CN106758540A - A kind of cigarette print silver foil and preparation method thereof - Google Patents
A kind of cigarette print silver foil and preparation method thereof Download PDFInfo
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- CN106758540A CN106758540A CN201611050469.1A CN201611050469A CN106758540A CN 106758540 A CN106758540 A CN 106758540A CN 201611050469 A CN201611050469 A CN 201611050469A CN 106758540 A CN106758540 A CN 106758540A
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- Prior art keywords
- coating
- cigarette
- silver paste
- art post
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of cigarette print silver foil and preparation method thereof, including art post paperboard and one layer of aluminium film, art post paperboard are used as background color by the floor height optical coating of flexographic printing one for the first time on three color flexible printing machines；Pass through flexographic printing bottom minute surface silver paste coating second, for the third time by flexographic printing surface layer minute surface silver paste coating, art post paperboard is whole wood pulp fiber, the surface roughness PPS methods of art post paperboard（um）≤ 1.5,150~300g/m of unit area paper grammes per square metre2；It is 0.1~0.12g/m with aluminum amount2, it is silver color.The beneficial effect of this product is, 1, with more environmental protection, product is degradable；2nd, because cigarette is few with print silver foil product processes operation, 3 road production processes are reduced compared to cigarette transfer aluminium foil paperboard, reduces power consumption, reduce hot gas and waste gas discharge；3rd, production cost is reduced, is that company creates benefit.
Description
Technical field
This product is related to Cigarette paper production industry, i.e., a kind of cigarette print silver foil and preparation method thereof, and the paperboard can be replaced
For traditional cigarette transfer aluminium foil paperboard, the product is degradable novel green packaging material, and its production method has reduction
Resource consumption and air pollution（Including waste heat discharge）The characteristics of.
Background technology
At present in Cigarette paper production industry, a large amount of production cigarettes are with aluminium foil paperboard, its production technology is shifted：Mute silver turns
Move film to be combined with art post paperboard after being coated with transfer adhesive, formed by shifting stripping technology, the product processes link
Many and consumption ample resources and raw material, while in product process, giving off hot gas and waste gas, there is certain dirt to environment
Dye.
The content of the invention
In order to improve environment, reduce consumption, the present invention proposes that a kind of cigarette print silver foil of transfer aluminium foil paperboard can be substituted
And preparation method thereof.
This cigarette print silver foil, it is characterised in that including art post paperboard and one layer of aluminium film, art post paperboard is in three color flexographic printings
On machine, background color is used as by the floor height optical coating of flexographic printing one for the first time；Applied by flexographic printing bottom minute surface silver paste for second
Material, for the third time by flexographic printing surface layer minute surface silver paste coating, art post paperboard is whole wood pulp fiber, and the surface roughness of art post paperboard is used
PPS methods（um）≤ 1.5,150~300g/m of unit area paper grammes per square metre2；It is 0.1~0.12g/ m with aluminum amount2, it is silver color.
Preparation method of this cigarette with silver foil is printed, it is characterised in that step is as follows：
First, with three color flexible printing machines, soft version is coated with a floor height optical coating, drying in art post paperboard；
2nd, with three color flexible printing machines, the soft version barrier coating minute surface silver paste coating in highlight coating,
Drying；
3rd, with three color flexible printing machines, the soft version coating surface layer mirror-like silver paste paint on minute surface silver paste bottom,
Drying；
4th, cool down, wind, be finished product.
The components by weight percent of the high-gloss paint in the step one is：
The Styrene-acrylic copolymer 60-80 of A, nano-scale particle,
B, polyvinyl butyral resin 20-40,
C, organobentonite 5-6,
D, thickener are the acrylic compounds 0.1-0.2 of hydrophobically-modified alkali swelling type, and defoamer is type siloxane 0.1-0.2, levelling
Agent is dimethyl silicone polymer 0.1-0.2.
E, water 200-220, by the internal reactor for 240-260 degrees Celsius of above-mentioned 5 kinds of raw material input, mix, and return
Stream stirring 11-12 hours, is made high-gloss paint；
Bottom minute surface silver paste coating in the step 2, is added after being modified in the high-gloss paint in step one
The weight ratio of aluminium powder, high-gloss paint and modified aluminium powder is 1：0.2-0.3.
Surface layer minute surface silver paste coating in the step 3, be add in the high-gloss paint in step one by it is modified with
The weight ratio of aluminium powder afterwards, high-gloss paint and modified aluminium powder is 1：0.4-0.6.
The preparation method of modified aluminium powder, comprises the following steps：
One, following each components are weighed by mass percentage,
A, aluminium powder, its grain graininess are 3-5 μm；
B, according to aluminium powder and ethyl acetate weight ratio for 3: 5 ratio weighs ethyl acetate,
The ethyl acetate that will be weighed is added in aluminium powder, uses magnetic stirrer 2-3h, is filtered after standing 2-3h, at 40-60 DEG C
2-3h is dried, pretreated aluminium powder is obtained；
2nd, A, add in reaction vessel the sodium carbonate liquor of appropriate 0.5-1% concentration, by weight, add 4-6 part to gather
Dimethyl diallyl ammonium chloride, 500-600r/min stirrings 5-15min；
B, above-mentioned pretreated aluminium powder 50-60 parts is added, 5-10min is stirred under same rotating speed, filtered simultaneously by filter cake suitable
Ultrasonic wave dispersion in the sodium carbonate liquor of 0.5-1% concentration is measured, 6-8 parts of carboxymethylcellulose calcium, 500-600r/min stirrings is added
5-10min,
C, pyrophyllite in powder 1-2 parts, illite powder 1-2 parts and kayexalate 0.1-0.2 parts is added, stirred under same rotating speed
10-20min is mixed, filter cake is filtered to obtain；
3rd, add in a reservoir it is above-mentioned in the filter cake and sodium tripolyphosphate 0.5-1 parts, lauric acid amide of ethanol 0.1- that obtain
0.2 part, gelatin 0.1-0.2 parts, sodium-based montmorillonite 0.1-0.2 parts, in 400-600r/min stirrings 15-30min under room temperature condition
After be vacuum dried, obtain final product.
The beneficial effect of this product is, 1, with more environmental protection, product is degradable；2nd, because cigarette is given birth to print silver card paper product
Production. art operation is few, and 3 road production processes are reduced compared to cigarette transfer aluminium foil paperboard, reduces power consumption, reduces hot gas
And waste gas discharge；3rd, production cost is reduced, is that company creates benefit.
Specific embodiment
This new product is described in detail below by the specific embodiment of the invention.
This cigarette print silver foil, it is characterised in that including art post paperboard and one layer of aluminium film, art post paperboard is in three color flexographic printings
On machine, background color is used as by the floor height optical coating of flexographic printing one for the first time；Applied by flexographic printing bottom minute surface silver paste for second
Material, for the third time by flexographic printing surface layer minute surface silver paste coating, art post paperboard is whole wood pulp fiber, and the surface roughness of art post paperboard is used
PPS methods（um）≤ 1.5, unit area paper grammes per square metre 250g/m2；It is 0.11g/ m with aluminum amount2, it is silver color.
Preparation method of this cigarette with silver foil is printed, it is characterised in that step is as follows：
First, with three color flexible printing machines, soft version is coated with a floor height optical coating, drying in art post paperboard；
2nd, with three color flexible printing machines, the soft version barrier coating minute surface silver paste coating in highlight coating,
Drying；
3rd, with three color flexible printing machines, the soft version coating surface layer mirror-like silver paste paint on minute surface silver paste bottom,
Drying；
4th, cool down, wind, be finished product.
The components by weight percent of the high-gloss paint in the step one is：
The Styrene-acrylic copolymer 70 of A, nano-scale particle,
B, polyvinyl butyral resin 30,
C, organobentonite 5.5,
D, thickener are the acrylic compounds 0.15 of hydrophobically-modified alkali swelling type, and defoamer is type siloxane 0.15, and levelling agent is poly-
Dimethyl siloxane 0.15.
E, water 210, by the internal reactor for 250 degrees Celsius of above-mentioned 5 kinds of raw material input, mix, and are refluxed 11-
12 hours, it is made high-gloss paint；
Bottom minute surface silver paste coating in the step 2, is added after being modified in the high-gloss paint in step one
The weight ratio of aluminium powder, high-gloss paint and modified aluminium powder is 1：0.25.
Surface layer minute surface silver paste coating in the step 3, be add in the high-gloss paint in step one by it is modified with
The weight ratio of aluminium powder afterwards, high-gloss paint and modified aluminium powder is 1：0.5.
The preparation method of modified aluminium powder, comprises the following steps：
One, following each components are weighed by mass percentage,
A, aluminium powder, its grain graininess are 5 μm；
B, according to aluminium powder and ethyl acetate weight ratio for 3: 5 ratio weighs ethyl acetate,
The ethyl acetate that will be weighed is added in aluminium powder, uses magnetic stirrer 2-3h, is filtered after standing 2-3h, dry at 50 DEG C
Dry 2-3h, obtains pretreated aluminium powder；
2nd, A, add in reaction vessel the sodium carbonate liquor of appropriate 0.5-1% concentration, by weight, add poly- the two of 5 parts
Methyl diallyl ammonium chloride, 500-600r/min stirrings 5-15min；
B, above-mentioned 55 parts pretreated of aluminium powder is added, 5-10min is stirred under same rotating speed, filtered and by filter cake appropriate
Ultrasonic wave dispersion in the sodium carbonate liquor of 0.5-1% concentration, adds 7 parts of carboxymethylcellulose calcium, 500-600r/min stirrings 5-
10min,
C, 0.15 part of 1.5 parts of pyrophyllite in powder, 1.5 parts of illite powder and kayexalate are added, stirred under same rotating speed
10-20min, filters to obtain filter cake；
3rd, add in a reservoir it is above-mentioned in the filter cake and 0.8 part of sodium tripolyphosphate, lauric acid amide of ethanol 0.15 that obtain
Part, 0.15 part of gelatin, 0.15 part of sodium-based montmorillonite, do in vacuum after 400-600r/min stirrings 15-30min under room temperature condition
It is dry, obtain final product.
It is 75 that the present embodiment is obtained cigarette print silver foil silver paste print gloss, and its print gloss is used higher than traditional cigarette
1 degree of the glossiness of aluminium foil paperboard is shifted, can be replaced completely.
Claims (6)
1. a kind of cigarette is used and prints silver foil, it is characterised in that including art post paperboard and one layer of aluminium film, art post paperboard is in three color flexographic printings
On machine, background color is used as by the floor height optical coating of flexographic printing one for the first time；Applied by flexographic printing bottom minute surface silver paste for second
Material, for the third time by flexographic printing surface layer minute surface silver paste coating, art post paperboard is whole wood pulp fiber, and the surface roughness of art post paperboard is used
PPS methods（um）≤ 1.5,150~300g/m of unit area paper grammes per square metre2；It is 0.1~0.12g/ m with aluminum amount2, it is silver color.
2. the preparation method that a kind of cigarette uses print silver foil, it is characterised in that step is as follows：
First, with three color flexible printing machines, soft version is coated with a floor height optical coating, drying in art post paperboard；
2nd, with three color flexible printing machines, the soft version barrier coating minute surface silver paste coating in highlight coating,
Drying；
3rd, with three color flexible printing machines, the soft version coating surface layer mirror-like silver paste paint on minute surface silver paste bottom,
Drying；
4th, cool down, wind, be finished product.
3. the preparation method that a kind of cigarette according to claim 2 uses print silver foil, it is characterised in that the bloom in step one
The components by weight percent of coating is：
The Styrene-acrylic copolymer 60-80 of A, nano-scale particle,
B, polyvinyl butyral resin 20-40,
C, organobentonite 5-6,
D, thickener are the acrylic compounds 0.1-0.2 of hydrophobically-modified alkali swelling type, and defoamer is type siloxane 0.1-0.2, levelling
Agent is dimethyl silicone polymer 0.1-0.2,
E, water 200-220, by the internal reactor for 240-260 degrees Celsius of above-mentioned 5 kinds of raw material input, are mixed, and backflow is stirred
Mix 11-12 hours, be made high-gloss paint.
4. the preparation method that a kind of cigarette according to claim 2 uses print silver foil, it is characterised in that the bottom in step 2
Minute surface silver paste coating, is aluminium powder of the addition after being modified, high-gloss paint and modified aluminium in the high-gloss paint in step one
The weight ratio of powder is 1：0.2-0.3.
5. the preparation method that a kind of cigarette according to claim 2 uses print silver foil, it is characterised in that the surface layer in step 3
Minute surface silver paste coating, is aluminium powder of the addition after being modified, high-gloss paint and modified aluminium in the high-gloss paint in step one
The weight ratio of powder is 1：0.4-0.6.
6. the preparation method that a kind of cigarette according to claim 2 uses print silver foil, it is characterised in that the preparation of modified aluminium powder
Method, comprises the following steps：
One, following each components are weighed by mass percentage,
A, aluminium powder, its grain graininess are 3-5 μm；
B, according to aluminium powder and ethyl acetate weight ratio for 3: 5 ratio weighs ethyl acetate,
The ethyl acetate that will be weighed is added in aluminium powder, uses magnetic stirrer 2-3h, is filtered after standing 2-3h, at 40-60 DEG C
2-3h is dried, pretreated aluminium powder is obtained；
2nd, A, add in reaction vessel the sodium carbonate liquor of appropriate 0.5-1% concentration, by weight, add 4-6 part to gather
Dimethyl diallyl ammonium chloride, 500-600r/min stirrings 5-15min；
B, above-mentioned pretreated aluminium powder 50-60 parts is added, 5-10min is stirred under same rotating speed, filtered simultaneously by filter cake suitable
Ultrasonic wave dispersion in the sodium carbonate liquor of 0.5-1% concentration is measured, 6-8 parts of carboxymethylcellulose calcium, 500-600r/min stirrings is added
5-10min,
C, pyrophyllite in powder 1-2 parts, illite powder 1-2 parts and kayexalate 0.1-0.2 parts is added, stirred under same rotating speed
10-20min is mixed, filter cake is filtered to obtain；
3rd, add in a reservoir it is above-mentioned in the filter cake and sodium tripolyphosphate 0.5-1 parts, lauric acid amide of ethanol 0.1- that obtain
0.2 part, gelatin 0.1-0.2 parts, sodium-based montmorillonite 0.1-0.2 parts, in 400-600r/min stirrings 15-30min under room temperature condition
After be vacuum dried, obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611050469.1A CN106758540B (en) | 2016-11-25 | 2016-11-25 | A kind of cigarette print silver foil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611050469.1A CN106758540B (en) | 2016-11-25 | 2016-11-25 | A kind of cigarette print silver foil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106758540A true CN106758540A (en) | 2017-05-31 |
| CN106758540B CN106758540B (en) | 2018-04-13 |
Family
ID=58910668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611050469.1A Active CN106758540B (en) | 2016-11-25 | 2016-11-25 | A kind of cigarette print silver foil and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112644109A (en) * | 2020-12-11 | 2021-04-13 | 上海美美良虹印刷有限公司 | Preparation method of highlight mirror silver card |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100310883A1 (en) * | 2009-06-03 | 2010-12-09 | Brungardt Clement L | Cationic Wet Strength Resin Modified Pigments In Water-Based Latex Coating Applications |
| CN102605678A (en) * | 2011-12-27 | 2012-07-25 | 常德市芙蓉实业发展有限责任公司 | Printing paperboard for environment-friendly cigarette |
| CN103756409A (en) * | 2014-01-09 | 2014-04-30 | 龙岩市物华环保产品有限公司 | Preparation method of environment-friendly water-based gold and silver printing ink |
| CN103866607A (en) * | 2014-03-25 | 2014-06-18 | 广州慧谷化学有限公司 | High-strength directly aluminizing water-based base coat and preparation method and application of high-strength directly aluminizing water-based base coat |
| CN104403407A (en) * | 2014-12-09 | 2015-03-11 | 武汉虹之彩包装印刷有限公司 | Silver ink with good metal printing effect and printing process using silver ink |
-
2016
- 2016-11-25 CN CN201611050469.1A patent/CN106758540B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100310883A1 (en) * | 2009-06-03 | 2010-12-09 | Brungardt Clement L | Cationic Wet Strength Resin Modified Pigments In Water-Based Latex Coating Applications |
| CN102605678A (en) * | 2011-12-27 | 2012-07-25 | 常德市芙蓉实业发展有限责任公司 | Printing paperboard for environment-friendly cigarette |
| CN103756409A (en) * | 2014-01-09 | 2014-04-30 | 龙岩市物华环保产品有限公司 | Preparation method of environment-friendly water-based gold and silver printing ink |
| CN103866607A (en) * | 2014-03-25 | 2014-06-18 | 广州慧谷化学有限公司 | High-strength directly aluminizing water-based base coat and preparation method and application of high-strength directly aluminizing water-based base coat |
| CN104403407A (en) * | 2014-12-09 | 2015-03-11 | 武汉虹之彩包装印刷有限公司 | Silver ink with good metal printing effect and printing process using silver ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112644109A (en) * | 2020-12-11 | 2021-04-13 | 上海美美良虹印刷有限公司 | Preparation method of highlight mirror silver card |
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| CN106758540B (en) | 2018-04-13 |
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