CN106752141A - Waterborne conductive anticorrosive paint - Google Patents

Waterborne conductive anticorrosive paint Download PDF

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Publication number
CN106752141A
CN106752141A CN201611154411.1A CN201611154411A CN106752141A CN 106752141 A CN106752141 A CN 106752141A CN 201611154411 A CN201611154411 A CN 201611154411A CN 106752141 A CN106752141 A CN 106752141A
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parts
liquid
natural minerals
waterborne
macromolecule
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CN201611154411.1A
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曾华
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BEIJING ADVANCED DEVELOP Co Ltd
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BEIJING ADVANCED DEVELOP Co Ltd
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Priority to CN201611154411.1A priority Critical patent/CN106752141A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of waterborne conductive anticorrosive paint, belongs to coating products field.The coating includes liquid component and solid constituent;The liquid component and solid constituent separate storage, mix when using the coating;The liquid component includes the raw material of following weight portion:1 15 parts of waterborne curing agents, 0 15 parts of liquid-state epoxy resins, 1 15 parts of natural minerals water-base cements, 1 15 parts of macromolecule adhesives;The solid constituent is 85 90 parts of conductor material granules.Coating products provided by the present invention except conductive energy, Corrosion Protection is double outstanding the characteristics of in addition to, also have the advantages that it is dry soon, adhesive force is strong, pliability is good, anti-corrosion treatment, easy to use, simple, the with low cost, excellent effect of making are carried out to metal using coating of the invention.

Description

Waterborne conductive anticorrosive paint
Technical field
The present invention relates to paint field, and in particular to a kind of waterborne conductive anticorrosive paint.
Background technology
Metal material can occur spontaneous corrosion process in use, and metal material and its product have nearly 1/ every year in the world 3 loss, so anticorrosive paint has important application.And in special dimensions such as some electric power transports, on the one hand require metal material Material has outside Anticorrosive Character, while also needing to keep the conductive characteristic of material.Conductive anti-corrosion coating is that recent decades grow up, Various material surfaces can be covered in, it is possessed the function new material such as conduction, anti-corrosion.The common conductive anti-corrosion coating in this area Have:Application for a patent for invention 201410024171.8 provide a kind of corrosion-resistant conductive coating, it include according to mass fraction meter as Lower raw material:Polyurethane resin 5-10 parts, epoxy resin 25-30 parts, acrylic resin 4-6 parts, graphite powder 20-25 parts, silicon powder 8-12 parts, polyvinylpyrrolidone 10-12 parts, sodium acid carbonate 5-10 parts, n-butanol 25-28 parts, isopropanol 10-14 parts, water 48- 50 parts.Application for a patent for invention 201410346045.4 then discloses a kind of nano anti-corrosion conductive coating, is characterized in, by weight Meter includes:5-20 parts of nano-carbon powder filler, epoxy resin-base 10-50 parts, nano magnetic iron oxide 10-20 parts, inert diluents Agent 10-40 parts, curing agent 10-50 parts, silane coupler 1-5 parts.The conduction that application for a patent for invention 201510948036.7 is provided Anticorrosive paint, including following percetage by weight composition:Matrix resin 15-18%, diluent 30-50%, curing agent 8-10%, Auxiliary agent 0.1-0.2%, conductive filler 3-5%;Wherein, described matrix resin is the mixed of epoxy resin KD-175 and acrylic resin Compound, the diluent is the mixture of dimethylbenzene, n-butanol and polyethylene glycol, and the curing agent is cashew nut modified polyamide 750, the auxiliary agent is dodecyl sodium sulfate, and the conductive filler is CNT and polyaniline mixture.
In electric lightening protection engineering field, common grounding body typically uses Hot-dip zinc-coated flat steel sheet, round steel or angle steel.Zinc-plating material with And the antiseptic property of the above-mentioned conventional corrosion-resistant conductive coating in this area is in the application on ground, its anti-corrosion, anti-corrosion its effect is good 's.But then hardly possible has good antisepsis in the environment of underground humidity, even water ooze bubble.
Therefore, this area exploitation one kind of still needing still can keep good antiseptic property in, immersion environment moist in underground Coating material.
The content of the invention
Above-mentioned not enough and demand based on this area, i.e. still lacking one kind can still can in, immersion environment moist in underground The coating products of good antiseptic property are kept, the present invention provides a kind of conductive anti-corrosion coating, can be anti-as the ideal of grounded metal Rotten electrically-conducting paint, in can be widely applied to various soil environments.
Technical scheme is as follows:
A kind of waterborne conductive anticorrosive paint, it is characterised in that including liquid component and solid constituent;The liquid component and Solid constituent separates storage, mixes when using the coating;
The liquid component includes the raw material of following weight portion:1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule adhesive;
The solid constituent is 85-90 parts of conductor material granule.
The waterborne conductive anticorrosive paint includes the raw material of following weight portion:
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 1 part of macromolecule adhesive, 85 parts of conductor material granules;
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of macromolecule adhesives, 90 parts of conductor material granules;
1 part of waterborne curing agent, 15 parts of natural minerals water-base cements, 1 part of macromolecule adhesive, 90 parts of conductor material granules;
7 parts of waterborne curing agents, 8 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 88 parts of conductor material granules;
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 1 part of macromolecule adhesive, 85 parts Conductor material granule;
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 90 parts of conductor material granules;
15 parts of waterborne curing agents, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 85 Part conductor material granule;
3 parts of waterborne curing agents, 6 parts of liquid-state epoxy resins, 2 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 87 parts Conductor material granule;
7 parts of waterborne curing agents, 4 parts of liquid-state epoxy resins, 11 parts of natural minerals water-base cements, 8 parts of macromolecule adhesives, 89 parts Conductor material granule;
14 parts of waterborne curing agents, 8 parts of liquid-state epoxy resins, 4 parts of natural minerals water-base cements, 12 parts of macromolecule adhesives, 86 Part conductor material granule;
5 parts of waterborne curing agents, 12 parts of liquid-state epoxy resins, 8 parts of natural minerals water-base cements, 2 parts of macromolecule adhesives, 88 parts Conductor material granule;
9 parts of waterborne curing agents, 3 parts of liquid-state epoxy resins, 14 parts of natural minerals water-base cements, 4 parts of macromolecule adhesives, 85 parts Conductor material granule;
2 parts of waterborne curing agents, 7 parts of liquid-state epoxy resins, 12 parts of natural minerals water-base cements, 5 parts of macromolecule adhesives, 85 parts Conductor material granule;
13 parts of waterborne curing agents, 10 parts of liquid-state epoxy resins, 5 parts of natural minerals water-base cements, 14 parts of macromolecule adhesives, 87 Part conductor material granule;
8 parts of waterborne curing agents, 9 parts of liquid-state epoxy resins, 10 parts of natural minerals water-base cements, 7 parts of macromolecule adhesives, 89 parts Conductor material granule;
11 parts of waterborne curing agents, 13 parts of liquid-state epoxy resins, 3 parts of natural minerals water-base cements, 6 parts of macromolecule adhesives, 90 Part conductor material granule;
10 parts of waterborne curing agents, 11 parts of liquid-state epoxy resins, 6 parts of natural minerals water-base cements, 3 parts of macromolecule adhesives, 86 Part conductor material granule;Or
6 parts of waterborne curing agents, 5 parts of liquid-state epoxy resins, 9 parts of natural minerals water-base cements, 13 parts of macromolecule adhesives, 88 parts Conductor material granule.
The waterborne curing agent is selected from:Closed isocyanate crosslinker, or, modified amine epoxy curing agent.
The natural minerals water-base cement refers to sodium metasilicate.
The macromolecule adhesive is selected from:Paste, fish glue or epoxy glue.
The conductor material granule is selected from nonmetal conductor material particle or metallic particles;
The nonmetal conductor material particle is selected from:The group being made up of graphite powder, bentonite, silica flour and carbon dust;
The metallic particles include copper powder, glass putty, and/or, stainless steel powder.
A kind of preparation method of waterborne conductive anticorrosive paint, it is characterised in that including:Prepare liquid component:The liquid Component includes the raw material of following weight parts:1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural ore deposit Thing water-base cement, 1-15 part of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule;
The liquid component and solid constituent separate storage.
The application method of the waterborne conductive anticorrosive paint, it is characterised in that mix the liquid component and solid constituent Close, the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh.
A kind of method for preventing metal erosion, it is characterised in that use the waterborne conductive anticorrosive paint, and/or it is described The coating that preparation method is prepared, after the liquid component and solid constituent are mixed, coats or brushes to the metal Surface;Or,
Using the application method, the coating is coated or brushed to the metallic surface;Or,
By 1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals water-base cement, 1-15 parts of high score Sub- adhesive, 85-90 part of conductor material granule, after mixing, coats or brushes to the metallic surface.
Application of the waterborne conductive anticorrosive paint in terms of earthing material is processed.
The present invention provides a kind of waterborne conductive anticorrosive paint, including following raw material:1-15 parts of waterborne curing agent, 0- 15 parts of liquid-state epoxy resins, 1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule adhesive, 85-90 parts of conductor material granules. In above-mentioned raw materials, waterborne curing agent, liquid-state epoxy resin, natural minerals water-base cement, macromolecule adhesive belong to the coating Liquid portion, and conductor material granule is the solid portion of the coating, two parts are in the mistake for being stored as coating products, transport Cheng Zhong, is to separate storage;Only when using coating products of the invention, just two parts are mixed and/or ground.
In the waterborne conductive anticorrosive paint that any embodiment of the present invention is provided, the content of each raw material components can take above-mentioned institute Any value in the range of columns value, specifically, the components by weight percent of waterborne curing agent can be 1,2,3 ..., 7,8,9, 10th ..., 13,14,15 parts;The components by weight percent of liquid-state epoxy resin can be 0,1,2,3 ..., 7,8,9,10 ..., 13, 14th, 15 parts;The components by weight percent of natural minerals water-base cement can with 1,2,3 ..., 7,8,9,10 ..., 13,14,15 parts;High score The components by weight percent of sub- adhesive can be 1,2,3 ..., 7,8,9,10 ..., 13,14,15 parts;The weight of macromolecule adhesive Amount component can be 85,86,87,88,89,90 parts;Each weight portion corresponding to any one group is each in above-mentioned these numerical points of selection Raw material, the coating obtained by mixing can realize the aqueous quick-drying of coating of the present invention, conductive corrosion-resistant effect.
In some preferred embodiments of the invention, the waterborne curing agent is selected from:Closed isocyanate crosslinker, Or, modified amine epoxy curing agent.Waterborne curing agent has the advantages that viscosity is low, of light color, solidfied material good toughness, low temperature It is moist without white birch, color inhibition, it is complete without pasta, low-temperature setting.Impact resistance is good, is particularly well-suited to water paint, while can make It is adhesion promoters and crosslinking agent, improves adhesive strength, water proofing property, wearability, scrub resistance, scratch resistance and resistance toization of coating Learn moral character.
The Main Function of the liquid-state epoxy resin is auxiliary bonding, filling and solidifies.
In some specific embodiments, the natural minerals water-base cement is sodium metasilicate, preferably liquid sodium silicate, also may be used Being the liquid form of sodium silicate solid.Liquid sodium silicate is colourless, slightly colored transparent or semitransparent viscous liquid.Solid Sodium metasilicate is colourless, slightly colored transparent or semitransparent glass blocks.Can directly buy;The natural minerals water-base cement master Be used to bonding, fill etc..
In other embodiments of the invention, the macromolecule adhesive is selected from:Paste, fish glue, or, epoxy glue.Institute State macromolecule adhesive and refer to a class adhesive material based on macromolecular compound, also referred to as polymer binder or macromolecule glues Knot agent, it has high intensity, high temperature resistant, high-durability, low toxicity and easy, with low cost etc. many benefits of technique.
In some specific embodiments of the invention, the conductor material granule is nonmetal conductor material particle or gold Metal particles;
The nonmetal conductor material particle is selected from one or more in graphite powder, bentonite, silica flour and carbon dust;
The preferably not oxidizable metallic of the metallic particles, including copper powder, glass putty, and/or, stainless steel powder.
The Main Function that conductor material granule is added in waterborne conductive anticorrosive paint of the present invention is to ensure coating The long-term conductive effect of product.The product that coating can as needed be coated is different, and products application environment is different, and selection addition is non- Metal Conductor Particles or not oxidizable metallic increase its conductive capability.
Some other embodiment of the invention additionally provides a kind of preparation method of waterborne conductive anticorrosive paint, including:Will Following weight parts raw material mixes:1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals are aqueous Glue, 1-15 part of producing high-molecular rubber alloy, 85-90 parts of conductor material granule.
Preferably, the preparation method also includes, by the raw material mix obtained by mixture grind repeatedly, make lapping degree Reach 50 mesh to 3000 mesh, the benefit of grinding is to make mixture uniform level higher, formed evenly, the more preferable coating of effect Product.
The present invention is also claimed a kind of method for preventing metal erosion, it is characterised in that use the coating and/or institute State the coating coating metal surface that preparation method is prepared.
The present invention is also claimed application of the described conductive anti-corrosion coating in terms of earthing material is processed.
In the raw material that coating of the invention is used, the curing agent of use, adhesive are aqueous feature, so as to cause this The there is provided coating of invention has the advantages that to do soon, and after tested, surface drying time is less than 1 hour, is parched under normal temperature environment Time is between 4-6 hours.Additionally, the coating of the invention obtained using the raw material of above-mentioned formula, through salt tolerant, acid proof test, Come off without foaming, nothing in 720 hours, nothing is got rusty;Detection is also carried out to its electric conductivity simultaneously, coating of the present invention is led Electrostrictive coefficient is in 1.57 × 104Ω to 3.21 × 105Ω.To sum up illustrate, coating of the present invention is except conductive energy, anti- Outside the characteristics of corrosive nature is double outstanding, also have the advantages that it is dry soon, adhesive force is strong, pliability is good, using coating of the invention Anti-corrosion treatment, easy to use, simple, the with low cost, excellent effect of making are carried out to metal.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, but is not intended to limit model of the invention Enclose.Unless otherwise specified, the operation for being used in following embodiments is conventional method, and the reagent for being used can be obtained with commercially available .
Embodiment 1-18,1-18 conductive anti-corrosion coatings of the present invention and its performance
Embodiment 1-18 provides various Ju Ti Pei Fangs of the conductive anti-corrosion coating in the scope of the present invention, and they are total to With the characteristics of be that antiseptic property and electric conductivity are double excellent.
In following Ju Ti Pei Fangs:Waterborne curing agent, liquid-state epoxy resin, natural minerals water-base cement, macromolecule adhesive category In the liquid portion of coating products of the present invention, and conductor material granule is the solid portion of coating products of the present invention.It is of the invention During transport, and/or storage, the liquid portion is to separate storage with solid portion to coating products;And using this When the coating of invention carries out the application in terms of anti-corrosion of metal conduction, for example, it is necessary to by the liquid portion before brushing or coating It is sufficiently mixed with solid portion and/or is ground.
Embodiment 19, the preparation method and application method of conductive anti-corrosion coating of the present invention
The present embodiment provides the preparation method of conductive anti-corrosion coating of the present invention, specifically includes following preparation process:
Prepare liquid component:The liquid component includes the raw material of following weight parts:1-15 parts of aqueous cyclammonium curing agent, 0- 15 parts of liquid-state epoxy resins, 1-15 parts of natural minerals water-base cement, 1-15 parts of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule;
The liquid component and solid constituent constitute coating products of the invention, but need to separate storage.
The present embodiment also provides the application method of conductive anti-corrosion coating of the present invention:Including, by the liquid component and Solid constituent mixes, and the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh, and the benefit of grinding is to make to mix Compound uniform level is higher, formed evenly, the more preferable coating products of effect.
In any of the above-described embodiment, the waterborne curing agent is selected from:Closed isocyanate crosslinker, or, modified amine Based epoxy resin curing agent.Have the advantages that viscosity is low, of light color, solidfied material good toughness, low temperature and moisture without white birch, color inhibition, It is complete without pasta, low-temperature setting.Impact resistance is good, is particularly well-suited to epoxy floor face and applies material.It is applied to aqueous acrylamide The water paint such as acid and polyurethane, as adhesion promoters and crosslinking agent.Improve the adhesive strength of coating, water proofing property, wearability, Scrub resistance, scratch resistance and chemical-resistant.
In certain embodiments, the natural minerals water-base cement is preferably the liquid of liquid sodium silicate or sodium silicate solid Body form.Liquid sodium silicate is colourless, slightly colored transparent or semitransparent viscous liquid.Sodium silicate solid is colourless, slightly The transparent or semitransparent glass blocks of color.Can directly buy;The natural minerals water-base cement is mainly used in bonding, fills Deng.
In some specific embodiments, the macromolecule adhesive is selected from:Paste, fish glue, or, epoxy glue.The height Molecule adhesive refers to the class adhesive material based on macromolecular compound, and also referred to as polymer binder or macromolecule is bonded Agent, it has high intensity, high temperature resistant, high-durability, low toxicity and easy, with low cost etc. many benefits of technique.
In certain embodiments, the conductor material granule is selected from nonmetal conductor material particle or metallic particles;
Preferably, the nonmetal conductor material particle is selected from the group being made up of graphite powder, bentonite, silica flour and carbon dust;
The preferably not oxidizable metallic of the metallic particles, such as but not limited to copper powder, glass putty, and/or, no Rust comminuted steel shot.
The Main Function that the conductor material granule is added in the coating that any of the above-described embodiment is provided is to ensure to apply Expect the long-term conductive effect of product.The product that coating can as needed be coated is different, and products application environment is different, selection addition Non-metal conductor particle or not oxidizable metallic increase its conductive capability.
In above-described embodiment, the waterborne conductive anticorrosive paint performance test methods are as follows:
The electric conductivity of waterborne conductive anticorrosive paint of the invention is according to GB/T1410-2006《Solid insulating material volume Resistivity and surface resistivity test method》Measure, No. 1-15 painting is can be seen that from the numerical value on the column of electrical conductivity one in upper table The electrical conductivity of material is in 1.57 × 104Ω to 3.21 × 105Ω, illustrates conductive anti-corrosion coating electric conductivity of the present invention It is excellent.
The antiseptic property of waterborne conductive anticorrosive paint of the invention is according to GB/T9274-1988《Paint and varnish resistant to liquid The measure of medium》Standard is measured, and in upper table, either salt tolerant or acidproof aspect, all possess good lasting corrosion resistance; Simultaneously in terms of salt spray resistance, the performance of above-mentioned 1-15 coating is:More than 300 hours non-foaming non-corrosives.
Except with excellent electric conductivity and antiseptic property, waterborne conductive anticorrosive paint provided by the present invention also has The advantage, surface drying such as simple are required in terms of technique for applying and construction technology:Less than 1 hour, 4-6 hours under normal temperature environment can be with Parch.
The attachment force data of conductive anti-corrosion coating is according to GB/T9286-1998 through experimental tests in above-described embodiment , adhesive force (drawing compartment away from 2mm) assay is 1 grade, and its adhesive force is excellent;
The pliability of waterborne conductive anticorrosive paint of the invention is according to GB/T 1731-93《Paint film flexibility determination method》 Measure, the pliability of paint film is represented with the minimum mandrel rod diameter for not causing paint film to destroy, measuring result is:1mm, illustrates the present invention Coating flexibility it is good.

Claims (10)

1. a kind of waterborne conductive anticorrosive paint, it is characterised in that including liquid component and solid constituent;The liquid component and solid Body component separates storage, mixes when using the coating;
The liquid component includes the raw material of following weight portion:1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 Part natural minerals water-base cement, 1-15 parts of macromolecule adhesive;
The solid constituent is 85-90 parts of conductor material granule.
2. waterborne conductive anticorrosive paint according to claim 1, it is characterised in that the raw material including following weight portion:
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 1 part of macromolecule adhesive, 85 parts of conductor material granules;
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of macromolecule adhesives, 90 parts of conductor material granules;
1 part of waterborne curing agent, 15 parts of natural minerals water-base cements, 1 part of macromolecule adhesive, 90 parts of conductor material granules;
7 parts of waterborne curing agents, 8 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 88 parts of conductor material granules;
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 1 part of macromolecule adhesive, 85 parts of conductors Material granule;
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 90 parts Conductor material granule;
15 parts of waterborne curing agents, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 85 parts lead Body material granule;
3 parts of waterborne curing agents, 6 parts of liquid-state epoxy resins, 2 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 87 parts of conductors Material granule;
7 parts of waterborne curing agents, 4 parts of liquid-state epoxy resins, 11 parts of natural minerals water-base cements, 8 parts of macromolecule adhesives, 89 parts of conductors Material granule;
14 parts of waterborne curing agents, 8 parts of liquid-state epoxy resins, 4 parts of natural minerals water-base cements, 12 parts of macromolecule adhesives, 86 parts lead Body material granule;
5 parts of waterborne curing agents, 12 parts of liquid-state epoxy resins, 8 parts of natural minerals water-base cements, 2 parts of macromolecule adhesives, 88 parts of conductors Material granule;
9 parts of waterborne curing agents, 3 parts of liquid-state epoxy resins, 14 parts of natural minerals water-base cements, 4 parts of macromolecule adhesives, 85 parts of conductors Material granule;
2 parts of waterborne curing agents, 7 parts of liquid-state epoxy resins, 12 parts of natural minerals water-base cements, 5 parts of macromolecule adhesives, 85 parts of conductors Material granule;
13 parts of waterborne curing agents, 10 parts of liquid-state epoxy resins, 5 parts of natural minerals water-base cements, 14 parts of macromolecule adhesives, 87 parts lead Body material granule;
8 parts of waterborne curing agents, 9 parts of liquid-state epoxy resins, 10 parts of natural minerals water-base cements, 7 parts of macromolecule adhesives, 89 parts of conductors Material granule;
11 parts of waterborne curing agents, 13 parts of liquid-state epoxy resins, 3 parts of natural minerals water-base cements, 6 parts of macromolecule adhesives, 90 parts lead Body material granule;
10 parts of waterborne curing agents, 11 parts of liquid-state epoxy resins, 6 parts of natural minerals water-base cements, 3 parts of macromolecule adhesives, 86 parts lead Body material granule;Or
6 parts of waterborne curing agents, 5 parts of liquid-state epoxy resins, 9 parts of natural minerals water-base cements, 13 parts of macromolecule adhesives, 88 parts of conductors Material granule.
3. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the waterborne curing agent is selected from:Envelope Closed form isocyanate crosslinking, or, modified amine epoxy curing agent.
4. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that natural minerals water-base cement refers to silicic acid Sodium.
5. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the macromolecule adhesive is selected from: Paste, fish glue or epoxy glue.
6. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the conductor material granule is selected from Nonmetal conductor material particle or metallic particles;
The nonmetal conductor material particle is selected from:The group being made up of graphite powder, bentonite, silica flour and carbon dust;
The metallic particles include copper powder, glass putty, and/or, stainless steel powder.
7. a kind of preparation method of waterborne conductive anticorrosive paint, it is characterised in that including:Prepare liquid component:The liquid group Dividing includes the raw material of following weight parts:1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals Water-base cement, 1-15 part of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule;
The liquid component and solid constituent separate storage.
8. the application method of any described coating of claim 1-6, it is characterised in that by the liquid component and solid constituent Mixing, the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh.
9. a kind of method for preventing metal erosion, it is characterised in that any described coating of usage right requirement 1-6, and/or power Profit requires the coating that the preparation method described in 7 is prepared, and after the liquid component and solid constituent are mixed, coats or brushes To the metallic surface;Or,
Using the application method described in claim 8, the coating is coated or brushed to the metallic surface;Or,
By 1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule glue Stick, 85-90 part of conductor material granule, after mixing, coats or brushes to the metallic surface.
10. application of the waterborne conductive anticorrosive paint described in claim 1- in terms of earthing material is processed.
CN201611154411.1A 2016-12-14 2016-12-14 Waterborne conductive anticorrosive paint Pending CN106752141A (en)

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CN113402961A (en) * 2021-06-10 2021-09-17 广州盛门新材料科技有限公司 Protective coating for zinc-plated material and preparation method and application thereof

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CN102417781A (en) * 2011-11-10 2012-04-18 武汉爱劳高科技有限责任公司 Earthed anticorrosive conductive paint and preparation process thereof
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CN103756514A (en) * 2014-01-17 2014-04-30 广州集泰化工有限公司 Waterborne two-component light-color in-tank electrostatic conduction anticorrosive paint and preparation method thereof
CN105038446A (en) * 2015-06-04 2015-11-11 上海电力学院 Water-based anticorrosive conducting paint and preparation method thereof
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US6479103B1 (en) * 1997-11-05 2002-11-12 Henkel Kommanditgesellschaft Auf Aktien Conductive organic coatings
WO2001051570A1 (en) * 2000-01-14 2001-07-19 Basf Coatings Ag Coating that contains a colloidally dispersed metallic bismuth
CN101508870A (en) * 2009-03-20 2009-08-19 武汉铁神化工有限公司 Electrostatic conductive anticorrosion paint and method of preparing the same
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CN113402961A (en) * 2021-06-10 2021-09-17 广州盛门新材料科技有限公司 Protective coating for zinc-plated material and preparation method and application thereof

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Application publication date: 20170531