CN106753065B - A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production - Google Patents
A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production Download PDFInfo
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- CN106753065B CN106753065B CN201611272073.1A CN201611272073A CN106753065B CN 106753065 B CN106753065 B CN 106753065B CN 201611272073 A CN201611272073 A CN 201611272073A CN 106753065 B CN106753065 B CN 106753065B
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- water
- adhesive
- quickstick
- corrugated board
- temperature production
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of quickstick MR adhesives for corrugated board temperature production, it is characterised in that by water, filler, polyvinyl alcohol, silicone emulsion, aluminum aluminum sulfate, crosslinking agent, TL water-proofing agent, Kathon CG, calgon, according to a certain ratio, centainly technique is reacted with requirement.It is mainly reacted using polyvinyl alcohol with cross-linking agents, generates certain tack, water resistance；Again plus TL water-proofing agent makes the water resistance of adhesive be further enhanced, and can meet different water-fast requirements according to dosage, and filler improves the solid content of glue, reduces the moisture of glue, the rate of drying of adhesive is improved in production.Invention adhesives have many advantages, such as that applicability is wide, tack is strong, at low cost, water-tolerant, meet the requirement of corrugated paper board production line temperature production.
Description
Technical field
The present invention relates to polymeric adhesive material fields, and in particular to a kind of quickstick for corrugated board temperature production
MR adhesive and its preparation method.
Background technique
Currently, adhesive used in the production of paper products such as corrugated board, honeycomb cardboard, carton, mostly uses greatly amylan viscous
Agent, polyvinyl alcohol modification adhesive, white glue with vinyl etc., its raw material sources of starch adhesive are extensive, and adhesive-preparing technology is simple, substantially by
Water, starch, alkali, borax, oxidant, stabilizer etc. by certain proportion, are centainly sequentially stirred to react, but actually make
Slow drying speed, speed are slow, water-resistance is poor with existing in the process, and the corrugated board of production, which easily gets damp, to feel like jelly, so as to cause bonding
Intensity decline, side pressure strength decline.Using common starch adhesive production corrugated board, there are one more prominent disadvantages
It is that required steam pressure is high, and production energy consumption is big, this energy-saving and emission-reduction policy existing with China runs in the opposite direction；Polyvinyl alcohol changes
Although property adhesive increases with white glue with vinyl bonding quick-drying performance than starch adhesive, it is poor that there is also tacks, at high cost,
Without water resistance, be not able to satisfy it is some require ordinary temperature production, quick-binding, the special paper products packet with water-fast moisture resistance performance
Fill the requirement of production.
Chinese invention patent CN1438284 discloses a kind of single side and corrugated paper board production line water-resistant type amylum adhesive
And its preparation method, its main feature is that water, starch, borax, sodium hydroxide, melamine resin, phenolic resin, styrene-acrylic emulsion, pure
Acrylic emulsion is stirred to react；Adhesive described in the invention has water-fast and humidity resistance, still, rate of drying phase when use
To relatively slowly, paper machine steam pressure is high, and energy consumption is high.
Chinese invention patent 201010213557.5 discloses a kind of adhesive for high-strength waterproof corrugated cases, this is viscous
Ingredients Weight proportion is in mixture：15~25 parts of cornstarch, 75~80 parts of water, 0.1~0.4 part of piece alkali, borax 0.3~0.6
Part, 0.5~1.2 part of intensive, adhesive water-tolerant described in the invention, still, that there are component compatibilities is poor for adhesive, holds
Easily layering.
Chinese invention patent 201510351715.6 discloses a kind of water resistance corrugated board adhesive and its preparation side
Method.The invention uses self-emulsification, utilizes polyester polyol, emulsifier, diisocyanate, dibutyl tin dilaurate, binary
Alcohol is the single-component water-based polyurethane adhesive that main Material synthesis is glued dedicated for water-resistant type corrugated board, although the bonding
Agent is i.e. curable at room temperature to strong, the water-tolerant by viscous adaptability for materials, but cannot answer extensively because its cost is too high
With.
Therefore, market in urgent need low temperature or normal temperature adhesive, tack is good, at low cost, and application is wide, has water-fast moisture resistance performance
Environment-friendly paper products adhesion agent.
Summary of the invention
Present invention aims in order to overcome the disadvantages and deficiencies of the prior art, have developed a kind of applicability it is extensive it is low at
Sheet, normal temperature adhesive, water-fast moisture resistance, function admirable a kind of quickstick MR adhesive and its system for corrugated board temperature production
Preparation Method.
The purpose of the invention is achieved by the following technical solution：
A kind of quickstick MR adhesive for corrugated board temperature production, it is characterised in that the mass ratio of each ingredient is：
Water 700, filler 50-200, polyvinyl alcohol 50-100, silicone emulsion 2-6, aluminum aluminum sulfate 5-20, crosslinking agent 1-5, TL water-proofing agent 1-
15, Kathon CG 1-3, calgon 0.5-5.
The crosslinking agent refers to one or both of borax, boric acid.
The filler refers at least one of kaolin, china clay, bentonite.
A kind of preparation method of the quickstick MR adhesive for corrugated board temperature production, it is characterised in that including following
Step：
(1), it adds water in reaction kettle, then sequentially adds filler, polyvinyl alcohol, the silicone emulsion liter in formula rate
Temperature is to 80-90 DEG C, insulation reaction 1 hour or so；
(2), 50 DEG C are then cooled to hereinafter, successively to add the aluminum aluminum sulfate in formula rate, crosslinking agent, TL water-fast
Agent, Kathon CG, calgon continue to be stirred to react 2 hours or so；
According to requiring to filter blowing after the assay was approved, that is, it is water-fast viscous to obtain a kind of quickstick for corrugated board temperature production
Mixture.
A kind of quickstick MR adhesive for corrugated board temperature production of the present invention mainly uses polyvinyl alcohol and other
The production of chemical industry auxiliary material, polyvinyl alcohol are reacted with aluminum aluminum sulfate, cross-linking agents, generate certain tack, water resistance；Again plus TL
Water-proofing agent (product is produced by the metallurgical Science and Technology Ltd. of Henan Province's expedition) reaction, obtains the water resistance of adhesive further
It improves, different water-fast requirements can be met according to dosage, filler improves the solid content of glue, reduces the moisture of glue, improves in production viscous
The rate of drying of mixture；Calgon improves the stability of adhesive, is not easy to be layered；Invention adhesives have applicability
Extensively, the advantages that tack is strong, at low cost, water-tolerant, meets the requirement of corrugated paper board production line temperature production.
Specific embodiment
Following example will be explained in detail operating method of the invention, but cannot function as limitation of the invention.
Embodiment one
A kind of quickstick MR adhesive for corrugated board temperature production, it is characterised in that the mass ratio of each ingredient is：
Water 700, filler 200, polyvinyl alcohol 80, silicone emulsion 2, aluminum aluminum sulfate 5, crosslinking agent 4, TL water-proofing agent 1, Kathon CG 2, hexa metaphosphoric acid
Sodium 2.
The crosslinking agent refers to one or both of borax, boric acid.
The filler refers at least one of kaolin, china clay, bentonite.
A kind of preparation method of the quickstick MR adhesive for corrugated board temperature production, it is characterised in that including following
Step：
(1), it adds water in reaction kettle, then sequentially adds filler, polyvinyl alcohol, the silicone emulsion liter in formula rate
Temperature is to 80-90 DEG C, insulation reaction 1 hour or so；
(2), 50 DEG C are then cooled to hereinafter, successively to add the aluminum aluminum sulfate in formula rate, crosslinking agent, TL water-fast
Agent, Kathon CG, calgon continue to be stirred to react 2 hours or so；
According to requiring to filter blowing after the assay was approved, that is, it is water-fast viscous to obtain a kind of quickstick for corrugated board temperature production
Mixture.
Embodiment two
A kind of quickstick MR adhesive for corrugated board temperature production, it is characterised in that the mass ratio of each ingredient is：
Water 700, filler 150, polyvinyl alcohol 100, silicone emulsion 2, aluminum aluminum sulfate 5, crosslinking agent 4, TL water-proofing agent 10, Kathon CG 2, six inclined phosphorus
Sour sodium 2.
The crosslinking agent refers to one or both of borax, boric acid.
The filler refers at least one of kaolin, china clay, bentonite.
A kind of preparation method of the quickstick MR adhesive for corrugated board temperature production, it is characterised in that including following
Step：
(1), it adds water in reaction kettle, then sequentially adds filler, polyvinyl alcohol, the silicone emulsion liter in formula rate
Temperature is to 80-90 DEG C, insulation reaction 1 hour or so；
(2), 50 DEG C are then cooled to hereinafter, successively to add the aluminum aluminum sulfate in formula rate, crosslinking agent, TL water-fast
Agent, Kathon CG, calgon continue to be stirred to react 2 hours or so；
According to requiring to filter blowing after the assay was approved, that is, it is water-fast viscous to obtain a kind of quickstick for corrugated board temperature production
Mixture.
For different formulations quickstick MR adhesive embodiment one of the present invention with embodiment two through detecting, technical indicator is as follows：
| Inspection project | Standard | Embodiment one | Embodiment two |
| Viscosity (27 DEG C), mPa.s | 1000-10000 | 2000 | 3000 |
| Solid content (105 DEG C) %, m/m | 15-35 | 29 | 27 |
| PH value | 7±1 | 6.5 | 6.5 |
| Adhesive speed (30 DEG C), S≤ | 10 | 8 | 5 |
| Resistance to cold water test (0-4 DEG C), h >= | It is determined according to different production requirements | 10 | 240 |
The foregoing is merely the present invention relates to certain embodiments, other are related to example since length is limited to the present invention, Bu Nengyi
One lists, and equally repairs as long as technical principle according to the present invention does above example in formula given to this invention and technique
Change or match variation, it is within the scope of the present invention.
Claims (5)
1. a kind of quickstick MR adhesive for corrugated board temperature production, it is characterised in that the mass ratio of each ingredient is：Water
800, filler 50-200, polyvinyl alcohol 50-100, silicone emulsion 2-6, aluminum aluminum sulfate 5-20, crosslinking agent 1-5, TL water-proofing agent 1-
15, Kathon CG 1-3, calgon 0.5-5.
2. a kind of quickstick MR adhesive for corrugated board temperature production according to claim 1, it is characterised in that：
Crosslinking agent refers to one or both of borax, boric acid.
3. a kind of quickstick MR adhesive for corrugated board temperature production according to claim 1, it is characterised in that：
Filler is kaolin.
4. a kind of quickstick MR adhesive for corrugated board temperature production according to claim 1, it is characterised in that：
Filler is bentonite.
5. a kind of method for preparing the quickstick MR adhesive described in claim 1 for corrugated board temperature production, special
Sign is to include the following steps：
(1), it adds water in reaction kettle, then sequentially adds the filler in formula rate, polyvinyl alcohol, silicone emulsion and be warming up to
80-90 DEG C, insulation reaction 1 hour；
(2), 50 DEG C are then cooled to hereinafter, successively adding the aluminum aluminum sulfate in formula rate, crosslinking agent, TL water-proofing agent, card
Pine, calgon, continue to be stirred to react 2 hours；
(3), according to requiring to filter blowing after the assay was approved, that is, it is water-fast viscous to obtain a kind of quickstick for corrugated board temperature production
Mixture.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611272073.1A CN106753065B (en) | 2016-12-30 | 2016-12-30 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611272073.1A CN106753065B (en) | 2016-12-30 | 2016-12-30 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
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| Publication Number | Publication Date |
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| CN106753065A CN106753065A (en) | 2017-05-31 |
| CN106753065B true CN106753065B (en) | 2018-11-23 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107384247A (en) * | 2017-07-12 | 2017-11-24 | 马鞍山科信网络科技有限公司 | A kind of based Wood Adhesives based on esterification modification tapioca and preparation method thereof |
| CN110922917B (en) * | 2019-11-04 | 2021-06-18 | 河南中包科技有限公司 | Adhesive for label clamp position of beer bottle labeling machine and preparation method |
| CN111662658A (en) * | 2020-07-10 | 2020-09-15 | 江门市豈铭实业有限公司 | Environment-friendly adhesive for carton printing and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1036949A (en) * | 1988-03-30 | 1989-11-08 | 中国科学院动物研究所 | The synthetic method of methoxy pvrethrins |
| CN1061611A (en) * | 1991-11-18 | 1992-06-03 | 朝阳市第一建筑工程公司 | Compound paste coating of polyvinyl alcohol and zinc oxide and preparation method |
| CN1079491A (en) * | 1992-06-04 | 1993-12-15 | 韩立泉 | high-strength polyvinyl alcohol adhesive and preparation method thereof |
| CN1122817A (en) * | 1995-09-22 | 1996-05-22 | 李恩光 | Glycoethenol and filler compound paste paint and mfg. method thereof |
-
2016
- 2016-12-30 CN CN201611272073.1A patent/CN106753065B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1036949A (en) * | 1988-03-30 | 1989-11-08 | 中国科学院动物研究所 | The synthetic method of methoxy pvrethrins |
| CN1061611A (en) * | 1991-11-18 | 1992-06-03 | 朝阳市第一建筑工程公司 | Compound paste coating of polyvinyl alcohol and zinc oxide and preparation method |
| CN1079491A (en) * | 1992-06-04 | 1993-12-15 | 韩立泉 | high-strength polyvinyl alcohol adhesive and preparation method thereof |
| CN1122817A (en) * | 1995-09-22 | 1996-05-22 | 李恩光 | Glycoethenol and filler compound paste paint and mfg. method thereof |
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| CN106753065A (en) | 2017-05-31 |
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Effective date of registration: 20180927 Address after: 450003 Building 1, block A, building 15, weir four road, Jinshui District, Zhengzhou, Henan, No. 1, unit 7, No. Applicant after: HENAN ZHONGBAO TECHNOLOGY Co.,Ltd. Applicant after: HENAN SHUOZHIJIA ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Address before: 450003 Building 1, block A, building 15, weir four road, Jinshui District, Zhengzhou, Henan, No. 1, unit 7, No. Applicant before: HENAN ZHONGBAO TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20230801 Address after: 450000 Room 401, building 10, Henan new technology market, 199 Yangjin Road, Jinshui District, Zhengzhou City, Henan Province Patentee after: HENAN ZHONGBAO TECHNOLOGY Co.,Ltd. Address before: 450003 Building 1, block A, building 15, weir four road, Jinshui District, Zhengzhou, Henan, No. 1, unit 7, No. Patentee before: HENAN ZHONGBAO TECHNOLOGY Co.,Ltd. Patentee before: HENAN SHUOZHIJIA ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |