CN106750898A - A kind of High impact resistance nanometer composite material - Google Patents
A kind of High impact resistance nanometer composite material Download PDFInfo
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Abstract
The present invention provides a kind of High impact resistance nanometer composite material, is related to technical field of polymer materials.High impact resistance nanometer composite material of the present invention includes following raw material：Polypropylene, clay, organic modifiers, kollag, oxidation nanometer carbon material, auxiliary agent, inorfil.High impact resistance nanometer composite material of the present invention has the premium properties such as high rigidity, high intensity, fracture toughness high and high temperature resistant.
Description
Technical field
The present invention relates to technical field of nano material, and in particular to a kind of High impact resistance nanometer composite material and preparation method thereof.
Background technology
Nano composite material is to develop very rapid frontier in material science in recent years.Nano composite material it is special
Function is mainly derived from the small-size effect and numerous Interface composites effects of particle, as long as with a small amount of nano particle by molten
Melt mixing or the mode of in-situ polymerization be added in polymer, can improve the mechanical performance of the polymer, barrier property and
Fire resistance.
Polypropylene because it has good processing characteristics and physics, chemical property be widely used in inner and outer decorative parts of automobile and
Electronics, shell of household appliances etc., are the most fast general-purpose thermoplastic plastics of current growth rate.But polypropylene also have rigidity it is low,
The shortcomings of poor heat resistance, big shrinkage factor, polyacrylic rigidity is generally improved using the method for addition glass fibre or talcum powder.
But the addition of glass can influence the increase of the moulding processability and surface quality of product, talcum powder also to increase polyacrylic close
Degree, so as to increase the weight of product parts.How on the basis of product weight is reduced as far as possible raising material as high as possible
The rigidity of material, as the modified field of Polymer Processing research direction more interested.
Nano material is added into polypropylene the inside in the prior art, nano composite material is formed.In general, it refers to dispersed phase
At least one-dimensional composite for being less than 100 nanometers of size.The specific function of nano composite material is mainly derived from the small of particle
Dimensional effect and numerous Interface composites effects, as long as with a small amount of nano particle by way of melting mixing or in-situ polymerization
It is added in polymer, mechanical performance, barrier property and the fire resistance of the polymer can be improved, but, prior art
In, difficulties in dispersion after a large amount of additions of Nano filling, obtained nano composite material bad mechanical property, anti-fight can not be high.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of High impact resistance nanometer composite material, solve in the prior art
Nano composite material bad mechanical property, the technical problem that anti-fight can not be high.
To realize object above, technical scheme is achieved by the following technical programs：
A kind of High impact resistance nanometer composite material, the High impact resistance nanometer composite material is made up of the raw material of following weight portion：
55~75 parts of polypropylene, 5~10 parts of clay, 3~7 parts of organic modifiers, 3~7 parts of kollag, oxidation nanometer carbon material 10
~15 parts, 2~4 parts of auxiliary agent, 2~4 parts of inorfil.
Preferably, the clay is inorganic clay.
Preferably, the inorganic clay be montmorillonite, saponite, hectorite, vermiculite, bentonite, nontronite, beidellite,
At least one in wolchonskoite, saponite, magadiite, kenyaite.
Preferably, the organic modifiers are many alkylammonium salts, many alkyl guanidine salts, many alkyl imidazole salt, many alkyl
At least one in benzoglioxaline salt, sulfonium salt.
Preferably, the kollag is layered solid material or inorganic compound.
Preferably, layered solid material is graphite；The inorganic compound is calcirm-fluoride or vulcanized lead.
Preferably, the inorfil is the one kind in glass fibre, carbon fiber, boron fibre, whisker, asbestos fibre.
Preferably, the oxidation nanometer carbon material is graphene oxide, oxide/carbon nanometer tube, oxidation gas-phase growth of carbon fibre
In at least one.
Preferably, the auxiliary agent is one or more in accelerator, diluent, toughener, compatilizer.
The present invention provides a kind of High impact resistance nanometer composite material, and advantage is compared with prior art：
High impact resistance nanometer composite material satisfactory mechanical property of the present invention, with high rigidity, high intensity, fracture toughness high and resistance to height
The premium properties such as temperature, anti-fight can be high, and High impact resistance nanometer composite material bending strength of the present invention can reach 270Mpa, bends
Modulus reaches 5.3Gpa, and compressive strength reaches 300Mpa；
High impact resistance nanometer composite material of the present invention passes through propylene, clay, organic modifiers, kollag, oxidation nanometer carbon
Material, auxiliary agent, the reasonable compounding of inorfil, it is ensured that material has high intensity, dimensionally stable, creep resistant is fatigue proof same
When, also possess excellent outward appearance.Additionally, its prices of raw materials for using is cheap, environmentally-friendly sanitary, it is suitable to industrialized production, can
Bring considerable economic benefit.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, with reference to the embodiment of the present invention pair
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making wound
The every other embodiment obtained under the premise of the property made work, belongs to the scope of protection of the invention.
Embodiment 1：
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：55 parts of polypropylene, 5 parts of clay, have
3 parts of machine modifying agent, 3 parts of kollag, 10 parts of oxidation nanometer carbon material, 2 parts of auxiliary agent, 2 parts of inorfil；
Wherein clay is montmorillonite；
Organic modifiers are many alkylammonium salts；
Kollag is graphite；
Inorfil is glass fibre；
Oxidation nanometer carbon material is graphene oxide；
Auxiliary agent is accelerator and toughener.
The preparation method of the present embodiment High impact resistance nanometer composite material, comprises the following steps：
S1, by the polypropylene of weight portion, clay, organic modifiers, kollag, oxidation nanometer carbon material, the inorganic fibre of auxiliary agent
Dimension is well mixed, obtains mixed material；
S2, by mixed material add double screw extruder in extruding pelletization, obtain final product acrylic resin, wherein double screw extruder spiral shell
Bar temperature is 260 DEG C, and screw speed is 150 r/min.
Embodiment 2
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：75 parts of polypropylene, 10 parts of clay, have
7 parts of machine modifying agent, 7 parts of kollag, 15 parts of oxidation nanometer carbon material, 4 parts of auxiliary agent, 4 parts of inorfil；
Wherein clay is that saponite, hectorite, vermiculite are mixed；
Organic modifiers are many alkylammonium salts, many alkyl guanidine salts, many alkyl imidazole salt are mixed；
Kollag is calcirm-fluoride；
Inorfil is boron fibre；
Oxidation nanometer carbon material is oxide/carbon nanometer tube；
Auxiliary agent is diluent, toughener, compatilizer.
The preparation method of the present embodiment High impact resistance nanometer composite material is with embodiment 1.
Embodiment 3
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：65 parts of polypropylene, 8 parts of clay, have
5 parts of machine modifying agent, 5 parts of kollag, 13 parts of oxidation nanometer carbon material, 3 parts of auxiliary agent, 3 parts of inorfil；
Wherein clay is that beidellite, wolchonskoite, saponite, magadiite are mixed；
Organic modifiers are many alkyl guanidine salts, many alkyl imidazole salt, polyalkylbenzene benzimidazole salt, sulfonium salt are mixed；
Kollag is vulcanized lead；
Inorfil is carbon fiber；
Oxidation nanometer carbon material is oxidation gas-phase growth of carbon fibre；
Auxiliary agent is accelerator, diluent, toughener.
The preparation method of the present embodiment High impact resistance nanometer composite material is with embodiment 1.
Embodiment 4
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：58 parts of polypropylene, 6 parts of clay, have
4 parts of machine modifying agent, 4 parts of kollag, 11 parts of oxidation nanometer carbon material, 2 parts of auxiliary agent, 4 parts of inorfil；
Wherein clay is that bentonite, nontronite, beidellite are mixed；
Organic modifiers are many alkyl guanidine salts；
Kollag is graphite；
Inorfil is whisker；
Oxidation nanometer carbon material is graphene oxide, oxide/carbon nanometer tube, oxidation gas-phase growth of carbon fibre are mixed；
Auxiliary agent is diluent, toughener, compatilizer.
The preparation method of the present embodiment High impact resistance nanometer composite material is with embodiment 1.
Embodiment 5
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：70 parts of polypropylene, 9 parts of clay, have
6 parts of machine modifying agent, 6 parts of kollag, 14 parts of oxidation nanometer carbon material, 4 parts of auxiliary agent, 3 parts of inorfil；
Wherein clay is nontronite；
Organic modifiers are sulfonium salt；
Kollag is calcirm-fluoride；
Inorfil is asbestos fibre；
Oxidation nanometer carbon material is oxide/carbon nanometer tube；
Auxiliary agent is accelerator and toughener.
The preparation method of the present embodiment High impact resistance nanometer composite material is with embodiment 1.
Embodiment 6
The present embodiment High impact resistance nanometer composite material is made up of the raw material of following weight portion：60 parts of polypropylene, 7 parts of clay, have
6 parts of machine modifying agent, 4 parts of kollag, 13 parts of oxidation nanometer carbon material, 3 parts of auxiliary agent, 4 parts of inorfil；
Wherein clay is montmorillonite；
Organic modifiers are many alkylammonium salts；
Kollag is graphite；
Inorfil is glass fibre；
Oxidation nanometer carbon material is graphene oxide；
Auxiliary agent is accelerator and toughener.
The preparation method of the present embodiment High impact resistance nanometer composite material is with embodiment 1.
In sum, High impact resistance nanometer composite material satisfactory mechanical property of the present invention, with high rigidity, high intensity, height
The premium properties such as fracture toughness and high temperature resistant, anti-fight can be high, and High impact resistance nanometer composite material bending strength of the present invention can
270Mpa is reached, bending modulus reaches 5.3Gpa, and compressive strength reaches 300Mpa；
High impact resistance nanometer composite material of the present invention passes through propylene, clay, organic modifiers, kollag, oxidation nanometer carbon
Material, auxiliary agent, the reasonable compounding of inorfil, it is ensured that material has high intensity, dimensionally stable, creep resistant is fatigue proof same
When, also possess excellent outward appearance.Additionally, its prices of raw materials for using is cheap, environmentally-friendly sanitary, it is suitable to industrialized production, can
Bring considerable economic benefit.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although ginseng
The present invention has been described in detail according to previous embodiment, it will be understood by those within the art that：It still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent is carried out to which part technical characteristic；And
These modifications are replaced, and do not make the spirit and model of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution
Enclose.
Claims (9)
1. a kind of High impact resistance nanometer composite material, it is characterised in that the High impact resistance nanometer composite material is by following weight
The raw material of part is made：55~75 parts of polypropylene, 5~10 parts of clay, 3~7 parts of organic modifiers, 3~7 parts of kollag, oxygen
Change 10~15 parts of nano-carbon material, 2~4 parts of auxiliary agent, 2~4 parts of inorfil.
2. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The clay is inorganic clay.
3. the High impact resistance nanometer composite material stated according to claim 2, it is characterised in that：The inorganic clay be montmorillonite,
In saponite, hectorite, vermiculite, bentonite, nontronite, beidellite, wolchonskoite, saponite, magadiite, kenyaite
It is at least one.
4. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The organic modifiers are many alkane
At least one in base ammonium salt, many alkyl guanidine salts, many alkyl imidazole salt, polyalkylbenzene benzimidazole salt, sulfonium salt.
5. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The kollag is stratiform
Solid material or inorganic compound.
6. High impact resistance nanometer composite material according to claim 5, it is characterised in that：Layered solid material is stone
Ink；The inorganic compound is calcirm-fluoride or vulcanized lead.
7. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The inorfil is glass fibers
One kind in dimension, carbon fiber, boron fibre, whisker, asbestos fibre.
8. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The oxidation nanometer carbon material is
At least one in graphene oxide, oxide/carbon nanometer tube, oxidation gas-phase growth of carbon fibre.
9. High impact resistance nanometer composite material according to claim 1, it is characterised in that：The auxiliary agent is accelerator, dilute
Release one or more in agent, toughener, compatilizer.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113247915A (en) * | 2021-06-08 | 2021-08-13 | 哈尔滨工程大学 | Method for preparing two-dimensional magadiite/graphene oxide nanosheet compound by using long-carbon-chain imidazole induction |
| CN113277591A (en) * | 2021-06-08 | 2021-08-20 | 哈尔滨工程大学 | Method for removing heavy metal ions in water by using magadiite/graphene oxide nanosheet compound |
| CN114621526A (en) * | 2022-03-18 | 2022-06-14 | 金华职业技术学院 | Environment-friendly polypropylene composite material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101111550A (en) * | 2004-12-01 | 2008-01-23 | 通用电气公司 | Nanocomposites comprising telechelic polyesters and organoclays |
| CN102884112A (en) * | 2010-05-04 | 2013-01-16 | 沙伯基础创新塑料知识产权有限公司 | Method of incorporating an additive into a polymer composition and dispersion used therein |
-
2016
- 2016-11-28 CN CN201611059965.3A patent/CN106750898A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101111550A (en) * | 2004-12-01 | 2008-01-23 | 通用电气公司 | Nanocomposites comprising telechelic polyesters and organoclays |
| CN102884112A (en) * | 2010-05-04 | 2013-01-16 | 沙伯基础创新塑料知识产权有限公司 | Method of incorporating an additive into a polymer composition and dispersion used therein |
Non-Patent Citations (2)
| Title |
|---|
| 王国全: "《聚合物共混改性原理与应用》", 30 January 2007, 中国轻工业出版社 * |
| 米特: "《耐热阻燃聚合物纳米复合材料》", 30 June 2015, 国防工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113247915A (en) * | 2021-06-08 | 2021-08-13 | 哈尔滨工程大学 | Method for preparing two-dimensional magadiite/graphene oxide nanosheet compound by using long-carbon-chain imidazole induction |
| CN113277591A (en) * | 2021-06-08 | 2021-08-20 | 哈尔滨工程大学 | Method for removing heavy metal ions in water by using magadiite/graphene oxide nanosheet compound |
| CN113277591B (en) * | 2021-06-08 | 2022-06-17 | 哈尔滨工程大学 | Preparation method of two-dimensional magadiite/graphene oxide nanosheet composite |
| CN113247915B (en) * | 2021-06-08 | 2022-07-29 | 哈尔滨工程大学 | Method for preparing two-dimensional magadiite/graphene oxide nanosheet compound by using long-carbon-chain imidazole induction |
| CN114621526A (en) * | 2022-03-18 | 2022-06-14 | 金华职业技术学院 | Environment-friendly polypropylene composite material and preparation method thereof |
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Application publication date: 20170531 |