CN106756413A - A kind of ceramic-metal composite - Google Patents
A kind of ceramic-metal composite Download PDFInfo
- Publication number
- CN106756413A CN106756413A CN201611056190.4A CN201611056190A CN106756413A CN 106756413 A CN106756413 A CN 106756413A CN 201611056190 A CN201611056190 A CN 201611056190A CN 106756413 A CN106756413 A CN 106756413A
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- ceramic
- metal composite
- tungsten
- iron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/12—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0005—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention provides a kind of ceramic-metal composite, and the weight portion of each component is:40 50 parts of alundum (Al2O3), 20 30 parts of aluminium powder, 15 25 parts of copper powder, 10 20 parts of titanium carbide, 10 20 parts of tungsten, 10 20 parts of iron.The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, prepares low cost, and with good heat endurance, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation.
Description
Technical field
The present invention relates to technical field of composite materials, and in particular to a kind of ceramic-metal composite.
Background technology
The composite that ceramic-metal composite is made up of one or more ceramic phases and metal phase or alloy.Gold
Ceramic phase in category ceramics is oxide or infusible compound with high-melting-point, high rigidity, and metal phase is mainly transition elements
(iron, cobalt, nickel, chromium, tungsten, molybdenum etc.) and its alloy.Different according to each composition phase percentage, cermet is divided into and is with ceramics
Matrix and with metal be the class of matrix two.Ceramic based ceramic metal mainly has following a few classes:1. oxide base cermet, to aoxidize
Aluminium, zirconium oxide, magnesia, beryllium oxide etc. are matrix, are composited with tungsten, chromium or cobalt, rotten with high temperature resistant, anti-chemistry
The features such as erosion, good thermal conductivity, high mechanical strength, can be used as the crucible and metal cutting tool of guided missile nozzle insert, smelting metal.
2. carbide-base ceramics.With titanium carbide, carborundum, tungsten carbide etc. as matrix, with the metal such as metallic cobalt, nickel, chromium, tungsten, molybdenum
It is composited, the features such as with high rigidity, high-wearing feature, high temperature resistant, for manufacturing cutting tool, high-temperature bearing, sealing ring, picking up
Silk die sleeve and turbine blade.3. nitride based ceramic metal.With titanium nitride, boron nitride, silicon nitride and tantalum nitride as matrix, have
Superhard, shaking property of heat resistanceheat resistant and good high temperature creep, using less.It is excellent with ceramics that ceramic-metal composite has metal concurrently
Point, its density is small, hardness is high, wear-resisting, thermal conductivity is good, will not be because of quenching or shock heating and embrittlement.Cermet both has metal
Toughness, high-termal conductivity and good heat endurance, and the characteristic such as the high temperature resistant with ceramics, corrosion-resistant and wear-resistant.Therefore,
Ceramic-metal composite can be widely used in the ground such as rocket, guided missile, the shell of supersonic plane, the flame jet of combustion chamber
Side.But there is the demand of anti-rapid heat cycle and resistance to high temperature oxidation to material to some field hot-extrusion molds, therefore need to be to existing gold
Category ceramic material constituent carries out reasonable disposition.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of ceramic-metal composite, with good thermally-stabilised
Property, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation.
To realize object above, the present invention is achieved by the following technical programs:A kind of ceramic-metal composite, respectively
The weight portion of component is:Alundum (Al2O3) 40-50 parts, aluminium powder 20-30 parts, copper powder 15-25 parts, titanium carbide 10-20 parts, tungsten 10-
20 parts, iron 10-20 parts.40 parts of the alundum (Al2O3), 20 parts of aluminium powder, 15 parts of copper powder, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron.
50 parts of the alundum (Al2O3), 30 parts of aluminium powder, 25 parts of copper powder, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.The alundum (Al2O3)
45 parts, 25 parts of aluminium powder, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.The preparation method of ceramic-metal composite, first
After by above-mentioned component material ball milling, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
Beneficial effect of the present invention:The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, prepares into
This is low, with good heat endurance, red hardness and excellent wearability high, but also with excellent anti-rapid heat cycle and anti-height
What temperature was aoxidized meets material.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, to this
Technical scheme in inventive embodiments is clearly and completely described, it is clear that described embodiment is that a part of the invention is real
Example is applied, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation
Property work under the premise of the every other embodiment that is obtained, belong to the scope of protection of the invention.
Embodiment 1:
A kind of ceramic-metal composite, the weight portion of each component is:40 parts of the alundum (Al2O3), 20 parts of aluminium powder, copper powder 15
Part, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron.50 parts of the alundum (Al2O3), 30 parts of aluminium powder, 25 parts of copper powder, 20 parts of titanium carbide,
20 parts of tungsten, 20 parts of iron.45 parts of the alundum (Al2O3), 25 parts of aluminium powder, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.
The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling after, be fitted into graphite jig, 1200 DEG C-
Sintered 30-40 minutes at a temperature of 1600 DEG C.
Embodiment 2:
A kind of ceramic-metal composite, the weight portion of each component is:50 parts of the alundum (Al2O3), 30 parts of aluminium powder, copper powder 25
Part, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling
Afterwards, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
Embodiment 3:
A kind of ceramic-metal composite, the weight portion of each component is:45 parts of the alundum (Al2O3), 25 parts of aluminium powder, copper powder 20
Part, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.The preparation method of ceramic-metal composite, first by above-mentioned component material ball milling
Afterwards, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
The present invention carries out reasonable disposition to raw material, through oversintering after being combined by one, low cost is prepared, with good
Heat endurance, red hardness and excellent wearability high meet material but also with excellent anti-rapid heat cycle and resistance to high temperature oxidation
Material.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating
In any this actual relation or order.And, term " including ", "comprising" or its any other variant be intended to
Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those
Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or
Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (5)
1. a kind of ceramic-metal composite, it is characterised in that:The weight portion of each component is:Alundum (Al2O3) 40-50 parts, aluminium powder
20-30 parts, copper powder 15-25 parts, titanium carbide 10-20 parts, tungsten 10-20 parts, iron 10-20 parts.
2. ceramic-metal composite as claimed in claim 1, it is characterised in that 40 parts of the alundum (Al2O3), aluminium powder 20
Part, 15 parts of copper powder, 10 parts of titanium carbide, 10 parts of tungsten, 10 parts of iron.
3. ceramic-metal composite as claimed in claim 1, it is characterised in that 50 parts of the alundum (Al2O3), aluminium powder 30
Part, 25 parts of copper powder, 20 parts of titanium carbide, 20 parts of tungsten, 20 parts of iron.
4. ceramic-metal composite as claimed in claim 1, it is characterised in that 45 parts of the alundum (Al2O3), aluminium powder 25
Part, 20 parts of copper powder, 15 parts of titanium carbide, 15 parts of tungsten, 15 parts of iron.
5. the preparation method of ceramic-metal composite as claimed in claim 1, it is characterised in that first by above-mentioned component material
After pellet mill, it is fitted into graphite jig, is sintered 30-40 minutes at a temperature of 1200 DEG C -1600 DEG C.
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CN201611056190.4A CN106756413A (en) | 2016-11-26 | 2016-11-26 | A kind of ceramic-metal composite |
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CN201611056190.4A CN106756413A (en) | 2016-11-26 | 2016-11-26 | A kind of ceramic-metal composite |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107774985A (en) * | 2017-10-19 | 2018-03-09 | 西安科技大学 | A kind of metal composite high-abrasive material |
CN109536812A (en) * | 2018-11-13 | 2019-03-29 | 武汉新科冶金设备制造有限公司 | Molten steel outlet reamer ceramet bit material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103418790A (en) * | 2012-05-17 | 2013-12-04 | 枣阳秦鸿新材料有限公司 | Anti-abrasion metal-ceramic composite product and preparation method thereof |
CN104178677A (en) * | 2014-08-20 | 2014-12-03 | 青岛骏泽盛泰智能科技有限公司 | Metal ceramic composite material |
CN104388718A (en) * | 2014-10-22 | 2015-03-04 | 苏州莱特复合材料有限公司 | Metal ceramic composite material and preparation method thereof |
CN104878270A (en) * | 2015-05-27 | 2015-09-02 | 杨文澍 | Metal ceramic composite material |
CN106048471A (en) * | 2016-07-08 | 2016-10-26 | 青岛百千川海洋生态科技有限公司 | Metal ceramic material |
-
2016
- 2016-11-26 CN CN201611056190.4A patent/CN106756413A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103418790A (en) * | 2012-05-17 | 2013-12-04 | 枣阳秦鸿新材料有限公司 | Anti-abrasion metal-ceramic composite product and preparation method thereof |
CN104178677A (en) * | 2014-08-20 | 2014-12-03 | 青岛骏泽盛泰智能科技有限公司 | Metal ceramic composite material |
CN104388718A (en) * | 2014-10-22 | 2015-03-04 | 苏州莱特复合材料有限公司 | Metal ceramic composite material and preparation method thereof |
CN104878270A (en) * | 2015-05-27 | 2015-09-02 | 杨文澍 | Metal ceramic composite material |
CN106048471A (en) * | 2016-07-08 | 2016-10-26 | 青岛百千川海洋生态科技有限公司 | Metal ceramic material |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107774985A (en) * | 2017-10-19 | 2018-03-09 | 西安科技大学 | A kind of metal composite high-abrasive material |
CN109536812A (en) * | 2018-11-13 | 2019-03-29 | 武汉新科冶金设备制造有限公司 | Molten steel outlet reamer ceramet bit material and preparation method thereof |
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Application publication date: 20170531 |