CN106746786B - A kind of clinker and its method for calcinating calcined using rice husk as crude fuel - Google Patents
A kind of clinker and its method for calcinating calcined using rice husk as crude fuel Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/44—Burning; Melting
- C04B7/4407—Treatment or selection of the fuel therefor, e.g. use of hazardous waste as secondary fuel ; Use of particular energy sources, e.g. waste hot gases from other processes
- C04B7/4423—Waste or refuse used as fuel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
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- Solid Fuels And Fuel-Associated Substances (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A kind of clinker and its method for calcinating calcined using rice husk as crude fuel of the present invention, clinker includes raw material and fuel, and raw material includes: 79.8~85.7 parts of lime stone, 1.9~3.1 parts of sandstone, 4.7~3.9 parts of gangue, 5.3~5.5 parts of iron ore mine, 8.3~1.8 parts of rice husk;Fuel includes: 4.5~8.1 parts of coal, 9.0~1.8 parts of rice husk.Its preparation method are as follows: after taking lime stone, sandstone, gangue and iron ore mine, grinding to be homogenized, be mixed into raw material powder;Raw material powder thermally decomposes in advance, and rice husk is added;Coal is handled, and is added after decomposing in raw material, is sintered into calcination of chamotte, is cooled into the clinker calcined using rice husk as crude fuel.Rice husk is used as crude fuel calcining cement in the present invention, and using existing cement plant production equipment, rice husk is decomposing fire door addition; clinker up to standard can be calcined out, reduces mineral resources usage amount, and reduce rice husk discarding amount; it economizes on resources, reduce CO2 emission, play the role of protecting environment.
Description
Technical field:
The invention belongs to field of material technology, and in particular to a kind of clinker calcined using rice husk as crude fuel and its forge
Firing method.
Background technique:
As the cement of one of the big basic material of building industry three, yield also with construction industry development and constantly increase
It is long.Cement industry is resource and energy consumption type industry, and cement is to add proper amount of gypsum by clinker, also plus is in right amount mixed sometimes
Material it is common it is levigate made of, the main crude fuel of clinker production is lime stone, siliceous raw material (such as clay) and coal, this
It is all a bit non-renewable natural mineral resource.
Resource and environment are the two principal themes of human development, and the mankind need to reduce resource consumption, protection environment, preserve our planet.
Building material industry is high energy consumption, the industry of maximum discharge as national economy important foundation.Wherein, cement industry is resource consumption
One of the rich and influential family that huge, greenhouse gas emission severely exceeds.Therefore new material, new technique are found to reduce cement industry pair
The consumption of resource and the pollution of environment are imperative.
Rice husk is that rice is processed into remaining principal by product after rice, and rice husk accounts for about the 20% of paddy kernel weight.Often
At 200,000,000 tons or so, the amount for generating rice husk is about 40,000,000 tons for year China's rice yield.
The nutriments such as the crude protein, the crude fat that contain in rice husk are very few, both can not provide energy or nothing to animal
Method provides protein, but also contains a large amount of plant fiber, is directly fed for animal, animal is difficult to digest, to cause stomach
Discomfort, therefore rice husk can not be used as the main raw material of animal feed.In rural area, the conventional process mode of rice husk is not separate rice husk
And straw, it mixture is dried to be placed in burner hearth carries out burning as fuel and is used to heat up water and cooks or burn a heatable brick bed, burn surplus ashes
It then may be used as the adsorbent of human and animal excreta, be finally also used as fertilizer and return to field, but when rice husk total amount is more, this
Kind way is just no longer applicable.Directly it can bury or burn in field when usually rice husk total amount is more, combusting rice hull can generate
CO2, and burn the rice hull ash generated and can raise and drifted to surrounding with the wind, thus this way not only occupy land resource but also
Environment is also polluted, environmental pressure is caused, currently, China handles rubbish, it is per ton to need 50~150 yuan of cost.
With the progress of science and technology, people gradually recognize the potential value of rice husk, and rice husk power generating is exactly example, 2t's
Rice husk can produce the heat for being equivalent to 1t standard coal, and the rice husk of 2~3kg can generate electricity 1kWh, but rice husk power generating can generate powder
Coal ash needs to make secondary treatment.Even if a small amount of rice husk is used as power generation, the utilization rate of rice husk is still very low, can not also eliminate rice husk
To immense pressure caused by environment.
Summary of the invention:
In view of the deficienciess of the prior art, the present invention provide a kind of clinker calcined using rice husk as crude fuel and its
Method for calcinating.The invention using rice husk as production Portland clinker one of raw material, substitution part of clay matter raw material and
Part coal, calcination of cement clinker can not only reduce the usage amount of mineral resources, but also can reduce the rice husk directly burned
Amount, so that the discharge for the carbon dioxide that economizes on resources, reduces, plays the role of protecting environment.Moreover, rice husk is used for manufacture of cement,
It will not be directly becoming clinker as generating the secondary wastes objects such as flying dust for generating electricity, primary environmental protection is in place.
To achieve the above object, the invention adopts the following technical scheme:
A kind of clinker calcined using rice husk as crude fuel, including raw material and fuel, in which:
The component and its mass fraction that raw material includes are as follows:
79.8~85.7 parts of lime stone,
1.9~3.1 parts of sandstone,
4.7~3.9 parts of gangue,
5.3~5.5 parts of iron ore mine,
8.3~1.8 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
4.5~8.1 parts of coal,
9.0~1.8 parts of rice husk.
A kind of clinker calcined using rice husk as crude fuel, the component and its mass fraction that raw material includes are as follows:
85.7 parts of lime stone,
3.1 parts of sandstone,
3.9 parts of gangue,
5.5 parts of iron ore mine,
1.8 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
8.1 parts of coal,
1.8 parts of rice husk.
A kind of clinker calcined using rice husk as crude fuel, the component and its mass fraction that raw material includes are as follows:
82.6 parts of lime stone,
2.6 parts of sandstone,
4.3 parts of gangue,
5.4 parts of iron ore mine,
5.1 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
6.3 parts of coal,
5.4 parts of rice husk.
A kind of clinker calcined using rice husk as crude fuel, the component and its mass fraction that raw material includes are as follows:
79.8 parts of lime stone,
1.9 parts of sandstone,
4.7 parts of gangue,
5.3 parts of iron ore mine,
8.3 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
4.5 parts of coal, 9.0 parts of rice husk.
The clinker calcined using rice husk as crude fuel, method for calcinating the following steps are included:
(1) prepared by raw material: pressing composition proportion, takes lime stone, sandstone, gangue and iron ore mine, be crushed respectively, powder
It after mill, homogenizing, is uniformly mixed, forms raw material powder;
(2) it preheats: raw material powder is preheated, form raw material after preheating;Wherein, preheating temperature is 150~700 DEG C, in advance
The hot time is 1~3min;
(3) it decomposes: raw material after preheating is decomposed, form raw material after decomposing;Wherein, decomposition temperature is 820~900
DEG C, the resolving time is 4~10s;
(4) rice husk is added: according to the ratio, to decomposition after rice husk is added in raw material;
(5) pulverized coal preparation: pressing composition proportion, take coal, after its grinding, is homogenized processing, forms coal dust;
(6) clinker burning: coal dust is added after decomposing in raw material, is calcined, generates calcination of chamotte;Wherein, calcining temperature
Degree is 1350~1450 DEG C, and calcination time is 8~15min;
(7) clinker cooling: calcination of chamotte is through being cooled into the clinker calcined using rice husk as crude fuel.
In the step (1), lime stone, sandstone, gangue and iron ore mine cross 0.08mm square hole screen sieve after grinding
Remaining 7~9%, crosses 0.02mm and tail over≤1.0%.
Clinker and 3% gypsum below are obtained into cement by grinding after ingredient mixing.
The method for calcinating of the clinker calcined using rice husk as crude fuel, the equipment used is dry-process cement rotary kiln.
It include dore furnace in the dry-process cement rotary kiln.
In the step (4), rice husk is raw rice husk and fuel rice husk, rice husk adding manner are as follows: by air blower, pass through
Fire door is decomposed to be blown into.
In the step (4), rice husk is the rice rice husk that is produced from Liaoning Province, rice husk Lower heat value 10850kJ/kg, rice husk
Ash content 80%.
In the step (5), coal is bituminous coal, coal Lower heat value 21700kJ/kg, ash content of coal 19%, coal mistake after grinding
The side 0.08mm tails over≤12%.
In the step (7), using the rate value for the clinker that rice husk is calcined as crude fuel are as follows:
KH=0.89~0.91
SM=2.69~2.71
IM=1.49~1.51
The method for calcinating of the cement of the present invention calcined using rice husk as crude fuel, using the production work in existing cement plant
Skill and equipment, by each component press quality proportioning, by prior art process feeding, with prior art the difference is that: rice husk
It is added decomposing fire door, clinker that meet national standards can be calcined out, cement can then be produced by adding gypsum.
Beneficial effects of the present invention:
(1) for the present invention using rice husk as a kind of crude fuel of production Portland clinker, substitution part of clay matter is former
Material and part coal calcination clinker, can not only reduce the usage amount of mineral resources, but also can reduce the rice directly burned
Shell amount, to economize on resources, reduce CO2Discharge, play the role of protect environment.
(2) rice husk is used for manufacture of cement, is different from generating the secondary wastes objects such as flying dust for generating electricity, but is directly becoming water
Mud clinker, primary environmental protection is in place.
(3) rice husk is agricultural wastes, and cost is mainly transportation cost.Rice husk is as fuel without being homogenized, being not required to powder
Mill, can direct feeding.It is used for clinker production using rice husk as crude fuel, there are significant economic results in society.
(4) it in calcination process, is added and both as raw material or is used as the rice husk of fuel, carry out burning clinker of cement, rice husk work
The broken of conventional raw material or fuel, grinding, homogenizing are needed not move through for crude fuel and in advance the process that thermally decomposes can reach production
It is required that simple flow, save the cost.
Detailed description of the invention:
Fig. 1 is the present invention using rice husk as the method for calcinating process flow chart of crude fuel calcination of cement clinker.
Specific embodiment:
Below with reference to embodiment, the present invention is described in further detail.
Following example 1~the lime stone of 3 uses, sandstone, gangue, the chemical component of iron ore mine are as shown in table 1;
Coal is bituminous coal, coal Lower heat value 21700kJ/kg, ash content of coal 19%;
Rice husk is the rice rice husk that is produced from Liaoning Province, rice husk Lower heat value 10850kJ/kg, rice husk ash 80%, rice husk ingredient
As shown in table 2;
The equipment that Examples 1 to 3 uses includes dore furnace in dry-process cement rotary kiln for dry-process cement rotary kiln;
Examples 1 to 3 using rice husk as the method for calcinating process flow chart of crude fuel calcination of cement clinker, as shown in Figure 1.
Embodiment 1
A kind of clinker calcined using rice husk as crude fuel, including raw material and fuel, in which: component that raw material includes and
Its mass fraction are as follows:
85.7 parts of lime stone,
3.1 parts of sandstone,
3.9 parts of gangue,
5.5 parts of iron ore mine,
1.8 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
8.1 parts of coal, 1.8 parts of rice husk.
The method for calcinating of the clinker calcined using rice husk as crude fuel the following steps are included:
(1) prepared by raw material: pressing composition proportion, takes lime stone, sandstone, gangue and iron ore mine, be crushed respectively, powder
0.08mm square hole screen is crossed after mill and tails over 8%, is crossed 0.02mm and is tailed over≤1.0%, is homogenized processing later, and be uniformly mixed,
Form raw material powder;
(2) it preheats: raw material powder is preheated, preheating temperature is 500 DEG C, preheating time 2min, forms original after preheating
Material;
(3) it decomposes: raw material after preheating is decomposed, decomposition temperature is 850 DEG C, resolving time 7s, is formed after decomposing
Raw material;
(4) pulverized coal preparation: pressing composition proportion, take coal, its grinding is tailed over≤12% to the side 0.08mm is crossed, is carried out later
Homogenizing processing, forms coal dust;
(5) rice husk is added: according to the ratio, by air blower, being blown by the decomposition fire door of dry-process cement rotary kiln into raw material after decomposition
Enter raw rice husk and fuel rice husk;
(6) clinker burning: coal dust is added after decomposing in raw material, is calcined, calcination temperature is 1400 DEG C, calcination time
For 12min, calcination of chamotte is generated;
(7) clinker cooling: calcination of chamotte through being cooled into the clinker calcined using rice husk as crude fuel, clinker
Rate value are as follows: KH=0.89, SM=2.7, IM=1.49.
The clinker the performance test results of the present embodiment calcining are as shown in table 3.
Embodiment 2
A kind of clinker calcined using rice husk as crude fuel, including raw material and fuel, in which: component that raw material includes and
Its mass fraction are as follows:
82.6 parts of lime stone,
2.6 parts of sandstone,
4.3 parts of gangue,
5.4 parts of iron ore mine,
5.1 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
6.3 parts of coal, 5.4 parts of rice husk.
The method for calcinating of the clinker calcined using rice husk as crude fuel the following steps are included:
(1) prepared by raw material: pressing composition proportion, takes lime stone, sandstone, gangue and iron ore mine, be crushed respectively, powder
0.08mm square hole screen is crossed after mill and tails over 7%, is crossed 0.02mm and is tailed over≤1.0%, is homogenized processing later, and be uniformly mixed,
Form raw material powder;
(2) it preheats: raw material powder is preheated, preheating temperature is 150 DEG C, preheating time 3min, forms original after preheating
Material;
(3) it decomposes: raw material after preheating is decomposed, decomposition temperature is 820 DEG C, resolving time 10s, is formed after decomposing
Raw material;
(4) pulverized coal preparation: pressing composition proportion, take coal, its grinding is tailed over≤12% to the side 0.08mm is crossed, is carried out later
Homogenizing processing, forms coal dust;
(5) rice husk is added: according to the ratio, by air blower, being blown by the decomposition fire door of dry-process cement rotary kiln into raw material after decomposition
Enter raw rice husk and fuel rice husk;
(6) clinker burning: coal dust is added after decomposing in raw material, is calcined, calcination temperature is 1350 DEG C, calcination time
For 15min, calcination of chamotte is generated;
(7) clinker cooling: calcination of chamotte through being cooled into the clinker calcined using rice husk as crude fuel, clinker
Rate value are as follows: KH=0.9, SM=2.69, IM=1.51.
The clinker the performance test results of the present embodiment calcining are as shown in table 4.
Embodiment 3
A kind of clinker calcined using rice husk as crude fuel, including raw material and fuel, in which: component that raw material includes and
Its mass fraction are as follows:
79.8 parts of lime stone,
1.9 parts of sandstone,
4.7 parts of gangue,
5.3 parts of iron ore mine,
8.3 parts of rice husk;
The component and its mass fraction that fuel includes are as follows:
4.5 parts of coal, 9.0 parts of rice husk.
The method for calcinating of the clinker calcined using rice husk as crude fuel the following steps are included:
(1) prepared by raw material: pressing composition proportion, takes lime stone, sandstone, gangue and iron ore mine, be crushed respectively, powder
0.08mm square hole screen is crossed after mill and tails over 9%, is crossed 0.02mm and is tailed over≤1.0%, is homogenized processing later, and be uniformly mixed,
Form raw material powder;
(2) it preheats: raw material powder is preheated, preheating temperature is 700 DEG C, preheating time 1min, forms original after preheating
Material;
(3) it decomposes: raw material after preheating is decomposed, decomposition temperature is 900 DEG C, resolving time 4s, is formed after decomposing
Raw material;
(4) pulverized coal preparation: pressing composition proportion, take coal, its grinding is tailed over≤12% to the side 0.08mm is crossed, is carried out later
Homogenizing processing, forms coal dust;
(5) rice husk is added: according to the ratio, by air blower, being blown by the decomposition fire door of dry-process cement rotary kiln into raw material after decomposition
Enter raw rice husk and fuel rice husk;
(6) clinker burning: coal dust is added after decomposing in raw material, is calcined, calcination temperature is 1450 DEG C, calcination time
For 8min, calcination of chamotte is generated;
(7) clinker cooling: calcination of chamotte through being cooled into the clinker calcined using rice husk as crude fuel, clinker
Rate value are as follows: KH=0.91, SM=2.71, IM=1.5.
The clinker the performance test results of the present embodiment calcining are as shown in table 5.
The chemical component of 1 lime stone of table, sandstone, gangue, iron ore mine
Project | Loss on ignition | SiO2 | Al2O3 | Fe2O3 | CaO | MgO | K2O | Na2O | SO3 | Cl- | Other |
Lime stone | 39.36 | 5.63 | 1.89 | 0.95 | 47.36 | 2.51 | 0.50 | 0.07 | 0.200 | 0.003 | 1.527 |
Sandstone | 1.18 | 90.00 | 3.56 | 1.65 | 1.60 | 0.78 | 0.42 | 0.36 | 0.350 | 0.002 | 0.098 |
Gangue | 24.03 | 41.25 | 21.52 | 8.10 | 1.16 | 1.07 | 0.63 | 0.39 | 0.200 | 0.006 | 1.644 |
Iron ore mine | 3.57 | 66.36 | 4.36 | 13.32 | 5.83 | 4.42 | 0.78 | 0.60 | 0.150 | 0.015 | 0.595 |
2 rice husk component list (weight %) of table
Loss on ignition | SiO2 | Al2O3 | Fe2O3 | CaO | Other |
80.2 | 16.5 | 0.4 | 0.1 | 0.2 | 2.6 |
The clinker the performance test results that 3 embodiment 1 of table is calcined using rice husk as crude fuel
The clinker the performance test results that 4 embodiment 2 of table is calcined using rice husk as crude fuel
The clinker the performance test results that 5 embodiment 3 of table is calcined using rice husk as crude fuel
Note: in table 3, table 4 and table 5:
1. national standard are as follows: " National Standard of the People's Republic of China GB/T 21372-2008 Portland clinker ";
2.C3S is tricalcium silicate, C2S is dicalcium silicate.
Claims (7)
1. a kind of method for calcinating for the clinker calcined using rice husk as crude fuel, which is characterized in that the method for calcinating is adopted
Equipment is dry-process cement rotary kiln, includes dore furnace in the dry-process cement rotary kiln, specifically includes the following steps:
(1) prepared by raw material: the clinker calcined using rice husk as crude fuel, including raw material and fuel, the raw material
Including component and its mass fraction are as follows: 79.8~85.7 parts of lime stone, 1.9~3.1 parts of sandstone, 4.7~3.9 parts of gangue,
5.3~5.5 parts of iron ore mine, 8.3~1.8 parts of rice husk;The component and its mass fraction that the fuel includes are as follows: coal 4.5~
8.1 parts, 9.0~1.8 parts of rice husk;By composition proportion, lime stone, sandstone, gangue and iron ore mine are taken, be crushed respectively,
It after grinding, homogenizing, is uniformly mixed, forms raw material powder;
(2) it preheats: raw material powder is preheated, form raw material after preheating;Wherein, preheating temperature is 150~700 DEG C, when preheating
Between be 1~3min;
(3) it decomposes: raw material after preheating is decomposed, form raw material after decomposing;Wherein, decomposition temperature is 820~900 DEG C, point
The solution time is 4~10s;
(4) rice husk is added: according to the ratio, to decomposition after rice husk is added in raw material;Wherein, the rice husk is raw rice husk and fuel
Rice husk, rice husk Lower heat value 10850kJ/kg, rice husk ash 80%, the rice husk adding manner are as follows: by air blower, by dividing
Solution fire door is blown into;
(5) pulverized coal preparation: pressing composition proportion, take coal, after its grinding, is homogenized processing, forms coal dust;
(6) clinker burning: coal dust is added after decomposing in raw material, is calcined, generates calcination of chamotte;Wherein, calcination temperature is
1350~1450 DEG C, calcination time is 8~15min;
(7) clinker cooling: calcination of chamotte is through being cooled into the clinker calcined using rice husk as crude fuel.
2. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (1), component and its mass fraction that raw material includes are as follows:
85.7 parts of lime stone,
3.1 parts of sandstone,
3.9 parts of gangue,
5.5 parts of iron ore mine,
1.8 parts of rice husk;
The component and its mass fraction that the fuel includes are as follows:
8.1 parts of coal,
1.8 parts of rice husk.
3. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (1), component and its mass fraction that raw material includes are as follows:
82.6 parts of lime stone,
2.6 parts of sandstone,
4.3 parts of gangue,
5.4 parts of iron ore mine,
5.1 parts of rice husk;
The component and its mass fraction that the fuel includes are as follows:
6.3 parts of coal,
5.4 parts of rice husk.
4. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (1), component and its mass fraction that raw material includes are as follows:
79.8 parts of lime stone,
1.9 parts of sandstone,
4.7 parts of gangue,
5.3 parts of iron ore mine,
8.3 parts of rice husk;
The component and its mass fraction that the fuel includes are as follows:
4.5 parts of coal,
9.0 parts of rice husk.
5. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (1), lime stone, sandstone, gangue and iron ore mine cross 0.08mm square hole screen after grinding and tail over 7~9%, mistake
0.02mm tails over≤1.0%.
6. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (5), coal is bituminous coal, and coal Lower heat value 21700kJ/kg, ash content of coal 19%, coal after grinding sieve excessively by the side 0.08mm
Tail over≤12%.
7. the method for calcinating of the clinker according to claim 1 calcined using rice husk as crude fuel, which is characterized in that institute
In the step of stating (7), using the rate value for the clinker that rice husk is calcined as crude fuel are as follows: KH=0.89~0.91;SM=2.69~
2.71;IM=1.49~1.51.
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CN1285329A (en) * | 2000-10-09 | 2001-02-28 | 内蒙古蒙西高新材料股份有限公司 | High performance compound silicate cement |
CN105819717B (en) * | 2016-03-12 | 2017-08-29 | 乔光明 | A kind of production method of clinker |
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Effective date of registration: 20191227 Address after: Wofosi Xiang Da Xie Yang Cun, Zhuolu County, Zhangjiakou City, 075000 Hebei Province Patentee after: Zhuolu Jinyu Cement Co., Ltd Address before: Hunnan Hunnan Road Shenyang city Liaoning province 110168 No. 9 Patentee before: Shenyang Building Univ. |