CN106800665A - A kind of disposable butyronitrile diamond texture gloves and its preparation technology - Google Patents
A kind of disposable butyronitrile diamond texture gloves and its preparation technology Download PDFInfo
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- CN106800665A CN106800665A CN201710025365.3A CN201710025365A CN106800665A CN 106800665 A CN106800665 A CN 106800665A CN 201710025365 A CN201710025365 A CN 201710025365A CN 106800665 A CN106800665 A CN 106800665A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
- C08L7/02—Latex
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
- C08L9/04—Latex
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/80—Friction or grip reinforcement
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
- C08J2307/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2309/02—Copolymers with acrylonitrile
- C08J2309/04—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of disposable butyronitrile diamond texture gloves and its preparation technology, the gloves include glove bulk, and the surfaces externally and internally of the glove bulk is impregnated by mould and forms diamond texture.The step of butyronitrile diamond texture gloves preparation technology is:S1, offer polymer emulsion;S2, offer coagulant solution;The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;S4, the mould immersion polymer emulsion that will have coagulator coating;S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;S7, the above-mentioned film of cleaning, drying;S8, gloves are peeled off from mould.
Description
Technical field
The present invention relates to disposable butyronitrile diamond texture gloves production technical field, a kind of disposable butyronitrile is related in particular to
Diamond texture gloves and its preparation technology.
Background technology
Nowadays, the use of butyronitrile latex examination gloves is more and more extensive, be not limited to it is medical, change its size, thickness
In the case of extend to family expenses, industrial.The ground such as Hebei, Shandong, Jiangsu have producer to build line production butyronitrile inspection hand one after another
Set, usually completes production by techniques such as fingerprint leaching coagulator, impregnation, crimping, drying, surface treatment, the demouldings.Rely on this
Production technology is planted, increases fingerprint surface pattern, so as to develop this diamond texture gloves.
At present, there are the following problems for the butyronitrile latex examination gloves of prior art:
The 1st, make glove surface that if there is texture outer surface of glove is had texture by chemical attack at present, or by particle
It is ejected into outer surface of glove and forms texture, these methods are all unsatisfactory, there is that such as dexterity is poor, gloves became uneven is even
Easily the shortcomings of cracking.The butyronitrile latex examination gloves of highway tread pattern shape hinders the sensitivity and sense of touch of gloves, anti-when gloves are used
Slip can be bad, and hand is perspired excessively during wearing, and influence is used.
2nd, current work gloves in order to easy to wear often using there is powder to process, such as talcum powder or starch, so
Easy contaminated wound, stimulate skin, leave residue in equipment and clothing.Existed using the method for preventing gloves from skidding in cotton lining
Effect is not ideal in practicality, effective only when sweat is less.
The content of the invention
Defect it is an object of the invention to be directed to above-mentioned prior art, there is provided a kind of disposable butyronitrile diamond texture gloves and
Its preparation technology, overcome the gloves latex block of prior art with the adhesion between gloves embryo it is poor, gloves frictional force are small, palm
Grasping fastness it is poor, dress fatigable defect for a long time.Compared with existing procucts, the gloves are dexterous comfortable, and thickness is uniform,
Skidproof effect is outstanding, and heat is not the glove slip that can effectively prevent hand perspiration from causing when dressing for a long time.
To achieve these goals, the technical scheme is that:
A kind of disposable butyronitrile diamond texture gloves, including glove bulk, the surfaces externally and internally of the glove bulk is by mould dipping
Into diamond texture.Preparation technology that is of the invention and providing above-mentioned disposable butyronitrile diamond texture gloves, the butyronitrile diamond texture gloves
The step of preparation technology is:
S1, offer polymer emulsion;
S2, offer coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
Used as the improvement to above-mentioned technical proposal, polymer emulsion can follow chemical resistance European standard EN374-3
Any polymer;Alternatively, polymer emulsion can be any polymer for following the FFDCA requirements of Food processing ground;Replace
, polymer emulsion can be any polymer of the European standard EN388 for following the mechanical risk of confrontation;Replace, polymer
Emulsion can be any polymer for following European standard EN372-3.
In one embodiment, polymer emulsion is Heveatex.
In an alternate embodiment, polymer emulsion is synthetic rubber copolymer emulsion;Synthetic rubber copolymer emulsion includes
The copolymer emulsion of acrylonitrile and butadiene.
In one embodiment, polymer emulsion is NBR latex, sulphur, zinc oxide, dibutyl dithiocaarbamate
Zinc (ZDBC), ammoniacal liquor, the mixture solution of potassium hydroxide;The NBR latex, sulphur, zinc oxide, dibutyl dithio amino
Zinc formate (ZDBC), ammoniacal liquor, the mass ratio of potassium hydroxide are 100:1.35:1.80:1.90:1:3:0.85.
In one embodiment, polymer emulsion can include additive, colouring agent, preservative, aromatic etc..
In one embodiment, coagulant solution is the calcium nitrate solution of mass fraction 35%.
In one embodiment, alternatively, coagulant solution can be molten coagulator disclosed in EP1638423B1
Liquid.
Compared with prior art, the present invention has the advantages and positive effects that:
Compared with existing procucts, dexterous comfortable, thickness is uniform, and skidproof effect goes out for disposable butyronitrile diamond texture gloves of the invention
Color, heat is not the glove slip that can effectively prevent hand perspiration from causing when dressing for a long time.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, may be used also
Other accompanying drawings are obtained with according to these accompanying drawings.
Fig. 1 is structural representation of the invention.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, institute
Any modification, equivalent substitution and improvements of work etc., should be included within the scope of the present invention.
As shown in figure 1, disposable butyronitrile diamond texture gloves of the invention, including glove bulk 1, the glove bulk 1
The diamond texture 2 that surfaces externally and internally is impregnated by mould.
The preparation technology of the disposable butyronitrile diamond texture gloves is as shown in the following examples:
Embodiment 1
S1, offer Heveatex make polymer emulsion;The polymer emulsion is to follow gathering for chemical resistance European standard EN374-3
Compound;
S2, the calcium nitrate solution of offer mass fraction 35% make coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
Embodiment 2
S1, offer synthetic rubber copolymer emulsion make polymer emulsion, and synthetic rubber copolymer emulsion includes acrylonitrile and fourth two
The copolymer emulsion of alkene;The polymer emulsion is the polymer for following the FFDCA requirements of Food processing ground;
S2, the coagulant solution provided disclosed in EP1638423B1 make coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
Embodiment 3
S1, provide NBR latex, sulphur, zinc oxide, zinc dibutyl dithiocarbamate (ZDBC), ammoniacal liquor, potassium hydroxide
Mixture solution makees polymer emulsion;The NBR latex, sulphur, zinc oxide, zinc dibutyl dithiocarbamate (ZDBC),
Ammoniacal liquor, the mass ratio of potassium hydroxide are 100:1.35:1.80:1.90:1:3:0.85.The polymer emulsion is followed to resistance to mechanical
Any polymer of the European standard EN388 of risk
S2, the calcium nitrate solution of offer mass fraction 35% make coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
Embodiment 4
S1, offer Heveatex make polymer emulsion;The polymer emulsion is any polymerization for following European standard EN372-3
Thing.Polymer emulsion can include additive, colouring agent, preservative, aromatic etc..
S2, the coagulant solution provided disclosed in EP1638423B1 make coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
Compared with prior art, the present invention has the advantages and positive effects that:
Compared with existing procucts, dexterous comfortable, thickness is uniform, and skidproof effect goes out for disposable butyronitrile diamond texture gloves of the invention
Color, heat is not the glove slip that can effectively prevent hand perspiration from causing when dressing for a long time.
Claims (8)
1. a kind of disposable butyronitrile diamond texture gloves, including glove bulk, it is characterised in that:The surfaces externally and internally of the glove bulk
Impregnated by mould and form diamond texture.
2. a kind of preparation technology of butyronitrile diamond texture gloves as claimed in claim 1 disposable, it is characterised in that:The butyronitrile is bored
The step of bag gloves preparation technology is:
S1, offer polymer emulsion;
S2, offer coagulant solution;
The mould of S3, offer diamond lines, and mould is immersed in coagulant solution;
S4, mould is taken out and dried from coagulant solution, die surface forms coagulator coating;
S4, the mould immersion polymer emulsion that will have coagulator coating;
S5, taking-up mould and drying from polymer emulsion, make die surface form polymer coating film;
S6, the above-mentioned mould with thin polymer film is soaked a polymer emulsion again, and dried, form thin polymer film;
S7, the above-mentioned film of cleaning, drying;
S8, gloves are peeled off from mould.
3. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Polymer emulsion is to abide by
Follow any polymer of chemical resistance European standard EN374-3;Or follow any polymerization of Food processing ground FFDCA requirements
Thing;Or follow any polymer of the European standard EN388 of the mechanical risk of confrontation;Or follow European standard EN372-3's
Any polymer.
4. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Polymer emulsion is day
Right latex.
5. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Polymer emulsion is to close
Into rubbery copolymer emulsion;Synthetic rubber copolymer emulsion includes the copolymer emulsion of acrylonitrile and butadiene.
6. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Polymer emulsion is fourth
Nitrile latex, sulphur, zinc oxide, zinc dibutyl dithiocarbamate (ZDBC), ammoniacal liquor, the mixture solution of potassium hydroxide;Institute
Stating NBR latex, sulphur, zinc oxide, zinc dibutyl dithiocarbamate (ZDBC), ammoniacal liquor, the mass ratio of potassium hydroxide is
100:1.35:1.80:1.90:1:3:0.85.
7. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Coagulant solution is matter
Measure the calcium nitrate solution of fraction 35%.
8. the preparation technology of disposable butyronitrile diamond texture gloves as claimed in claim 2, it is characterised in that:Coagulant solution be
Coagulant solution disclosed in EP1638423B1.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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CN201710025365.3A CN106800665A (en) | 2017-01-13 | 2017-01-13 | A kind of disposable butyronitrile diamond texture gloves and its preparation technology |
PCT/CN2017/077323 WO2018129805A1 (en) | 2017-01-13 | 2017-03-20 | Disposable butyronitrile gloves with diamond pattern and manufacturing process therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710025365.3A CN106800665A (en) | 2017-01-13 | 2017-01-13 | A kind of disposable butyronitrile diamond texture gloves and its preparation technology |
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CN106800665A true CN106800665A (en) | 2017-06-06 |
Family
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CN201710025365.3A Pending CN106800665A (en) | 2017-01-13 | 2017-01-13 | A kind of disposable butyronitrile diamond texture gloves and its preparation technology |
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WO (1) | WO2018129805A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107212491A (en) * | 2017-07-31 | 2017-09-29 | 南京润京乳胶制品有限公司 | Domestic purpose gloves and its preparation technology in a kind of natural rubber light |
CN108299688A (en) * | 2018-02-05 | 2018-07-20 | 山东登升安防科技有限公司 | A kind of three-dimensional pattern slip-proof glove and its preparation process |
CN113492480A (en) * | 2021-07-01 | 2021-10-12 | 东台市华亿手套有限公司 | Process for synthesizing butyronitrile glove coagulant |
CN114290586A (en) * | 2021-12-30 | 2022-04-08 | 苏州嘉乐威新材料股份有限公司 | Method for preparing interventional therapy gloves and gloves prepared by same |
CN116079968A (en) * | 2023-03-24 | 2023-05-09 | 鲨克里特科技有限公司 | Glove hand mould with micro-texture structure and manufacturing method thereof |
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CN112480501B (en) * | 2020-10-09 | 2023-06-27 | 中红普林医疗用品股份有限公司 | Production process for improving cross-linking density of nitrile glove under condition of not increasing energy consumption |
CN113320063B (en) * | 2021-06-07 | 2022-10-11 | 桂林恒保健康防护有限公司 | Antiviral medical latex product and preparation method thereof |
CN113999440B (en) * | 2021-10-22 | 2023-08-01 | 南京瑞润新材料科技有限公司 | Manufacturing method of medical latex glove with high elasticity and breakage resistance |
CN115785492A (en) * | 2022-12-14 | 2023-03-14 | 南通强生新材料科技股份有限公司 | Chemical-resistant gloves and preparation method thereof |
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CN103637437A (en) * | 2013-11-12 | 2014-03-19 | 青岛劲手劳保用品有限公司 | Five-finger reinforced type work protective glove and preparation method thereof |
CN203608874U (en) * | 2013-11-16 | 2014-05-28 | 山东登升劳保用品有限公司 | Water-sucking antiskid glove |
CN105188435A (en) * | 2013-12-13 | 2015-12-23 | 约翰·约瑟夫·弗朗 | Ambidextrous fish scale-textured glove |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107212491A (en) * | 2017-07-31 | 2017-09-29 | 南京润京乳胶制品有限公司 | Domestic purpose gloves and its preparation technology in a kind of natural rubber light |
CN108299688A (en) * | 2018-02-05 | 2018-07-20 | 山东登升安防科技有限公司 | A kind of three-dimensional pattern slip-proof glove and its preparation process |
CN113492480A (en) * | 2021-07-01 | 2021-10-12 | 东台市华亿手套有限公司 | Process for synthesizing butyronitrile glove coagulant |
CN114290586A (en) * | 2021-12-30 | 2022-04-08 | 苏州嘉乐威新材料股份有限公司 | Method for preparing interventional therapy gloves and gloves prepared by same |
CN116079968A (en) * | 2023-03-24 | 2023-05-09 | 鲨克里特科技有限公司 | Glove hand mould with micro-texture structure and manufacturing method thereof |
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Publication number | Publication date |
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WO2018129805A1 (en) | 2018-07-19 |
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