CN106745471A - A kind of photocatalysis pollution of river thing decomposition apparatus - Google Patents

A kind of photocatalysis pollution of river thing decomposition apparatus Download PDF

Info

Publication number
CN106745471A
CN106745471A CN201611224856.2A CN201611224856A CN106745471A CN 106745471 A CN106745471 A CN 106745471A CN 201611224856 A CN201611224856 A CN 201611224856A CN 106745471 A CN106745471 A CN 106745471A
Authority
CN
China
Prior art keywords
convex lens
horizontal frame
water surface
parts
fibrous braid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201611224856.2A
Other languages
Chinese (zh)
Other versions
CN106745471B (en
Inventor
冯婷
马建锋
赵文昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou University
Original Assignee
Changzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou University filed Critical Changzhou University
Priority to CN201611224856.2A priority Critical patent/CN106745471B/en
Publication of CN106745471A publication Critical patent/CN106745471A/en
Application granted granted Critical
Publication of CN106745471B publication Critical patent/CN106745471B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

Landscapes

  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Physical Water Treatments (AREA)

Abstract

The present invention discloses a kind of photocatalysis pollution of river thing decomposition apparatus, including:One horizontal frame, it is fixed on more than the water surface;Fibrous braid, it is covered in the horizontal frame surface, and the side of the fibrous braid is hung down from horizontal frame edge, is in contact with the water surface;Opposite side corresponding thereto hangs down from horizontal pane edge, near the water surface without the contact water surface;The fibrous braid surface is also loaded the catalyst with visible light activity;Convex lens, it supports the top for being fixed on horizontal frame by support;The convex lens are made up of two parts of radial symmetric, and described two parts can form a thin film system for constant flow by without any power, so as to obtain more preferable catalytic effect, and need not pass through additional means separating catalyst.Hinge is rotationally linked and is integrated.

Description

A kind of photocatalysis pollution of river thing decomposition apparatus
Technical field
The present invention relates to a kind of photocatalysis pollution of river thing decomposition apparatus, belong to sewage disposal technology neck in environmental protection Domain.
Background technology
Traditional method for treating water efficiency is low, high cost, there are secondary pollution problems, and waste water control always cannot be well Solution.The development and application of nanometer technology are likely to thoroughly solve this problem., A.Fujishima and K.Honda in 1972 In n-type semiconductor TiO2The photoelectrocatalysis decomposition of water, TiO are found that on electrode2Oxidation activity is higher, and chemical stability is good, Harmless to the human body, low cost is pollution-free, has a wide range of application, thus is most paid attention to, and is that current most widely used nanometer light is urged Change material, be also the environmental type catalyst for most developing future.
Research shows, nano-TiO2Various toxic compounds can be processed, can be by the hydro carbons in water, halogenated hydrocarbons, acid, surface Soon complete oxidation is CO for activating agent, dyestuff, itrogenous organic substance, organophosphorus insecticide, timber preservative and fuel oil etc.2、 H2The innocuous substances such as O.But up to the present nano-photo catalytic TiO2Technology is not used widely in terms of wastewater treatment yet, main If because nano particle separates difficulty, without simply applicable processing equipment.
Loaded in carrier surface by nano particle, can solve the problems, such as that particle is separated.But it is loaded with nano particle When carrier is soaked in water, the solution that exciting light must be transmitted through thicker (often more than several centimeters) can just be irradiated to catalysis In agent.And in fact, either in ultraviolet region or visible region, organic solution (especially colored organic wastewater) is all Different degrees of light absorbs are had, this will certainly cause the different degrees of light loss of exciting light, so as to get up to catalyst surface Luminous intensity declines, so that the yield in light induced electron and hole declines, the final degradation efficiency for causing pollutant is reduced.
Patent CN 102515303A disclose a kind of device for photocatalytic abatement of organic pollution of riverway, can obtain preferably Water treatment efficiency, but need the flowing of electric power and water.Equally, several patents such as CN104609571B, CN104609572B are disclosed Method be all that the flowing for needing river can just obtain photocatalysis effect.If the fluid ability of river is not enough to pushing meanss Rotate, then treatment facility may be made to fail.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, a kind of photocatalysis pollution of river thing decomposition apparatus are proposed, The device is simple, non-power consumption, only utilizes sun light action, you can reach preferable treatment effect.
The invention discloses a kind of photocatalysis pollution of river thing decomposition apparatus, including:
Horizontal frame, it is fixed on more than the water surface;
Fibrous braid, it is covered in the horizontal frame surface, and the fibrous braid side from horizontal frame Edge hangs down, and is in contact with the water surface;Opposite side corresponding thereto hangs down from horizontal pane edge, near the water surface without contact water Face;The fibrous braid surface is also loaded the catalyst with visible light activity;
Convex lens, it supports the top for being fixed on horizontal frame by support;The convex lens are by two of radial symmetric Divide and constitute, described two parts are rotationally linked by hinge and are integrated.
In preferred technical scheme, the two ends of described convex lens are provided with temperature sensing spring, the two of the described convex lens of control Part is rotated by axle center of hinge;When temperature sensing spring expanded by heating, two parts of convex lens are integrally formed, it is combined into complete Convex lens.
The beneficial effects of the invention are as follows:Using the capillarity of fibrous braid, water is connect from fibrous braid and water Tactile one end capillary is drunk up, and korneforos is instilled from the other end, and relatively thin liquid film is formed on fibrous braid surface, without any dynamic Power can form a thin film system for constant flow, so as to obtain more preferable catalytic effect, and need not pass through additional means Separating catalyst.
The convex lens of top can be with optically focused, and when the morning sun rises, temperature is relatively low, sun oblique fire, and now convex The half of lens can just to the sun, and as the sun continues to rise, temperature is raised, and temperature sensing spring pushes convex lens two parts to water Flat, large area receives to shine upon and focus the light into catalyst surface, improves catalytic efficiency.
Experiment is proved:For the concentration of II containing gold orange in the waste water of 25mg/L, the gold after 12h is persistently processed by the equipment The clearance of orange II is up to 97.2%.
Brief description of the drawings
Fig. 1 is structural representation of the invention
Specific embodiment
Reference picture, an including horizontal frame 1 is fixed on more than the water surface, and the surface of horizontal frame 1 is coated with fibrous braid 2, the sagging contact water surface in the one end of fibrous braid 2, the other end it is sagging close to the water surface without contact the water surface, the surface of fibrous braid 2 It is loaded with the catalyst-silver phosphate with visible light activity.
One convex lens 3 is radially divided into symmetrical two parts by its center of circle, and two parts of convex lens 3 pass through side hinge 4 links are integrated, but can be with hinge 4 as axis rotation;Rotation of the two parts of convex lens 3 with hinge 4 as axle center is by two ends It is individually fixed in the two-part temperature sensing spring 5 of convex lens 3 to control, when temperature sensing spring 5 is heated, then expands, can be by convex lens Two parts are combined into complete convex lens;Two parts of convex lens 3 support 6 tops for being fixed on horizontal frame 1 by support.Operation When device is fixed on river course surface, organic matter degradation in urban river water can be completed under the irradiation of sunshine.

Claims (1)

1. a kind of photocatalysis pollution of river thing decomposition apparatus, it is characterized in that including:
Horizontal frame, it is fixed on more than the water surface;
Fibrous braid, it is covered in the horizontal frame surface, and the fibrous braid side from horizontal frame edge Hang down, be in contact with the water surface;Opposite side corresponding thereto hangs down from horizontal pane edge, near the water surface without the contact water surface;Institute State fibrous braid surface and be also loaded the catalyst with visible light activity;
Convex lens, it supports the top for being fixed on horizontal frame by support;The convex lens by radial symmetric two parts structure Into described two parts are rotationally linked by hinge and are integrated.
In preferred technical scheme, the two ends of described convex lens are provided with temperature sensing spring, two parts of the described convex lens of control Rotated by axle center of hinge;When temperature sensing spring expanded by heating, two parts of convex lens are integrally formed, complete convex lens is combined into Mirror.
CN201611224856.2A 2016-12-27 2016-12-27 Photocatalysis river pollutant degradation device Active CN106745471B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611224856.2A CN106745471B (en) 2016-12-27 2016-12-27 Photocatalysis river pollutant degradation device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611224856.2A CN106745471B (en) 2016-12-27 2016-12-27 Photocatalysis river pollutant degradation device

Publications (2)

Publication Number Publication Date
CN106745471A true CN106745471A (en) 2017-05-31
CN106745471B CN106745471B (en) 2020-02-14

Family

ID=58920963

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611224856.2A Active CN106745471B (en) 2016-12-27 2016-12-27 Photocatalysis river pollutant degradation device

Country Status (1)

Country Link
CN (1) CN106745471B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000279820A (en) * 1999-03-29 2000-10-10 Matsushita Electric Ind Co Ltd Photocatalyst
CN101941745A (en) * 2010-09-09 2011-01-12 河海大学 Sunlight intensity stabilizing device for experiments
US20130008775A1 (en) * 2011-07-05 2013-01-10 Osman Ahmed Photocatalytic Panel and System for Recovering Output Products Thereof
CN104671458A (en) * 2015-01-26 2015-06-03 常州大学 River pollutant removal device
CN105776410A (en) * 2016-03-28 2016-07-20 朱连文 Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000279820A (en) * 1999-03-29 2000-10-10 Matsushita Electric Ind Co Ltd Photocatalyst
CN101941745A (en) * 2010-09-09 2011-01-12 河海大学 Sunlight intensity stabilizing device for experiments
US20130008775A1 (en) * 2011-07-05 2013-01-10 Osman Ahmed Photocatalytic Panel and System for Recovering Output Products Thereof
CN104671458A (en) * 2015-01-26 2015-06-03 常州大学 River pollutant removal device
CN105776410A (en) * 2016-03-28 2016-07-20 朱连文 Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof

Also Published As

Publication number Publication date
CN106745471B (en) 2020-02-14

Similar Documents

Publication Publication Date Title
Khan et al. Heterogeneous photodegradation of industrial dyes: An insight to different mechanisms and rate affecting parameters
Akyol et al. Photocatalytic degradation of Remazol Red F3B using ZnO catalyst
Saien et al. Organic pollutants removal from petroleum refinery wastewater with nanotitania photocatalyst and UV light emission
Gar Alalm et al. Solar photocatalytic degradation of phenol by TiO2/AC prepared by temperature impregnation method
Poulios et al. Photocatalytic oxidation of Auramine O in the presence of semiconducting oxides
Ochiai et al. Photoelectrochemical properties of TiO2 photocatalyst and its applications for environmental purification
Tanveer et al. Solar assisted photo degradation of wastewater by compound parabolic collectors: Review of design and operational parameters
Daneshvar et al. Immobilization of TiO2 nanopowder on glass beads for the photocatalytic decolorization of an azo dye CI Direct Red 23
Kuo et al. Solar photocatalytic decolorization of dyes in solution with TiO2 film
Cowie et al. Solar disinfection (SODIS) provides a much underexploited opportunity for researchers in photocatalytic water treatment (PWT)
Hassaan et al. Principles of photocatalysts and their different applications: a review
Singh et al. Preliminary study on optimization of pH, oxidant and catalyst dose for high COD content: solar parabolic trough collector
Akyol et al. The degradation of an azo dye in a batch slurry photocatalytic reactor
Khezrianjoo et al. Photocatalytic degradation of acid yellow 36 using zinc oxide photocatalyst in aqueous media
Rengifo-Herrera et al. Why five decades of massive research on heterogeneous photocatalysis, especially on TiO2, has not yet driven to water disinfection and detoxification applications? Critical review of drawbacks and challenges
Joseph et al. Photocatalytic degradation of cationic dye simulated wastewater using four radiation sources, UVA, UVB, UVC and solar lamp of identical power output
Pattanaik et al. TiO2 photocatalysis: progress from fundamentals to modification technology
Monteagudo et al. Fresnel lens to concentrate solar energy for the photocatalytic decoloration and mineralization of orange II in aqueous solution
CN106673119A (en) Reinforced photocatalytic pollutant degradation device
Borges et al. Photocatalysis as a potential tertiary treatment of urban wastewater: new photocatalytic materials
Singh et al. Performance of advanced photocatalytic detoxification of municipal wastewater under solar radiation-A mini review
CN103771638B (en) A kind of photocatalysis method with ultrasonic atomizatio enhanced sewage treatment effect
Behnajady et al. Horizontally rotating disc recirculated photoreactor with TiO2-P25 nanoparticles immobilized onto a HDPE plate for photocatalytic removal of p-nitrophenol
Lin et al. Photocatalytic degradation of morphine, methamphetamine, and ketamine by illuminated TiO 2 and ZnO
Chakrabarti Solar photocatalysis for environmental remediation

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant