CN106800766A - A kind of good high-low temperature resistant cable material of rigidity - Google Patents

A kind of good high-low temperature resistant cable material of rigidity Download PDF

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Publication number
CN106800766A
CN106800766A CN201611182052.0A CN201611182052A CN106800766A CN 106800766 A CN106800766 A CN 106800766A CN 201611182052 A CN201611182052 A CN 201611182052A CN 106800766 A CN106800766 A CN 106800766A
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parts
nano silicon
low temperature
temperature resistant
cable material
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唐亮
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Anhui Xinli Cable Material Co Ltd
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Anhui Xinli Cable Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H6/00Macromolecular compounds derived from lignin, e.g. tannins, humic acids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

Abstract

The invention discloses a kind of good high-low temperature resistant cable material of rigidity, its raw material includes by weight:30 60 parts of polyphenylene oxide, 5 15 parts of polytrifluorochloroethylene, 8 14 parts of polypropylene, 27 parts of bisphenol A-type polyarylate, 0.2 0.6 parts of cumyl peroxide, 0.1 0.6 parts of diethylenetriamines, 0.4 0.9 parts of diethylentriamine, 26 parts of modified sodium lignosulfonate, 5 12 parts of montmorillonite, 6 10 parts of sepiolite, 28 parts of porous konilite, 15 parts of nano silicon, 12 parts of ointment, 12 parts of pine tar, 12 parts of antioxidant D, 12 parts of antioxidant A, 12 parts of dimethicone.Rigidity of the invention is good, can be good with high-low temperature resistant, chemical stability, and ageing-resistant performance is excellent, not only with good processing characteristics and mechanical performance, and is not easily broken, while enhancing ageing-resistant intensity.

Description

A kind of good high-low temperature resistant cable material of rigidity
Technical field
The present invention relates to plastics arts, more particularly to a kind of good high-low temperature resistant cable material of rigidity.
Background technology
With the development of cable industries, people to the requirement more and more higher of the performances such as security, the aesthetic property of cable, And traditional cable material is improved, and it is the fundamental way for improving cable performance, macromolecule cable plastics material is than tradition Cable material has the advantages that many protrusions, and light weight, mechanical performance are superior, easy processing shaping, and material is repeatable to be utilized, and is also had Remarkable attractive, decorative effect, but these macromolecular materials there is also some shortcomings, such as rigidity is poor, not high-low temperature resistant, Poor chemical stability, ageing-resistant can not meet demand, it would be highly desirable to solve.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of good high-low temperature resistant cable material of rigidity, just Property is good, can be with high-low temperature resistant, and chemical stability is good, and ageing-resistant performance is excellent, not only with good processing characteristics and mechanicalness Can, and be not easily broken.
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:Polyphenylene oxide 30-60 Part, polytrifluorochloroethylene 5-15 parts, polypropylene 8-14 parts, 2-7 parts of bisphenol A-type polyarylate, cumyl peroxide 0.2-0.6 Part, diethylenetriamines 0.1-0.6 parts, diethylentriamine 0.4-0.9 parts, modified sodium lignosulfonate 2-6 parts, montmorillonite 5-12 Part, sepiolite 6-10 parts, porous konilite 2-8 parts, nano silicon 1-5 parts, ointment 1-2 parts, pine tar 1-2 parts, prevent old 1-2 parts, antioxidant A 1-2 parts, dimethicone 1-2 parts of agent D.
Preferably, modified sodium lignosulfonate is prepared using following technique:Nano silicon, absolute ethyl alcohol, water are mixed Stirring is closed, adds ammoniacal liquor regulation system pH value to continue to stir to 8.5-9, add ten trifluoro octyl group trimethoxy silanes to continue to stir Mix, it is 6.2-6.4 that ammonium chloride to system pH is added dropwise, and is filtrated to get pretreatment nano silicon;By sodium lignin sulfonate plus Enter placement in NaAc_HAc buffer solution, add zytase, pretreatment nano silicon stirring, add peroxidating Thing enzyme, hydrogenperoxide steam generator stirring obtain modified sodium lignosulfonate.
Preferably, modified sodium lignosulfonate is prepared using following technique:Nano silicon, absolute ethyl alcohol, water are mixed Stirring 20-40min is closed, whipping temp is 55-65 DEG C, add ammoniacal liquor regulation system pH value to continue to stir 60- to 8.5-9 100min, adds ten trifluoro octyl group trimethoxy silanes to continue to stir 20-40min, and it is 6.2- that ammonium chloride to system pH is added dropwise 6.4, it is filtrated to get pretreatment nano silicon;15- is placed during sodium lignin sulfonate is added into NaAc_HAc buffer solution 45min, it is 45-55 DEG C that temperature is maintained in placement process, adds zytase, pretreatment nano silicon stirring 60- 100min, adds peroxidase, hydrogenperoxide steam generator stirring 15-25min, and whipping temp is 35-42 DEG C, obtains modified wooden Plain sodium sulfonate.
Preferably, modified sodium lignosulfonate is prepared using following technique:By weight by 5-15 parts of nano silicon, 20-40 parts of absolute ethyl alcohol, 10-16 parts of water mix 20-40min, and whipping temp is 55-65 DEG C, adds ammoniacal liquor regulation system PH value continues to stir 60-100min to 8.5-9, adds 1-2 parts of ten trifluoro octyl group trimethoxy silanes to continue to stir 20-40min, It is 6.2-6.4 that ammonium chloride to system pH is added dropwise, and is filtrated to get pretreatment nano silicon;It is wooden by 5-15 parts by weight Plain sodium sulfonate places 15-45min in adding 40-60 parts of NaAc_HAc buffer solution, and it is 45- that temperature is maintained in placement process 55 DEG C, 0.01-0.06 parts of zytase, 2-6 parts of pretreatment nano silicon stirring 60-100min are added, add 0.04- 0.07 part of peroxidase, 1-2 parts of concentration are the hydrogenperoxide steam generator stirring 15-25min of 12-14wt%, and whipping temp is 35- 42 DEG C, obtain modified sodium lignosulfonate.
Preferably, polyphenylene oxide, polytrifluorochloroethylene, polypropylene, bisphenol A-type polyarylate, the weight of modified sodium lignosulfonate Amount is than being 40-50:8-12:10-12:4-6:3-5.
Preferably, the weight ratio of modified sodium lignosulfonate, montmorillonite, sepiolite, porous konilite, nano silicon It is 3-5:6-10:7-9:4-6:2-4.
Preferably, the weight ratio of ointment and pine tar is 1.3-1.7:1.4-1.6.
The present invention is obtained using conventional fabrication process.
In modified sodium lignosulfonate of the invention, not only storage stability is good for pretreatment nano silicon, and tool Have high-low temperature resistant, ageing-resistant performance, while also as the introducing of fluoro-containing group and assign pretreatment nano silicon have it is resistance to Solvent, chemically stable and relatively low surface can, and sodium lignin sulfonate is by after NaAc_HAc buffer solution treatment, successively Activated by zytase and cause that carbohydrate disconnects with lignin molecule connecting key, reactivity increases, peroxidase Catalysis, with hydrogen peroxide as oxygen source, the surface excess of product is high after polymerization, and with pretreatment nano silicon mixing Good dispersion, adhesion is strong, makes that the mechanical property of modified sodium lignosulfonate is extremely excellent, and ageing-resistant performance is fabulous.
Because polypropylene has good filler pardon and cross linkable, the present invention uses itself and polyphenylene oxide, poly- trifluoro The poly- virtue of vinyl chloride, bisphenol A-type coordinates, and controls the content of said components and is acted on modified sodium lignosulfonate, and solidification crosslinking is close Degree is high, makes rigidity of the invention good, can be good with high-low temperature resistant, chemical stability, and ageing-resistant performance is excellent;And modified lignin resin sulphur Sour sodium and montmorillonite, sepiolite, porous konilite, nano silicon mating reaction, and appropriate ointment, pine tar are added, no Only there is good processing characteristics and mechanical performance, and it is balanced rigidity of the invention is reached with pliability, is not easily broken, while Enhance ageing-resistant intensity.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:30 parts of polyphenylene oxide, 15 parts of polytrifluorochloroethylene, 8 parts of polypropylene, 7 parts of bisphenol A-type polyarylate, 0.2 part of cumyl peroxide, diethylenetriamines 0.6 part, 0.4 part of diethylentriamine, 6 parts of modified sodium lignosulfonate, 5 parts of montmorillonite, 10 parts of sepiolite, 2 parts of porous konilite, 5 parts of nano silicon, 1 part of ointment, 2 parts of pine tar, 1 part of antioxidant D, 2 parts of antioxidant A, 1 part of dimethicone.
Embodiment 2
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:60 parts of polyphenylene oxide, 5 parts of polytrifluorochloroethylene, 14 parts of polypropylene, 2 parts of bisphenol A-type polyarylate, 0.6 part of cumyl peroxide, diethylenetriamines 0.1 part, 0.9 part of diethylentriamine, 2 parts of modified sodium lignosulfonate, 12 parts of montmorillonite, 6 parts of sepiolite, 8 parts of porous konilite, 1 part of nano silicon, 2 parts of ointment, 1 part of pine tar, 2 parts of antioxidant D, 1 part of antioxidant A, 2 parts of dimethicone.
Modified sodium lignosulfonate is prepared using following technique:Nano silicon, absolute ethyl alcohol, water are mixed, Add ammoniacal liquor regulation system pH value to continue to stir to 8.5-9, add ten trifluoro octyl group trimethoxy silanes to continue to stir, chlorine is added dropwise It is 6.2-6.4 to change ammonium to system pH, is filtrated to get pretreatment nano silicon;Sodium lignin sulfonate is added into acetic acid-vinegar Placed in sour sodium cushioning liquid, add zytase, pretreatment nano silicon stirring, add peroxidase, peroxide Change hydrogen solution stirring and obtain modified sodium lignosulfonate.
Embodiment 3
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:40 parts of polyphenylene oxide, 12 parts of polytrifluorochloroethylene, 10 parts of polypropylene, 6 parts of bisphenol A-type polyarylate, 0.3 part of cumyl peroxide, diethylenetriamines 0.4 part, 0.5 part of diethylentriamine, 5 parts of modified sodium lignosulfonate, 6 parts of montmorillonite, 9 parts of sepiolite, 4 parts of porous konilite, 4 parts of nano silicon, 1.3 parts of ointment, 1.6 parts of pine tar, 1.2 parts of antioxidant D, 1.8 parts of antioxidant A, dimethicone 1.2 parts.
Modified sodium lignosulfonate is prepared using following technique:Nano silicon, absolute ethyl alcohol, water are mixed 30min, whipping temp is 60 DEG C, adds ammoniacal liquor regulation system pH value to continue to stir 80min to 8.5-9, adds ten trifluoro octyl groups Trimethoxy silane continues to stir 30min, and it is 6.2-6.4 that ammonium chloride to system pH is added dropwise, and is filtrated to get pretreatment nanometer two Silica;30min is placed during sodium lignin sulfonate is added into NaAc_HAc buffer solution, maintenance temperature is in placement process 50 DEG C, zytase, pretreatment nano silicon stirring 80min are added, add peroxidase, hydrogenperoxide steam generator to stir 20min is mixed, whipping temp is 38 DEG C, obtains modified sodium lignosulfonate.
Embodiment 4
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:50 parts of polyphenylene oxide, 8 parts of polytrifluorochloroethylene, 12 parts of polypropylene, 4 parts of bisphenol A-type polyarylate, 0.5 part of cumyl peroxide, diethylenetriamines 0.2 part, 0.7 part of diethylentriamine, 3 parts of modified sodium lignosulfonate, 10 parts of montmorillonite, 7 parts of sepiolite, 6 parts of porous konilite, 2 parts of nano silicon, 1.7 parts of ointment, 1.4 parts of pine tar, 1.8 parts of antioxidant D, 1.4 parts of antioxidant A, dimethicone 1.6 parts.
Modified sodium lignosulfonate is prepared using following technique:By weight by 5 parts of nano silicons, 40 parts of anhydrous second Alcohol, 10 parts of water mix 40min, and whipping temp is 55 DEG C, add ammoniacal liquor regulation system pH value to continue to stir to 8.5-9 100min, adds 1 part of ten trifluoro octyl group trimethoxy silane to continue to stir 40min, and it is 6.2- that ammonium chloride to system pH is added dropwise 6.4, it is filtrated to get pretreatment nano silicon;60 parts of Acetic acid-sodium acetates are added to delay 5 parts of sodium lignin sulfonates by weight Rush and 15min is placed in solution, it is 55 DEG C that temperature is maintained in placement process, add 0.01 part of zytase, 6 parts of pretreatment nanometers Silica stirs 60min, adds 0.07 part of peroxidase, 1 part of concentration to be stirred for the hydrogenperoxide steam generator of 14wt% 15min, whipping temp is 42 DEG C, obtains modified sodium lignosulfonate.
Embodiment 5
A kind of good high-low temperature resistant cable material of rigidity proposed by the present invention, its raw material includes by weight:40 parts of polyphenylene oxide, 12 parts of polytrifluorochloroethylene, 10 parts of polypropylene, 6 parts of bisphenol A-type polyarylate, 0.3 part of cumyl peroxide, diethylenetriamines 0.4 part, 0.5 part of diethylentriamine, 5 parts of modified sodium lignosulfonate, 6 parts of montmorillonite, 9 parts of sepiolite, 4 parts of porous konilite, 4 parts of nano silicon, 1.3 parts of ointment, 1.6 parts of pine tar, 1.2 parts of antioxidant D, 1.8 parts of antioxidant A, dimethicone 1.2 parts.
Modified sodium lignosulfonate is prepared using following technique:By weight by 15 parts of nano silicons, 20 parts it is anhydrous Ethanol, 16 parts of water mix 20min, and whipping temp is 65 DEG C, add ammoniacal liquor regulation system pH value to continue to stir to 8.5-9 60min, adds 2 part of ten trifluoro octyl group trimethoxy silane to continue to stir 20min, and it is 6.2- that ammonium chloride to system pH is added dropwise 6.4, it is filtrated to get pretreatment nano silicon;15 parts of sodium lignin sulfonates are added into 40 parts of Acetic acid-sodium acetates by weight 45min is placed in cushioning liquid, it is 45 DEG C that temperature is maintained in placement process, adds 0.06 part of zytase, 2 parts of pretreatments and receives Rice silica stirring 100min, adds 0.04 part of peroxidase, 2 parts of concentration to be stirred for the hydrogenperoxide steam generator of 12wt% 25min, whipping temp is 35 DEG C, obtains modified sodium lignosulfonate.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (7)

1. the good high-low temperature resistant cable material of a kind of rigidity, it is characterised in that its raw material includes by weight:Polyphenylene oxide 30-60 parts, Polytrifluorochloroethylene 5-15 parts, polypropylene 8-14 parts, 2-7 parts of bisphenol A-type polyarylate, cumyl peroxide 0.2-0.6 parts, two Ethylenetriamine 0.1-0.6 parts, diethylentriamine 0.4-0.9 parts, modified sodium lignosulfonate 2-6 parts, montmorillonite 5-12 parts, sea Afrodite 6-10 parts, porous konilite 2-8 parts, nano silicon 1-5 parts, ointment 1-2 parts, pine tar 1-2 parts, antioxidant D 1- 2 parts, antioxidant A 1-2 parts, dimethicone 1-2 parts.
2. the good high-low temperature resistant cable material of rigidity according to claim 1, it is characterised in that modified sodium lignosulfonate is used It is prepared by following technique:By nano silicon, absolute ethyl alcohol, water mix, add ammoniacal liquor regulation system pH value to 8.5-9 after Continuous stirring, adds ten trifluoro octyl group trimethoxy silanes to continue to stir, and it is 6.2-6.4, filtering that ammonium chloride to system pH is added dropwise Obtain pre-processing nano silicon;Placed during sodium lignin sulfonate is added into NaAc_HAc buffer solution, add wood poly- Carbohydrase, pretreatment nano silicon stirring, add peroxidase, hydrogenperoxide steam generator stirring to obtain modified lignin resin sulfonic acid Sodium.
3. the good high-low temperature resistant cable material of rigidity according to claim 1 or claim 2, it is characterised in that modified sodium lignosulfonate Prepared using following technique:Nano silicon, absolute ethyl alcohol, water are mixed into 20-40min, whipping temp is 55-65 DEG C, add ammoniacal liquor regulation system pH value to 8.5-9 continue stir 60-100min, add ten trifluoro octyl group trimethoxy silanes after Continuous stirring 20-40min, it is 6.2-6.4 that ammonium chloride to system pH is added dropwise, and is filtrated to get pretreatment nano silicon;By wood Quality sodium sulfonate places 15-45min in adding NaAc_HAc buffer solution, and it is 45-55 DEG C that temperature is maintained in placement process, Zytase, pretreatment nano silicon stirring 60-100min are added, adds peroxidase, hydrogenperoxide steam generator to stir 15-25min is mixed, whipping temp is 35-42 DEG C, obtains modified sodium lignosulfonate.
4. the good high-low temperature resistant cable material of rigidity according to claim any one of 1-3, it is characterised in that modified lignin resin sulphur Sour sodium is prepared using following technique:5-15 parts of nano silicon, 20-40 parts of absolute ethyl alcohol, 10-16 parts of water are mixed by weight Stirring 20-40min is closed, whipping temp is 55-65 DEG C, add ammoniacal liquor regulation system pH value to continue to stir 60- to 8.5-9 100min, adds 1-2 parts of ten trifluoro octyl group trimethoxy silanes to continue to stir 20-40min, and ammonium chloride to system pH is added dropwise is 6.2-6.4, is filtrated to get pretreatment nano silicon;5-15 parts of sodium lignin sulfonate is added into 40-60 portions of vinegar by weight 15-45min is placed in acid-sodium acetate buffer, it is 45-55 DEG C that temperature is maintained in placement process, adds 0.01-0.06 parts Zytase, 2-6 part of pretreatment nano silicon stirring 60-100min, add 0.04-0.07 parts of peroxidase, 1-2 parts Concentration is the hydrogenperoxide steam generator stirring 15-25min of 12-14wt%, and whipping temp is 35-42 DEG C, obtains modified lignin resin sulphur Sour sodium.
5. the good high-low temperature resistant cable material of rigidity according to claim any one of 1-4, it is characterised in that polyphenylene oxide, poly- three Fluorine vinyl chloride, polypropylene, bisphenol A-type polyarylate, the weight ratio of modified sodium lignosulfonate are 40-50:8-12:10-12:4-6: 3-5。
6. the good high-low temperature resistant cable material of rigidity according to claim any one of 1-5, it is characterised in that modified lignin resin sulphur Sour sodium, montmorillonite, sepiolite, porous konilite, the weight ratio of nano silicon are 3-5:6-10:7-9:4-6:2-4.
7. the good high-low temperature resistant cable material of rigidity according to claim any one of 1-6, it is characterised in that ointment and pine tar Weight ratio be 1.3-1.7:1.4-1.6.
CN201611182052.0A 2016-12-20 2016-12-20 A kind of good high-low temperature resistant cable material of rigidity Pending CN106800766A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116903966A (en) * 2023-09-06 2023-10-20 潍坊潍星联合橡塑有限公司 Heat-resistant and aging-resistant cable outer sheath material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101080782A (en) * 2004-12-17 2007-11-28 通用电气公司 Flame retardant electrical wire
CN106220919A (en) * 2016-08-15 2016-12-14 赵俊 A kind of low smoke and zero halogen oil resistant 1E type used in nuclear power station K3 level communication removal cable

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101080782A (en) * 2004-12-17 2007-11-28 通用电气公司 Flame retardant electrical wire
CN106220919A (en) * 2016-08-15 2016-12-14 赵俊 A kind of low smoke and zero halogen oil resistant 1E type used in nuclear power station K3 level communication removal cable

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116903966A (en) * 2023-09-06 2023-10-20 潍坊潍星联合橡塑有限公司 Heat-resistant and aging-resistant cable outer sheath material
CN116903966B (en) * 2023-09-06 2023-11-17 潍坊潍星联合橡塑有限公司 Heat-resistant and aging-resistant cable outer sheath material

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