CN106756413A - A kind of ceramic-metal composite - Google Patents

A kind of ceramic-metal composite Download PDF

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Publication number
CN106756413A
CN106756413A CN201611056190.4A CN201611056190A CN106756413A CN 106756413 A CN106756413 A CN 106756413A CN 201611056190 A CN201611056190 A CN 201611056190A CN 106756413 A CN106756413 A CN 106756413A
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CN
China
Prior art keywords
parts
ceramic
metal composite
tungsten
iron
Prior art date
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Pending
Application number
CN201611056190.4A
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Chinese (zh)
Inventor
王举
孙益民
芮定文
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ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Original Assignee
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
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Application filed by ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd filed Critical ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority to CN201611056190.4A priority Critical patent/CN106756413A/en
Publication of CN106756413A publication Critical patent/CN106756413A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/12Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0005Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention provides a kind of ceramic-metal composite, and the weight portion of each component is:40 50 parts of alundum (Al2O3), 20 30 parts of aluminium powder, 15 25 parts of copper powder, 10 20 parts of titanium carbide, 10 20 parts of tungsten, 10 20 parts of iron.The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, prepares low cost, and with good heat endurance, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation.

Description

A kind of ceramic-metal composite
Technical field
The present invention relates to technical field of composite materials, and in particular to a kind of ceramic-metal composite.
Background technology
The composite that ceramic-metal composite is made up of one or more ceramic phases and metal phase or alloy.Gold Ceramic phase in category ceramics is oxide or infusible compound with high-melting-point, high rigidity, and metal phase is mainly transition elements (iron, cobalt, nickel, chromium, tungsten, molybdenum etc.) and its alloy.Different according to each composition phase percentage, cermet is divided into and is with ceramics Matrix and with metal be the class of matrix two.Ceramic based ceramic metal mainly has following a few classes:1. oxide base cermet, to aoxidize Aluminium, zirconium oxide, magnesia, beryllium oxide etc. are matrix, are composited with tungsten, chromium or cobalt, rotten with high temperature resistant, anti-chemistry The features such as erosion, good thermal conductivity, high mechanical strength, can be used as the crucible and metal cutting tool of guided missile nozzle insert, smelting metal. 2. carbide-base ceramics.With titanium carbide, carborundum, tungsten carbide etc. as matrix, with the metal such as metallic cobalt, nickel, chromium, tungsten, molybdenum It is composited, the features such as with high rigidity, high-wearing feature, high temperature resistant, for manufacturing cutting tool, high-temperature bearing, sealing ring, picking up Silk die sleeve and turbine blade.3. nitride based ceramic metal.With titanium nitride, boron nitride, silicon nitride and tantalum nitride as matrix, have Superhard, shaking property of heat resistanceheat resistant and good high temperature creep, using less.It is excellent with ceramics that ceramic-metal composite has metal concurrently Point, its density is small, hardness is high, wear-resisting, thermal conductivity is good, will not be because of quenching or shock heating and embrittlement.Cermet both has metal Toughness, high-termal conductivity and good heat endurance, and the characteristic such as the high temperature resistant with ceramics, corrosion-resistant and wear-resistant.Therefore, Ceramic-metal composite can be widely used in the ground such as rocket, guided missile, the shell of supersonic plane, the flame jet of combustion chamber Side.But there is the demand of anti-rapid heat cycle and resistance to high temperature oxidation to material to some field hot-extrusion molds, therefore need to be to existing gold Category ceramic material constituent carries out reasonable disposition.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of ceramic-metal composite, with good thermally-stabilised Property, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation.
To realize object above, the present invention is achieved by the following technical programs:A kind of ceramic-metal composite, respectively The weight portion of component is:Alundum (Al2O3) 40-50 parts, aluminium powder 20-30 parts, copper powder 15-25 parts, titanium carbide 10-20 parts, tungsten 10- 20 parts, iron 10-20 parts.40 parts of the alundum (Al2O3), 20 parts of aluminium powder, 15 parts of copper powder, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron. 50 parts of the alundum (Al2O3), 30 parts of aluminium powder, 25 parts of copper powder, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.The alundum (Al2O3) 45 parts, 25 parts of aluminium powder, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.The preparation method of ceramic-metal composite, first After by above-mentioned component material ball milling, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
Beneficial effect of the present invention:The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, prepares into This is low, with good heat endurance, red hardness and excellent wearability high, but also with excellent anti-rapid heat cycle and anti-height What temperature was aoxidized meets material.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, to this Technical scheme in inventive embodiments is clearly and completely described, it is clear that described embodiment is that a part of the invention is real Example is applied, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation Property work under the premise of the every other embodiment that is obtained, belong to the scope of protection of the invention.
Embodiment 1:
A kind of ceramic-metal composite, the weight portion of each component is:40 parts of the alundum (Al2O3), 20 parts of aluminium powder, copper powder 15 Part, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron.50 parts of the alundum (Al2O3), 30 parts of aluminium powder, 25 parts of copper powder, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.45 parts of the alundum (Al2O3), 25 parts of aluminium powder, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron. The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling after, be fitted into graphite jig, 1200 DEG C- Sintered 30-40 minutes at a temperature of 1600 DEG C.
Embodiment 2:
A kind of ceramic-metal composite, the weight portion of each component is:50 parts of the alundum (Al2O3), 30 parts of aluminium powder, copper powder 25 Part, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling Afterwards, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
Embodiment 3:
A kind of ceramic-metal composite, the weight portion of each component is:45 parts of the alundum (Al2O3), 25 parts of aluminium powder, copper powder 20 Part, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling Afterwards, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, low cost is prepared, with good Heat endurance, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation Material.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating In any this actual relation or order.And, term " including ", "comprising" or its any other variant be intended to Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention has been described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.

Claims (5)

1. a kind of ceramic-metal composite, it is characterised in that:The weight portion of each component is:Alundum (Al2O3) 40-50 parts, aluminium powder 20-30 parts, copper powder 15-25 parts, titanium carbide 10-20 parts, tungsten 10-20 parts, iron 10-20 parts.
2. ceramic-metal composite as claimed in claim 1, it is characterised in that 40 parts of the alundum (Al2O3), aluminium powder 20 Part, 15 parts of copper powder, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron.
3. ceramic-metal composite as claimed in claim 1, it is characterised in that 50 parts of the alundum (Al2O3), aluminium powder 30 Part, 25 parts of copper powder, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.
4. ceramic-metal composite as claimed in claim 1, it is characterised in that 45 parts of the alundum (Al2O3), aluminium powder 25 Part, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.
5. the preparation method of ceramic-metal composite as claimed in claim 1, it is characterised in that first by above-mentioned component material After pellet mill, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
CN201611056190.4A 2016-11-26 2016-11-26 A kind of ceramic-metal composite Pending CN106756413A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611056190.4A CN106756413A (en) 2016-11-26 2016-11-26 A kind of ceramic-metal composite

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CN201611056190.4A CN106756413A (en) 2016-11-26 2016-11-26 A kind of ceramic-metal composite

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107774985A (en) * 2017-10-19 2018-03-09 西安科技大学 A kind of metal composite high-abrasive material
CN109536812A (en) * 2018-11-13 2019-03-29 武汉新科冶金设备制造有限公司 Molten steel outlet reamer ceramet bit material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103418790A (en) * 2012-05-17 2013-12-04 枣阳秦鸿新材料有限公司 Anti-abrasion metal-ceramic composite product and preparation method thereof
CN104178677A (en) * 2014-08-20 2014-12-03 青岛骏泽盛泰智能科技有限公司 Metal ceramic composite material
CN104388718A (en) * 2014-10-22 2015-03-04 苏州莱特复合材料有限公司 Metal ceramic composite material and preparation method thereof
CN104878270A (en) * 2015-05-27 2015-09-02 杨文澍 Metal ceramic composite material
CN106048471A (en) * 2016-07-08 2016-10-26 青岛百千川海洋生态科技有限公司 Metal ceramic material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103418790A (en) * 2012-05-17 2013-12-04 枣阳秦鸿新材料有限公司 Anti-abrasion metal-ceramic composite product and preparation method thereof
CN104178677A (en) * 2014-08-20 2014-12-03 青岛骏泽盛泰智能科技有限公司 Metal ceramic composite material
CN104388718A (en) * 2014-10-22 2015-03-04 苏州莱特复合材料有限公司 Metal ceramic composite material and preparation method thereof
CN104878270A (en) * 2015-05-27 2015-09-02 杨文澍 Metal ceramic composite material
CN106048471A (en) * 2016-07-08 2016-10-26 青岛百千川海洋生态科技有限公司 Metal ceramic material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107774985A (en) * 2017-10-19 2018-03-09 西安科技大学 A kind of metal composite high-abrasive material
CN109536812A (en) * 2018-11-13 2019-03-29 武汉新科冶金设备制造有限公司 Molten steel outlet reamer ceramet bit material and preparation method thereof

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Application publication date: 20170531