaded resin for ink-jet printing
CN103382690B (en) * 2013-06-24 2016-03-09 广东绿之彩印刷科技股份有限公司 A kind of gold and silver paperboard with siphon micropore and preparation method thereof and application
CN203403326U (en) * 2013-06-24 2014-01-22 佛山市绿之彩印刷有限公司 Gold and silver paperboard with siphon micropores
CN104530892B (en) * 2015-01-20 2016-08-31 中山市博海精细化工有限公司 A kind of compound gold card paper environment-friendly type aqueous varnish and preparation method thereof

Also Published As

Publication number Publication date
CN106812022A (en) 2017-06-09

Similar Documents

Publication Publication Date Title
CN111254738B (en) Antifouling printing method for paper printed matter
CN106812022B (en) Aqueous coating gold, silver paperboard of one kind and preparation method thereof
CN108472974A (en) The manufacturing method of pretreatment liquid, ink group and printed article
CN103756496A (en) Environment-friendly printed matter oil polish
CN106223120A (en) A kind of heat sublimation transfer printing paper coating process
CN102501676A (en) Matte waterproof polypropylene photo paper applicable for aqueous ink
CN103818130B (en) A kind of production method and its device of paper package box matte
CN105437813A (en) Laser medical film and preparation method thereof
CN101122105A (en) Gravure technique for making white cardboard having same surface effect as gold cardboard
CN103882781A (en) Surface ink blotting type gold and silver cardboard and manufacturing method thereof
ES2924476T3 (en) Formulation and its use as defoamer
CN102501675A (en) Matte polypropylene inkjet photo paper suitable for ECO-solvent ink
CN106381063B (en) A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing
CN110936744A (en) Gold and silver snap ring ink-preserving printing method
CN105479957A (en) Flexible printing process for corrugated carton
CN106916326B (en) Printing material of synthetic paper and preparation method
CN105331188B (en) Art printing ink for crystallized metal printing
CN108178950A (en) A kind of highlight water-based gloss oil
CN208630121U (en) A kind of dumb light pigment blocking film
CN110406287A (en) The highlighted color face oil glazing process of one kind
CN204738181U (en) Dull polish silver card paper
CN101565917B (en) Intaglio printing paper coating
CN105348912B (en) For printing general environmentally friendly alcohol water type ink of torsion film and preparation method thereof
CN104018398A (en) Preparation method of surface sizing liquid composition for digital ink-jet printing paper
CN107201121A (en) The anti-skidding matte gloss oil of elastic handfeel

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant