CN106811689B - A kind of preparation method of tensile strength >=2000MPa hot forming steel - Google Patents

A kind of preparation method of tensile strength >=2000MPa hot forming steel Download PDF

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Publication number
CN106811689B
CN106811689B CN201710030911.2A CN201710030911A CN106811689B CN 106811689 B CN106811689 B CN 106811689B CN 201710030911 A CN201710030911 A CN 201710030911A CN 106811689 B CN106811689 B CN 106811689B
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hot forming
tensile strength
2000mpa
forming steel
hot
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CN106811689A (en
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赵征志
梁江涛
尹鸿祥
王婧惠
梁驹华
赵月
陈伟健
李枫
高鹏飞
何青
唐荻
崔衡
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University of Science and Technology Beijing USTB
Railway Engineering Research Institute of CARS
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University of Science and Technology Beijing USTB
Metals and Chemistry Research Institute of CARS
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
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  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

A kind of preparation method of tensile strength >=2000MPa hot forming steel, belongs to metal material field.Chemical composition is by percentage to the quality:C 0.3%~0.5%, Si 1.2%~1.7%, Mn1.4%~2.0%, Al0.01%~0.07%, Cr≤1.5%, P≤0.008%, S≤0.005%, B 0.001%~0.01%, Ti 0.05%~0.1%, Nb0.01%~0.08%, remaining is Fe and inevitable impurity element;Hot forming steel is obtained using smelting, hot rolling, cold rolling, bell-type annealing, steel preparation flow of the present invention is simple, after austenitizing quenching, yield strength Rp0.2=1000MPa~1200MPa, tensile strength Rm >=2000MPa, elongation percentage A50=8%~9%;Using bell-type annealing technique, base-material intensity before hot forming is down to yield strength 424MPa~588MPa, tensile strength 616MPa~760MPa, elongation percentage A50 is improved to 17.3%~20.4%, greatly reduce carry out before hot forming shape cut and cutting process in uncoiling caused by because intensity is too high it is difficult, uncoiling broken belt, shear blanking embrittlement, edge stress is too high, damage shearing blade the problems such as, for realizing that the high-strength lightweight of automobile has very important meaning.

Description

A kind of preparation method of tensile strength >=2000MPa hot forming steel
Technical field
The invention belongs to automobile cold-rolled super-high strength steel technical field, more particularly to a kind of tensile strength >=2000MPa Hot forming steel and preparation method thereof.
Background technology
The intensity of body of a motor car depends on the design and armor plate strength of vehicle body, therefore the steel plate at the important protection position of vehicle body is strong Degree just seems most important, and thermoforming steel plate is undoubtedly the outstanding person in all kinds of high-strength plates.
Hot forming steel plate technology refer to by steel plate after high-temperature heating it is once-forming, and rapid cooling is so as to carrying comprehensively Risen a kind of technology of armor plate strength, it is hot press-formed after steel plate, its yield strength up to 1000Mpa height, every square li Rice can bear more than 10 tons of pressure, and this material with when on automobile, situation is not almost changed much in car body weight Under, endurance improves 30%, so that the intensity of automobile reaches a brand-new level, at present, uses the vapour of hot forming steel Car can reach five-star standard in Euro-NCAP crash tests.
Use of the hot forming steel on automobile body part, not only can because of its high intensity and be thinned part thickness from And lightweight is realized, and when automobile hits, especially at front and side impact, can effectively reduce driving cabin change Shape, the safety of driver and crew is protected, substantially increase the safety coefficient of automobile.
At present, conventional superhigh-strength hot forming steel is mostly 22MnB5 and 30MnB5 steel both at home and abroad, 22MnB5 drop stampings into Yield strength >=1000MPa after shape, tensile strength >=1500MPa, elongation percentage is 5% or so;Bent after 30MnB5 is hot press-formed Intensity >=1000MPa is taken, tensile strength >=1600MPa, elongation percentage is 5% or so;Therefore how plasticity be not greatly lowered In the case of, improving the intensity of steel turns into one of urgent problem to be solved in hot forming techniques.
The present invention by the optimization of rational composition design and preparation technology parameter, obtained while improving intensity compared with Good elongation percentage, comprehensive mechanical property is excellent, there is extraordinary realisation and economy.
The content of the invention
It is an object of the invention to provide a kind of tensile strength >=2000MPa hot forming steel and preparation method thereof, with biography System hot forming steel is compared, and tensile strength >=2000MPa after steel austenitizing quenching of the present invention, plasticity is more preferable, elongation percentage A50= 8%~9%, the present invention not only can effectively reach automotive light weight technology purpose, and substantially increase safety coefficient, in addition, this Invention uses bell-type annealing technique, and the base-material intensity before hot forming is down into yield strength 424MPa-588MPa, tensile strength 616MPa-760MPa, elongation percentage A50 are improved to 17.3%-20.4%, so as to greatly reduce progress shape cutting before hot forming With in cutting process because intensity is too high caused by uncoiling it is difficult, uncoiling broken belt, shear blanking embrittlement, edge stress mistake Height, damage shearing blade a series of problems, such as, have extraordinary realisation and economy.
A kind of preparation method of tensile strength >=2000MPa hot forming steel, it is characterised in that chemical composition is with quality hundred Ratio is divided to be calculated as:C 0.3%~0.5%, Si 1.2%~1.7%, Mn 1.4%~2.0%, Al 0.01%~0.07%, Cr ≤ 1.5%, P≤0.008%, S≤0.005%, B 0.001%~0.01%, Ti 0.05%~0.1%, Nb 0.01%~ 0.08%, remaining is Fe and inevitable impurity element.
Preparation process is as follows:
(1) strand for meeting mentioned component is smelted;
(2) strand enters heating furnace using hot-loading and hot-conveying mode, and furnace atmosphere is weak oxide atmosphere, and strand goes out heating furnace Temperature is 1200 DEG C~1250 DEG C, and the soaking time after strand to temperature in stove is 0.5h-1h;
(3) strand after coming out of the stove passes through two passage roughing, then carries out finish rolling, 800 DEG C~900 DEG C of finish rolling finishing temperature, Last percentage pass reduction is 20%~30%, and whole roller repairing batches, and coiling temperature is 600 DEG C~700 DEG C, obtains 5mm thickness Hot-rolled strip;
(4) hot-rolled strip pickling and cold-rolling, cold rolling total reduction are 65%~85%, and the cold rolling reduction ratio of last a time controls In 8%-15%, the thick cold rolling straps of 1.2mm are obtained;
(5) cold rolling strap carries out bell-type annealing, and the rate of heat addition is 0.5 DEG C/s, when being heated to 700 DEG C, is incubated 2-8h, Ran Houkong It is cooled to room temperature, obtains hot forming steel band;
Hot forming steel band after annealing carries out austenitizing quenching, 850 DEG C~950 DEG C of austenitizing temperature, quenching cooling Speed is more than 30 DEG C/s, and the mechanical property of steel band is after quenching:Rp0.2=1000MPa~1200MPa, Rm >=2000MPa, A50 =8%~9%.
Further, chemical composition contains Cr 0.6%~1.2% by percentage to the quality.
Further, chemical composition contains B 0.002~0.005% by percentage to the quality.
Further, chemical composition contains Nb0.03%~0.06% by percentage to the quality.
Further, the yield strength of hot forming steel is 424MPa~588MPa after bell-type annealing, and tensile strength is 616MPa~760MPa, elongation percentage A50=17.3%~20.4%.
Beneficial effects of the present invention
Compared with traditional 30MnB5 steel, the mechanical property of steel of the present invention is substantially dominant in intensity and ductility, the present invention Steel preparation flow is simple, and the Composition And Process of reasonably optimizing, which designs, causes steel of the present invention to have excellent mechanical property, austenitizing After quenching, yield strength Rp0.2=1000MPa~1200MPa, tensile strength Rm >=2000MPa, elongation percentage A50=8%~ 9%;Also, the present invention use bell-type annealing technique, by the base-material intensity before hot forming be down to yield strength 424MPa~ 588MPa, tensile strength 616MPa~760MPa, elongation percentage A50 are improved to 17.3%~20.4%, so as to greatly reduce heat Carried out before shaping shape cut and cutting process in uncoiling caused by because intensity is too high it is difficult, uncoiling broken belt, shearing falls Expect embrittlement, edge stress is too high, damage shearing blade a series of problems, such as, have extraordinary realisation and economy.
Brief description of the drawings
Fig. 1:Microstructure picture after the quenching of the embodiment of the present invention 1;
Fig. 2:Microstructure picture after the quenching of comparative example 1 of the present invention.
Embodiment
Embodiment 1
The chemical composition of embodiment 1 is 0.38%C, 1.48%Si, 1.58%Mn, 0.035%Al by percentage to the quality, 0.91%Cr, 0.005%P, 0.004%S, 0.0037%B, 0.07%Ti, 0.048%Nb, remaining is for Fe and inevitably Impurity element.
Preparation process is:Smelt the strand for meeting component requirements;For strand hot-loading and hot-conveying to heating furnace, furnace atmosphere is weak oxygen Change atmosphere, strand goes out furnace temp for 1220 DEG C, and the soaking time arrived in stove after temperature is 40min;After coming out of the stove, strand is carried out Two passage roughing, multi-pass finish rolling, 850 DEG C of finish rolling finishing temperature, last percentage pass reduction are 25%, whole roller repairing volume Take, coiling temperature is 650 DEG C, obtains 5mm thickness hot-rolled strips;Hot-rolled strip pickling and cold-rolling, cold rolling total reduction 72%, last a time The control of cold rolling reduction ratio 12%, obtain the thick cold rolling straps of 1.2mm;Cold rolling strap progress bell-type annealing, 700 DEG C of annealing temperature, Time 2h, is then air-cooled to room temperature, obtains hot forming steel band, detects the mechanical property of steel band, the specific performance index such as institute of table 1 Show;Hot forming steel band after annealing carries out austenitizing quenching, 930 DEG C of austenitizing temperature, quenches, 50 DEG C/s of cooldown rate, The mechanical property of steel band is detected after quenching and carries out microstructure observation, obtained mechanical property is as shown in table 1, and microscopic structure is such as Shown in Fig. 1.
Embodiment 2
The chemical composition of embodiment 2 is 0.42%C, 1.57%Si, 1.72%Mn, 0.037%Al by percentage to the quality, 1.06%Cr, 0.008%P, 0.002%S, 0.0041%B, 0.031%Ti, 0.036%Nb, remaining is for Fe and inevitably Impurity element.
Preparation process is:Smelt the strand for meeting component requirements;For strand hot-loading and hot-conveying to heating furnace, furnace atmosphere is weak oxygen Change atmosphere, strand goes out furnace temp for 1220 DEG C, and the soaking time arrived in stove after temperature is 50min;After coming out of the stove, strand is carried out Two passage roughing, multi-pass finish rolling, 870 DEG C of finish rolling finishing temperature, last percentage pass reduction are 21%, whole roller repairing volume Take, coiling temperature is 660 DEG C, obtains 5mm thickness hot-rolled strips;Hot-rolled strip pickling and cold-rolling, cold rolling total reduction 72%, last a time The control of cold rolling reduction ratio 14%, obtain the thick cold rolling straps of 1.2mm;Cold rolling strap progress bell-type annealing, 700 DEG C of annealing temperature, Time 5h, is then air-cooled to room temperature, obtains hot forming steel band, detects the mechanical property of steel band, the specific performance index such as institute of table 1 Show;Hot forming steel band after annealing carries out austenitizing quenching, 890 DEG C of austenitizing temperature, quenches, cooling velocity, 40 DEG C/s, The mechanical property of steel band is detected after quenching and carries out microstructure observation, obtained mechanical property is as shown in table 1.
Embodiment 3
The chemical composition of embodiment 3 is 0.33%C, 1.39%Si, 1.84%Mn, 0.061%Al by percentage to the quality, 1.33%Cr, 0.005%P, 0.003%S, 0.0032%B, 0.049%Ti, 0.051%Nb, remaining is for Fe and inevitably Impurity element, preparation process is substantially the same manner as Example 1, only difference is that the time of bell-type annealing is 8h, bell-type moves back The mechanical property of steel is as shown in table 1 after the mechanical property of steel plate, austenitizing quenching after fire.
Comparative example 1
Choose University of Science & Technology, Beijing's journal in October, 2014 phase open source literature of volume 36 10《30SiMnCrB5 hot forming steel Microstructure and mechanical property》The 30SiMnCrB5 hot formings steel of middle report is as a comparison case.The steel chemical composition is with quality hundred Ratio is divided to be calculated as:0.3%C, 1.5%Si, 1.0%Mn, 1.0%Cr, 0.002%B, remaining is Fe and inevitable impurity.
After strand forging after smelting, 5 passes are carried out after 1200 DEG C are incubated 1h, obtain the hot rolling that thickness is 6mm Plate, it is 870 DEG C to control finishing temperature, and water cooling cools to room temperature with the furnace to being incubated in holding furnace after 660 DEG C after 1h simulations are batched; Then pass through pickling and cold-rolling, cold rolling reduction ratio 75%, obtain 1.5mm thickness cold-reduced sheets;Then tied again in box Muffle furnace Crystalline substance annealing, 760 DEG C of annealing temperature;Then austenitizing quenching simulation, heating-up temperature 950 are carried out on Simulated Tests For The Heat Treatment machine DEG C, 10min is incubated, then simulation cooling;Mechanics properties testing and microstructure observation are then carried out, the mechanical property measured is such as Shown in table 1, microscopic structure is as shown in Figure 2.
The mechanical property of the embodiment of table 1 and comparative example
It was found from the mechanical property of the embodiment of table 1 and comparative example:Embodiment 1, embodiment 2, the yield strength of embodiment 3 are omited Higher than comparative example 1, tensile strength is higher 200-300MPa than comparative example, and elongation percentage is lower slightly, and overall performance is seen, while realizing high-strength There is preferably elongation percentage value;The intensity of all embodiments is decreased obviously after bell-type annealing, correspondingly, on elongation percentage is obvious Rise, and as downward trend is presented in the extension intensity of bell-type annealing time, and elongation percentage is optimal to be incubated 5h performances, it is overall suitable For the uncoiling shearing requirement before hot forming.
It should be noted last that above-described embodiment, to the purpose of the present invention, technical scheme and beneficial Effect is further described, and should be understood that the embodiment that the foregoing is only the present invention, and It is non-to be used to limit the present invention, all any modifications within the spirit and principle of technical solution of the present invention, made, equivalent substitution, Improve etc., it should be included within the claims of the present invention.

Claims (5)

1. a kind of preparation method of tensile strength >=2000MPa hot forming steel, it is characterised in that chemical composition is with quality percentage Than being calculated as:C 0.3%~0.5%, Si 1.2%~1.7%, Mn 1.4%~2.0%, Al 0.01%~0.07%, Cr≤ 1.5%, P≤0.008%, S≤0.005%, B 0.001%~0.01%, Ti 0.05%~0.1%, Nb 0.01%~ 0.08%, remaining is Fe and inevitable impurity element;
Preparation process is as follows:
(1) strand for meeting mentioned component is smelted;
(2) strand enters heating furnace using hot-loading and hot-conveying mode, and furnace atmosphere is weak oxide atmosphere, and strand goes out the temperature of heating furnace For 1200 DEG C~1250 DEG C, the soaking time after strand to temperature in stove is 0.5h-1h;
(3) strand after coming out of the stove passes through two passage roughing, then carries out finish rolling, 800 DEG C~900 DEG C of finish rolling finishing temperature, finally A time reduction ratio is 20%~30%, and whole roller repairing batches, and coiling temperature is 600 DEG C~700 DEG C, obtains 5mm thickness hot rollings Band;
(4) hot-rolled strip pickling and cold-rolling, cold rolling total reduction are 65%~85%, and the cold rolling reduction ratio control of last a time exists 8%-15%, obtain the thick cold rolling straps of 1.2mm;
(5) cold rolling strap carries out bell-type annealing, and the rate of heat addition is 0.5 DEG C/s, when being heated to 700 DEG C, is incubated 2-8h, is then air-cooled to Room temperature, obtain hot forming steel band;
Hot forming steel band after annealing carries out austenitizing quenching, 850 DEG C~950 DEG C of austenitizing temperature, quenches cooling velocity More than 30 DEG C/s, the mechanical property of steel band is after quenching:Rp0.2=1000MPa~1200MPa, Rm >=2000MPa, A50= 8%~9%.
A kind of 2. preparation method of tensile strength >=2000MPa hot forming steel as claimed in claim 1, it is characterised in that Cr contents are 0.6%~1.2%.
3. a kind of tensile strength >=2000MPa as claimed in claim 1 hot forming steel Preparation Method, it is characterised in that B contains Measure as 0.002~0.005%.
A kind of 4. preparation method of tensile strength >=2000MPa hot forming steel as claimed in claim 1, it is characterised in that Nb contents are 0.03%~0.06%.
A kind of 5. preparation method of tensile strength >=2000MPa hot forming steel as claimed in claim 1, it is characterised in that The yield strength of hot forming steel is 424MPa~588MPa after bell-type annealing, and tensile strength is 616MPa~760MPa, elongation percentage A50=17.3%~20.4%.
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CN103469090A (en) * 2013-09-17 2013-12-25 北京科技大学 Annealing method of ultrahigh-strength hot-forming steel
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