CN106810968A - Impervious antireflective coating material and compound water-proof - Google Patents

Impervious antireflective coating material and compound water-proof Download PDF

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Publication number
CN106810968A
CN106810968A CN201510867049.1A CN201510867049A CN106810968A CN 106810968 A CN106810968 A CN 106810968A CN 201510867049 A CN201510867049 A CN 201510867049A CN 106810968 A CN106810968 A CN 106810968A
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China
Prior art keywords
impervious
antireflective coating
coating material
emulsion
water
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CN201510867049.1A
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Chinese (zh)
Inventor
熊玉钦
徐恩顺
刘宝印
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Beijing Oriental Yuhong Waterproof Technology Co Ltd
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Beijing Oriental Yuhong Waterproof Technology Co Ltd
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Priority to CN201510867049.1A priority Critical patent/CN106810968A/en
Priority to PCT/CN2016/107239 priority patent/WO2017092611A1/en
Publication of CN106810968A publication Critical patent/CN106810968A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of impervious antireflective coating material, the impervious antireflective coating material includes main body emulsion and inorganic filler, wherein, the main body emulsion is macromolecule emulsion, and in the main body emulsion have can with calcium ion occur complex reaction functional group, and the impervious coating in alkalescence.Invention additionally discloses a kind of compound water-proof.While thering is the impermeabilisation coating to form impermeabilisation dope layer and there is moistureproof and waterproof to act on; it is also equipped with the function of the permeability resistance of enhancing concrete; when concrete is subjected to displacement with splash guard; because protective coating can be attached on concrete; so as to strengthen the permeability resistance of concrete; and when 1~2mm crackles occurs in concrete, ability is made up with crack.Also, compound water-proof provided by the present invention is applied to carries out waterproof to Concrete bottom plate structure.

Description

Impervious antireflective coating material and compound water-proof
Technical field
The invention belongs to buildings waterproof field, and in particular to a kind of impervious antireflective coating material and one Plant compound water-proof.
Background technology
It is in the engineering constructions such as building, traffic, subway, tunnel to use concrete structure more, In these areas, the water-impervious requirement to concrete structure is very high.
In order to realize the infiltration energy of concrete structure, it is often necessary in concrete knot The surface coating antiseepage water paint of structure, can be in concrete knot after the water-impervious paint solidification The surface of structure forms antiseepage antireflective coating layer.
CN103351769 discloses a kind of acrylate mono-component waterproofing paint, the propylene Acid esters mono-component waterproofing paint has good permeability resistance, cohesive force and flexibility, overall Elasticity and elongation percentage, can realize that coating water-repellent paint occurs that 2-3mm is wide to be opened in concrete Split and impermeable effect.
But above-mentioned water-repellent paint cannot be used for Concrete bottom plate structure.In concrete floor When carrying out waterproof, it usually needs use splash guard.But splash guard typically cannot with anti- The structural concrete attachment poured after on water plate, once splash guard is destroyed, water will be anti- Channelling between water plate and concrete, when concrete is cracked, whole water-proof system failure.
Therefore, waterproof how is carried out to Concrete bottom plate structure urgently to be resolved hurrily as this area Technical problem.
The content of the invention
Include the impermeabilisation it is an object of the invention to provide a kind of impervious antireflective coating material and one kind The compound water-proof of coating, the compound water-proof is applied to enter Concrete bottom plate structure Row waterproof.
To achieve these goals, as one aspect of the present invention, there is provided a kind of impervious Antireflective coating material, wherein, the impervious antireflective coating material includes main body emulsion and inorganic filler, wherein, The main body emulsion is have on macromolecule emulsion, and the strand side chain of the main body emulsion Having can occur the functional group of complex reaction, and the impervious coating in alkalescence with calcium ion.
Preferably, the anion of the functional group is CN-、SCN-、F-、COOH-、 OH-In any one;Or, the functional group includes ligand molecule NH3Or H2O。
Preferably, the main body emulsion includes acrylic emulsions.
Preferably, the main body emulsion be selected from pure-acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, In acrylate and vinyl acetate emulsion, vinyl acetate-ethylene copolymerization emulsions and carbonic ester emulsion any one or The mixture of any several persons.
Preferably, the inorganic filler is selected from pearl filler, perlite filler, titanium white Any one or any several persons' in powder filler, kaolin clay filler, wollastonite packing is mixed Compound.
Preferably, the particle diameter of the inorganic filler is between 10 μm to 150 μm.
Preferably, the impervious antireflective coating material also includes water, dispersant, wetting agent, froth breaking Any one or any several persons of agent, thickener and auxiliary agent.
Preferably, the total mass ratio of each component of the impervious antireflective coating material is 100wt%, Also, each component of the impervious antireflective coating material has following mass percent:
Preferably, the dispersant is dispersant DP270, dispersant DA40, dispersant Any one in 5040 or the arbitrarily mixing of several persons.
Preferably, the defoamer is defoamer 7010, defoamer NXZ, defoamer Any one in F-111, defoamer A10 or the arbitrarily mixing of several persons.
Preferably, the auxiliary agent is in preservative, anti-settling agent, antifreezing agent, coalescents Any one or any several persons mixing.
Preferably, the wetting agent is wetting agent NP10, wetting agent X405, wetting agent The mixture of any one or any several persons in CF10, wetting agent DM-410.
As another aspect of the present invention, there is provided a kind of compound water-proof, wherein, institute Compound water-proof is stated including water-proof substrate and at least one table of the water-proof substrate is arranged on Impervious antireflective coating layer on face, the water-proof substrate is made up of macromolecular material, described impervious Antireflective coating layer is formed by above-mentioned impermeabilisation paint solidification provided by the present invention.
Preferably, the water-proof substrate by EVA waterproof materials, TPO waterproof materials, Any one in HDPE waterproof materials is made.
Impervious antireflective coating material in the present invention is sprayed or brushed on splash guard, impermeabilisation is applied Material has good wetability on splash guard, and uniform impervious antireflective coating material is formed after film forming Layer, after doing solid work, the surface hand of impermeabilisation dope layer is touched and not glued, and the protective coating is dry Rear pouring concrete after dry film forming with solidification counter can glue, for anti-viscous waterproof construction.It is impervious While antireflective coating material layer has moistureproof and waterproof to act on, it is also equipped with strengthening the permeability resistance of concrete Function, when concrete is subjected to displacement with splash guard, due to protective coating can be attached to it is mixed On solidifying soil, so as to strengthen the permeability resistance of concrete, and there is 1~2mm in concrete During crackle, ability is made up with crack.Also, compound water-proof provided by the present invention Suitable for carrying out waterproof to Concrete bottom plate structure.
Specific embodiment
To make those skilled in the art more fully understand technical scheme, tie below Specific embodiment is closed to be described in further detail the present invention.
As one aspect of the present invention, there is provided a kind of impervious antireflective coating material, the impermeabilisation Coating includes main body emulsion and inorganic filler, wherein, the main body emulsion is macromolecule latex Liquid, having on the strand side chain of the main body emulsion can occur complexing instead with calcium ion The functional group answered, and the impervious coating is in alkalescence.
When using impervious antireflective coating material provided by the present invention, the impermeabilisation is applied first Material is coated in formation impermeabilisation dope layer on splash guard, then again by concreting anti- On infiltration dope layer.
Because the main body emulsion is macromolecule emulsion, also, match somebody with somebody with the impervious coating The plate that the splash guard that conjunction is used is made for macromolecular material, therefore, the impervious antireflective coating material Layer has preferable wettability on splash guard, equably can spread on splash guard, Impervious antireflective coating material is bonded on splash guard securely by solidification.Simultaneously as the master Having in precursor emulsion can occur the anion or ligand point of complex reaction with calcium ion Son, therefore, when concreting is on impermeabilisation dope layer, main body emulsion and coagulation There is complex reaction in the calcium ion in soil, such that it is able to ensure impermeabilisation dope layer securely It is counter to be bonded on concrete.
In addition, inorganic filler is also included in impervious coating, it is impervious such that it is able to increase The surface roughness of dope layer, one side inorganic filler particle be cast in impervious dope layer The contact surface area of the concrete structure on surface, on the other hand, inorganic filler particle can be with Cast setting is formed with concrete structure, concrete structure and impermeabilisation dope layer is increased Between bond strength.
Also, the impervious antireflective coating material is alkalescence, concrete is also alkalescence, therefore, Impervious antireflective coating material will not reduce the intensity of concrete structure.
Impermeabilisation dope layer can either be securely joined with splash guard, again can with securely It is counter to be bonded on concrete, such that it is able to ensure not to be shifted between splash guard and concrete The permeability resistance of concrete structure is enhanced simultaneously, improves waterproof effect.
In the present invention, main body emulsion is macromolecule emulsion, therefore, the impervious coating There is certain elasticity after the impervious dope layer solidification for being formed, when being cast in impervious antireflective coating material When concrete structure on layer produces less crack, the impermeabilisation dope layer has more The ability in crack is closed, so as to further increase water resistance.
Since impervious antireflective coating material provided by the present invention is suitable to be combined with splash guard using, So, impervious antireflective coating material provided by the present invention is also applied for entering Concrete bottom plate structure Row waterproof.
In the present invention, there is no special restriction to the functional group, if can with it is mixed There is complex reaction in the calcium ion in solidifying soil.Preferably, the functional group it is cloudy from Son is CN-、SCN-、F-、COOH-、OH-In any one, above-mentioned anion is Ligand, can form very steady with metal ion (that is, the above calcium ion) Fixed complex compound.
Or, the functional group can include ligand molecule NH3Or H2O.It is above-mentioned to match somebody with somebody Position body molecule can also form the complex compound of stabilization with calcium ion.
In the present invention, the specific composition to main body emulsion does not do special restriction, makees It is a kind of preferred embodiment of the invention, the main body emulsion includes acrylic emulsions. Acrylic emulsions include COOH-, the complexing to form stabilization can be complexed with calcium ion Thing.
When the main body emulsion is acrylic emulsions, the main body emulsion can be selected from Pure-acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, vinyl acetate-ethylene copolymerization The mixture of any one or any several persons in emulsion and carbonic ester emulsion.
When the main body emulsion is acrylic emulsions, the acrylic emulsions can be with Selected from the acrylic emulsions with following trade names:Wacker 547、Wacker 558、 Dow 2468、Dow 2471、Dow 2475,Acronal CN11、Acronal PA237、 Acronal SC138、Dow TX-011、Dow TX-100、Dow Ultra-E、Dow AC-8356、BASF 400s、Dow AC-818、Dow 2848、BASF TB2012、 Dow R16w、Dow Primal EC 1791、UCAR 8152。
Generally, splash guard is by EVA waterproof materials, TPO waterproof materials, HDPE waterproofs Any one in material is made.Therefore, main body emulsion selection acrylic emulsions can be with Improve the wetability of main body emulsion and splash guard.
As a kind of preferred embodiment of the invention, when the main body emulsion is acetic acid second During alkene-ethylene copolymerization emulsions, splash guard preferably has EVA waterproof materials to be made, so that can To mention wetability of the impervious antireflective coating material on splash guard to greatest extent, be is anti- Infiltration coating uniformly continuous ground film forming on splash guard.
Carbonic ester emulsion is a kind of abbreviation, and specifically, carbonic ester emulsion is carbonic ester propylene Yogurt liquid.
In the present invention, to the species of inorganic filler also without special limitation.As this The preferred embodiment of invention, the inorganic filler can be selected from pearl filler, pearl In rock filler, titanium dioxide filler, kaolin clay filler, wollastonite packing any one or The mixture of any several persons.
There is relatively large roughness and really after hardening in order to ensure impervious antireflective coating material Protect the mobility of the impervious antireflective coating material, it is preferable that the particle diameter of the inorganic filler exists Between 10 μm to 150 μm.
In order to improve wetability of the impervious antireflective coating material on splash guard, it is preferable that institute Stating impervious antireflective coating material can include wetting agent.In the present invention, the wetting agent is preferably In wetting agent NP10, wetting agent X405, wetting agent CF10, wetting agent DM-410 The mixture of any one or any several persons.
In order to increase the stability of the impervious antireflective coating material, it is preferable that the impermeabilisation is applied Material also includes any one of water, dispersant, defoamer, thickener and auxiliary agent or any Several persons.
It is easily understood that the total mass ratio of each component of the impervious antireflective coating material is 100wt%.
Preferably, each component of the impervious antireflective coating material has following mass percent:
Preferably, the defoamer is defoamer 7010, defoamer NXZ, defoamer Any one in F-111, defoamer A10 or the arbitrarily mixing of several persons.
Preferably, the auxiliary agent is in preservative, anti-settling agent, antifreezing agent, coalescents One of or any several persons mixing.
Preferably, the water used in heretofore described impervious antireflective coating material be deionized water, Any one in pure water and distilled water, it is certainly, described impervious in order to cost-effective Water used in antireflective coating material can be the running water of soft.
As another aspect of the present invention, there is provided a kind of compound water-proof, this is compound anti- Water plate includes water-proof substrate and is arranged on anti-at least one surface of the water-proof substrate Permeation coating, the water-proof substrate is made up of macromolecular material, the impervious antireflective coating layer by Above-mentioned impermeabilisation paint solidification provided by the present invention is formed.
Preferably, the water-proof substrate by EVA waterproof materials, TPO waterproof materials, Any one in HDPE waterproof materials is made.
Compound water-proof provided by the present invention is particularly suited for entering Concrete bottom plate structure Row waterproof.
Embodiment
Embodiment 1
The present embodiment provides a kind of impervious antireflective coating material, and the impervious antireflective coating material includes such as the following group Point:
The main body emulsion is vinegar-acrylic emulsion BLJ-358, and described filler is pearl filler, The dispersant is dispersant DP270, and the defoamer is defoamer F-111, described to help Agent is anti-settling agent.
The present embodiment provides a kind of preparation method of impervious antireflective coating material, according to above-mentioned coating Formula carry out following step:
Impervious antireflective coating material is prepared in accordance with the following methods:
(1) running water is weighed by formula is accurate, is added in dispersion cylinder, speed of agitator is 100 Rev/min, stir;
(2) dispersant, wetting agent, defoamer, thickener, auxiliary agent are accurately weighed, plus Enter in dispersion cylinder, speed of agitator is 100 revs/min, and stirring at low speed 3 minutes, stirring is equal It is even;
(3) mixing speed is improved to 200 revs/min, is slowly uniformly added into and is accurately weighed Filler, addition in 10 minutes finishes, stirs;
(4) it is accurate to weigh emulsion and then be slowly uniformly added into paint mixing cylinder, feed within 5 minutes Finish, speed of agitator is 200 revs/min, and low speed disperses 5 minutes, stirs, and stands 5 Minute, obtain impervious antireflective coating material.
Embodiment 2
The present embodiment provides a kind of impervious antireflective coating material, and the impervious antireflective coating material is according to weight meter Contain following component:
The main body emulsion is styryl acrylic emulsion bc-991, and described filler is perlite filler, The dispersant is dispersant 5040, and the wetting agent is wetting agent NP10, the froth breaking Agent is defoamer A10, and the auxiliary agent is antifreezing agent.
Impervious antireflective coating material is prepared according to the method disclosed in embodiment 1.
Embodiment 3
The present embodiment provides a kind of impervious antireflective coating material, and the impervious antireflective coating material is according to weight meter Contain following component:
The main body emulsion is silicon-acralyte latex SD-528, and described filler is kaolin and silicon ash (weight ratio is 1 to stone:1), the dispersant is dispersant DA40, and the wetting agent is Wetting agent CF10, the defoamer is defoamer 7010, and the auxiliary agent is preservative.
The impervious antireflective coating material is prepared according to the method disclosed in embodiment 1.
Embodiment 4
The present embodiment provides a kind of impervious antireflective coating material, and the impervious antireflective coating material is according to weight meter Contain following component:
The main body emulsion is propene carbonate emulsion CAS No.108-32-7, described filler It is pearl filler, the dispersant is dispersant DP270, the wetting agent is wetting Agent NP10, the defoamer is that (weight ratio is for defoamer NXZ and defoamer F-111 3:2), for antifreezing agent and coalescents, (weight ratio is 1 to the auxiliary agent:3).
The impervious antireflective coating material is prepared according to the method disclosed in embodiment 1.
Embodiment 5
The present embodiment provides a kind of impervious antireflective coating material, and the impervious antireflective coating material is according to weight meter Contain following component:
The present embodiment provides a kind of preparation method of impervious antireflective coating material, according to above-mentioned coating Formula carry out following step:
(1) running water is weighed by formula is accurate, is added in dispersion cylinder, speed of agitator is 100 Rev/min, stir;
(2) dispersant, wetting agent, defoamer, thickener, auxiliary agent are accurately weighed, plus Enter in dispersion cylinder, speed of agitator is 100 revs/min, and stirring at low speed 3 minutes, stirring is equal It is even;
(3) mixing speed is improved to 200 revs/min, is slowly uniformly added into and is accurately weighed Color stuffing, addition in 10~15 minutes finishes, stirs;
(4) it is accurate to weigh emulsion and then be slowly uniformly added into paint mixing cylinder, feed within 5~8 minutes Finish, speed of agitator is 200 revs/min, and low speed disperses 5 minutes, stirs, and is stood 5 minutes, obtain impervious antireflective coating material.
Experimental example
The impervious antireflective coating material in embodiment 1 to embodiment 5 is set respectively as follows On water-proof substrate, compound water-proof, and the casting concrete on compound water-proof are formed:
(1) impervious antireflective coating material is sprayed on water-proof substrate, forms continuous impermeabilisation and apply The bed of material;
(2) to obtain compound water-proof after impervious antireflective coating layer is dried;
(2) casting concrete on compound water-proof.
Experimental example 1
In step (1), water-proof substrate is TPO splash guards.
Experimental example 2
In step (1), water-proof substrate is HDPE splash guards.
Experimental example 3
In step (1), water-proof substrate is EVA splash guards.
Compound water-proof to pouring concrete is carried out after conserving one week to above-described embodiment Performance test, obtains the experimental result shown in table 1:
For the ease of observation, " peel strength with TPO splash guards " is designated as performance A, " peel strength with HDPE splash guards " is designated as performance B, will be " with EVA waterproofs The peel strength of plate " is designated as performance C, by " peel strength with concrete " being designated as property Energy D, performance E is designated as by " impermeability with anti-adhesive coating layer mortar specimen ", by " ten times After drying and watering cycle, the peel strength with concrete " performance F is designated as, by " ten dry and wets are followed After ring, concrete permeability resistance " it is designated as performance G.
Table 1
For the ease of contrast, impervious test is carried out without treatment mortar specimen, it is final to obtain Test result be, without treatment mortar specimen it is permeable under 0.2MPa hydraulic pressure.
Impervious test comparison is carried out by table 1 and without treatment mortar specimen, this The impervious antireflective coating material that is there is provided of invention be coated on water-proof substrate formed compound water-proof it Afterwards, impermeabilisation dope layer counter can not only be bonded at the concrete being cast on compound water-proof It is in structure and strong with larger combination between impermeabilisation dope layer and water-proof substrate Degree, it is not easy to peeled off with water-proof substrate.
Impervious antireflective coating material in the present embodiment sprays or brushes the protection formed in splash guard and applies The performance of layer is instead glued between waterproof roll between conventional waterproof plate and self-adhesion, although do not possessed Effect of complete leakage-proof, but can be the permeability resistance of pouring concrete and crack after strengthening Making up property, so that preferably protection structure concrete, delays infiltration, with property higher Valency ratio, compared with single ply waterproofing plate, has very big competitiveness in tunnel water proofing application.
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present And the illustrative embodiments for using, but the invention is not limited in this.For ability For those of ordinary skill in domain, the situation of spirit and substance of the present invention is not being departed from Under, various changes and modifications can be made therein, and these variations and modifications are also considered as of the invention Protection domain.

Claims (14)

1. a kind of impervious antireflective coating material, it is characterised in that the impervious antireflective coating material includes main body Emulsion and inorganic filler, wherein, the main body emulsion is macromolecule emulsion, and the master Having on the strand side chain of precursor emulsion can occur the function of complex reaction with calcium ion Group, and the impervious coating is in alkalescence.
2. impervious antireflective coating material according to claim 1, it is characterised in that the official The anion that can be rolled into a ball is CN-、SCN-、F-、COOH-、OH-In any one;Or Person, the functional group includes ligand molecule NH3Or H2O。
3. impervious antireflective coating material according to claim 1, it is characterised in that the master Precursor emulsion includes acrylic emulsions.
4. impervious antireflective coating material according to claim 3, it is characterised in that the master Precursor emulsion is selected from pure-acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, acetic acid second Any one in alkene-ethylene copolymerization emulsions and carbonic ester emulsion or the arbitrarily mixing of several persons Thing.
5. impervious antireflective coating material as claimed in any of claims 1 to 4, it is special Levy and be, the inorganic filler is selected from pearl filler, perlite filler, titanium dioxide and fills out The mixture of any one or any several persons in material, kaolin clay filler, wollastonite packing.
6. impervious antireflective coating material according to claim 5, it is characterised in that the nothing The particle diameter of machine filler is between 10 μm to 150 μm.
7. impervious antireflective coating material as claimed in any of claims 1 to 4, it is special Levy and be, the impervious antireflective coating material also include water, dispersant, wetting agent, defoamer, Any one or any several persons of thickener and auxiliary agent.
8. impervious antireflective coating material according to claim 7, it is characterised in that described anti- Permeate coating each component total mass ratio be 100wt%, also, the impermeabilisation apply Each component of material has following mass percent:
9. impervious antireflective coating material according to claim 7, it is characterised in that described point Powder is any one in dispersant DP270, dispersant DA40, dispersant 5040 Or the mixing of any several persons.
10. impervious antireflective coating material according to claim 7, it is characterised in that described Defoamer is defoamer 7010, defoamer NXZ, defoamer F-111, defoamer A10 In any one or any several persons mixing.
11. impervious antireflective coating materials according to claim 7, it is characterised in that described Auxiliary agent is any one in preservative, anti-settling agent, antifreezing agent, coalescents or any The mixing of several persons.
12. impervious antireflective coating materials according to claim 7, it is characterised in that described Wetting agent is wetting agent NP10, wetting agent X405, wetting agent CF10, wetting agent DM-410 In any one or any several persons mixture.
13. a kind of compound water-proofs, it is characterised in that the compound water-proof includes anti- Water base plate and the impervious antireflective coating layer being arranged at least one surface of the water-proof substrate, The water-proof substrate is made up of macromolecular material, and the impervious antireflective coating layer is by claim 1 Impermeabilisation paint solidification into 12 described in any one is formed.
14. compound water-proofs according to claim 13, it is characterised in that described Water-proof substrate is by EVA waterproof materials, TPO waterproof materials, HDPE waterproof materials Any one is made.
CN201510867049.1A 2015-12-01 2015-12-01 Impervious antireflective coating material and compound water-proof Pending CN106810968A (en)

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CN110484082A (en) * 2018-08-29 2019-11-22 含山县金中环装饰材料有限公司 A kind of concrete protection osmosis type anticorrosive paint
CN112239620A (en) * 2020-09-24 2021-01-19 桐城市儒和建材有限公司 Environment-friendly pollution-free interior wall water-based paint and preparation method thereof
CN114292558A (en) * 2021-12-30 2022-04-08 广西青龙化学建材有限公司 Maintenance-free acrylate spray film waterproof material with composite structure and preparation method thereof
CN116589930A (en) * 2023-06-25 2023-08-15 阁美仕(广东)建材有限公司 Crack-resistant and seepage-proof joint mixture for door and window frames and preparation method thereof

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CN108129078A (en) * 2017-12-21 2018-06-08 天津新滨工程技术检测有限公司 A kind of modification spray liniment, lightweight precast concrete plate and preparation method
CN110484082A (en) * 2018-08-29 2019-11-22 含山县金中环装饰材料有限公司 A kind of concrete protection osmosis type anticorrosive paint
CN112239620A (en) * 2020-09-24 2021-01-19 桐城市儒和建材有限公司 Environment-friendly pollution-free interior wall water-based paint and preparation method thereof
CN114292558A (en) * 2021-12-30 2022-04-08 广西青龙化学建材有限公司 Maintenance-free acrylate spray film waterproof material with composite structure and preparation method thereof
CN114292558B (en) * 2021-12-30 2022-07-12 广西青龙化学建材有限公司 Maintenance-free acrylate spray film waterproof material with composite structure and preparation method thereof
CN116589930A (en) * 2023-06-25 2023-08-15 阁美仕(广东)建材有限公司 Crack-resistant and seepage-proof joint mixture for door and window frames and preparation method thereof
CN116589930B (en) * 2023-06-25 2023-11-07 阁美仕(广东)建材有限公司 Crack-resistant and seepage-proof joint mixture for door and window frames and preparation method thereof

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