CN106752954B - Ccb高密封防水涂料 - Google Patents
Ccb高密封防水涂料 Download PDFInfo
- Publication number
- CN106752954B CN106752954B CN201710015041.1A CN201710015041A CN106752954B CN 106752954 B CN106752954 B CN 106752954B CN 201710015041 A CN201710015041 A CN 201710015041A CN 106752954 B CN106752954 B CN 106752954B
- Authority
- CN
- China
- Prior art keywords
- asphalt
- butyl
- emulsifier
- silane
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003973 paint Substances 0.000 title claims abstract description 38
- 238000007789 sealing Methods 0.000 title claims abstract description 32
- 239000005871 repellent Substances 0.000 title claims abstract description 31
- 239000010426 asphalt Substances 0.000 claims abstract description 83
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 63
- 239000002562 thickening agent Substances 0.000 claims abstract description 48
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 12
- -1 allyl trimethoxy silicon Alkane Chemical class 0.000 claims description 94
- 239000000203 mixture Substances 0.000 claims description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical class C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 18
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 238000012545 processing Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 238000005538 encapsulation Methods 0.000 claims description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003365 glass fiber Substances 0.000 claims description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 7
- 238000004078 waterproofing Methods 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 230000003014 reinforcing effect Effects 0.000 claims description 5
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 claims description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- HRHBQGBPZWNGHV-UHFFFAOYSA-N azane;bromomethane Chemical compound N.BrC HRHBQGBPZWNGHV-UHFFFAOYSA-N 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000003607 modifier Substances 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 37
- 239000002585 base Substances 0.000 description 35
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 23
- 229910000077 silane Inorganic materials 0.000 description 23
- 239000012875 nonionic emulsifier Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 19
- 150000001412 amines Chemical class 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000011295 pitch Substances 0.000 description 15
- 150000001299 aldehydes Chemical class 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- 239000004814 polyurethane Substances 0.000 description 14
- 229920002635 polyurethane Polymers 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 150000002989 phenols Chemical class 0.000 description 12
- 150000004985 diamines Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 7
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 6
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- 125000003700 epoxy group Chemical group 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 description 6
- 229920000136 polysorbate Polymers 0.000 description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229920003086 cellulose ether Polymers 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 229920000768 polyamine Polymers 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 4
- XQESJWNDTICJHW-UHFFFAOYSA-N 2-[(2-hydroxy-5-methyl-3-nonylphenyl)methyl]-4-methyl-6-nonylphenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CC=2C(=C(CCCCCCCCC)C=C(C)C=2)O)=C1O XQESJWNDTICJHW-UHFFFAOYSA-N 0.000 description 4
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 4
- 125000003368 amide group Chemical group 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- NPZTUJOABDZTLV-UHFFFAOYSA-N hydroxybenzotriazole Substances O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 229940018564 m-phenylenediamine Drugs 0.000 description 4
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 235000010413 sodium alginate Nutrition 0.000 description 4
- 239000000661 sodium alginate Substances 0.000 description 4
- 229940005550 sodium alginate Drugs 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WGRZHLPEQDVPET-UHFFFAOYSA-N 2-methoxyethoxysilane Chemical compound COCCO[SiH3] WGRZHLPEQDVPET-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004113 Sepiolite Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- DZBUGLKDJFMEHC-UHFFFAOYSA-N benzoquinolinylidene Natural products C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 150000001896 cresols Chemical class 0.000 description 3
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002462 imidazolines Chemical class 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- 229910052624 sepiolite Inorganic materials 0.000 description 3
- 235000019355 sepiolite Nutrition 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- BGGPPIRDKCLJKP-UHFFFAOYSA-M trimethyl(nonadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCC[N+](C)(C)C BGGPPIRDKCLJKP-UHFFFAOYSA-M 0.000 description 3
- 229940094989 trimethylsilane Drugs 0.000 description 3
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
- DYULYMCXVSRUPB-UHFFFAOYSA-N 1,4-bis(phenylmethoxy)benzene Chemical compound C=1C=CC=CC=1COC(C=C1)=CC=C1OCC1=CC=CC=C1 DYULYMCXVSRUPB-UHFFFAOYSA-N 0.000 description 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide Substances CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- KHWQFISNNNRGLV-UHFFFAOYSA-N 2,4,6-tributylphenol Chemical compound CCCCC1=CC(CCCC)=C(O)C(CCCC)=C1 KHWQFISNNNRGLV-UHFFFAOYSA-N 0.000 description 2
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 2
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 2
- HNURKXXMYARGAY-UHFFFAOYSA-N 2,6-Di-tert-butyl-4-hydroxymethylphenol Chemical compound CC(C)(C)C1=CC(CO)=CC(C(C)(C)C)=C1O HNURKXXMYARGAY-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- PZPVXSMCRLNVRD-UHFFFAOYSA-N 2,6-dibutylphenol Chemical compound CCCCC1=CC=CC(CCCC)=C1O PZPVXSMCRLNVRD-UHFFFAOYSA-N 0.000 description 2
- UDFARPRXWMDFQU-UHFFFAOYSA-N 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methylsulfanylmethyl]phenol Chemical class CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CSCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 UDFARPRXWMDFQU-UHFFFAOYSA-N 0.000 description 2
- YEDUAINPPJYDJZ-UHFFFAOYSA-N 2-hydroxybenzothiazole Chemical compound C1=CC=C2SC(O)=NC2=C1 YEDUAINPPJYDJZ-UHFFFAOYSA-N 0.000 description 2
- SGHSRBYSXCNJLP-UHFFFAOYSA-N 2-methyl-4,6-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC(C)=C(O)C(CCCCCCCCC)=C1 SGHSRBYSXCNJLP-UHFFFAOYSA-N 0.000 description 2
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Abstract
本发明提供一种CCB高密封防水涂料,按重量份计,其制备原料包含:石油沥青、沥青乳化剂、超支化硅烷偶联剂、3,4‑乙烯二氧噻吩、沥青改性剂、增稠剂、增强剂和水。
Description
技术领域
本发明涉及一种防水涂料,具体得涉及一种高密封防水涂料。
技术背景
建筑防水材料是指应用于建筑物的构筑物中起着防潮、防漏,保护建筑物和构筑物及其构件不受水侵蚀破坏作用的一类建筑材料。
传统的油性防水产品“有毒”(焦油气、甲苯、二甲苯等),而水性防水产品虽然可以解决聚氨酯等油性产品的有毒问题,但是却无法解决水性防水产品的防水、密封效果不理想的状况。为了具备防水性,传统的防水产品的颜料体积浓度(PVC)均低于临界颜料体积浓度(CPVC),因此形成的漆膜致密而无孔,从而依靠基料树脂的防水性阻止外部水分的侵入。但是这样的漆膜使墙体内部产生的潮气无法透过漆膜排出,这些潮气在漆膜下积聚,使漆膜与基材之间附着力降低,并随着时间的延长造成漆膜疏松、鼓泡,并进而出现起泡、开裂和剥落等现象。
针对上述情况,本发明提供一种无挥发性有机溶剂的水性防水涂料,所述防水涂料无需热熔,直接涂抹,施工容易;可在潮湿潮气的混凝土基面及金属、玻璃等多种界面上施工;同时具有高自愈功能,抗窜水能力强;富有橡胶的弹性与柔性,抗裂性能好,能够应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理等领域,具有优异的防水和密封效果,特别适合低温密封效果。
发明内容
本发明的第一方面提供一种CCB高密封防水涂料,按重量份计,其制备原料包含:
作为本发明的一种实施方式,所述沥青乳化剂选自季铵盐类沥青乳化剂、木质胺类沥青乳化剂、酰胺基多胺类沥青乳化剂、咪唑啉类沥青乳化剂、烷基酚聚氧乙烯醚沥青乳化剂、烷基酚与环氧乙烷缩合物沥青乳化剂中的一种或多种。
作为本发明的一种实施方式,所述沥青乳化剂为季铵盐类沥青乳化剂、酰胺基多胺类沥青乳化剂、烷基酚聚氧乙烯醚沥青乳化剂中的一种或多种。
作为本发明的一种实施方式,所述超支化硅烷偶联剂由硅烷偶联剂和超支化硅氧烷制备得到。
作为本发明的一种实施方式,所述增稠剂选自纤维素醚及其衍生物、碱溶胀型增稠剂、碱溶性增稠剂、聚氨酯增稠剂、疏水改性非聚氨酯增稠剂、无机增稠剂、络合型有机金属化合物类增稠剂、聚丙烯酰胺、聚丙烯酸钠、海藻酸钠中的一种或者一种以上的混合物。
作为本发明的一种实施方式,所述增强剂选自白炭黑、二氧化钛、重钙粉、沉淀硫酸钡、高岭土、聚丙烯纤维、玻璃纤维、滑石粉、胺类化合物、玄武岩、辉绿岩、石灰岩中的一种或者一种以上的混合物。
作为本发明的一种实施方式,所述制备原料还包含:长碳链烷基改性松香酸。
作为本发明的一种实施方式,所述长碳链烷基改性松香酸的长碳链烷基上有极性基团。
作为本发明的一种实施方式,所述极性基团选自羟基、羧基或磺酸基中的一种。
本发明的第二方面提供上述的CCB高密封防水涂料应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理等领域。
具体实施方式
参选以下本发明的优选实施方法的详述以及包括的实施例可更容易地理解本发明的内容。除非另有限定,本文使用的所有技术以及科学术语具有与本发明所属领域普通技术人员通常理解的相同的含义。当存在矛盾时,以本说明书中的定义为准。
如本文所用术语“由…制备”与“包含”同义。本文中所用的术语“包含”、“包括”、“具有”、“含有”或其任何其它变形,意在覆盖非排它性的包括。例如,包含所列要素的组合物、步骤、方法、制品或装置不必仅限于那些要素,而是可以包括未明确列出的其它要素或此种组合物、步骤、方法、制品或装置所固有的要素。
连接词“由…组成”排除任何未指出的要素、步骤或组分。如果用于权利要求中,此短语将使权利要求为封闭式,使其不包含除那些描述的材料以外的材料,但与其相关的常规杂质除外。当短语“由…组成”出现在权利要求主体的子句中而不是紧接在主题之后时,其仅限定在该子句中描述的要素;其它要素并不被排除在作为整体的所述权利要求之外。
当量、浓度、或者其它值或参数以范围、优选范围、或一系列上限优选值和下限优选值限定的范围表示时,这应当被理解为具体公开了由任何范围上限或优选值与任何范围下限或优选值的任一配对所形成的所有范围,而不论该范围是否单独公开了。例如,当公开了范围“1至5”时,所描述的范围应被解释为包括范围“1至4”、“1至3”、“1至2”、“1至2和4至5”、“1至3和5”等。当数值范围在本文中被描述时,除非另外说明,否则该范围意图包括其端值和在该范围内的所有整数和分数。
单数形式包括复数讨论对象,除非上下文中另外清楚地指明。“任选的”或者“任意一种”是指其后描述的事项或事件可以发生或不发生,而且该描述包括事件发生的情形和事件不发生的情形。
说明书和权利要求书中的近似用语用来修饰数量,表示本发明并不限定于该具体数量,还包括与该数量接近的可接受的而不会导致相关基本功能的改变的修正的部分。相应的,用“大约”、“约”等修饰一个数值,意为本发明不限于该精确数值。在某些例子中,近似用语可能对应于测量数值的仪器的精度。在本申请说明书和权利要求书中,范围限定可以组合和/或互换,如果没有另外说明这些范围包括其间所含有的所有子范围。
此外,本发明要素或组分前的不定冠词“一种”和“一个”对要素或组分的数量要求(即出现次数)无限制性。因此“一个”或“一种”应被解读为包括一个或至少一个,并且单数形式的要素或组分也包括复数形式,除非所述数量明显旨指单数形式。
“聚合物”意指通过聚合相同或不同类型的单体所制备的聚合化合物。通用术语“聚合物”包含术语“均聚物”、“共聚物”、“三元共聚物”与“共聚体”。
“共聚体”意指通过聚合至少两种不同单体制备的聚合物。通用术语“共聚体”包括术语“共聚物”(其一般用以指由两种不同单体制备的聚合物)与术语“三元共聚物”(其一般用以指由三种不同单体制备的聚合物)。其亦包含通过聚合四或更多种单体而制造的聚合物。“共混物”意指两种或两种以上聚合物通过物理的或化学的方法共同混合而形成的聚合物。
本发明的第一方面提供一种CCB高密封防水涂料,按重量份计,其制备原料包含:
石油沥青
石油沥青是原油加工过程的一种产品,在常温下是黑色或黑褐色的粘稠的液体、半固体或固体,主要含有可溶于三氯乙烯的烃类及非烃类衍生物,其性质和组成随原油来源和生产方法的不同而变化。石油沥青的组分及其主要物性如下:油分、树脂、地沥青质。油分为淡黄色至红褐色的油状液体,在石油沥青中,油分的含量为40%~60%。油分赋予沥青以流动性;树脂又称脂胶,为黄色至黑褐色半固体粘稠物质,沥青脂胶中绝大部分属于中性树脂。
石油沥青是由多种结构复杂的碳氢化合物及其非金属衍生物所组成的混合物。石油沥青的化学组成元素主要是碳和氢,其中碳约占80%~87%,氢约占10%~15%,其次是一些非烃元素,如氧、硫、氮等,此外还含有微量的镍、钒、铁、铅等金属元素。
石油沥青按照用途分为建筑石油沥青、道路石油沥青、防水防潮石油沥青和普通石油沥青。石油沥青的牌号主要根据针入度、延度和软化点等指标划分,并以针入度值表示。同一品种的石油沥青材料,牌号越高,则粘性越小,针入度越大,塑性越好,延度越大,温度敏感性越大,软化点越低。建筑石油沥青分为10号和30号两个牌号;道路石油沥青分十个牌号。
本发明中,所述石油沥青选自70号石油沥青、90号石油沥青或者110号石油沥青中的一种。作为本发明的一种优选方式,所述石油沥青选自70号或者90号石油沥青。
70号石油沥青的性能指标:针入度60-80;15度延度AB级大于100,C级大于40;软化点1-3和1-4区A级是大于46,B级大于44,C级大于43,2-2和2-3和2-4区A级是大于45,B级大于43,C级大于43。
90号石油沥青的性能指标:针入度80-100;15度延度AB级大于100,C级大于50;软化点1-2和1-3和1-4区A级是大于45,B级大于43,C级大于42,2-2和2-3A级是大于44,B级大于42,C级大于42。
本发明中,所述石油沥青购买于中国石化股份有限公司茂名分公司。
作为本发明的一种实施方式,所述石油沥青的重量份为20-40份,作为本发明的优选方式,所述石油沥青的重量份为25份。
沥青乳化剂
乳化沥青是将冷沥青加热到流动状态,然后经过机械力的作用使得、沥青能以一种细小的颗粒状态分散在含有一定量乳化剂的水溶液中,形成水包油状的沥青乳液,这种沥青乳液在常温下呈液态,具有高度的流动性。乳化剂是影响乳化沥青破乳的关键因素。乳化剂的类型为离子型乳化剂和非离子型乳化剂;离子型乳化剂又分为两性离子型乳化剂、阴离子型乳化剂和阳离子型乳化剂。
其中,阳离子型乳化剂的品种有很多,归纳起来主要分为以下六类:季铵盐类、胺化木质素类、烷基胺类、酰胺类、咪唑啉类和环氧乙烷双胺类。
作为本发明的一种实施方式,所述非离子乳化剂是脂肪酸甘油酯的聚乙二醇衍生物或偏脂肪酸酯的聚乙二醇衍生物或己糖醇酐或这些乳化剂的混合物。偏脂肪酸酯的聚乙二醇衍生物和己糖醇酐的代表性示例是POE(聚乙二醇)20失水山梨糖醇单硬脂酸酯,POP(聚丙二醇)20失水山梨糖醇单硬脂酸酯,POE20失水山梨糖醇三硬脂酸酯,POE10失水山梨糖醇二硬脂酸酯,POE15失水甘露醇单棕榈酸酯,POE10失水甘露醇二肉豆蔻酸酯,POE20失水山梨糖醇二油酸酯,POE20失水山梨糖醇单油酸酯,POE20失水山梨糖醇三油酸酯,POE20半乳糖醇单硬脂酸酯,POE20半乳糖醇二油酸酯,POE30失水山梨糖醇单硬脂酸酯,POE20失水山梨糖醇单棕榈酸酯,POE5失水山梨糖醇单油酸酯等。
作为本发明的一种优选方式,所述非离子乳化剂优选为烷氧基化的非离子乳化剂,尤其是包括在本结构化体系中的仅包含碳、氢和氧的那些乳化剂;也可使用酰氨基官能化和其它杂原子官能化的类型;更优选乙氧基化、丙氧基化、丁氧基化或混合烷氧基化的脂族或芳族烃链的非离子乳化剂,例如乙氧基化/丙氧基化脂族或芳族烃链的非离子乳化剂。适宜的烃基部分可包含6至22个碳原子,并且可以是直链、支链、脂环或芳族部分,并且该非离子乳化剂可衍生自伯醇或仲醇。
优选的烷氧基化乳化剂可选自乙氧基化的和乙氧基化/丙氧基化的或丙氧基化/乙氧基化的直链或轻度支化的一元脂肪醇的非离子缩合物类,其中该一元脂肪醇可以是天然的或合成的。烷基苯基烷氧基化物,如壬基苯基乙氧基化物,也是适宜使用的。
尤其适宜作为非离子乳化剂的是伯脂肪醇与1至75摩尔、更适宜1至15摩尔、优选1至11摩尔C2-C3烯化氧的缩合产物。特别优选的是具有含8至20个碳原子烷基的醇与2至9摩尔、并且特别是3或5摩尔环氧乙烷/摩尔醇的缩合产物。
含氮作为杂原子的适宜的非离子乳化剂包括多羟基脂肪酰胺,其具有结构式R1CONR2Z,其中R1是C5-C31的烃基,优选直链的C7-C19的烷基或链烯基,更优选直链的C11-C17的烷基或链烯基,或它们的混合物;R2是H、C1-C18、优选C1-C4的烃基、2-羟乙基、2-羟丙基、乙氧基、丙氧基,或它们的混合物,优选C1-C4的烷基,更优选甲基;并且Z是具有直链烃基链(至少有3个羟基直接连在该链上)的多羟基烃基,或其烷氧基化衍生物(优选乙氧基化或丙氧基化衍生物)。优选地,Z衍生自还原糖,如葡萄糖,相应优选的化合物是C11-C17烷基的N-甲基葡糖胺。
可用于本发明的其它非离子乳化剂包括:所谓的“封端”非离子物,其中一个或多个-OH部分被-OR所置换,其中R典型地为低级烷基,如C1-C3的烷基;长链烷基多糖,更具体地讲是聚葡萄糖苷和/或低聚糖类,以及可由脂肪酸酯化衍生出的非离子乳化剂。
本发明中所述的乳化剂为非离子乳化剂,包括Span系列的失水山梨醇脂肪酸酯类非离子乳化剂,Tween系列的聚氧乙烯失水山梨醇脂肪酸酯类非离子乳化剂,或OP系列的烷基酚聚氧乙烯醚类非离子乳化剂。
本发明中所述的沥青乳化剂为复合乳化剂,非离子乳化剂和离子型乳化剂按一定比例混合形成的复合型乳化剂,可以是Span系列的失水山梨醇脂肪酸酯类非离子乳化剂与Tween系列的聚氧乙烯失水山梨醇脂肪酸酯类非离子乳化剂复合的乳化剂,Span系列的乳化剂与Tween系列的乳化剂的重量比例为5~10∶1;Span系列的失水山梨醇脂肪酸酯类非离子乳化剂与OP系列的烷基酚聚氧乙烯醚类非离子乳化剂复合的乳化剂,Span系列的乳化剂与OP系列的乳化剂的重量比例为5~10∶1;或Tween系列的聚氧乙烯失水山梨醇脂肪酸酯类非离子乳化剂与OP系列的烷基酚聚氧乙烯醚类非离子乳化剂复合的乳化剂,Tween系列的乳化剂与OP系列的乳化剂的重量比例为5~10∶1。
所述的Span系列的失水山梨醇脂肪酸酯类非离子乳化剂是Span20、Span40、Span60、Span65、Span80或Span85等;Tween系列的聚氧乙烯失水山梨醇脂肪酸酯类非离子乳化剂是Tween20、Tween40、Tween60、Tween80或Tween85等;OP系列的烷基酚聚氧乙烯醚类非离子乳化剂是OP-4、OP-6、OP-7、OP-9或OP-10等。
季铵盐类阳离子沥青乳化剂是应用最为广泛的阳离子乳化剂,主要有烷基季铵盐,杂环结构的季铵盐,连接酰胺、酯、醚等基团的季铵盐等。
季铵盐型沥青乳化剂大部分是由伯胺、仲胺或叔胺与烷基化试剂作用而成,通常使用的烷基化试剂有氯甲烷、硫酸二甲酯、硫酸二乙酯、苄基氯、氯乙醇、环氧乙烷、高碳卤代烷和一些取代的卤甲烷、取代的环氧化合物像环氧氯丙烷、烷基氯甲基醚、烷基缩水甘油醚等。另外,利用造纸制浆废液的主要成分(木质素),通过曼尼希反应合成木素胺与卤化烷或烷基硫酸盐在碱水中共热合成性能优良的季铵盐型沥青乳化剂。通过研究发现:烷烃中碳链少于14的季铵盐不宜作沥青乳化剂;一些支链上有苯环或苄基的季铵盐的应用效果差;十八烷基三甲基类季铵盐具有较好的乳化效果。目前,我国生产的季铵盐类阳离子沥青乳化剂有十六~十九烷基。
作为本发明的一种实施方式,所述季铵盐类阳离子沥青乳化剂选自十六烷基三甲基溴化铵、十八烷基三甲基溴化铵和十九烷基三甲基溴化铵中的一种或多种。
本发明中,所述季铵盐类阳离子沥青乳化剂为十六烷基三甲基溴化铵、十八烷基三甲基溴化铵和十九烷基三甲基溴化铵按照重量比为1:0.3:0.7共混。
本发明中,所述沥青乳化剂的重量份为0.1-2份。
超支化硅烷偶联剂
本发明中所述超支化硅烷偶联剂由硅烷偶联剂和超支化硅氧烷制备得到。
硅烷偶联剂是一类在分子中同时含有两种不同化学性质基团的有机硅化合物。
本发明中,所述硅烷偶联剂选自A-151、A-171、A-172、KH-540、KH-550、KH-551、KH-560、KH-570、KH-580、KH-602、KH-791、KH-901、KH-902中的一种或多种。
作为本发明的一种实施方式,所述硅烷偶联剂选自含有至少两个甲氧基的硅烷偶联剂。
作为本发明的一种实施方式,所述硅烷偶联剂选自含有双键的硅烷偶联剂。
作为本发明的一种实施方式,所述硅烷偶联剂选自含有长碳链烷基的硅烷偶联剂。
作为本发明的一种实施方式,所述硅烷偶联剂选自乙烯基三甲氧基硅烷、甲基乙烯基二甲氧基硅烷、甲基苯基二甲氧基硅烷、乙烯基苯基二甲氧基硅烷、乙烯基苯基二甲氧基硅烷、丙基三甲氧基硅烷、乙烯基三(2-甲氧基乙氧基)硅烷、丁基三甲氧基硅烷、十二氟庚基丙基三甲氧基硅烷、二甲基二甲氧基硅烷、异丁基异丙基二甲氧基硅烷、3-(丙烯酰氧基)丙基二甲基甲氧基硅烷、3-甲氧基-2-(三甲基硅烷基)-吡啶、3-甲氧基-4-(三甲基硅烷基)-吡啶、甲基三甲氧基硅烷、叔丁基(乙基)二甲氧基硅烷、3-氨基丙基三甲氧基硅烷、十二烷基(甲基)二甲氧基硅烷、十六烷基三甲氧基硅烷、乙烯基甲氧基二甲基硅烷、甲基乙烯基二甲氧基硅烷、(乙烯基二甲氧基硅烷基)-苯、甲基乙烯基二甲氧基硅烷、乙烯基甲氧基二甲基硅烷、苯乙烯乙基三甲氧基硅烷、乙烯基三(2-甲氧基乙氧基)硅烷中的一种。
作为本发明的一种优选方式,所述硅烷偶联剂选自甲基乙烯基二甲氧基硅烷、甲基苯基二甲氧基硅烷、乙烯基苯基二甲氧基硅烷、二甲基二甲氧基硅烷、3-甲氧基-2-(三甲基硅烷基)-吡啶、甲基三甲氧基硅烷、十二烷基(甲基)二甲氧基硅烷、十六烷基三甲氧基硅烷、甲基乙烯基二甲氧基硅烷中的一种。
超支化硅氧烷:
高度支化聚合物是一种结构独特的三维球状大分子物质,因其特殊的化学物理性质以及在各领域的应用潜能而受到广泛的关注,正在向改性、应用等方向蓬勃发展。而超支化聚合物作为高度支化的聚合物中的一类,与树枝状聚合物相比不强求其结构的规整性,因而合成难度小,合成步骤简单,一般采用“一步法”就可以完成。
本发明中,所述超支化硅氧烷由二胺和含有环氧基团的硅烷、含有碳碳双键的硅烷制备得到。
作为本发明的一种实施方式,所述二胺选自间苯二胺、邻苯二胺、乙二胺、1,2-丙二胺、1,3-丙二胺、1,4-丁二胺、1,6-己二胺、1,8-辛二胺、2,7-萘二胺、1,7-庚二胺、1,2-萘二胺、1,5-萘二胺、1,6-萘二胺、1,7-萘二胺、2,6-萘二胺、1,10-癸二胺、己二酰二胺、2-氟丁二胺、3,5-吡啶二胺、3,6-喹啉二胺、1,3-吩嗪二胺、1,2-吩嗪二胺、1,7-吖啶二胺、2,9-吖啶二胺、4,5-哒嗪二胺、4,6-喹啉二胺中的一种。
作为本发明的一种优选方式,所述二胺选自1,10-癸二胺、1,8-辛二胺、1,7-吖啶二胺中的一种。
作为本发明的一种实施方式,所述含有环氧基团的硅烷选自2-(3,4-环氧环己烷基)乙基三乙氧基硅烷、(2-叔丁基环氧乙烷-2-基)-三甲基硅烷、三甲基(环氧乙烷-2-基)硅烷、2-[[3-(乙氧基二甲基硅烷基)丙氧基]甲基]-环氧乙烷、3-缩水甘油醚氧基丙基三甲氧基硅烷、三甲氧基-[3-(环氧乙烷-2-基甲氧基)丙基]硅烷、2-(3,4-环氧环己烷)乙基三甲氧基硅烷、3-[(2,3)-环氧丙氧]丙基甲基二甲氧基硅烷、3-氯丙基-二甲氧基-[3-(2-环氧乙烷基甲氧基)丙基]硅烷、5,6-环氧己基三乙氧基硅烷、(3-(2,3-环氧丙氧基)丙基)(2-甲氧基乙氧基)二甲基硅烷中的一种。
作为本发明的一种优选方式,所述含有环氧基团的硅烷选自3-氯丙基-二甲氧基-[3-(2-环氧乙烷基甲氧基)丙基]硅烷、3-[(2,3)-环氧丙氧]丙基甲基二甲氧基硅烷、2-(3,4-环氧环己烷)乙基三甲氧基硅烷、三甲氧基-[3-(环氧乙烷-2-基甲氧基)丙基]硅烷、3-缩水甘油醚氧基丙基三甲氧基硅烷中的一种。
作为本发明的一种实施方式,所述含有碳碳双键的硅烷选自2-[1-[[(叔丁基)二甲基硅烷基]氧基]-3-丁烯-1-基]呋喃、二氯乙烯基乙基-硅烷、3-(三甲基硅烷基)-4-戊烯酸、二甲基二乙烯基硅烷、1,1,1-三甲基-N-2-丙烯-1-基-硅烷胺、1-[(叔丁基)二甲基硅烷基]-2-丙烯-1-醇、乙烯基三(2-甲氧基乙氧基)硅烷、[[1-乙氧基-2-氟-2-(三甲基硅烷基)乙烯基]氧基]三甲基硅烷、二烯丙基二甲基硅烷、3-(丙烯酰氧基)丙基二甲基甲氧基硅烷、(二甲氧基)(甲基丙烯酰基氧基甲基)(甲基)硅烷、N-(二甲基-丙-2-烯基硅烷基)-N-苯基苯胺、[(E)-丁-2-烯基]-三乙氧基硅烷、3-甲基丙烯酰氧基丙基甲基二甲氧基硅烷、甲基乙烯基二甲氧基硅烷、三甲基硅烷基甲基异丁烯酸酯、3-丙烯酰氧基丙基三乙氧基硅烷、丙烯酰氧基甲基三甲氧基硅烷、烯丙基三甲氧基硅烷中的一种。
作为本发明的一种优选方式,所述含有碳碳双键的硅烷选自乙烯基三(2-甲氧基乙氧基)硅烷、3-(丙烯酰氧基)丙基二甲基甲氧基硅烷、(二甲氧基)(甲基丙烯酰基氧基甲基)(甲基)硅烷、3-甲基丙烯酰氧基丙基甲基二甲氧基硅烷、甲基乙烯基二甲氧基硅烷、3-丙烯酰氧基丙基三乙氧基硅烷、丙烯酰氧基甲基三甲氧基硅烷、烯丙基三甲氧基硅烷中的一种。
作为本发明的一种实施方式,所述二胺、含有环氧基团的硅烷和含有碳碳双键的硅烷的重量比为0.2:1:0.8。
本发明中,所述超支化硅氧烷的制备方法如下:将0.2重量份的二胺和0.4重量份的含有环氧基团的硅烷在氮气气氛,碱性环境下,80℃反应6小时,随后将剩余的含有环氧基团的硅烷和含有碳碳双键的硅烷投入,在氮气气氛下,酸性环境下,60℃反应4小时,即可制备得到所述超支化硅氧烷。
本发明中,所述硅烷偶联剂和超支化硅氧烷的重量比为1:(2-4),作为本发明的一种实施方式,所述硅烷偶联剂和超支化硅氧烷的重量比为1:2.5。
所述超支化硅烷偶联剂的制备方法如下:将超支化硅氧烷和硅烷偶联剂在氮气气氛下,酸性环境下,60℃下反应4小时,即可制备得到超支化硅烷偶联剂。
本发明中,所述超支化硅烷偶联剂的重量份为0.1-0.5份。
3,4-乙烯二氧噻吩,化学式C6H6O2S,CAS号126213-50-1。
沥青改性剂
沥青改性剂是指在沥青或沥青混合料中加入的天然或人工合成的有机或无机材料,可熔融或分散在沥青中以改善或提高沥青的防水性能的物质。
本发明中所述沥青改性剂为热塑性弹性体沥青改性剂、树脂沥青改性剂、橡胶沥青改性剂中的一种或一种以上混合物。
橡胶沥青改性剂有天然橡胶、丁苯橡胶、聚氯丁二烯、聚丁二烯、聚苯乙烯异戊二烯共聚物等。
树脂沥青改性剂有乙烯醋酸乙烯共聚物、聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、聚醋酸乙烯、环氧树脂、酚醛树脂等。
热塑性弹性体沥青改性剂有苯乙烯-丁二烯-苯乙烯共聚物等。
本发明中,所述沥青改性剂选自上述热塑性弹性体沥青改性剂、树脂沥青改性剂、橡胶沥青改性剂中的一种或多种。
作为本发明的一种实施方式,所述沥青改性剂的重量份为5-10份。
增稠剂
本发明中增稠剂是指增加粘度并控制其流动性的物质。在本发明中,加入其是为防止长期存放期间在上层和下层之间产生浓度不均。由于加入增稠剂改善了胶乳组合物的机械稳定性,可以有效防止诸如当本发明石油沥青与其它组分混合时,在长期存放期间由于组分间颗粒尺寸和比重的差异造成上、下层之间浓度不均的问题。
可提及聚合物多糖如黄原胶作为本发明增稠剂。在本发明中,当组合物中的表面活性剂含量(固含量)是100质量份时,增稠剂含量优选为0-2质量份,更优选0.1-1.5质量份。当增稠剂含量小于上述范围时,长期存放期间可能会出现在上层和下层之间浓度不均,因此这种情形不是优选的。当含量超过上述范围时,粘度有可能变得不必要地高,以致缺乏实用性,因此这种情形不是优选的。
本发明中,所述增稠剂是纤维素醚及其衍生物、碱溶胀型增稠剂、碱溶性增稠剂、聚氨酯增稠剂、疏水改性非聚氨酯增稠剂、无机增稠剂、络合型有机金属化合物类增稠剂、聚丙烯酰胺、聚丙烯酸钠、海藻酸钠中的一种或者一种以上的混合物。
本发明中,所述纤维素醚及其衍生物包括羟乙基纤维素、甲基羟乙基纤维素、乙基羟乙基纤维素、甲基羟丙基纤维素、甲基纤维素、疏水改性纤维素、黄原胶、瓜尔胶。
所述的碱溶胀型增稠剂包括非缔合型聚丙烯酸盐碱溶胀型乳液、缔合型聚丙烯酸盐碱溶胀型乳液。
所述的聚氨酯增稠剂和疏水改性非聚氨酯增稠剂包括阴离子型缔合聚氨酯增稠剂、阳离子型缔合聚氨酯增稠剂、非离子型缔合聚氨酯增稠剂、疏水改性氨基增稠剂、疏水改性聚醚增稠剂、疏水改性聚脲增稠剂。
所述的无机增稠剂包括膨润土、凹凸棒土、气相二氧化硅、海泡石。海泡石是化学结构式为Si12Mg8O30(OH)4(OH2)4·8H2O的含水硅酸镁,很早以来就使用它的触变性能来增加粘度、防止沉淀和形成小滴。在组成上膨润土不同于海泡石,但是它们有类似性能。用它来增稠涂料、油墨和其它液体组合物。通过使纤维素酯甲基化而得到甲基纤维素。羧甲基纤维素可以叫做甲基纤维素的衍生物。它们被广泛使用,主要作为胶水。
碱溶性增稠剂一般为丙烯酸树脂,如罗门哈斯AP-10、AP-50、ASE-60、TT-615、TT-935;海明斯德谦的Rheolate 125、Rheolate 150、Rheolate 425、Rheolate450。
作为本发明的一种实施方式,所述增稠剂选自纤维素醚及其衍生物、碱溶性增稠剂、碱溶胀型增稠剂、聚氨酯增稠剂、疏水改性非聚氨酯增稠剂、无机增稠剂、络合型有机金属化合物类增稠剂、聚丙烯酰胺、聚丙烯酸钠、海藻酸钠中的一种或者一种以上的混合物。
本发明中,所述增稠剂的重量份为0.1-2份。
增强剂
本发明中,所述的增强剂为白炭黑或二氧化钛。
本发明中,所述的增强剂是胺类化合物,该胺类化合物是由酚类、醛类溶液和胺类合成得到。
所述的胺类化合物的合成是:按胺类、酚类、醛类的摩尔比为:(0.5-1.3)∶1∶(0.8-1.1),选取胺类、酚类和醛类,醛类配制成醛类溶液,醛类溶液浓度为20-45wt%,备用;在附有搅拌器、冷凝器、滴液漏斗、温度计的反应器中,加入胺类和酚类,搅拌均匀并加热至40-120℃后,恒温30-90分钟,再滴加醛类溶液,加完后,升高反应温度为80-150℃继续反应1-4h,降温至室温,最后真空脱水,即得到胺类化合物。
所述的胺类化合物的合成还可以是:按胺类、酚类、醛类的摩尔比为:(0.5-1.3)∶1∶(0.8-1.1),选取胺类、酚类和醛类,醛类配制成醛类溶液,醛类溶液浓度为20-45wt%,备用;在附有搅拌器、冷凝器、滴液漏斗、温度计的反应器中,加入酚类和醛类溶液的混合溶,搅拌均匀并加热至60-100℃后,恒温30-90分钟,滴加胺类,加完后,升高反应温度至90-150℃继续反应1-4h,降温至室温,最后真空脱水,即得到胺类化合物。
所述的酚类可以是苯酚、辛基酚、壬基酚、腰果酚或甲酚等烷基酚。
所述的醛类可以是甲醛、乙醛、水杨醛、对羟基苯甲醛或丁醛。
所述的胺类包括脂肪胺、脂环胺或芳香胺。
所述的脂肪胺可以是乙二胺、己二胺、二乙烯三胺、三乙烯回胺、四乙烯五胺、尿素、(2,3二甲基)二亚丁基三胺(TAB)、多乙烯多胺或多元胺。
所述的脂环胺可以是(4,4-二氨基)二苯基甲烷(MDA)、异佛尔酮二胺(IPDA)、甲基环戊二胺(TAC)或邻二胺甲基环戊烷(TDC)。
所述的芳香胺可以是间苯二胺、间苯二甲胺或DDM(75wt%左右的4,4-二氨基二苯基甲烷和25wt%左右的多苯基多氨基甲烷的混合物)。
优选增强剂为可增强高低温与抗老化性能的柔韧型添加剂,与沥青的相容性好,采用干拌方式添加,用量为不超过特种改性沥青质量的10%。
作为本发明的一种实施方式,所述增强剂选自白炭黑、二氧化钛、重钙粉、沉淀硫酸钡、高岭土、聚丙烯纤维、玻璃纤维、滑石粉、胺类化合物、玄武岩、辉绿岩、石灰岩中的一种或者一种以上的混合物。
本发明中所述玻璃纤维可以提高复合材料湿态物理机械强度、湿态电气性能,并改善玻璃纤维的集束性、保护性和加工性。
本发明中,所述增强剂的加入量为0.1-2份。
根据需要,本发明的胶乳组合物还可含有分散剂,稳定剂,防老剂,UV吸收剂、抗剥落剂、防腐剂、变形剂以及保护性胶体,如聚(丙烯酸钠)、聚乙烯醇、干酪素、明胶、羧甲基纤维素或羟乙基纤维素。
抗老剂
抗老剂可以分为酚类抗老剂、胺类抗老剂、亚磷酸酯类抗老剂、含硫酯类抗老剂。
作为酚类抗老剂的实例,包括但不限于:1-羟基-3-甲基-4-异丙基苯、2,6-二叔丁基苯酚、2,6-二叔丁基-4-乙基苯酚、2,6-二叔丁基-4-甲基苯酚、2,6-二叔丁基-4-正丁基苯酚、4-羟甲基-2,6-二叔丁基苯酚、叔丁基羟基茴香醚、2-(1-甲基环己基)-4,6-二甲基苯酚、2,4-二甲基-6-叔丁基苯酚、2-甲基-4,6-二壬基苯酚、2,6-二叔丁基-α-二甲氨基-对甲酚、2,4,6-三叔丁基苯酚、6-(4-羟基-3,5-二叔丁基苯胺基)-2,4-双(辛基硫代)-1,3,5-三嗪、4,6-双(4-羟基-3,5-二叔丁基苯氧基)-2-正辛基硫代-1,3,5-三嗪、β-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯、β-(4—羟基—3,5—二叔丁基苯基)丙酸正十八碳醇酯、苯乙烯化苯酚、4,4′-二羟基联苯、丁基化辛基化苯酚、丁基化苯乙烯化甲酚、2,2′-甲撑双(4-甲基-6-叔丁基苯酚)、2,2′-甲撑双(4-乙基-6-叔丁基苯酚)、2,2′-甲撑双(4-甲基-6-环己基苯酚)、4,4′-甲撑双(2,6-二叔丁基苯酚)、2,2′-甲撑双(6-α-甲基苄基对甲酚)、4,4′-异丙叉双酚、4,4′-丁叉双(3-甲基-6-叔丁基苯酚)、1,1-双(4-羟基苯)环己烷、2,2′-甲撑双(4-甲基-6-(α-甲基环己基)苯酚)、1,3,5-三甲基-2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯、1,1,3-三(2-甲基-4-羟基-5-叔丁基苯基)丁烷、四(3-(3′5′-二叔丁基-4′-羟基苯基)丙酸)季戊四醇酯、4,4′-硫代双(6-叔丁基-3-甲基苯酚)、4,4′-硫代双(2-甲基-6-叔丁基苯酚)、2,2′-硫代双(4-甲基-6-叔丁基苯酚)、己二醇双(β-(3,5-二叔丁基-4-羟基苯基)丙酸酯)、2,2′-硫代双(3,-(3,5-二叔丁基-4-羟基苯基)丙酸乙酯)、N,N′-六甲撑双(3,5-二叔丁基-4-羟基苯丙酰胺)、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)1,3,5—三嗪-2,4,6-(1H,3H,5H)-三酮、1,3,5-三(3,5-二叔丁基-4-羟基苄基)均三嗪-2,4,6-(1H,3H,5H)三酮、异氰脲酸三[β-(3,5-二叔丁基-4-羟基苯基)丙酰氧基乙酯]、双[3,3-双(3′-叔丁基-4′-羟基苯基)丁酸]乙二醇酯、1,1′-硫代双(2-萘酚)、双(3,5-二叔丁基-4-羟基苄基)硫醚、2,5-二叔丁基对苯二酚、2,5-二叔戊基对苯二酚、3,5-二叔丁基-4-羟基苄基磷酸二(十八)酯、3,5-二叔丁基-4-羟基苄基磷酸二乙酯、辛基化苯酚、三甘醇双-3-(3-叔丁基-4-羟基-5-甲基苯基)丙酸酯、对苯二酚二苄醚、“Ethyl”Antioxidant 728、“Ethyl”Antioxidant 733、“Ethyl”Antioxidant 735、Cyanox 96、Cyanox 53、Cyanox LF、Cyanox 1735、AntioxidantQ-328、Santonox、Antioxidant MBP-5P、MBP-5T、TBM-6P、TBM-6T、Irganox 1890、MD-1024、Seenox M-100、M-200、M-220、Vanox GT、SKT、Escoflex A122、A123、Sumilizer MPO、Sumilizer-NW、Sumilizer CS-4、Sumilizer CS-42、Santowhite MK、Nonox-HO、Nonox-EX、Nonox-EXN、Nonox-EXP、Nonox-WMP、Nonox-WSO、Antioxidant KSM、KSM-EM-33%、TSP、DS、DS/F、NKF、Naugawhite、Naugawhite 434、Naugawhite 431、Naugawhite Powder。
作为胺类抗老剂的实例,包括但不限于:N-苯基-α-萘胺、N-苯基-β-萘胺、丁间醇醛-α-萘胺、N,N′-二苯基对苯二胺、N-异丙基-N′-苯基对苯二胺、N,N′-二-β-萘基对苯二胺、N,N′-双(1,4-二甲基戊基)对苯二胺、N,N′-双(1-乙基-3-甲基戊基)对苯二胺、N-环己基-N′-苯基对苯二胺、N,N′-双(1-甲基庚基)对苯二胺、N-(1,3-二甲基丁基)-N′-苯基对苯二胺、N-苯基-N′-辛基对苯二胺、6-乙氧基-2,2,4-三甲基-1,2-二氢化喹啉、2,2,4-三甲基-1,2-二氢化喹啉聚合体、6-十二烷基-2,2,4-三甲基-1,2-二氢化喹啉、N-(甲基丙烯酰基氧代-2-羟基丙基)-N′-苯基对苯二胺、N-环己基-对甲氧基苯胺、对,对′-二甲氧基二苯胺、对-(对-甲苯基磺酰胺基)二苯胺、双-(苯基异丙叉)-4,4′-二苯胺、N,N′-二苯基乙二胺、N,N′-二邻甲苯基乙二胺、N,N′-二苯基丙二胺、对-异丙氧基二苯胺、N,N′-二仲丁基对苯二胺、N,N′-二甲基-N,N′-二(1-甲基丙基)对苯二胺、对,对′-二辛基二苯胺、4,4′-双(α-甲基苄基)-二苯胺、Antioxidant 445、Goodrite 3120、Goodrite 3140、Irganox LD-62、Wingstay 29。
作为亚磷酸酯类抗老剂的实例,包括但不限于:亚磷酸三苯酯、亚磷酸三(壬基苯酯)、亚磷酸三异辛酯、亚磷酸三异癸酯、亚磷酸苯二异癸酯、三硫代亚磷酸三月桂酯、亚磷酸三月桂酯、亚磷酸三(十八酯)、二亚磷酸季戊四醇二异癸酯、二亚磷酸季戊四醇二硬脂醇酯、4,4′-丁叉双(亚磷酸(3-甲基-6-叔丁基苯基)二(十三烷基)酯)、亚磷酸二苯·异辛酯、亚磷酸苯二异辛酯、亚磷酸二苯辛酯、亚磷酸二苯·异癸酯、亚磷酸二辛酯、亚磷酸二月桂酯、亚磷酸二甲酯、亚磷酸二油醇酯、亚磷酸二癸酯、亚磷酸二丁酯、亚磷酸双十三酯、亚磷酸双十四酯、亚磷酸三乙酯、亚磷酸三丁酯、亚磷酸三异丙酯、亚磷酸三辛酯、亚磷酸-苯·双(壬基苯)酯、亚磷酸二苯·壬基苯酯、亚磷酸三(2-氯乙)酯、亚磷酸三(2,4-二叔丁基苯基)酯、亚磷酸双酚A酯、亚磷酸三(单壬基苯和二壬基苯混合酯)、Mark 329、Mark 1500、Mark C、Wytox 345、Wytox 438、Wytox X-540。
作为含硫酯类抗老剂的实例,包括但不限于:硫代二丙酸二月桂酯、硫代二丙酸二硬脂醇酯、β,β′-硫代二丁酸二(十八)酯、硫代二丙酸月桂十八酯、硫代二丙酸二(十三)酯、硫代二丙酸二(十四)酯。
抗老剂还可以是其它类型抗老剂,其具体实例包括但不限于:2-巯基苯并咪唑、2-巯基甲基苯并咪唑、2-巯基苯并咪唑锌盐、N-水杨叉-N′-水杨酰肼、1,2-双(2-羟基苯甲酰)肼、N,N′-二乙酰基己二酰基二酰肼、Naugard XL-1、Irganox MD 1024、Eastman inhibitorOABH、Sandostab P-EPQ、Mark 260、HCA、Perkanox PC-19、Mark AO-23、Mark AO-412S、MarkCDA 1、Mark CDA-6、Nonox CNS、Seenox 412S、巯基乙酸戊酯。
作为本发明的一种实施方式,所述抗老剂优选为酚类抗老剂。所述酚类抗老剂选自1-羟基-3-甲基-4-异丙基苯、2,6-二叔丁基苯酚、2,6-二叔丁基-4-乙基苯酚、2,6-二叔丁基-4-甲基苯酚、2,6-二叔丁基-4-正丁基苯酚、4-羟甲基-2,6-二叔丁基苯酚、叔丁基羟基茴香醚、2-(1-甲基环己基)-4,6-二甲基苯酚、2,4-二甲基-6-叔丁基苯酚、2-甲基-4,6-二壬基苯酚、2,6-二叔丁基-α-二甲氨基-对甲酚、2,4,6-三叔丁基苯酚、6-(4-羟基-3,5-二叔丁基苯胺基)-2,4-双(辛基硫代)-1,3,5-三嗪、4,6-双(4-羟基-3,5-二叔丁基苯氧基)-2-正辛基硫代-1,3,5-三嗪、β-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯、β-(4—羟基—3,5—二叔丁基苯基)丙酸正十八碳醇酯、苯乙烯化苯酚、4,4′-二羟基联苯、丁基化辛基化苯酚、丁基化苯乙烯化甲酚、2,2′-甲撑双(4-甲基-6-叔丁基苯酚)、2,2′-甲撑双(4-乙基-6-叔丁基苯酚)、2,2′-甲撑双(4-甲基-6-环己基苯酚)、4,4′-甲撑双(2,6-二叔丁基苯酚)、2,2′-甲撑双(6-α-甲基苄基对甲酚)、4,4′-异丙叉双酚、4,4′-丁叉双(3-甲基-6-叔丁基苯酚)、1,1-双(4-羟基苯)环己烷、2,2′-甲撑双(4-甲基-6-(α-甲基环己基)苯酚)、1,3,5-三甲基-2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯、1,1,3-三(2-甲基-4-羟基-5-叔丁基苯基)丁烷、四(3-(3′5′-二叔丁基-4′-羟基苯基)丙酸)季戊四醇酯、4,4′-硫代双(6-叔丁基-3-甲基苯酚)、4,4′-硫代双(2-甲基-6-叔丁基苯酚)、2,2′-硫代双(4-甲基-6-叔丁基苯酚)、己二醇双(β-(3,5-二叔丁基-4-羟基苯基)丙酸酯)、2,2′-硫代双(3,-(3,5-二叔丁基-4-羟基苯基)丙酸乙酯)、N,N′-六甲撑双(3,5-二叔丁基-4-羟基苯丙酰胺)、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)1,3,5—三嗪-2,4,6-(1H,3H,5H)-三酮、1,3,5-三(3,5-二叔丁基-4-羟基苄基)均三嗪-2,4,6-(1H,3H,5H)三酮、异氰脲酸三[β-(3,5-二叔丁基-4-羟基苯基)丙酰氧基乙酯]、双[3,3-双(3′-叔丁基-4′-羟基苯基)丁酸]乙二醇酯、1,1′-硫代双(2-萘酚)、双(3,5-二叔丁基-4-羟基苄基)硫醚、2,5-二叔丁基对苯二酚、2,5-二叔戊基对苯二酚、3,5-二叔丁基-4-羟基苄基磷酸二(十八)酯、3,5-二叔丁基-4-羟基苄基磷酸二乙酯、辛基化苯酚、三甘醇双-3-(3-叔丁基-4-羟基-5-甲基苯基)丙酸酯、对苯二酚二苄醚中的至少一种。
作为本发明的一种优选方式,本发明中所述抗老剂为抗老剂264。
长碳链烷基改性松香酸
松香是松树分泌的黏稠液体经蒸馏而得到的一种天然树脂,主要成分为树脂酸,分子式为C19H29COOH,分子量为302.4,软化点70-80℃,熔点95-135℃,不溶于水,在热水中部分乳化,在汽油、煤油中的溶解性较差,但易溶于乙醇、丙酮、***、氯仿、四氯化碳等有机溶剂。松香按来源可分为三种类型:即脂松香、木松香和浮油(妥尔油)松香。枞酸是松香树脂酸的典型代表,由一个极性羧基和一个由碳氢元素组成的三元环组成,具有两个化学反应中心-羧基与双键,具备了双键和羧基的一般反应特性,具有酯化、歧化、氨解、加成、成盐、氢化、聚合、脱羧等反应。松香酸分子是一个典型的两性分子。
本发明中,长碳链烷基改性松香酸为碳原子数为C3-C15的长碳链烷基改性松香酸。
作为本发明的一种实施方式,所述长碳链烷基上有极性基团。
作为本发明的一种实施方式,所述极性基团选自羟基、羧基或磺酸基中的一种。
所述极性基团为羧基时,所述长碳链烷基改性松香酸的制备方法如下:将6-氨基己酸和松香酸按照重量比溶解在DMSO(二甲基亚砜)中,加入EDCI(碳化二亚胺)和HOBT(1-羟基苯并***),室温下搅拌2小时,将产物用水洗涤三次,EA萃取,即可制备得到长碳链烷基改性松香酸。
本发明中,所述长碳链烷基改性松香酸的重量份为0.1-3份。
本发明的第二方面提供所述CCB高密封防水涂料的制备工艺:
1、原料处理:将沥青改性剂、3,4-乙烯二氧噻吩和抗老剂在172℃下搅拌2.4小时;
2、皂液制备:将水加热至65℃下加入乳化剂进行搅拌至完全溶解;
3、防水涂料制备:将石油沥青和沥青改性剂在160-180℃下搅拌1-3小时后,得到混合物A,将混合物A与皂液共混并一同研磨,得到混合物B;随后启动乳化机进行深度乳化,加入防腐剂等助剂进行充分搅拌,即可制备得到。
上述步骤2中可以依需要加入功能性助剂,例如增稠剂、增强剂等。
本发明的第三方面提供所述CCB高密封防水涂料应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理等领域。
本发明提供的高密封防水涂料可适用于广东鼎新高新科技股份有限公司CCB系列产品的密封防水处理。
CCB是指化学反应(Chemical modification)和改性化学反应粘结(ChemicalBonding)的简称。
作为本发明的一种实施方式,本发明中所述CCB高密封防水涂料的制备原料还包含c5石油树脂,购买于上海宝钢化工有限公司。
机理解释:本发明提供的CCB高密封防水涂料可应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理等领域,具有优异的防水和密封效果,特别适合低温密封效果。其可能的原因是因为3,4-乙烯二氧噻吩在聚合后形成的分子链中含有噻吩环,噻吩上的硫原子半径较大,会增加芳香环上的电子云密度,使成膜后的分子链之间的相互作用更紧密,提高了致密性;同时长碳链烷基改性松香酸弥补了期间的空隙,增加了致密性;同时超支化硅烷偶联剂的加入,特别得提高了所述防水涂料在低温下的防水密封效果。
实施方式1:本实施方式提供一种CCB高密封防水涂料,按重量份计,其制备原料包含:
实施方式2:实施方式1所述的CCB高密封防水涂料,所述沥青乳化剂选自季铵盐类沥青乳化剂、木质胺类沥青乳化剂、酰胺基多胺类沥青乳化剂、咪唑啉类沥青乳化剂、烷基酚聚氧乙烯醚沥青乳化剂、烷基酚与环氧乙烷缩合物沥青乳化剂中的一种或多种。
实施方式3:实施方式1所述的CCB高密封防水涂料,所述沥青乳化剂为季铵盐类沥青乳化剂、酰胺基多胺类沥青乳化剂、烷基酚聚氧乙烯醚沥青乳化剂中的一种或多种。
实施方式4:实施方式1所述的CCB高密封防水涂料,所述超支化硅烷偶联剂由硅烷偶联剂和超支化硅氧烷制备得到。
实施方式5:实施方式1所述的CCB高密封防水涂料,所述增稠剂选自纤维素醚及其衍生物、碱溶胀型增稠剂、碱溶性增稠剂、聚氨酯增稠剂、疏水改性非聚氨酯增稠剂、无机增稠剂、络合型有机金属化合物类增稠剂、聚丙烯酰胺、聚丙烯酸钠、海藻酸钠中的一种或者一种以上的混合物。
实施方式6:实施方式1所述的CCB高密封防水涂料,所述增强剂选自白炭黑、二氧化钛、重钙粉、沉淀硫酸钡、高岭土、聚丙烯纤维、玻璃纤维、滑石粉、胺类化合物、玄武岩、辉绿岩、石灰岩中的一种或者一种以上的混合物。
实施方式7:实施方式1所述的CCB高密封防水涂料,所述制备原料还包含:长碳链烷基改性松香酸。
实施方式8:实施方式7所述的CCB高密封防水涂料,所述长碳链烷基改性松香酸的长碳链烷基上有极性基团。
实施方式9:实施方式8所述的CCB高密封防水涂料,所述极性基团选自羟基、羧基或磺酸基中的一种。
实施方式10:实施方式1-9任一项所述的CCB高密封防水涂料,其应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理领域。
下面通过实施例对本发明进行具体描述。有必要在此指出的是,以下实施例只用于对本发明作进一步说明,不能理解为对本发明保护范围的限制,该领域的专业技术人员根据上述本发明的内容做出的一些非本质的改进和调整,仍属于本发明的保护范围。
另外,如果没有其它说明,所用原料都是市售的,且以下物料所用份数均为重量份。
实施例1:本实施例提供一种CCB高密封防水涂料,按重量份计,其制备原料包含:
所述石油沥青为90号沥青;所述沥青乳化剂为十六烷基三甲基溴化、十八烷基三甲基溴化铵和十九烷基三甲基溴化铵按照重量比为1:0.3:0.7共混。
所述超支化硅烷偶联剂为甲基乙烯基二甲氧基硅烷和超支化硅氧烷反应得到,所述超支化硅氧烷由1,10-癸二胺、2-(3,4-环氧环己烷)乙基三甲氧基硅烷和烯丙基三甲氧基硅烷制备得到。
所述超支化硅氧烷的制备步骤如下:将0.2重量份的二胺和0.4重量份的含有环氧基团的硅烷溶于甲苯中,在氮气气氛,碱性环境下(NaOH溶液),80℃反应6小时,随后将剩余的含有环氧基团的硅烷和含有碳碳双键的硅烷投入,在氮气气氛下,60℃反应4小时,即可制备得到所述超支化硅氧烷。
所述超支化硅烷偶联剂的制备方法如下:将超支化硅氧烷和硅烷偶联剂溶解于甲苯中,在氮气气氛下,60℃下反应4小时,即可制备得到超支化硅烷偶联剂。
所述硅烷偶联剂和超支化硅氧烷的重量比为1:2.5。
3,4-乙烯二氧噻吩,CAS号126213-50-1。
沥青改性剂为苯乙烯-丁二烯-苯乙烯共聚物。
抗老剂为抗老剂264(抗氧剂1010)。
增稠剂为聚丙烯酰胺、聚丙烯酸钠、按照重量比为1:1共混。
增强剂为聚丙烯纤维、玻璃纤维、滑石粉按照重量比为1:1:1共混。
长碳链烷基改性松香酸为:将6-氨基己酸和松香酸按照重量比溶解在DMSO(二甲基亚砜)中,加入EDCI(碳化二亚胺)和HOBT(1-羟基苯并***),室温下搅拌2小时,将产物用水洗涤三次,EA萃取,即可制备得到长碳链烷基改性松香酸。
6-氨基己酸和松香酸的重量比4:5。
所述CCB高密封防水涂料的制备步骤:
1、原料处理:将沥青改性剂、3,4-乙烯二氧噻吩和抗老剂在172℃下搅拌2.4小时;
2、皂液制备:将水加热至65℃下加入乳化剂进行搅拌至完全溶解,加入增稠剂、增强剂等功能性助剂;
3、防水涂料制备:将石油沥青和沥青改性剂在180℃下搅拌2小时后,得到混合物A,将混合物A与皂液共混并一同研磨,得到混合物B;随后启动乳化机进行深度乳化,加入防腐剂等助剂进行充分搅拌,即可制备得到。
实施例2:与实施例1的区别在于,制备原料无3,4-乙烯二氧噻吩。
实施例3:与实施例1的区别在于,所述3,4-乙烯二氧噻吩的重量份为2份。
实施例4:与实施例1的区别在于,制备原料无长碳链烷基改性松香酸。
实施例5:与实施例1的区别在于,所述长碳链烷基无极性基团。
实施例6:与实施例1的区别在于,长碳链烷基改性松香酸的重量份为
实施例7:与实施例1的区别在于,所述长碳链烷基的碳原子数为2。
实施例8:与实施例1的区别在于,所述超支化硅烷偶联剂替换为甲基乙烯基二甲氧基硅烷。
实施例9:与实施例1的区别在于,无超支化硅烷偶联剂。
实施例10:与实施例1的区别在于,所述硅烷偶联剂和超支化硅氧烷的重量比为1:5。
实施例11:与实施例1的区别在于,所述制备原料包含1重量份的C5石油树脂,(购买于上海宝钢化工有限公司)。
施工过程:对地下室等节点处进行施工,将节点部位的垃圾、浮浆、粉尘等清理干净,防水涂料涂刷于节点部位,待干燥后进行观察测试。
测试:
前述的实例仅是说明性的,用于解释本公开的特征的一些特征。所附的权利要求旨在要求可以设想的尽可能广的范围,且本文所呈现的实施例仅是根据所有可能的实施例的组合的选择的实施方式的说明。因此,申请人的用意是所附的权利要求不被说明本发明的特征的示例的选择限制。而且在科技上的进步将形成由于语言表达的不准确的原因而未被目前考虑的可能的等同物或子替换,且这些变化也应在可能的情况下被解释为被所附的权利要求覆盖。
Claims (2)
1.一种CCB高密封防水涂料,其特征在于,按重量份计,其制备原料包含:
其中,所述沥青乳化剂为十六烷基三甲基溴化、十八烷基三甲基溴化铵和十九烷基三甲基溴化铵按照重量比为1:0.3:0.7共混;
所述超支化硅烷偶联剂为甲基乙烯基二甲氧基硅烷和超支化硅氧烷反应得到,所述超支化硅氧烷由1,10-癸二胺、2-(3,4-环氧环己烷)乙基三甲氧基硅烷和烯丙基三甲氧基硅烷制备得到;且所述甲基乙烯基二甲氧基硅烷和超支化硅氧烷的重量比为1:2.5;
所述增稠剂为重量比为1:1的聚丙烯酰胺和聚丙烯酸钠的混合物;
所述增强剂为重量比为1:1:1的聚丙烯纤维、玻璃纤维、滑石粉的混合物;
所述长碳链烷基改性松香酸的长碳链烷基上有极性基团,且所述极性基团选自羟基、羧基或磺酸基中的一种。
2.权利要求1所述的CCB高密封防水涂料,其应用于地下室防水处理、管材钢筋等接头处理、下水道管材的密封处理、卷材的密封处理领域。
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