CN106766362A - Coking system and its residual neat recovering system - Google Patents

Coking system and its residual neat recovering system Download PDF

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Publication number
CN106766362A
CN106766362A CN201710054844.8A CN201710054844A CN106766362A CN 106766362 A CN106766362 A CN 106766362A CN 201710054844 A CN201710054844 A CN 201710054844A CN 106766362 A CN106766362 A CN 106766362A
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CN
China
Prior art keywords
outlet
working medium
liquid
entrance
inlet
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Granted
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CN201710054844.8A
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Chinese (zh)
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CN106766362B (en
Inventor
毛旸
徐列
韩冬
陈本成
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Beijing Huatai Coking Engineering Technology Co Ltd
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Beijing Huatai Coking Engineering Technology Co Ltd
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Priority to CN201710054844.8A priority Critical patent/CN106766362B/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B27/00Machines, plants or systems, using particular sources of energy
    • F25B27/02Machines, plants or systems, using particular sources of energy using waste heat, e.g. from internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K27/00Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
    • F01K27/02Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00Fluid-circulation arrangements
    • F25B41/40Fluid line arrangements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y02A30/274Relating to heating, ventilation or air conditioning [HVAC] technologies using waste energy, e.g. from internal combustion engine
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

The present invention provides a kind of residual neat recovering system, including heat pump and the first TRT, the heat pump includes the first evaporator and the first condenser, first evaporator includes that cryogenic liquid inlet and high-temp liquid are exported, first condenser includes that high-temp liquid entrance and cryogenic liquid are exported, first TRT includes that thermal source inlet and low-temperature receiver are exported, the thermal source inlet and corresponding low-temperature receiver outlet, the high-temp liquid outlet of the thermal source inlet of first TRT and first evaporator, generated electricity with the heat using the liquid from high-temp liquid outlet outflow, and, the low-temperature receiver outlet is connected with the high-temp liquid entrance of the heat pump, can be exported from the low-temperature receiver after the thermal source inlet flows into the fluid temperature reduction of first TRT and flow into first condenser.The present invention also provides a kind of coking system.Coking system including the residual neat recovering system has relatively low energy consumption.

Description

Coking system and its residual neat recovering system
Technical field
The present invention relates to coking production field, in particular it relates to the waste heat recovery of a kind of coking system and the coking system System.
Background technology
At present, in domestic coking process flow, because the demand of coking furnace gas purification process to coal gas, it is necessary to carry out repeatedly Heating, cooling, accordingly, it is desirable to provide for coal gas heat up thermal source and for coal gas cooling low-temperature receiver.Due to carrying respectively Supplying heat source and low-temperature receiver, cause coking production technique to consume energy high, and the energy cannot be utilized effectively.
Therefore, coking process power consumption how is reduced as this area technical problem urgently to be resolved hurrily.
The content of the invention
It is an object of the invention to provide a kind of residual neat recovering system for coking system and including the waste heat recovery system The coking system of system, the residual neat recovering system can reclaim the waste heat in cooling water in coking process, and waste heat is carried out again Utilize, such that it is able to reduce the energy consumption of coking process.
To achieve these goals, as one aspect of the present invention, there is provided a kind of residual neat recovering system, wherein, this is remaining Heat recovery system includes heat pump and the first TRT, and the heat pump includes the first evaporator and the first condenser, described first Evaporator includes that cryogenic liquid inlet and high-temp liquid are exported, and first condenser includes high-temp liquid entrance and cryogenic liquid Outlet, first TRT includes thermal source inlet and low-temperature receiver outlet, the thermal source inlet and corresponding low-temperature receiver outlet, The high-temp liquid outlet of the thermal source inlet of first TRT and first evaporator, with using from the high temperature The heat of the liquid of liquid outlet outflow is generated electricity, also, low-temperature receiver outlet is connected with the high-temp liquid entrance of the heat pump, is led to Can be exported described in inflow from the low-temperature receiver after the fluid temperature reduction for crossing the thermal source inlet inflow first TRT First condenser.
Preferably, the heat pump includes heating steam inlet and condensation-water drain, and the heating steam inlet is cold with described Solidifying water out connection, the heating steam inlet is used to being passed through the steam for heating, the steam condensation into after liquid from institute State condensation-water drain outflow.
Preferably, the residual neat recovering system also includes condensate tank, and the condensate tank connects with the condensation-water drain Lead to, and the condensate tank is connected with the cryogenic liquid inlet of the heat pump.
Preferably, the residual neat recovering system also includes condensed water small pump, the entrance of the condensed water small pump and institute Condensate tank connection is stated, the outlet of the condensed water small pump is connected with the cryogenic liquid inlet of the heat pump.
Preferably, first TRT includes that the second evaporator, the second condenser, the first turbine and first generate electricity Machine, the thermal source inlet includes the first thermal source inlet, and the low-temperature receiver outlet includes that the first low-temperature receiver is exported,
Second evaporator also includes the outlet of the first generating working medium and the first generating working medium entrance, second evaporator For accommodating the generating working medium flowed into by the first generating working medium entrance in second evaporator, first thermal source enters Mouth and first low-temperature receiver outlet are respectively formed on first evaporator, and first thermal source inlet is exported with first low-temperature receiver Connection, is added with using the liquid by first thermal source inlet inflow second evaporator to the generating working medium Heat, and stream can be exported by first low-temperature receiver by the liquid that first thermal source inlet flows into second evaporator Go out, the first generating working medium outlet is connected with the air intake of first turbine;
First turbine is used to drive the electrical power generators;
Second condenser includes the second generating working medium entrance for interconnecting and the outlet of the second generating working medium, described the Two generating working medium entrances are connected with the venthole of first turbine, with to the generating work flowed out from first turbine Matter carries out cooling condensation, obtains the generating working medium of liquid, and the generating working medium of the liquid can be by second generating working medium Outlet is flowed out second condenser and reaches the first generating working medium entrance of second evaporator.
Preferably, first TRT also includes preheater and working medium pump,
The preheater includes the 3rd generating working medium entrance for interconnecting and the outlet of the 3rd generating working medium, the 3rd hair Electric working medium entrances and the second generating working medium outlet, the 3rd generating working medium outlet enter with first generating working medium Mouth connection, the preheater is pre- for being carried out to the generating working medium for flowing into the preheater by the 3rd generating working medium entrance Heat;
The entrance of the working medium pump and the second generating working medium outlet, the outlet of the working medium pump and the described 3rd Generating working medium entrance is connected.
Preferably, the thermal source inlet includes Secondary Heat Source entrance, and the low-temperature receiver outlet includes that the second low-temperature receiver is exported, described Secondary Heat Source entrance and second low-temperature receiver outlet are both formed on the preheater, and the Secondary Heat Source entrance and described the Two low-temperature receiver outlets, the high-temp liquid outlet of the Secondary Heat Source entrance and first evaporator, described second is cold Source outlet is connected with the high-temp liquid entrance of first evaporator, and the preheater is flowed into by the Secondary Heat Source entrance Liquid can be exported by second low-temperature receiver and flowed out.
Preferably, the residual neat recovering system also includes system circulation pump, and the entrance of the system circulation pump is low with described Geothermal liquid outlet.
Preferably, the residual neat recovering system also includes the second TRT, and second TRT includes the second whirlpool Turbine, the second generator and the 3rd condenser, the 3rd condenser go out including steam inlet, coolant inlet and coolant Mouthful, the steam inlet connects with the venthole of second turbine, the Low Temperature Liquid of the coolant inlet and the heat pump Body outlet, the cooling liquid outlet is connected with the cryogenic liquid inlet of the heat pump.
As another aspect of the present invention, there is provided a kind of coking system, the coking system includes primary cooler, and its feature exists In the coking system also includes residual neat recovering system, and the residual neat recovering system is returned for above-mentioned waste heat provided by the present invention Receipts system, the cryogenic liquid inlet of the heat pump is connected with the liquid outlet of the primary cooler, the cryogenic liquid outlet of the heat pump Liquid inlet with the primary cooler is connected.
Preferably, the coking system also includes refrigeration plant, the cryogenic liquid of the outlet of the refrigeration plant and the heat pump Entrance is connected, the cryogenic liquid outlet of the entrance of the refrigeration plant and the heat pump.
Preferably, the coking system also includes final cooling tower, the Low Temperature Liquid of the liquid inlet of the final cooling tower and the heat pump Body outlet, the liquid outlet of the final cooling tower is connected with the cryogenic liquid inlet of the heat pump.
Residual neat recovering system provided by the present invention can not only utilize the temperature flowed out from cooling device higher to follow Heat in ring water is generated electricity, additionally it is possible to which the liquid of temperature reduction is re-used as cooling device as low-temperature receiver by the use of after generating electricity Cooling medium.Technique electricity consumption is can serve as using the waste heat electricity of recirculated water, so as in a disguised form reduce the energy of whole technique Consumption.
Brief description of the drawings
Accompanying drawing is, for providing a further understanding of the present invention, and to constitute the part of specification, with following tool Body implementation method is used to explain the present invention together, but is not construed as limiting the invention.In the accompanying drawings:
Fig. 1 is the schematic diagram of coking system provided by the present invention.
Description of reference numerals
100:Heat pump 200:First TRT
210:First turbine 220:Second evaporator
230:Second condenser 240:Preheater
250:First generator 260:Working medium pump
300:Primary cooler 400:Final cooling tower
500:Second TRT 510:Second turbine
520:3rd condenser 530:Second generator
600:Condensate tank 700:Condensed water small pump
800:System circulation pump 900:Vapour source
Specific embodiment
Specific embodiment of the invention is described in detail below in conjunction with accompanying drawing.It should be appreciated that this place is retouched The specific embodiment stated is merely to illustrate and explain the present invention, and is not intended to limit the invention.
As one aspect of the present invention, there is provided a kind of residual neat recovering system, wherein, as shown in figure 1, the waste heat recovery system System includes the TRT 200 of heat pump 100 and first.
Heat pump 100 includes the first evaporator and the first condenser, and first evaporator includes cryogenic liquid inlet and height Geothermal liquid is exported, and first condenser includes that high-temp liquid entrance and cryogenic liquid are exported.
First TRT 200 includes thermal source inlet and low-temperature receiver outlet, thermal source inlet and corresponding low-temperature receiver outlet.Should The high-temp liquid outlet of the thermal source inlet of the first TRT 200 and first evaporator, with using from the high temperature The heat of the liquid of liquid outlet outflow is generated electricity, also, low-temperature receiver outlet is connected with the high-temp liquid entrance of the heat pump, is led to Cross the thermal source inlet and flow into after the fluid temperature reduction of the first TRT 200 and can flow into described the from low-temperature receiver outlet One condenser.
Residual neat recovering system provided by the present invention is mainly used in reclaiming the heat in recirculated water.Circulation fluid is from cooling device After middle outflow, temperature is raised, therefore carries more heat.The recirculated water with higher heat passes through cryogenic liquid inlet Into the first evaporator of heat pump 100.The liquid of 100 pairs of evaporators of entrance first of heat pump heats up, the liquid after intensification from In the high-temp liquid output flow of the first evaporator to the first TRT 200, the first TRT 200 is using high-temp liquid Heat is generated electricity.Temperature is reduced after heat in high-temp liquid is used to generate electricity, and becomes cryogenic liquid.The cryogenic liquid can be used Make low-temperature receiver liquid.By low-temperature receiver liquid by the way that after the first condenser that low-temperature receiver entrance is passed through heat pump, the temperature of low-temperature receiver liquid is entered one Step is reduced, and exports outflow from the cryogenic liquid of first condenser.
The low-temperature receiver outlet of the first condenser is connected with the liquid inlet of cooling device, using the cryogenic liquid from the first condenser The cryogenic liquid of outflow is cooled down to the device for needing cooling.
It follows that residual neat recovering system provided by the present invention can not only utilize the temperature flowed out from cooling device Heat in recirculated water higher is generated electricity, additionally it is possible to which the liquid of temperature reduction is re-used as low-temperature receiver by the use of after generating electricity The cooling medium of cooling device.Technique electricity consumption is can serve as using the waste heat electricity of recirculated water, so as in a disguised form reduce whole The energy consumption of technique.
It is readily seen, the residual neat recovering system belongs to a circulatory system for closing, in temperature liquid higher Heat for generating cause its temperature reduction after, be still used as the cooling medium in cooling device, therefore, using the present invention The residual neat recovering system for being provided can also reduce the waste of circulation fluid.
Residual neat recovering system provided by the present invention is preferred for coking field.Specifically, coking system includes primary cooler 300, the cryogenic liquid inlet of heat pump 100 and the outlet of primary cooler 300, the cryogenic liquid outlet of heat pump 100 and primary cooler 300 entrance connection.
Additionally, in coking field, the height of primary cooler 300 is about 30 meters, and heat pump is arranged on the bottom of primary cooler 300. The liquid of the outlet outflow of primary cooler 300 flows to heat pump 100 from 30 meters of height, when liquid reaches the first cryogenic liquid inlet When, kinetic energy higher is already had, such that it is able to be used as the partial power that liquid is circulated in whole residual neat recovering system, from And the power in residual neat recovering system required for fluid circulation can be reduced, reduce further energy consumption.
The water flowed out from the primary cooler 300 of coking system still has temperature (about 43 DEG C) higher, also, just cold The water flowed out in device 300 is also very big, and heat therein is considerable.Returned using residual neat recovering system provided by the present invention After receiving wherein heat, the heat of the recovery can be used to generate electricity, and for plant area powers, such that it is able to largely reduce coking The overall energy consumption of factory.
In the present invention, the concrete form to heat pump 100 does not do special restriction, for example, heat pump 100 can be compression Formula heat pump, or absorption heat pump, can also be jet type heat pump.
In Fig. 1 in shown specific embodiment, heat pump 100 is absorption heat pump.The heat source of absorption heat pump Can be cyclic ammonia water, steam or combustion gas.
As mentioned above it is possible, the residual neat recovering system is mainly used in coking system, and commonly used in coking process 0.4MPa to 0.6MPa, temperature are 150 DEG C of low-pressure saturated steam, therefore, for energy saving, heat pump 100 can be using steaming Vapour is used as heat source.Correspondingly, heat pump 100 include heating steam inlet and condensation-water drain, the heating steam inlet with The condensation-water drain connection.Heating steam inlet is connected with vapour source 900, for being passed through the steam as heat source.Steam After vapour enters heat pump 100, heat is absorbed, temperature reduction, condenses into liquid, from condensation-water drain outflow.
Preferably, the residual neat recovering system also includes condensate tank 600, and the condensate tank 600 goes out with the condensed water Mouth is connected, and condensate tank 600 is connected with the cryogenic liquid inlet of heat pump.The water of steam condensation can serve as waste heat recovery The circulating cooling make-up water of system, further saves water source.
As mentioned above it is possible, in order to ensure the condensed water of heating vapour-condensing knot can successfully flow to heat pump 100 Cryogenic liquid inlet, it is preferable that the residual neat recovering system also include condensed water small pump 700, the condensed water small pump 700 Entrance connected with condensate tank 600, the outlet of condensed water small pump 700 is connected with the first high-temp liquid entrance of heat pump 100.
Condensed water small pump 700 can provide power for the liquid circulation between heat pump 100 and condensate tank 600.
In the present invention, the concrete structure to the first TRT 200 does not have special restriction, it is preferable that the first hair Electric installation 200 includes the second evaporator 220, the second condenser 230, the first turbine 210 and the first generator 250.The heat Source inlet includes the first thermal source inlet, and the low-temperature receiver outlet includes that the first low-temperature receiver is exported.
Second evaporator 220 includes the outlet of the first generating working medium and the first generating working medium entrance, and the second evaporator 220 is used for Receiving flows into the generating working medium in second evaporator 220 by the first generating working medium entrance.First thermal source inlet It is respectively formed on the second evaporator 220 with first low-temperature receiver outlet, and the first thermal source inlet and the first low-temperature receiver outlet, with profit The generating working medium is heated with the liquid for flowing into by first thermal source inlet the second evaporator, and by described the The liquid that one thermal source inlet flows into the second evaporator 220 can export outflow by first low-temperature receiver.The first generating work Matter outlet is connected with the air intake of the first turbine 210, and first turbine 210 is used to drive the first generator 250 to generate electricity.
Specifically, the high-temp liquid for being flowed out from heat pump 100 is heated to the generating working medium in the second evaporator 220, So that generating working medium is vaporized, and in the first turbine of inflow, promote the rotation of the first turbine.First turbine 210 drives first Generator 250 rotates so that the first generator 250 can generate electricity.
In the present invention, the concrete structure to the first turbine 210 does not do particular determination, for example, the first turbine 210 can Being any one in steam turbine, screw expansion agent and radial-inward turbine.
Second condenser 230 includes the second generating working medium entrance for interconnecting and the outlet of the second generating working medium, described the Two generating working medium entrances are connected with the venthole of the first turbine 210, are entered with to the generating working medium flowed out from the first turbine Row cooling is condensed, and obtains the generating working medium of liquid, and the generating working medium of the liquid can be exported by second generating working medium Flow out second condenser and reach the first generating working medium entrance of the second evaporator 220.
The first TRT used in residual neat recovering system system shown in Fig. 1 is organic Rankine TRT (ORC, Organic Rankine Cycle Power Generation).When high-temp liquid is flowed into the second evaporator 220, Heat in high-temp liquid is absorbed by the generating working medium in the second evaporator 220 so that generating working medium is vaporized.Gaseous generating work Matter enters the first turbine 210, promotes the first turbine 210 to rotate, and drives the first generator 250 to generate electricity.
In order to save generating working medium, it is preferable that generating working medium is could be arranged in the first TRT 200 described first Closed cycle is carried out in TRT.That is, the generating working medium flowed out from the first turbine 210 can loop back the second evaporator 220。
Preferably, the first TRT 200 can also include preheater 240 and working medium pump 260.
Preheater 240 includes the 3rd generating working medium entrance for interconnecting and the outlet of the 3rd generating working medium, the 3rd hair Electric working medium entrances and the second generating working medium outlet, the 3rd generating working medium outlet enter with first generating working medium Mouth connection.Preheater 240 is pre- for being carried out to the generating working medium for flowing into the preheater 240 by the 3rd generating working medium entrance Heat.The preheated device 240 of generating working medium flows into the second evaporator 220 after preheating, so that into the second evaporator 220 Generating working medium has had certain temperature, so can cause that generating working medium is vaporized more thoroughly, improve generating efficiency.
Second generating working medium outlet described in the entrance of working medium pump 260, the outlet of working medium pump 260 generates electricity with the described 3rd Working medium entrances are connected.Working medium pump 260 is used to realize that the generating working medium is evaporated in the preheater 240, second of the first TRT Circulated between device 220, the second condenser 230.
As mentioned above it is possible, preheater 240 is used to heat generating working medium.Therefore, in the present invention, to preheater How 240 heat the generating working medium does not have special restriction.For example, the high-temp liquid that obtained in heat pump 100 can be drawn Enter preheater 240, so as to be heated to the generating working medium.Specifically, the thermal source inlet includes Secondary Heat Source entrance institute Stating low-temperature receiver outlet includes that the second low-temperature receiver is exported, and the Secondary Heat Source entrance and second low-temperature receiver outlet are both formed in preheater On 240.The high-temp liquid outlet of the Secondary Heat Source entrance and first evaporator, the second low-temperature receiver outlet and institute The high-temp liquid entrance connection of the first evaporator is stated, the liquid for flowing into preheater 240 by the Secondary Heat Source entrance can lead to Cross the second low-temperature receiver outlet outflow.
The high-temp liquid obtained in heat pump 100 is incorporated into preheater 240 by Secondary Heat Source entrance, it should be pointed out that It is that generating working medium does not mix mutually with the high-temp liquid being introduced into preheater 240.That is, Secondary Heat Source entrance and the 3rd hair Do not connected mutually between electric working medium entrances.
After high-temp liquid flows through preheater 240, the generating working medium that heat is preheated in device absorbs, temperature reduction, from second Low-temperature receiver outlet outflow, and heat pump 100 is flowed into by the first low-temperature receiver entrance, after lowering the temperature through the first condenser in heat pump 100, can be with Used as the coolant of cooling-cycle device.
In order to ensure the fluid in residual neat recovering system provided by the present invention being capable of smooth circulation, it is preferable that described remaining Heat recovery system also includes system circulation pump 800, the entrance of the system circulation pump 800 and the cryogenic liquid outlet.
As mentioned above it is possible, when the residual neat recovering system is used for coking system, cooling-cycle device is primary cooler 300, because the height of primary cooler 300 is 30m, therefore, system circulation pump 800 provides less power and can ensure that liquid described It is circulated in residual neat recovering system.
In order to further reduce the energy consumption of coking system, the waste heat of coking system is recycled, it is preferable that the waste heat Recovery system also includes the second TRT 500, and second TRT includes the second turbine 510, the and of the second generator 530 3rd condenser 520.3rd condenser 520 includes steam inlet, coolant inlet and cooling liquid outlet, the steam inlet with The cryogenic liquid outlet of the venthole connection of the second turbine 510, the coolant inlet and heat pump 100, the cooling Liquid outlet is connected with the cryogenic liquid inlet of heat pump 100.
In the present invention, the second TRT 500 is CDQ TRTs, for reclaiming the waste heat in dry quenching system. In the present invention, the cryogenic liquid produced using heat pump 100 is cooled down to the 3rd condenser 520, can be by the 3rd condenser The condensate obtained in 520 is added in primary cooler.Also, the elevated liquid of temperature after being cooled down to the 3rd condenser 520 Body can be flowed into heat pump 100, carry out cogeneration.
Similarly, in the present invention, the concrete structure to the second turbine 510 does not do special restriction yet, for example, second Turbine 510 can be any one in steam turbine, screw expansion agent and radial-inward turbine.
As another aspect of the present invention, there is provided a kind of coking system, as shown in figure 1, the coking system is including just cold Device 300, wherein, the coking system also includes residual neat recovering system, and the residual neat recovering system is on provided by the present invention Residual neat recovering system is stated, the cryogenic liquid inlet of heat pump 100 is connected with the liquid outlet of primary cooler 300, the cryogenic liquid of heat pump 100 Outlet is connected with the liquid inlet of primary cooler 300.
As mentioned above it is possible, residual neat recovering system provided by the present invention can not only utilize what is flowed out from cooling device Heat in temperature recirculated water higher is generated electricity, additionally it is possible to by the use of after generating electricity the liquid of temperature reduction as low-temperature receiver, again Cooling medium as cooling device.Technique electricity consumption is can serve as using the waste heat electricity of recirculated water, so as in a disguised form reduce The energy consumption of whole technique.
It is readily seen, the residual neat recovering system belongs to a circulatory system for closing, in temperature liquid higher Heat for generating cause its temperature reduction after, be still used as the cooling medium in cooling device, therefore, using the present invention The residual neat recovering system for being provided can also reduce the waste of circulation fluid.
As mentioned above it is possible, in order to promote the liquid circulation in coking system, it is preferable that the residual neat recovering system can be with Including system circulation pump 800, in this embodiment, the cryogenic liquid outlet of heat pump 100 by system circulation pump 800 with it is first The liquid inlet connection of cooler.Specifically, the cryogenic liquid outlet of heat pump 100 is connected with the entrance of system circulation pump 800, and system is followed The outlet of ring pump 800 is connected with the liquid inlet of primary cooler.
Except primary cooler 300, coking system also includes other recirculated cooling water devices.
Preferably, the coking system also includes refrigeration plant 1000, the outlet of the refrigeration plant 1000 and the low temperature of heat pump 100 Liquid inlet connection, the entrance of refrigeration plant 100 and the cryogenic liquid outlet of heat pump 100.In coking system, refrigeration plant 1000 are cooled down for Hua Chan workshop sections.In the present invention, the cryogenic liquid for being produced using heat pump 100 can be entered to Hua Chan workshop sections Row cooling, reduces the setting of cooling device, reduces cost.
Preferably, the coking system also includes final cooling tower 400, the liquid inlet of the final cooling tower 400 and the low temperature of heat pump 100 Liquid outlet is connected, and the liquid outlet of final cooling tower 400 is connected with the cryogenic liquid inlet of heat pump 100.Similarly, produced using heat pump Cryogenic liquid be also used as the coolant of final cooling tower 400.
As a example by producing the coking system of dry complete 1,400,000 t/a of Jiao per year, primary cooler 300, final cooling tower 400, refrigeration plant 1000, with And the 3rd condenser 520 be about 43 DEG C to the liquid that heat pump 100 is provided, therefore, using waste heat recovery system provided by the present invention System can reclaim about 8300 × 104The heat of kcal/h is used for heat supply or generating.Meanwhile, the cryogenic liquid of heat pump 100 outlet stream The cryogenic liquid temperature for going out is about 32 DEG C, can serve as primary cooler 300, final cooling tower 400, the condenser of refrigeration plant 1000 and the 3rd 520 cooling source.It follows that exhaust heat recovery power generation is carried out using above-mentioned residual neat recovering system provided by the present invention, not only Existingization can be cancelled and produce recirculating cooling water system, kind of refrigeration cycle cooling water system, power generation cycle cooling water system, additionally it is possible to Save about 240m3The supplement water of/h.For coking system, the energy saving of high degree reduces cost.
It is understood that the embodiment of above principle being intended to be merely illustrative of the present and the exemplary implementation for using Mode, but the invention is not limited in this.For those skilled in the art, essence of the invention is not being departed from In the case of god and essence, various changes and modifications can be made therein, and these variations and modifications are also considered as protection scope of the present invention.

Claims (12)

1. a kind of residual neat recovering system, it is characterised in that the residual neat recovering system includes heat pump and the first TRT, the heat Pump includes the first evaporator and the first condenser, and first evaporator includes that cryogenic liquid inlet and high-temp liquid are exported, institute State the first condenser to be exported including high-temp liquid entrance and cryogenic liquid, first TRT includes thermal source inlet and low-temperature receiver Outlet, the thermal source inlet and corresponding low-temperature receiver outlet, the thermal source inlet of first TRT steam with described first The high-temp liquid outlet of device is sent out, is generated electricity with the heat using the liquid from high-temp liquid outlet outflow, also, it is described Low-temperature receiver outlet is connected with the high-temp liquid entrance of the heat pump, and the liquid of first TRT is flowed into by the thermal source inlet First condenser can be flowed into after temperature reduction from low-temperature receiver outlet.
2. residual neat recovering system according to claim 1, it is characterised in that the heat pump includes heating steam inlet and cold Solidifying water out, the heating steam inlet is connected with the condensation-water drain, and the heating steam inlet is used to be passed through for adding The steam of heat, the steam condensation into after liquid from condensation-water drain outflow.
3. residual neat recovering system according to claim 2, it is characterised in that the residual neat recovering system also includes condensate Case, the condensate tank is connected with the condensation-water drain, and the condensate tank connects with the cryogenic liquid inlet of the heat pump It is logical.
4. residual neat recovering system according to claim 3, it is characterised in that the residual neat recovering system also includes condensed water Small pump, the entrance of the condensed water small pump is connected with the condensate tank, the outlet of the condensed water small pump with it is described The cryogenic liquid inlet connection of heat pump.
5. residual neat recovering system as claimed in any of claims 1 to 4, it is characterised in that described first generates electricity dress Put including the second evaporator, the second condenser, the first turbine and the first generator, the thermal source inlet enters including the first thermal source Mouthful, the low-temperature receiver outlet includes that the first low-temperature receiver is exported,
Second evaporator also includes the outlet of the first generating working medium and the first generating working medium entrance, and second evaporator is used for Accommodate the generating working medium flowed into by the first generating working medium entrance in second evaporator, first thermal source inlet with The first low-temperature receiver outlet is respectively formed on first evaporator, and first thermal source inlet is exported with first low-temperature receiver and connected It is logical, the generating working medium is heated with using the liquid by first thermal source inlet inflow second evaporator, And outflow, institute can be exported by first low-temperature receiver by the liquid that first thermal source inlet flows into second evaporator The outlet of the first generating working medium is stated to be connected with the air intake of first turbine;
First turbine is used to drive the electrical power generators;
Second condenser includes the second generating working medium entrance for interconnecting and the outlet of the second generating working medium, second hair Electric working medium entrances are connected with the venthole of first turbine, are entered with to the generating working medium flowed out from first turbine Row cooling is condensed, and obtains the generating working medium of liquid, and the generating working medium of the liquid can be exported by second generating working medium Flow out second condenser and reach the first generating working medium entrance of second evaporator.
6. residual neat recovering system according to claim 5, it is characterised in that first TRT also includes preheater And working medium pump,
The preheater includes the 3rd generating working medium entrance for interconnecting and the outlet of the 3rd generating working medium, the 3rd generating work Matter entrance and the second generating working medium outlet, the 3rd generating working medium outlet connect with the first generating working medium entrance Logical, the preheater is used to preheat the generating working medium for flowing into the preheater by the 3rd generating working medium entrance;
The entrance of the working medium pump and the second generating working medium outlet, the outlet of the working medium pump generate electricity with the described 3rd Working medium entrances are connected.
7. residual neat recovering system according to claim 6, it is characterised in that the thermal source inlet enters including Secondary Heat Source Mouthful, the low-temperature receiver outlet includes that the second low-temperature receiver is exported, and the Secondary Heat Source entrance and second low-temperature receiver outlet are both formed in institute State on preheater, and the Secondary Heat Source entrance and the second low-temperature receiver outlet, the Secondary Heat Source entrance and described The high-temp liquid outlet of one evaporator, the second low-temperature receiver outlet connects with the high-temp liquid entrance of first evaporator Logical, the liquid for flowing into the preheater by the Secondary Heat Source entrance can be exported by second low-temperature receiver and flowed out.
8. residual neat recovering system as claimed in any of claims 1 to 4, it is characterised in that the waste heat recovery system System also includes system circulation pump, the entrance of the system circulation pump and the cryogenic liquid outlet.
9. residual neat recovering system as claimed in any of claims 1 to 4, it is characterised in that the waste heat recovery system System also includes the second TRT, and second TRT includes the second turbine, the second generator and the 3rd condenser, institute Stating the 3rd condenser includes steam inlet, coolant inlet and cooling liquid outlet, the steam inlet and second turbine Venthole connection, the cryogenic liquid outlet of the coolant inlet and the heat pump, the cooling liquid outlet with it is described The cryogenic liquid inlet connection of heat pump.
10. a kind of coking system, the coking system includes primary cooler, it is characterised in that the coking system also includes waste heat Recovery system, residual neat recovering system of the residual neat recovering system described in any one in claim 1 to 9, the heat pump Cryogenic liquid inlet connected with the liquid outlet of the primary cooler, the outlet of the cryogenic liquid of the heat pump and the primary cooler enter Liquid mouthful connection.
11. coking systems according to claim 10, it is characterised in that the coking system also includes refrigeration plant, described The outlet of refrigeration plant is connected with the cryogenic liquid inlet of the heat pump, the cryogenic liquid of the entrance of the refrigeration plant and the heat pump Outlet.
12. coking system according to claim 10 or 11, it is characterised in that the coking system also includes final cooling tower, The cryogenic liquid outlet of the liquid inlet of the final cooling tower and the heat pump, the liquid outlet of the final cooling tower and the heat pump Cryogenic liquid inlet is connected.
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CN110439638A (en) * 2019-08-01 2019-11-12 天津裕嘉源环保科技有限公司 Process system and method for producing low-pressure saturated steam by upgrading industrial wastewater
CN117128636A (en) * 2023-08-16 2023-11-28 江苏鼎视能源科技有限公司 Heat energy recovery device of air conditioner water cooling unit capable of partially recovering heat

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CN205370873U (en) * 2015-12-17 2016-07-06 广东五星太阳能股份有限公司 Formula of directly expanding solar thermal power generation system based on overlapping rankine cycle
CN206469540U (en) * 2017-01-24 2017-09-05 北京华泰焦化工程技术有限公司 Coking system and its residual neat recovering system

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US20040237527A1 (en) * 2003-02-18 2004-12-02 Yasuyoshi Kato Exhaust heat recovery system
CN201125751Y (en) * 2007-10-24 2008-10-01 陈深佃 Power generation system using low temperature heat power supply or environment heat power supply to generate power
CN101613115A (en) * 2009-07-29 2009-12-30 马鞍山钢铁股份有限公司 A kind of application of condensed fluid of gas in final cooling process in coke oven gas purification unit
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110439638A (en) * 2019-08-01 2019-11-12 天津裕嘉源环保科技有限公司 Process system and method for producing low-pressure saturated steam by upgrading industrial wastewater
CN110439638B (en) * 2019-08-01 2022-05-13 天津裕嘉源环保科技有限公司 Process system and method for producing low-pressure saturated steam by improving quality of industrial wastewater
CN117128636A (en) * 2023-08-16 2023-11-28 江苏鼎视能源科技有限公司 Heat energy recovery device of air conditioner water cooling unit capable of partially recovering heat

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